KR910001026A - 세제 날분의 해응집에 의한 세제 과립의 형성 - Google Patents
세제 날분의 해응집에 의한 세제 과립의 형성 Download PDFInfo
- Publication number
- KR910001026A KR910001026A KR1019900008445A KR900008445A KR910001026A KR 910001026 A KR910001026 A KR 910001026A KR 1019900008445 A KR1019900008445 A KR 1019900008445A KR 900008445 A KR900008445 A KR 900008445A KR 910001026 A KR910001026 A KR 910001026A
- Authority
- KR
- South Korea
- Prior art keywords
- detergent
- weight
- coagulant
- mixtures
- lump
- Prior art date
Links
- 239000003599 detergent Substances 0.000 title claims 16
- 239000008187 granular material Substances 0.000 title claims 10
- 239000000843 powder Substances 0.000 title claims 10
- 230000015572 biosynthetic process Effects 0.000 title 1
- 238000000034 method Methods 0.000 claims 23
- 239000000203 mixture Substances 0.000 claims 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 7
- 239000000701 coagulant Substances 0.000 claims 6
- 239000003945 anionic surfactant Substances 0.000 claims 5
- 238000004519 manufacturing process Methods 0.000 claims 5
- 229920000620 organic polymer Polymers 0.000 claims 4
- -1 alkylbenzene sulfonates Chemical class 0.000 claims 3
- 239000002736 nonionic surfactant Substances 0.000 claims 3
- 239000002245 particle Substances 0.000 claims 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 2
- 150000008051 alkyl sulfates Chemical class 0.000 claims 2
- DNEHKUCSURWDGO-UHFFFAOYSA-N aluminum sodium Chemical group [Na].[Al] DNEHKUCSURWDGO-UHFFFAOYSA-N 0.000 claims 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims 2
- 235000013312 flour Nutrition 0.000 claims 2
- 229920000058 polyacrylate Polymers 0.000 claims 2
- 229920001223 polyethylene glycol Polymers 0.000 claims 2
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 claims 2
- 235000019832 sodium triphosphate Nutrition 0.000 claims 2
- 235000019818 tetrasodium diphosphate Nutrition 0.000 claims 2
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims 1
- 229910019142 PO4 Inorganic materials 0.000 claims 1
- 239000002202 Polyethylene glycol Substances 0.000 claims 1
- 239000004115 Sodium Silicate Substances 0.000 claims 1
- 229910052782 aluminium Inorganic materials 0.000 claims 1
- 239000002280 amphoteric surfactant Substances 0.000 claims 1
- 125000000129 anionic group Chemical group 0.000 claims 1
- 239000002519 antifouling agent Substances 0.000 claims 1
- HXDRSFFFXJISME-UHFFFAOYSA-N butanedioic acid;2,3-dihydroxybutanedioic acid Chemical compound OC(=O)CCC(O)=O.OC(=O)C(O)C(O)C(O)=O HXDRSFFFXJISME-UHFFFAOYSA-N 0.000 claims 1
- 125000002091 cationic group Chemical group 0.000 claims 1
- 239000003093 cationic surfactant Substances 0.000 claims 1
- 239000002738 chelating agent Substances 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 150000001860 citric acid derivatives Chemical class 0.000 claims 1
- 239000007859 condensation product Substances 0.000 claims 1
- 235000014113 dietary fatty acids Nutrition 0.000 claims 1
- 239000000194 fatty acid Substances 0.000 claims 1
- 229930195729 fatty acid Natural products 0.000 claims 1
- 150000004665 fatty acids Chemical class 0.000 claims 1
- 239000000796 flavoring agent Substances 0.000 claims 1
