KR910015620A - 불포화 카르복실산 에스테르의 중합체 또는 공중합체의 제조방법 - Google Patents
불포화 카르복실산 에스테르의 중합체 또는 공중합체의 제조방법 Download PDFInfo
- Publication number
- KR910015620A KR910015620A KR1019910002348A KR910002348A KR910015620A KR 910015620 A KR910015620 A KR 910015620A KR 1019910002348 A KR1019910002348 A KR 1019910002348A KR 910002348 A KR910002348 A KR 910002348A KR 910015620 A KR910015620 A KR 910015620A
- Authority
- KR
- South Korea
- Prior art keywords
- unsaturated carboxylic
- compound
- trivalent organic
- olefin
- methacrylate
- Prior art date
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/10—Esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/10—Esters
- C08F20/12—Esters of monohydric alcohols or phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/10—Esters
- C08F20/12—Esters of monohydric alcohols or phenols
- C08F20/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F20/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/54—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polymerization Catalysts (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Graft Or Block Polymers (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 폴리에틸렌 -PMMA 공중합체의 IR 스펙트럼을 도시한 도면.
Claims (9)
- 개시제로서, (a)삼가 유기 Sc 화합물. (b)삼가 유기 Y 화합물, 및 (c) 삼가 유기 란타니드(La, Ce, Pr, Nd, Pm, Sm, Eu, Ga, Tb, Dy, Ho, Er, Tm, Yb, Lu) 화합물 중에서 선택된 적어도 한가지의 유기금속 화합물 존재하에 불포화 카르복실산 에스테르를 중합시키는 단계로 이루어진 불포화 카르복실산 에스테르의 중합체 제조방법.
- 제1항에 있어서, 불포화 카르복실산 에스테르가 아크릴레이트, 메타아크릴레이트, 또는 그 혼합물인 것을 특징으로 하는 제조방법.
- 제1항에 있어서, 개시제가 상기 유기금속 화합물과 유기 알루미늄 화합물들중에서 선택된 적어도 한가지 화합물로 이루어진 것을 특징으로 하는 제조방법.
- 제3항에 있어서, 불포화 카르복실산 에스테르가 아크릴레이트, 또는 메타아크릴레이트, 그 혼합물인 것을 특징으로 하는 제조방법.
- 개시제로서, (a)삼가 유기 Sc 화합물. (b)삼가 유기 Y 화합물, 및 (c) 삼가 유기 란타니드(La, Ce, Pr, Nd, Pm, Sm, Eu, Ga, Tb, Dy, Ho, Er, Tm, Yb, Lu)화합물 중에서 선택된 적어도 한가지의 유기금속 화합물 존재하에 불포화 카르복실산 에스테르를 α-올레핀과 공중합시키는 단계로 이루어진 불포화 카르복실산 에스테르 공중합체의 제조방법.
- 제5항에 있어서, 불포화 카르복실산 에스테르가 아크릴레이트, 메타아크릴레이트, 또는 그 혼합물이며 α-올레핀이 에틸렌인 것을 특징으로 하는 제조방법.
- 제5항에 있어서, α-올레핀에 대한 불포화 카르복실산 에스테르의 비율이 0.0001 : 1-1 : 1인 것을 특징으로 하는 제조방법.
- 제5항에 있어서, 개시제가 상기 유기금속 화합물과 유기 알루미늄 화합물들 중에서 선택된 적어도 한가지 화합물로 이루어진 것을 특징으로 하는 제조방법.
- 제8항에 있어서, 불포화 카르복실산 에스테르가 아크릴레이트, 메타아크릴레이트, 또는 그 혼합물이며 α-올레핀이 에틸렌인 것을 특징으로 하는 제조방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP02-33549 | 1990-02-14 | ||
JP3354990 | 1990-02-14 | ||
JP02-54337 | 1990-03-06 | ||
JP5433790A JP2850152B2 (ja) | 1990-03-06 | 1990-03-06 | エチレン系共重合体の製造方法 |
JP27989990A JP2882674B2 (ja) | 1990-02-14 | 1990-10-18 | ポリメタクリル酸エステル及びポリアクリル酸エステルの製造方法 |
JP02-279899 | 1990-10-18 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR910015620A true KR910015620A (ko) | 1991-09-30 |
KR0155998B1 KR0155998B1 (ko) | 1998-12-01 |
Family
ID=27288113
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019910002348A KR0155998B1 (ko) | 1990-02-14 | 1991-02-12 | 불포화 카르복실산 에스테르의 중합체 또는 공중합체의 제조방법 |
Country Status (5)
Country | Link |
---|---|
US (1) | US5132369A (ko) |
EP (1) | EP0442476B1 (ko) |
KR (1) | KR0155998B1 (ko) |
CA (1) | CA2035650C (ko) |
DE (1) | DE69110490T2 (ko) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20130014533A (ko) * | 2010-03-04 | 2013-02-07 | 크로다 인터내셔날 피엘씨 | 마찰 감소 첨가제 |
Families Citing this family (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5422406A (en) * | 1992-10-16 | 1995-06-06 | Northwestern University | Rare earth homogeneous catalysts for the ring-opening polymerization and copolymerization of strained-ring olefins |
US5998499A (en) | 1994-03-25 | 1999-12-07 | Dentsply G.M.B.H. | Liquid crystalline (meth)acrylate compounds, composition and method |
US6353061B1 (en) | 1993-05-26 | 2002-03-05 | Dentsply Gmbh | α, ω-methacrylate terminated macromonomer compounds |
US6369164B1 (en) | 1993-05-26 | 2002-04-09 | Dentsply G.M.B.H. | Polymerizable compounds and compositions |
