KR910004546A - N-(치환된 벤질옥시) 이민 유도체, 이의 제조방법, 이의 용도 및 이의 사용방법 - Google Patents

N-(치환된 벤질옥시) 이민 유도체, 이의 제조방법, 이의 용도 및 이의 사용방법 Download PDF

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KR910004546A
KR910004546A KR1019900012853A KR900012853A KR910004546A KR 910004546 A KR910004546 A KR 910004546A KR 1019900012853 A KR1019900012853 A KR 1019900012853A KR 900012853 A KR900012853 A KR 900012853A KR 910004546 A KR910004546 A KR 910004546A
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South Korea
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group
independently selected
groups
lower alkyl
hydrogen atom
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KR1019900012853A
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KR950002839B1 (ko
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겐지 쓰바타
노부유키 니이노
가쓰토시 엔도
요시노부 야마모토
히데오 간노
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고다이라 다스쿠
니혼 노야쿠 가부시키가이샤
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Publication of KR910004546A publication Critical patent/KR910004546A/ko
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C251/00—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
    • C07C251/02—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton containing imino groups
    • C07C251/20—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton containing imino groups having carbon atoms of imino groups being part of rings other than six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D207/30—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
    • C07D207/32—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • C07D207/33—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms with substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • C07D207/335—Radicals substituted by nitrogen atoms not forming part of a nitro radical
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    • A01N41/04—Sulfonic acids; Derivatives thereof