- 235000013355 food flavoring agent Nutrition 0.000 claims 1
- 239000000417 fungicide Substances 0.000 claims 1
- 159000000011 group IA salts Chemical class 0.000 claims 1
- 238000002156 mixing Methods 0.000 claims 1
- 230000007935 neutral effect Effects 0.000 claims 1
- 235000021317 phosphate Nutrition 0.000 claims 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims 1
- 229920005646 polycarboxylate Polymers 0.000 claims 1
- 229920000642 polymer Polymers 0.000 claims 1
- 239000000047 product Substances 0.000 claims 1
- 238000010298 pulverizing process Methods 0.000 claims 1
- 150000004760 silicates Chemical class 0.000 claims 1
- 229910021647 smectite Inorganic materials 0.000 claims 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims 1
- 229910052911 sodium silicate Inorganic materials 0.000 claims 1
- 239000003381 stabilizer Substances 0.000 claims 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims 1
- 239000000375 suspending agent Substances 0.000 claims 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 claims 1
- 239000002888 zwitterionic surfactant Substances 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/0082—Special methods for preparing compositions containing mixtures of detergents one or more of the detergent ingredients being in a liquefied state, e.g. slurry, paste or melt, and the process resulting in solid detergent particles such as granules, powders or beads
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3761—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in solid compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
내용 없음.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (25)
- (a)(1) 물 약 5중량% 내지 약 40중량%, (2) 음이온성, 쯔비티이온성, 양이온성, 양성 및 비이온성 계면활성제로 이루어지는 그룹중에서 선택된 성분 약 20중량% 내지 약 90중량%, 수용성 유기 중합체, 세제 빌더 및 이들의 혼합물. (3) 평균 입자 크기 약 200μ미만의 미세 분말인 해응집제 0중량% 내지 25중량%의 사실상 균일한 혼합물을 함유하는 날분 덩어리를 형성시키고, (b) 날분 덩어리를 고전단 혼합기 내에서 초당 약 10m 이상의 팁 속도로 평균 입자 크기 약 200μ미만의 미세 분말인 해응집제 유효량과 약 9:1 내지 약 1:5의 비로 혼합함을 특징으로 하는 세제 과립 제조방법.
- 제1항에 있어서, 단계(a)의 날분 덩어리가 물이외의 성분 하나 이상을 함유할 경우, 단계(a)에서 가하는 모든 성분을 약 35℃내지 100℃의 온도에서 날분 덩어리에 혼련시켜 넣음을 특징으로 하는 세제 과립 제조방법.
- 제1항에 있어서, 날분 덩어리가 단계(a)(2)의 성분 약 25중량% 내지 약 60중량%를 함유함을 특징으로 하는 세제 과립 제조방법.
- 제3항에 있어서, 날분 덩어리가 물 약 5중량% 내지 약 15중량%를 함유함을 특징으로 하는 세제 과립 제조방법.
- 제4항에 있어서, 단계(a)의 성분을 약 40℃내지 80℃의 온도에서 함께 혼련시킴을 특징으로 하는 세제 과립 제조방법.
- 제5항에 있어서, 단계(a)의 성분을 약 50℃내지 70℃의 온도에서 함께 혼련시킴을 특징으로 하는 세제 과립 제조방법.
- 제1항에 있어서, 단계(a)(2)의 성분이 음이온성 계면활성제임을 특징으로 하는 세제 과립 제조방법.
- 제1항에 있어서, 단계(a)(2)의 성분이 음이온성 계면활성제, 비이온성 계면활성제, 수용성 유기 중합체 및 세제 빌더임을 특징으로 하는 세제 과립 제조방법.
- 제7항에 있어서, 음이온성 계면활성제가 C10-18알킬 설페이트임을 특징으로 하는 세제 과립 제조방법.
- 제8항에 있어서, 음이온성 계면활성제가 C10-18알킬 설페이트와 C10-18직쇄 알킬벤젠 설포네이트와의 약 2:1 내지 1:2 의 비의 혼합물임을 특징으로 하는 세제 과립 제조방법.
- 제10항에 있어서, 비이온성 계면활성제가 C12-15알콜과 알콜 1몰당 에틸렌 옥사이드 약 5 내지 약 20몰과의 축합 생성물임을 특징으로 하는 세제 과립 제조방법.
- 제1항에 있어서, 단계(a)(2)의 성분이 분자량 약 4,000 내지 10,000의 폴리아크릴레이트 중합체, 분자량 약 2000내지 50,000의 폴리에틸렌 글리콜 및 이들의 혼합물로 이루어지는 그룹중에서 선택된 수용성 유기 중합체임을 특징으로 하는 세제 과립 제조방법.
- 제10항에 있어서, 수용성 유기 중합체가 분자량 약 5,000내지 10,000의 폴리아크릴레이트 또는 분자량 약 4,000내지 10,000의 폴리에틸렌 글리콜임을 특징으로 하는 세제 과립 제조방법.
- 제12항에 있어서, 단계(a)(2)의 성분이 인산염, 탄산염, 규산염, C10-18지방산, 폴리카복실레이트 및 이들의 혼합물로 이루어지는 그룹중에서 선택된 세제빌더를 함유함을 특징으로 하는 세제 과립 제조방법.
