KR910019965A - 오르토-치환된 시클로프로판카르복실산의 벤질 에스테르 - Google Patents
오르토-치환된 시클로프로판카르복실산의 벤질 에스테르 Download PDFInfo
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- KR910019965A KR910019965A KR1019910009015A KR910009015A KR910019965A KR 910019965 A KR910019965 A KR 910019965A KR 1019910009015 A KR1019910009015 A KR 1019910009015A KR 910009015 A KR910009015 A KR 910009015A KR 910019965 A KR910019965 A KR 910019965A
- Authority
- KR
- South Korea
- Prior art keywords
- alkyl
- substituted
- ortho
- phenyl
- cyclopropane
- Prior art date
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- YMGUBTXCNDTFJI-UHFFFAOYSA-N cyclopropanecarboxylic acid Chemical class OC(=O)C1CC1 YMGUBTXCNDTFJI-UHFFFAOYSA-N 0.000 title claims 10
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 title claims 4
- -1 C 2 -C 8 -alkyl Chemical group 0.000 claims 26
- 125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 claims 5
- 229910052736 halogen Inorganic materials 0.000 claims 4
- 150000002367 halogens Chemical class 0.000 claims 4
- 125000001424 substituent group Chemical group 0.000 claims 4
- 125000003118 aryl group Chemical group 0.000 claims 3
- 125000004093 cyano group Chemical group *C#N 0.000 claims 3
- 125000005843 halogen group Chemical group 0.000 claims 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 3
- 229910052757 nitrogen Inorganic materials 0.000 claims 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 3
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 3
- SNOOUWRIMMFWNE-UHFFFAOYSA-M sodium;6-[(3,4,5-trimethoxybenzoyl)amino]hexanoate Chemical compound [Na+].COC1=CC(C(=O)NCCCCCC([O-])=O)=CC(OC)=C1OC SNOOUWRIMMFWNE-UHFFFAOYSA-M 0.000 claims 3
- YCTWGXIFDPOXPX-UHFFFAOYSA-N 1,2,3-trimethylsiline Chemical compound CC1=CC=C[Si](C)=C1C YCTWGXIFDPOXPX-UHFFFAOYSA-N 0.000 claims 2
- 125000006276 2-bromophenyl group Chemical group [H]C1=C([H])C(Br)=C(*)C([H])=C1[H] 0.000 claims 2
- 125000006275 3-bromophenyl group Chemical group [H]C1=C([H])C(Br)=C([H])C(*)=C1[H] 0.000 claims 2
- 125000004199 4-trifluoromethylphenyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)C(F)(F)F 0.000 claims 2
- 230000000844 anti-bacterial effect Effects 0.000 claims 2
- 208000015181 infectious disease Diseases 0.000 claims 2
- 230000002458 infectious effect Effects 0.000 claims 2
- 238000000034 method Methods 0.000 claims 2
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 2
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 claims 2
- 125000004215 2,4-difluorophenyl group Chemical group [H]C1=C([H])C(*)=C(F)C([H])=C1F 0.000 claims 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims 1
- 241000233866 Fungi Species 0.000 claims 1
- 241000607479 Yersinia pestis Species 0.000 claims 1
- 239000003899 bactericide agent Substances 0.000 claims 1
- 125000001207 fluorophenyl group Chemical group 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- 230000000361 pesticidal effect Effects 0.000 claims 1
- 239000000575 pesticide Substances 0.000 claims 1
- 239000007787 solid Substances 0.000 claims 1
- 230000001954 sterilising effect Effects 0.000 claims 1
- 238000004659 sterilization and disinfection Methods 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C251/00—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
- C07C251/32—Oximes
- C07C251/34—Oximes with oxygen atoms of oxyimino groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/74—Esters of carboxylic acids having an esterified carboxyl group bound to a carbon atom of a ring other than a six-membered aromatic ring
- C07C69/743—Esters of carboxylic acids having an esterified carboxyl group bound to a carbon atom of a ring other than a six-membered aromatic ring of acids with a three-membered ring and with unsaturation outside the ring
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
- A01N37/50—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids the nitrogen atom being doubly bound to the carbon skeleton
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C251/00—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
- C07C251/32—Oximes
- C07C251/34—Oximes with oxygen atoms of oxyimino groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals
- C07C251/48—Oximes with oxygen atoms of oxyimino groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals with the carbon atom of at least one of the oxyimino groups bound to a carbon atom of a six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/74—Esters of carboxylic acids having an esterified carboxyl group bound to a carbon atom of a ring other than a six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/02—Systems containing only non-condensed rings with a three-membered ring
Landscapes
- Organic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Dentistry (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Plant Pathology (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (9)
- 하기 일반식(Ⅰ)의 오르토-치환된 시클로프로판카르복실산의 벤질 에스테르:상기식에서, X는 질소 또는 =CH-이고 A는 하기의 시클로프로판 라디칼들 중 하나이다:상기식에서, R1은 시아노, C2-C8-알킬, 트르플루오로메틸, C3-C|8-알켄일, 트리메틸실린, C1-C4-알콕시카르보닐, 페닐-C1-C8또는 페닐-C3-C8-알켄일이고, 여기에서 각각의 방향족부분은 C1-C8-알킬, 부분적으로 또는 완전히 할로겐화된 C1-C|8-알킬 또는 C1-C8-알콕시, 에틸시페닐, 2-브로모페닐, 3-브로모페닐, 2-트리플루오로메틸페닐, 4-트리플루오로메틸페닐, 2,4-디플루오로메틸페닐, 2,6-디플루오로메틸페닐, 2-플루오로-6-클로로페닐, 2,4-디메틸페닐, 2,6-디메틸페닐 또는 2,3,6-트리클로로페닐 중 3개 이하의 치환기, 또는 1-5개의 할로겐원자로 더 치환될 수 있고, R3는 C1-C8-알킬 부분적으로 또는 완전히 할로겐화된 C1-C8-알킬 또는 C1-C8-알콕시 중 3개 이하의 치환기 또는 1-5개의 할로겐 원자로 치환될 수 있는 페닐이고 R4는 메틸 또는 할로겐이고, Hal은 할로겐이며 단, R1이 트리플루오로메틸페닐 또는 트리메틸실릴인 경우 X는 =CH-이다.