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Abstract

내용 없음.

Description

N-(치환된 벤질옥시) 이민 유도체, 이의 제조방법, 이의 용도 및 이의 사용방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (8)

  1. 일반식(I)의 N-(치환된 벤질옥시)-이민 유도체
    상기식에서, R1및 R2는 서로 독립적으로 저급알킬, 그룹이고, R3및 R4는 서로 독립적으로 수소원자 ; 시아노그룹 ; 니트로그룹; 알킬그룹 ; 할로알킬그룹 ; 사이클로알킬그룹 ; 알콕시그룹 ; 할로알콕시그룹 ; 알킬티오그룹 ; 할로알킬티오그룹 ; 알킬설포닐그룹 ; 알킬설피닐그룹 ; 알케닐티오그룹 ; 알키닐티오 그룹 ; 알콕시알킬 그룹 ; 알킬티오알킬그룹 ; 사이클로알킬티오그룹 ; 저급 알콕시 카보니알킬티오알킬 그룹 ; 수소원자, 할로겐 원자, 시아노그룹, 니트로그룹, 저급알킬 그룹, 저급 할로알킬 그룹, 저급 알콕시 그룹, 저급 할로알콕시 그룹, 저급 알킬티오 그룹, 저급 할로알킬티오 그룹, 아미노 그룹 (여기서, 아미노그룹은 수소원자, 포르밀그룹, 저급 알킬 그룹 및 저급 알킬카보닐 그룹 중에서 독립적으로 선택된 치환체를 갖는다), 저급 알콕시카보닐 그룹, 모노 또는 디-저급 알킬아미노카보닐 그룹 모노- 또는 디-저급 알킬 아미노 카보닐옥시 그룹, 메틸렌디옥시 그룹 페닐그룹(여기서 페닐 그룹은 수소원자, 할로겐원자, 저급 알킬 그룹 및 저급 할로알킬 그룹 중에서 독립적으로 선택된 1 내지 5개의 치환체를 갖는다), 페녹시 그룹 (여기서, 페녹시그룹은 수소원자, 할로겐원자, 시아노그룹, 니트로그룹, 저급 알킬 그룹 및 저급 할로알킬 그룹중에서 독립적으로 선택된 1 내지 5개의 치환체를 갖는다), 모르폴리노그룹(여기서, 모르폴리노 그룹은 저급 알킬 그룹 중에서 독립적으로 선택된 치환체를 가질 수 있다), 피리미딜옥시그룹(여기서, 피리미딜옥시그룹은 저급 알킬그룹중에서 독립적으로 선택된 치환체를 가질 수 있다), 및 모르폴리노카보닐그룹 (여기서, 모르폴리노카보닐그룹은 저급 알킬 그룹중에서 독립적으로 선택된 치환체를 가질 수 있다)중에서 독립적으로 선택된 1 내지 5개의 치환체를 갖는 페닐 그룹 ; 수소원자, 할로겐원자, 저급 알킬 그룹 및 저급 할로알킬 그룹 중에서 독립적으로 선택된 1 내지 5개의 치환체를 갖는 페녹시 알킬 그룹 ; 수소원자, 할로겐원자, 저급 알킬그룹 및 저급할로알킬 그룹중에서 독립적으로 선택된 1 내지 5개의 치환체를 갖는 페닐티오그룹 ; 수소원자, 할로겐원자, 저급 알킬 그룹 및 저급 할로알킬 그룹중에서 독립적으로 선택된 1내지 5개의 치환체를 갖는 페닐알킬티오그룹 ; 수소원자, 할로겐원자, 저급 알킬 그룹 및 저급 할로알킬그룹중에서 독립적으로 선택된 1 내지 5개의 치환체를 갖는 페닐설포닐그룹 ; 수소원자, 할로겐원자, 저급 알킬 그룹 및 저급 할로알킬 그룹중에서 독립적으로 선택된 1 내지 5개의 치환체를 갖는 페닐티오알킬그룹 ; 수소원자, 할로겐원자, 저급알킬 그룹 및 저급 할로알킬그룹 중에서 독립적으로 선택된 1 내지 5개의 치환체를 갖는 페닐알킬티오 그룹 ; 수소원자, 저급 알킬 그룹 및 저급 할로알킬 페닐그룹 및 벤질 그룹중에서 독립적으로 선택된 치환체를 갖는 아미노알킬그룹 ; 푸르푸릴티오알킬 그룹 ; 저급 알킬 그룹중에서 독립적으로 선택된 치환체를 가질 수 있는 모르폴리노알킬그룹 ; -CO-R5그룹[여기서 R5는 저급 알킬그룹, 저급 할로알킬 그룹 ; 저급 알콕시 그룹 ; 저급 할로알콕시 그룹 ; 저급 알킬티오 그룹 ; 저급 할로알킬티오 그룹 ; 수소원자, 저급알킬 그룹, 저급 할로알킬 그룹 및 페닐그룹 중에서 독립적으로 선택된 치환체를 갖는 아미노그룹 ; 수소원자, 할로겐원자, 시아노그룹, 니트로그룹, 저급알킬 그룹, 저급 할로알킬 그룹, 저급 알콕시 그룹, 저급 할로알콕시 그룹, 저급 알킬티오그룹, 저급 할로알킬티오 그룹, 저급 알킬설피닐그룹, 저급 할로알킬설피닐 그룹, 