- 제13항에 있어서, 세제 빌더가 트리폴리인산 나트륨, 피로인산 사나트륨, 시트로산염, 타타레이트 석신삼염, 규산나트륨 및 이들의 혼합물로 이루어지는 그룹중에서 선택됨을 특징으로 하는 세제 과립 제조방법.
- 제1항에 있어서, 해응집제가 규산알루미늄, 탄산염, 분말, 트리폴리인산염 분말, 피로인산 사나트륨 분말, 시트로산염, 황산염 및 이들의 혼합물로 이루어지는 그룹중에서 선택됨을 특징으로 하는 세제 과립 제조방법.
- 제16항에 있어서, 해응집제가 평균 입자 크기가 약 100μ미만인 미세 분말임을 특징으로 하는 세제 과립 제조방법.
- 제17항에 있어서, 단계(a)의 날분 덩어리가 해응집제 약 5중량% 미만을 함유함을 특징으로 하는 세제 과립 제조방법.
- 제18항에 있어서, 해응집제가 규산알루미늄 나트륨임을 특징으로 하는 세제 과립 제조방법.
- 제19항에 있어서, 날분 덩어리 대 규산알루미늄 나트륨의 비가 약 4:1 내지 약 1:2임을 특징으로 하는 세제 과립 제조방법.
- 제20항에 있어서, 고전단 혼합기의 팁 속도가 초당 약 20 내지 35m임을 특징으로 하는 세제 과립 제조방법.
- 제1항에 있어서, 세제 과립이 수용성 중성 또는 알칼리성 염, 서즈 조절제, 오염 현탁제, 오염 방지제, 살균제, pH조정제, 킬레이트제, 스멕타이트 클레이, 효소-안정화제, 향료, 형광 증백제 및 이들의 혼합물로 이루어지는 그룹 중에서 선택된 추가의 세제 성분을 완제품의 0중량% 내지 약 50중량% 함유함을 특징으로 하는 세제 과립 제조방법.
- 제1항의 방법에 따라 제조된 세제 과립.
- 제11항의 방법에 따라 제조된 세제 과립.
- 제21항의 방법에 따라 제조된 세제 과립.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US36472589A | 1989-06-09 | 1989-06-09 | |
US364725 | 1989-06-09 |
Publications (1)
Publication Number | Publication Date |
---|---|
KR910001026A true KR910001026A (ko) | 1991-01-30 |
Family
ID=23435796
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019900008445A KR910001026A (ko) | 1989-06-09 | 1990-06-09 | 세제 날분의 해응집에 의한 세제 과립의 형성 |
Country Status (24)
Country | Link |
---|---|
US (1) | US5178798A (ko) |
EP (1) | EP0402111B1 (ko) |
JP (1) | JP2818258B2 (ko) |
KR (1) | KR910001026A (ko) |
CN (1) | CN1027287C (ko) |
AR (1) | AR242984A1 (ko) |
AT (1) | ATE118031T1 (ko) |
AU (1) | AU644074B2 (ko) |
BR (1) | BR9002721A (ko) |
CA (1) | CA2017921C (ko) |
DE (1) | DE69016504T2 (ko) |
DK (1) | DK0402111T3 (ko) |
EG (1) | EG19506A (ko) |
ES (1) | ES2067674T3 (ko) |
FI (1) | FI99023C (ko) |
GR (1) | GR3014947T3 (ko) |
IE (1) | IE65739B1 (ko) |
MA (1) | MA21869A1 (ko) |
MX (1) | MX170959B (ko) |
NZ (1) | NZ233999A (ko) |
PE (1) | PE35490A1 (ko) |
PT (1) | PT94313B (ko) |
SA (1) | SA90110027B1 (ko) |
TR (1) | TR24390A (ko) |
Families Citing this family (31)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR0170424B1 (ko) * | 1990-07-05 | 1999-01-15 | 호르스트 헤를레,요한 글라슬 | 세제 및 청정제용 표면 활성제 과립의 제조방법 |
DE4038476A1 (de) * | 1990-12-03 | 1992-06-04 | Henkel Kgaa | Feste waschmittel |
DE4038609A1 (de) * | 1990-12-04 | 1992-06-11 | Henkel Kgaa | Verfahren zur herstellung von zeolith-granulaten |
EP0510746A3 (en) * | 1991-04-12 | 1993-09-08 | The Procter & Gamble Company | Process for preparing condensed detergent granules |
JP3192469B2 (ja) * | 1991-05-17 | 2001-07-30 | 花王株式会社 | ノニオン洗剤粒子の製造方法 |
DE4127323A1 (de) * | 1991-08-20 | 1993-02-25 | Henkel Kgaa | Verfahren zur herstellung von tensidgranulaten |
GB9125035D0 (en) * | 1991-11-26 | 1992-01-22 | Unilever Plc | Detergent compositions and process for preparing them |
US5486317A (en) * | 1992-02-14 | 1996-01-23 | The Procter & Gamble Company | Process for making detergent granules by neutralization of sulphonic acids |
DE69220773T2 (de) * | 1992-02-14 | 1998-02-12 | Procter & Gamble | Verfahren zur Herstellung von Detergenskörnchen durch Neutralisation von Sulfonsäuren |
US5259994A (en) * | 1992-08-03 | 1993-11-09 | The Procter & Gamble Company | Particulate laundry detergent compositions with polyvinyl pyrollidone |