- 하기 일반식(Ⅰa)의 오르토-치환된 시클로프로판카르복실산의 벤질 에스테르:상기식에서, X는 질소 또는 =CH- 이고, R1′시아노 C2-C4-알킬,트리메틸실릴, C3-또는C4-알켄일, 트리메틸실릴, C1또는 C2-알콕시카르보닐, 페닐- C1-C4-알킬 또는 페닐-C3또는 -C4-알켄일이며, 여기에서 각각의 방향족부분은 할로겐, 또는 메틸, 2,4-디플루오로페닐, 2,6-디플루오로페닐, 2-플루오로-6-클로로페닐 또는 2,3,6-트리클로로페닐에 의해 더 1치환될 수 있고 단, R1이 트리메틸실질 또는 트루플루오로메틸인 경우 X=CH- 이어야 한다.
- 고체 또는 액체 및 하기 일반식(Ⅰ)의 오르토-치환된 시클로프로판 카르복실산의 벤질에스테를 함유하는 살균제.상기식에서, X는 질소 또는 =CH- 이고, A는 하기의 시클로프로판 라디칼들 중 하나이다.상기식에서, R1은 시아노, C2-C8-알킬, 트르플루오로메틸, C3-C8-알켄일, 트리메틸실린, C1-C4-알콕시카르보닐, 페닐-C1-C8또는 페닐-C3-C8-알켄일이고, 여기에서 각각의 방향족부분은 C1-C8-알킬, 부분적으로 또는 완전히 할로겐화된 C1-C8-알킬 또는 C1-C8-알콕시, 에틸시페닐, 2-브로모페닐, 3-브로모페닐, 2-트리플루오로메틸페닐, 4-트리플루오로메틸페닐, 2,4-디플루오로메틸페닐, 2,6-디플루오로메틸페닐, 2-플루오로-6-클로로페닐, 2,4-디메틸페닐, 2,6-디메틸페닐 또는 2,3,6-트리클로로페닐 중 3개 이하의 치환기, 또는 1-5개의 할로겐원자로 더 치환될 수 있고, R3는 C1-C8-알킬 부분적으로 또는 완전히 할로겐화된 C1-C8-알킬 또는 C1-C8-알콕시 중 3개 이하의 치환기 또는 1-5개의 할로겐 원자로 치환될 수 있는 페닐이고 R4는 메틸 또는 할로겐이고, Hal은 할로겐이며 단, R1이 트리플루오로메틸페닐 또는 트리메틸실릴인 경우 X는 =CH-이다.
- 비활성 담체 및 하나 이상의 제1항에 따른 오르토- 치환된 시클로프로판-카르복실산의 벤질에스테르(Ⅰ)을 함유하는 살충제.
- 살균적양의 제1항에 따르는 오르토- 치환된 시클로프로판-카르복실산의 벤질에스테르(Ⅰ)를 균류, 균감염의 가능성이 있는 식물, 이들의 서식지 또는 균감염 가능성이 있는 식물의 종자에 작용시키는 살균방법.
- 살균적양의 제1항에 따르는 오르토- 치환된 시클로프로판-카르복실산의 벤질에스테르(Ⅰ)를 해충 또는 이들의 서식지에 작용시키는 살충방법.