저급 알킬설포닐 그룹, 저급 할로알킬설포닐 그룹, 저급 알콕시 알킬그룹, 아미노그룹 (여기서, 아미노그룹은 수소원자, 저급 알킬 그룹, 저급 알킬카보닐 그룹, 저급 할로알킬카보닐 그룹, 저급 알킬설포닐 그룹, 저급 할로알킬설포닐 그룹 저급 알콕시카보닐그룹 및 저급 할로알콕시카보닐 그룹 중에서 독립적으로 선택된 치환체를 갖는다), 페닐그룹 (여기서, 페닐그룹은 수소원자, 할로겐원자, 저급 알킬 그룹 및 저급 할로알킬 그룹중에서 독립적으로 선택된 1 내지 5개의 치환체를 갖는다), 페녹시그룹 (여기서, 페녹시그룹은 수소원자, 할로겐원자, 시아노그룹, 니트로그룹, 저급 알킬 그룹, 저급 할로알킬 그룹중에서 독립적으로 선택된 1 내지 5개의 치환체를 갖는다), 벤질그룹, (여기서, 벤질그룹은 수소원자 할로겐원자, 자급 할로알킬 저급 알킬 그룹 중에서 선택된 1 내지 5개의 치환체를 갖는다), 벤질옥시 그룹(여기서, 벤질옥시 그룹(여기서 벤질옥시 그룹은수소 원자, 할로겐원자, 저급 할로알킬 그룹중에서 선택된 1 내지 5개의 치환체를 갖는다), 피리딜옥시그룹 (여기서, 피리딜옥시그룹은 수소원자, 할로겐원자, 저급알킬 그룹 및 저급 할로알킬 그룹중에서 독립적으로 선택된 1내지 4개의 치환체를 갖는다), 메틸렌디옥시 그룹 및 인접한 탄소원자에 결합된 탄소수 3 내지 4의 알킬렌 그룹중에서 독립적으로 선택된 1 내지 5개의 치환체를 갖는 페닐 그룹 ; 수소원자, 할로겐원자, 저급 알킬 그룹, 저급 할로알킬그룹, 저급 알콕시그룹, 저급 할로알콕시 그룹, 저급 알킬티오 그룹 및 저급 할로알킬티오 그룹중에서 독립적으로 선택된 1 내지 5개의 치환체를 갖는 벤질옥시그룹 ; 나프틸 그룹, 또는 산소원자, 황원자 및 질소원자중에서 독립적으로 선택된 1 내지 3개의 헤테로원자를 갖고 환상에 저급 알킬 그룹, 저급 할로알킬 그룹, 저급 알콕시그룹 및 저급 할로알콕시 그룹중에서 선택된 치환체를 갖는 5- 또는 6- 원환을 나타낸다] ; 수소원자, 저급 알킬 그룹, 저급 할로알킬 그룹, 저급 알케닐 그룹, 저급 알키닐 그룹, 저급 알콕시 알킬 그룹, 저급 디알콕시알킬 그룹, 모노- 또는 디-저급 알킬아미노알킬 그룹, 페닐그룹 (여기서, 페닐그룹은 수소원자, 할로겐원자, 저급 알킬그룹 및 저급 할로알킬그룹 중에서 독립적으로 선택된 1 내지 5개의 치환체를 갖는다), 피리딜알킬 그룹 및 모르폴리노알킬 그룹중에서 독립적으로 선택된 치환체를 갖는 아미노그룹 ; 수소원자, 할로겐원자, 저급 알킬 그룹, 저급 할로알킬 그룹, 저급 알콕시그룹, 저급 할로알콕시 그룹, 저급 알킬티오 그룹 및 저급 할로알킬티오 그룹중에서 독립적으로 선택된 1 내지 5개의 치환체를 갖는 페닐 알킬 그룹 ; 수소원자, 할로겐원자, 저급 알킬 그룹 및 저급할로알킬 그룹중에서 독립적으로 선택된 1 내지 5개의 치환체를 갖는 페닐 알케닐 그룹 ; 나프틸그룹 ; 저급 디알킬포스포닐 그룹 ; 도는 산소원자, 황원자 및 질소원자중에서 독립적으로 선택된 1 내지 3개의 헤테로원자를 갖고 수소원자, 할로겐원자. 시아노그룹, 니트로그룹, 저급 알킬 그룹, 저급 알콕시 그룹, 저급 할로알콕시 그룹, 저급 알킬티오 그룹, 저급 할로알킬티오 그룹, 저급 알콕시카보닐 그룹, 페닐그룹(여기서 페닐그룹은 수소 원자 및 할로겐원자중에서 독립적으로 선택된 1 내지 5개의 치환체를 갖는다), 벤질그룹, 피리딜그룹, 피리미딜그룹 및 디옥솔란 그룹중에서 독립적으로 선택된 치환체를 갖는 5 내지 7원 헤테로환, 또는 벤젠 또는 사이클로알칸과 융합된 이의 헤테로환이거나, R3및 R4는 함께 산소원자, 황원자, 질소원자, 카보닐그룹, 및 저급 알킬 그룹 또는 페닐그룹 중에서 선택된 치환체를 갖는 질소원자중에서 선택된 1 내지 3개의 원자 또는 그룹으로 중단될 수 있고, 상기그룹은 알킬렌 또는 알케닐렌쇄상에 저급 알킬그룹, 저급 할로알킬 그룹, 저급 알콕시 그룹 및 저급 할로알콕시 그룹중에서 독립적으로 선택된 치환체를 가질 수 있으며 벤젠환과 융합되어 환을 형성할 수 있다.