EP0592033A1 (en) * | 1992-10-07 | 1994-04-13 | The Procter & Gamble Company | Process for making peroxyacid containing particles |
US5739097A (en) * | 1993-02-11 | 1998-04-14 | Henkel Kommanditgesellschaft Auf Aktien | Process for the production of surfactant granules |
ES2115246T3 (es) * | 1993-02-26 | 1998-06-16 | Procter & Gamble | Composiciones detergentes que comprenden granulados de enzimas muy activos. |
USH1604H (en) * | 1993-06-25 | 1996-11-05 | Welch; Robert G. | Process for continuous production of high density detergent agglomerates in a single mixer/densifier |
ATE195549T1 (de) * | 1994-01-17 | 2000-09-15 | Procter & Gamble | Verfahren zur herstellung von reinigungsmittelgranulaten |
US5431857A (en) * | 1994-01-19 | 1995-07-11 | The Procter & Gamble Company | Process for producing a high density detergent composition having improved solubility by agglomeration of anionic surfactants and an agglomerating agent |
US5759982A (en) * | 1994-06-17 | 1998-06-02 | The Procter & Gamble Company | Laundry bars with polyethylene glycol as a processing aid |
US5968892A (en) * | 1994-06-17 | 1999-10-19 | Hutchins; James Peyton | Non-brittle laundry bars comprising coconut alkyl sulfate and polyethylene glycol |
WO1996023048A1 (en) * | 1995-01-26 | 1996-08-01 | The Procter & Gamble Company | Process for the manufacture of granular detergent compositions comprising nonionic surfactant |
US5858957A (en) * | 1995-01-26 | 1999-01-12 | The Procter & Gamble Company | Process for the manufacture of granular detergent compositions comprising nonionic surfactant |
US6140301A (en) * | 1995-04-27 | 2000-10-31 | The Procter & Gamble Company | Process for producing granular detergent components or compositions |
US6673765B1 (en) * | 1995-05-15 | 2004-01-06 | Ecolab Inc. | Method of making non-caustic solid cleaning compositions |
GB9513327D0 (en) * | 1995-06-30 | 1995-09-06 | Uniliver Plc | Process for the production of a detergent composition |
US5962389A (en) * | 1995-11-17 | 1999-10-05 | The Dial Corporation | Detergent having improved color retention properties |
US5726142A (en) * | 1995-11-17 | 1998-03-10 | The Dial Corp | Detergent having improved properties and method of preparing the detergent |
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US9228157B2 (en) | 2009-04-24 | 2016-01-05 | Conopco, Inc. | Manufacture of high active detergent particles |
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US4162994A (en) * | 1977-11-10 | 1979-07-31 | Lever Brothers Company | Powdered detergent compositions containing a calcium salt of an anionic surfactant |
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US4692271B1 (en) * | 1977-12-09 | 1997-07-22 | Albright & Wilson | Concentrated aqueous surfactant compositions |
US4253993A (en) * | 1978-05-29 | 1981-03-03 | The Procter & Gamble Company | Shampoo in flake form |
JPS5564564A (en) * | 1978-11-10 | 1980-05-15 | Lion Corp | Preparation of highly concentrated aqueous solution or slurry of sulfate salt |