US5563219A (en) * | 1993-07-16 | 1996-10-08 | Mitsui Toatsu Chemicals, Inc. | Process for Preparing block copolymer of monoolefin |
US5446117A (en) * | 1993-08-19 | 1995-08-29 | Queen's University At Kingston | Process for producing amorphous syndiotactic polystyrene |
CA2146816A1 (en) | 1994-04-22 | 1995-10-23 | Joachim E. Klee | Process and composition for preparing a dental polymer product |
JP3426699B2 (ja) * | 1994-04-27 | 2003-07-14 | 住友化学工業株式会社 | 不飽和カルボン酸及びその誘導体からなる重合体の製造方法 |
DE69515697T2 (de) * | 1994-12-22 | 2000-11-02 | Mitsubishi Rayon Co | Blockcopolymere und verfahren zur herstellung |
DE69717116T2 (de) * | 1996-07-25 | 2003-07-10 | Mitsubishi Rayon Co | Verfahren zur herstellung von poly(meth)acrylsaüreestern |
US6288184B1 (en) | 1999-09-29 | 2001-09-11 | Sri International | Hydrolytically degradable olefin copolymers |
US7037992B2 (en) | 1999-09-29 | 2006-05-02 | Sri International | Olefin copolymers containing hydrolytically cleavable linkages and use thereof in degradable products |
DE10144140A1 (de) * | 2001-09-07 | 2003-03-27 | Roehm Gmbh | Verfahren zur Herstellung von Polymerisaten und Copolymerisaten von Acrylverbindungen |
CN101679565B (zh) | 2007-03-30 | 2012-05-23 | Lg化学株式会社 | 包含链烯烃、丙烯酸酯和不饱和有机酸的共聚物及其制备方法 |
SE534021C2 (sv) | 2009-08-13 | 2011-04-05 | Vigmed Ab | Skyddsanordning för en kateternålspets |
SE535169C2 (sv) | 2010-04-13 | 2012-05-08 | Vigmed Ab | Skyddsanordning av polymer för en kateternålspets |
DE102010038685A1 (de) * | 2010-07-30 | 2012-02-02 | Evonik Röhm Gmbh | Fluoreszenzkonversionssolarzelle Herstellung im Plattengußverfahren |
MY166306A (en) | 2010-09-23 | 2018-06-25 | Vigmed Ab | Needle tip shielding device |
CA2838600A1 (en) * | 2011-07-05 | 2013-01-10 | Vigmed Ab | Needle guard with an active state and a passive state |
WO2014185508A1 (ja) | 2013-05-16 | 2014-11-20 | 株式会社クラレ | フィルム |
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CA1212932A (en) * | 1982-04-01 | 1986-10-21 | Derek K. Jenkins | Polymerisation of conjugated dienes |
US4801666A (en) * | 1985-03-25 | 1989-01-31 | Northwestern University | Olefin and cycloalkene polymerization with organolanthanide catalysts |
US4668773A (en) * | 1985-03-25 | 1987-05-26 | Northwestern University | Organolanthanide catalysts |
US4665046A (en) * | 1985-10-21 | 1987-05-12 | The Dow Chemical Company | Organoactinide polymer catalysts |
JPS6414217A (en) * | 1987-07-08 | 1989-01-18 | Tosoh Corp | Production of ethylene copolymer |
JP2693478B2 (ja) * | 1988-04-08 | 1997-12-24 | 花王株式会社 | ポリメタクリル酸エステルの製造方法 |
US5064802A (en) * | 1989-09-14 | 1991-11-12 | The Dow Chemical Company | Metal complex compounds |
US5066741A (en) * | 1990-03-22 | 1991-11-19 | The Dow Chemical Company | Process for preparation of syndiotactic vinyl aromatic polymers |
US5066739A (en) * | 1990-07-30 | 1991-11-19 | Phillips Petroleum Company | Olefin polymerization with cyclopentadienyl lanthanidealkyl of hydride in presence of hydrogen |
-
1991
- 1991-02-04 CA CA002035650A patent/CA2035650C/en not_active Expired - Fee Related
- 1991-02-12 KR KR1019910002348A patent/KR0155998B1/ko not_active IP Right Cessation
- 1991-02-13 DE DE69110490T patent/DE69110490T2/de not_active Expired - Fee Related
- 1991-02-13 EP EP91102031A patent/EP0442476B1/en not_active Expired - Lifetime
- 1991-02-14 US US07/655,491 patent/US5132369A/en not_active Expired - Lifetime
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20130014533A (ko) * | 2010-03-04 | 2013-02-07 | 크로다 인터내셔날 피엘씨 | 마찰 감소 첨가제 |
Also Published As
Publication number | Publication date |
---|---|
CA2035650A1 (en) | 1991-08-15 |
DE69110490D1 (de) | 1995-07-27 |
EP0442476B1 (en) | 1995-06-21 |
CA2035650C (en) | 1997-02-25 |
US5132369A (en) | 1992-07-21 |
DE69110490T2 (de) | 1996-03-21 |
KR0155998B1 (ko) | 1998-12-01 |
EP0442476A2 (en) | 1991-08-21 |
EP0442476A3 (en) | 1992-01-22 |
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