  2. 제1항에 있어서, R1및 R2가 서로 독립적으로 저급 알킬 그룹이고, R3및 R4가 서로 독립적으로 알킬그룹 ; 할로알킬그룹 ; 알콕시그룹 ; 할로알콕시그룹 ; 알킬티오그룹 ; 할로알킬티오그룹 ; 알킬설포닐그룹 ; 알콕시알킬그룹 ; 알킬 티오알킬그룹 ; 할로겐원자, 시아노그룹 ; 니트로그룹 ; 저급 알킬 그룹 ; 저급 할로알킬 그룹, 저급 알콕시 그룹, 저급 할로알콕시 그룹, 저급 알킬티오 그룹, 저급 할로알킬티오 그룹, 아미노 그룹, (여기서, 아미노그룹은 수소원자, 포르밀그룹, 저급알킬그룹 및 저급 알킬카보닐 그룹중에서 독립적으로 선택된 치환체를 갖는다), 및 페닐그룹(여기서, 페닐그룹은 수소원자, 할로겐원자, 저급알킬그룹 및 저급 할로알킬그룹중에서 독립적으로 선택된 1 내지5개의 치환체를 갖는다)중에서 독립적으로 선택된 1 내지 5개의 치환체를 갖는 페닐 그룹 ; 수소원자, 저급 알킬그룹, 저급 할로알킬그룹, 페닐그룹 및 벤질그룹 중에서 독립적으로 선택된 치환체를 갖는 아미노알킬 그룹 ; -CO-R5그룹 [여기서, R5는 페닐 그룹(여기서, 페닐그룹은 수소원자, 할로겐원자. 시아노그룹, 니트로그룹, 저급 알킬그룹, 저급 할로알킬그룹, 저급 알콕시그룹, 저급 할로알콕시그룹, 저급알킬티오그룹, 저급 할로알킬티오그룹, 저급 알킬설피닐 그룹, 저급 할로알킬설피닐 그룹, 저급 알킬설포닐그룹, 저급 할로알킬설포닐그룹, 저급 알콕시알킬 그룹, 및 아미노그룹 (여기서, 아미노그룹은 수소원자, 저급 알킬 그룹, 저급 알킬카보닐 그룹, 저급 할로알킬카보닐 그룹, 저급 알킬설포닐 그룹, 저급 할로알킬설포닐 그룹, 저급 알콕시카보닐 그룹 및 저급 할로알콕시카보닐 그룹 중에서 독립적으로 선택된 치환체를 갖는다)중에서 선택된 1 내지 5개의 치환체를 갖는 페닐 그룹을 나타낸다] ; 또는 산소원자, 황원자 및 질소원자중에서 독립적으로 선택된 1 내지 3개의 헤테로원자를 갖고 수소원자, 할로겐원자. 시아노그룹, 니트로그룹, 저급 알킬 그룹, 저급 알콕시 그룹, 저급 할로알콕시 그룹, 저급 알킬티오 그룹, 저급 할로알킬티오 그룹, 저급 알콕시카보닐 그룹, 페닐그룹(여기서, 페닐그룹은 수소원자 및 할로겐원자 중에서 독립적으로 선택된 1 내지 5개의 치환체를 갖는다), 벤질그룹, 피리딜 그룹, 피리미질그룹 및 디옥솔란그룹 중에서 독립적으로 선택된 치환체를 갖거나, 벤젠 또는 사이클로알칸과 융합된 5 내지 7원 헤테로환인 N-(치환된 벤질옥시)이민 유도체.
  3. 제2항에 있어서, 벤젠 또는 사이클로알칸과 융합된 5 내지 7원 헤테로환 또는 상기 헤테로환이 푸란, 티오펜, 피롤, 피라졸, 이미다졸, 트리아졸, 옥사졸, 티아졸, 피리딘, 피리다진, 피리미딘, 피라진, 피롤리딘, 피페리딘, 모르플린, 티오모르플란, 피페라진, 헥사메틸렌, 이민, 테트라하이드록퀴놀린, 테트라하이드로이소퀴놀린, 2, 3-디하이드로-1,4-벤조옥사진, 옥타하이드로-1,4-벤조옥사진 또는 인돌린 N-(치환된 벤질옥시)이민 유도체.