US4487710A (en) * | 1982-03-01 | 1984-12-11 | The Procter & Gamble Company | Granular detergents containing anionic surfactant and ethoxylated surfactant solubility aid |
JPS598800A (ja) * | 1982-07-05 | 1984-01-18 | ライオン株式会社 | カチオン界面活性剤の造粒方法 |
JPS59216619A (ja) * | 1983-05-24 | 1984-12-06 | Lion Corp | カチオン界面活性剤の造粒方法 |
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-
1990
- 1990-05-30 CA CA002017921A patent/CA2017921C/en not_active Expired - Fee Related
- 1990-06-05 AR AR90317029A patent/AR242984A1/es active
- 1990-06-06 DE DE69016504T patent/DE69016504T2/de not_active Expired - Lifetime
- 1990-06-06 DK DK90306137.2T patent/DK0402111T3/da active
- 1990-06-06 AT AT90306137T patent/ATE118031T1/de not_active IP Right Cessation
- 1990-06-06 ES ES90306137T patent/ES2067674T3/es not_active Expired - Lifetime
- 1990-06-06 EP EP90306137A patent/EP0402111B1/en not_active Expired - Lifetime
- 1990-06-07 TR TR90/0557A patent/TR24390A/xx unknown
- 1990-06-07 EG EG33790A patent/EG19506A/xx active
- 1990-06-08 IE IE207590A patent/IE65739B1/en not_active IP Right Cessation
- 1990-06-08 FI FI902875A patent/FI99023C/fi not_active IP Right Cessation
- 1990-06-08 MA MA22137A patent/MA21869A1/fr unknown
- 1990-06-08 BR BR909002721A patent/BR9002721A/pt unknown
- 1990-06-08 MX MX021071A patent/MX170959B/es unknown
- 1990-06-08 PT PT94313A patent/PT94313B/pt not_active IP Right Cessation
- 1990-06-08 PE PE1990170618A patent/PE35490A1/es unknown
- 1990-06-08 NZ NZ233999A patent/NZ233999A/en unknown
- 1990-06-08 AU AU56966/90A patent/AU644074B2/en not_active Ceased
- 1990-06-09 CN CN90104553A patent/CN1027287C/zh not_active Expired - Fee Related
- 1990-06-09 KR KR1019900008445A patent/KR910001026A/ko not_active Application Discontinuation
- 1990-06-11 JP JP2152492A patent/JP2818258B2/ja not_active Expired - Fee Related
- 1990-08-18 SA SA90110027A patent/SA90110027B1/ar unknown
-
1991
- 1991-11-01 US US07/786,649 patent/US5178798A/en not_active Expired - Lifetime
-
1995
- 1995-02-02 GR GR940404110T patent/GR3014947T3/el unknown
Also Published As
Publication number | Publication date |
---|---|
CA2017921A1 (en) | 1990-12-09 |
FI99023C (fi) | 1997-09-25 |
FI902875A0 (fi) | 1990-06-08 |
AU5696690A (en) | 1990-12-13 |
PT94313A (pt) | 1991-02-08 |
MA21869A1 (fr) | 1990-12-31 |
AR242984A1 (es) | 1993-06-30 |
BR9002721A (pt) | 1991-08-20 |
US5178798A (en) | 1993-01-12 |
EP0402111A2 (en) | 1990-12-12 |
ES2067674T3 (es) | 1995-04-01 |
CA2017921C (en) | 1995-05-16 |
EP0402111A3 (en) | 1991-02-20 |
SA90110027B1 (ar) | 2003-01-22 |
AU644074B2 (en) | 1993-12-02 |
CN1048407A (zh) | 1991-01-09 |
GR3014947T3 (en) | 1995-05-31 |
DE69016504D1 (de) | 1995-03-16 |
PT94313B (pt) | 1999-12-31 |
EG19506A (en) | 1995-06-29 |
CN1027287C (zh) | 1995-01-04 |
ATE118031T1 (de) | 1995-02-15 |
DK0402111T3 (da) | 1995-06-26 |
PE35490A1 (es) | 1991-01-16 |
EP0402111B1 (en) | 1995-02-01 |
IE902075L (en) | 1990-12-09 |
DE69016504T2 (de) | 1995-07-13 |
MX170959B (es) | 1993-09-22 |
JP2818258B2 (ja) | 1998-10-30 |
NZ233999A (en) | 1991-12-23 |
IE65739B1 (en) | 1995-11-15 |
TR24390A (tr) | 1991-09-01 |
FI99023B (fi) | 1997-06-13 |
JPH03115400A (ja) | 1991-05-16 |
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