- 제1항에 있어서 R1이 n-프로필이고 X가 CH인것을 특징으로 하는 일반식(Ⅰ)의 오르토- 치환된 시클로프로판-카르복실산의 벤질에스테르
- 제1항에 있어서 R1이 n-프로필이고 X가 n인것을 특징으로 하는 일반식(Ⅰ)의 오르토- 치환된 시클로프로판-카르복실산의 벤질에스테르
- 제1항에 있어서 R1이 알릴이고 X가 CH인것을 특징으로 하는 일반식(Ⅰ)의 오르토- 치환된 시클로프로판-카르복실산의 벤질에스테르※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEP4017488.3 | 1990-05-31 | ||
| DE4017488A DE4017488A1 (de) | 1990-05-31 | 1990-05-31 | Ortho-substituierte benzylester von cyclopropancarbonsaeuren |
| DE4024094A DE4024094A1 (de) | 1990-07-30 | 1990-07-30 | Ortho-substituierte benzylester von cyclopropancarbonsaeuren |
| DEP4024094.0 | 1990-07-30 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR910019965A true KR910019965A (ko) | 1991-12-19 |
Family
ID=25893698
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019910009015A KR910019965A (ko) | 1990-05-31 | 1991-05-31 | 오르토-치환된 시클로프로판카르복실산의 벤질 에스테르 |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US5371268A (ko) |
| EP (1) | EP0459285B1 (ko) |
| JP (1) | JP2986246B2 (ko) |
| KR (1) | KR910019965A (ko) |
| AT (1) | ATE115540T1 (ko) |
| AU (1) | AU632421B2 (ko) |
| CA (1) | CA2043090A1 (ko) |
| DE (1) | DE59103850D1 (ko) |
| DK (1) | DK0459285T3 (ko) |
| ES (1) | ES2066264T3 (ko) |
| HU (1) | HU212872B (ko) |
| IL (1) | IL98082A (ko) |
| NZ (1) | NZ238298A (ko) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6231715B1 (en) * | 1994-12-20 | 2001-05-15 | Kimberly-Clark Worldwide, Inc. | Elongate, semi-tone printing process |
| US20080188689A1 (en) * | 2007-02-06 | 2008-08-07 | Gauri Sankar Lal | Preparation of organic compounds bearing a trifluoromethyl group on a quaternary carbon |
| CN102531898A (zh) * | 2011-11-16 | 2012-07-04 | 江苏华达化工集团有限公司 | 对环己酮甲酸酯经氟化生产4,4-二氟环己基甲酸酯的方法 |
| WO2020092802A1 (en) * | 2018-11-01 | 2020-05-07 | The University Of Memphis Research Foundation | Controlling biofilms with cyclopropanated fatty acids |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE354571C (de) * | 1922-06-13 | Josef Michael Wenz | Unmittelbar beheizter Backofen | |
| AU1718883A (en) * | 1982-07-26 | 1984-02-02 | National Research Development Corp. | Pesticides |
| DE3733870A1 (de) * | 1987-10-07 | 1989-04-27 | Basf Ag | Orthosubstituierte carbonsaeure-benzylester und fungizide, die diese verbindungen enthalten |
| DE3827361A1 (de) * | 1988-08-12 | 1990-03-01 | Basf Ag | Oximether, verfahren zu ihrer herstellung und diese verbindungen enthaltende fungizide |
-
1991
- 1991-05-08 IL IL9808291A patent/IL98082A/en unknown
- 1991-05-22 DK DK91108247.7T patent/DK0459285T3/da active
- 1991-05-22 EP EP91108247A patent/EP0459285B1/de not_active Expired - Lifetime
- 1991-05-22 ES ES91108247T patent/ES2066264T3/es not_active Expired - Lifetime
- 1991-05-22 DE DE59103850T patent/DE59103850D1/de not_active Expired - Lifetime
- 1991-05-22 AT AT91108247T patent/ATE115540T1/de not_active IP Right Cessation
- 1991-05-23 CA CA002043090A patent/CA2043090A1/en not_active Abandoned
- 1991-05-29 NZ NZ238298A patent/NZ238298A/en unknown
- 1991-05-29 JP JP3125770A patent/JP2986246B2/ja not_active Expired - Fee Related
- 1991-05-30 AU AU78013/91A patent/AU632421B2/en not_active Ceased
- 1991-05-30 HU HU911813A patent/HU212872B/hu not_active IP Right Cessation
- 1991-05-31 KR KR1019910009015A patent/KR910019965A/ko not_active Application Discontinuation
-
1994
- 1994-03-14 US US08/209,358 patent/US5371268A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| AU7801391A (en) | 1991-12-05 |
| DE59103850D1 (de) | 1995-01-26 |
| HUT57698A (en) | 1991-12-30 |
| IL98082A0 (en) | 1992-06-21 |
| JP2986246B2 (ja) | 1999-12-06 |
| NZ238298A (en) | 1994-06-27 |
| ES2066264T3 (es) | 1995-03-01 |
| EP0459285A1 (de) | 1991-12-04 |
| CA2043090A1 (en) | 1991-12-01 |
| ATE115540T1 (de) | 1994-12-15 |
| JPH04235945A (ja) | 1992-08-25 |
| US5371268A (en) | 1994-12-06 |
| AU632421B2 (en) | 1992-12-24 |
| DK0459285T3 (da) | 1995-01-23 |
| IL98082A (en) | 1994-12-29 |
| EP0459285B1 (de) | 1994-12-14 |
| HU212872B (en) | 1996-12-30 |
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