  4. 일반식(II)의 화합물을 일반식(III)의 화합물과 반응시킴을 특징으로 하여, 일반식(I)의 N-(치환된 벤질옥시)이민 유도체를 제조하는 방법.
    상기식에서, R1및 R2는 서로 독립적으로 저급알킬 그룹이고, R3및 R4는 서로 독립적으로 수소원자 ; 시아노그룹 ; 니트로그룹 ; 알킬그룹 ; 할로알킬그룹 ; 사이클로알킬그룹 ; 알콕시그룹 ; 할로알코시그룹 ; 알킬티오그룹 ; 할로알킬티오그룹 ; 알킬설포닐그룹 ; 알킬설피닐그룹 ; 알케닐티오그룹 ; 알키닐티오그룹 ; 알콕시알킬그룹 ; 알킬티오알킬그룹 ; 사이클로알킬티오그룹 ; 저급 알콕시 카보니알킬티오알킬 그룹 ; 수소원자, 할로겐원자, 시아노그룹, 니트로그룹, 저급 알킬 그룹, 저급 할로알킬 그룹, 저급 알콕시 그룹, 저급 할로알콕시 그룹, 저급 알킬티오 그룹, 저급 할로알킬티오 그룹, 그룹(여기서, 아미노그룹은 수소원자, 포르밀그룹, 저급 알킬 그룹 및 및 저급 알킬카보닐 그룹중에서 독립적으로 선택된 치환체를 갖는다), 저급 알콕시카보닐 그룹, 모노 또는 디-저급 알킬아미노카보닐 그룹 모노 - 또는 디-저급 알킬 아미노 카보닐옥시 그룹, 메틸렌디옥시 그룹 페닐그룹(여기서, 페닐 그룹은 수소원자, 할로겐원자, 저급 알킬 그룹 및 저급 할로알킬 그룹 중에서 독립적으로 선택된 1 내지 5개의 치환체를 갖는다), 페녹시 그룹(여기서, 페녹시그룹은 수소원자, 할로겐원자, 시아노그룹, 니트로그룹, 저급 알킬 그룹 및 저급 할로알킬 그룹중에서 독립적으로 선택된 1 내지 5개의 치환체를 갖는다), 모르폴리노그룹 (여기서, 모르폴리노 그룹은 저급 알킬 그룹 중에서 독립적으로 선택된 치환체를 가질 수 있다), 피리미딜옥시그룹 (여기서, 피리미딜옥시그룹은 저급 알킬그룹 중에서 독립적으로 선택된 치환체를 가질 수 있다), 및 모르폴리노카보닐그룹 (여기서, 모르폴리노카보닐그룹은 저급 알킬 그룹중에서 독립적으로 선택된 치환체를 가질 수 있다)중에서 독립적으로 선택된 1 내지 5개의 치환체를 갖는 페녹시알킬 그룹 ; 수소원자, 할로겐원자, 저급 알킬그룹 및 저급 할로알킬 그룹 중에서 독립적으로 선택된 1 내지 5개의 치환체를 갖는 페녹시 알킬그룹 ; 수소원자, 할로겐원자, 저급 알킬 그룹 및 저급 할로알킬 그룹 중에서 독립적으로 선택된 1 내지 5개의 치환체를 갖는 페닐알킬티오그룹 ; 수소원자, 할로겐 원자, 저급 알킬 그룹 및 저급 할로알킬그룹 중에서 독립적으로 선택된 1 내지 5개의 치환체를 갖는 펜닐설포닐그룹 ; 수소원자, 할로겐원자, 저급 알킬 그룹 및 저급 할로알킬그룹중에서 독립적으로 선택된 1 내지 5개의 치환체를 갖는 페닐티오알킬그룹 ; 수소원자, 할로겐원자, 저급 알킬 그룹 및 저급 할로알킬 그룹 중에서 독립적으로 선택된 1 내지 5개의 치환체를 갖는 페닐알킬티오알킬 그룹 ; 수소원자, 저급 알킬 그룹 및 저급 할로알킬 페닐그룹 및 벤질 그룹중에서 독립적으로 선택된 치환체를 갖는 아미노알킬그룹 ; 푸르푸릴티오알킬그룹; 저급 알킬그룹중에서 독립적으로 선택된 치환체를 가질 수 있는 모르폴리노알킬그룹 ; -COR5그룹 [여기서, R5는 저급 알킬그룹, 저급 할로알킬 그룹 ; 저급 알콕시 그룹 ; 저급 할로알콕시 그룹 ; 저급 알킬티오 그룹 ; 저급 할로알킬티오 그룹 ; 수소원자, 저급 알킬 그룹, 저급 할로알킬 그룹 및 페닐그룹 중에서 독립적으로 선택된 치환체를 갖는 아미노그룹 ; 수소원자, 할로겐원자, 시아노그룹, 니트로그룹, 저급알킬그룹, 저급 할로알킬그룹, 적브 알콕시그룹, 저급 할로알콕시 그룹, 저급 알킬티오그룹, 저급 할로알킬티오그룹, 저급 알킬설피닐 그룹, 저급 할로알킬설피닐 그룹, 저급 알킬설포닐 그룹, 저급 할로알킬설포닐 그룹, 저급 알콕시 알킬그룹, 아미노그룹 (여기서, 아미노그룹은 수소원자, 저급 알킬 그룹, 저급 알킬카보닐 그룹, 저급 할로알킬카보닐 그룹, 저급 알킬설포닐 그룹, 저급 할로알킬설포닐 그룹 저급 알콕시카보닐그룹 및 저급 할로알콕시카보닐 그룹중에서 독립적으로 선택된 치환체를 갖는다), 페닐그룹 (여기서, 페닐그룹은 수소원자, 할로겐원자, 저급 알킬 그룹 및 저급 할로알킬 그룹 중에서 독립적으로 선택된 1 내지 5개의 치환체를 갖는다), 페녹시 그룹 (여기서, 페녹시그룹은 수소원자, 할로겐원자, 시아노그룹, 니트로그룹, 저급 알킬 그룹 및 저급 할로알킬 그룹중에서 독립적으로 선택된 1 내지 5개의 치환체를 갖는다), 벤질 그룹(여기서, 벤질그룹은 수소원자, 할로겐원자, 저급 알킬 그룹 및 저급 할로알킬 그룹중에서 독립적으로 선택된 1 내지 5개의 치환체를 갖는다), 벤질옥시그룹 (여기서, 벤질옥시그룹은 수소원자, 할로겐원자, 저급 알킬 그룹 및 저급 할로알킬 그룹 중에서 독립적으로 선택된 1 내지 5개의 치환체를 갖는다), 피리딜옥시그룹 (여기서, 피리딜옥시그룹은 수소원자, 할로겐원자, 저급 알킬 그룹 및 저급 할로알킬 그룹중에서 독립적으로 선택된 1 내지 4개의 치환체를 갖는다), 메틸렌디옥시 그룹 및 인접한 탄소원자에 결합된 탄소수 3 내지 4의 알킬렌 그룹 중에서 독립적으로 선택된 1 내지 5개의 치환체를 갖는 페닐 그룹 ; 수소원자, 할로겐원자, 저급 알킬 그룹, 저급 할로알킬 그룹, 저급 알콕시 그룹, 저급 할로알콕시 그룹, 저급 알킬티오 그룹 및 저급 할로알킬티오 그룹 중에서 독립적으로 선택된 1 내지 5개의 체환체를 갖는 벤질옥시그룹 ; 나프틸 그룹, 또는 산소원자, 황원자 및 질소원자 중에서 독립적으로 선택된 1 내지 3개의 헤테로원자를 갖고 환상에 저급 알킬 그룹, 저급 할로알킬 그룹, 저급 알콕시그룹 및 저급 할로알콕시 그룹 중에서 선택된 치환체를 갖는 5- 또는 6-원환을 나타낸다] ; 수소원자, 저급 알킬 그룹, 저급 할로알킬 그룹, 저급 알케닐 그룹, 저급 알키닐 그룹, 저급 알콕시알킬 그룹, 저급 디알콕시알킬 그룹, 모노- 또는 디-저급 알킬아미노알킬그룹, 페닐그룹(여기서, 페닐그룹은 수소원자, 할로겐원자, 저급 알킬그룹 및 저급 할로알킬 그룹중에서 독립적으로 선택된 1 내지 5개의치환체를 갖는다), 피리딜알킬 그룹 및 모르폴리노알킬 그룹중에서 독립적으로 선택된 치환체를 갖는 아미노그룹; 수소원자,할로겐원자,페닐 알케닐 그룹 ; 나프틸 그룹 ; 저급 디알킬포스포닐 그룹 ; 또는 산소원자, 황원자 및 질소원자중에서 독립적으로 선택된 1 내지 3개의 헤테로원자를 갖고 수소원자, 할로겐원자, 시아노그룹, 니트로그룹, 저급 알킬 그룹, 저급 알콕시 그룹, 저급 할로알콕시 그룹, 저급 알킬티오 그룹, 저급 할로알킬티오 그룹, 저급 알콕시카보닐 그롭, 페닐그룹(여기서, 페닐 그룹은 수소원자 및 할로겐원자중에서 독립적으로 선택된 1 내지 5개의 치환체를 갖는다), 벤질그룹, 피리딜그룹, 피리미딜 그룹 및 디옥솔란 그룹중에서 독립적으로 선택된 치환체를 갖는 5 내지 7원 헤테로환, 또는 벤젠 또는 사이클로알칸과 융합된 이의 헤테로환이거나, R3및 R4는 함께 산소원자, 황원자, 질소원자, 카보닐그룹, 및 저급 알킬 그룹 또는 페닐그룹 중에서 선택된 치환체를 갖는 질소원자중에서 선택된 1 내지 3개의 원자 또는 그룹으로 중단될 수 있고, 알킬렌 또는 알케닐렌쇄상에 저급 알킬그룹, 저급 할로알킬 그룹, 저급 알콕시 그룹 및 저급 할로알콕시 그룹중에서 독립적으로 선택된 치환체를 가질 수 있으며 벤젠환과 융합되어 융합된 환을 형성할수 있는 알킬렌 또는 알케닐렌 그룹이다.
  5. 농업적으로 또는 원예학적으로 살진균활성을 나타내는 양의 제1항의 N-(치환된 벤질옥시)이민 유도체 및 농업적 또는 원예학적 불활성 담체로서 허용되는 담체를 함유하는 농업용 또는 원예용 살진균제.
  6. 농업적으로 또는 원예학적으로 살진균활성을 나타내는 양의 제2항의 N-(치환된 벤질옥시)이민 유도체 및 농업적 또는 불활성 담체로서 허용되는 담체를 함유하는 농업용 또는 원예용 살진균제.
  7. 농업적으로 또는 원예학적으로 살진균활성을 나타내는 양의 제3항의 N-(치환되 벤질옥시)이민 유도체 및 농업적 또는 원예학적 불활성 담체로서 허용되는 담체를 함유하는 농업용 또는 원예용 살진균제.
  8. 활성성분으로서, 제5항의 농업용 또는 원예용 살진균제를 10아르(are)당 0.1 내지 1,000g의 양으로 적용시켜 식물병을 방제하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019900012853A 1989-08-22 1990-08-21 N-(치환된 벤질옥시) 이민 유도체, 이의 제조방법, 이를 함유하는 살진균제 및 이의 사용방법 KR950002839B1 (ko)

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EP0414153A1 (en) 1991-02-27
AU6112790A (en) 1991-02-28
KR950002839B1 (ko) 1995-03-27
JPH03169842A (ja) 1991-07-23
DE69006290T2 (de) 1994-05-05
AU628625B2 (en) 1992-09-17
CN1024662C (zh) 1994-05-25
DE69006290D1 (de) 1994-03-10
CN1088384A (zh) 1994-06-29

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