KR900701871A - 사출성형용의 선형 저밀도 에틸렌 인터폴리머 - Google Patents
사출성형용의 선형 저밀도 에틸렌 인터폴리머Info
- Publication number
- KR900701871A KR900701871A KR1019900700055A KR900700055A KR900701871A KR 900701871 A KR900701871 A KR 900701871A KR 1019900700055 A KR1019900700055 A KR 1019900700055A KR 900700055 A KR900700055 A KR 900700055A KR 900701871 A KR900701871 A KR 900701871A
- Authority
- KR
- South Korea
- Prior art keywords
- product
- lldpe
- octene
- ratio
- density
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/02—Ethene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/34—Auxiliary operations
- B29C44/36—Feeding the material to be shaped
- B29C44/38—Feeding the material to be shaped into a closed space, i.e. to make articles of definite length
- B29C44/42—Feeding the material to be shaped into a closed space, i.e. to make articles of definite length using pressure difference, e.g. by injection or by vacuum
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Containers Having Bodies Formed In One Piece (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 고분자량에 대해 경사진 본 발명의 전형적인 동일한 형태의 분자량 분포를 나타낸다, 제2도는 본 발명의 예가 아닌 2가지 형태의 분자량 분포의 예를 나타낸다.
Claims (20)
- 용융된 LLDPE 중합체를 사출성형시킴으로써 벽두께가 O.15내지 1.5mm인 LLDPE 제품이 제조되는, (i)0.91 내지 0.945g/cc 범위의 밀도를 제공하기에 충분한 양의 적어도 하나의 공중합된 C5-C12α-올레핀 함유한 특성 (ii)ASTM D-1238에 의해 측정된 바와 같이 6O내지 200g/1O분 범위의 융용유속을 갖는 특성 (iii)ASTM D-1238으로 측정시, 7.2내지 18의 I10/I2비를 갖는 특성이 조합 함유된 선형 저밀도 폴리에틸렌(LLDPE)의 제조방법
- 제1항에 있어서, LLDPE 중합체가 80내지 200g/1O분의 용융유속을 갖는 방법.
- 제1항에 있어서, LLDPE 중합체가 밀도O.91내지 O.945g/cc를 제공하기에 충분한양의 공중합화된 헥산, 4-메틸펜탄-1, 및/ 또는 옥텐-1을 함유하는 방법.
- 제1항에 있어서, α-올레핀이 옥텐-1을 포함하는 방법.
- 제1항에 있어서, LLDPE가 7.2내지 14의 I10/I2비를 갖는 방법.
- 제1항에 있어서, LLDPE 제품이 용기 및/ 또는 용기용 덮개를 포함하는 방법.
- 제1항에 있어서 LLDPE 제품이 용기용 덮개인 방법.
- 제1항에 있어서, LLDPE 제품이 O.15 내지 lmm의 벽두께인 방법.
- 제1항에 있어서, LLDPE 중합체가 에틸렌/옥텐-1 공중합체이고 (i)옥텐-1이 0.915인 내지 0.94g/cc범위의 밀도를 제공하기에 충분한 양으로 존재하고 (ii)용융유속이 80내지 160g/1O분이며 (iii)I10/I2비가 7.2내지 10인 방법
- 제1항에 있어서, LLDPE중합체가 에틸렌/헥센-1공중합체이고, (i)헥센-1이 O.915 내지 O.94g/cc 범위의 밀도를 제공하기에 충분한 양으로 존재하고 (ii)용융유속이 8O 내지 160g/1O분이며 (iii) I10/I2비가 7.2 내지 1O인 방법.
- 제1항의 방법으로 제조된 사출성형제품.
- 제11항에 있어서, 벽두께가 O.15 내지 1mm범위이고 액체 식용 식물섬유를 사용하여 측정시 LLDPE 중합제의 내환경 옹력 균열성(ESCR)이 100분 이상인 제품.
- 제11항에 있어서, 제품이 용기, 덮개, 또는 용기와 덮개인 제품.
- 제11항에 있이서, LLDPE 중합체의 밀도가 O.91 내지 O.94g/cc인 제품.
- 제11항에 있어서, α-올레핀이 헥센-1, 4-메틸펜텐-1, 및 옥텐-1중 적어도 하나인 제품.
- 제11항에 있어서, α-올레핀이 옥텐-1인 제품.
- 제11항에 있어서, α-올레핀이 핵센-1인 제품.
- 제11항에 있어서, 용융유속이 8O 내지 160인 제품.
- 제11항에 있어서, I10/I2비가 7.2내지 14인 제품.
- 제11항에 있어서, I10/I2비가 7.2내지 10인 제품.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/193,433 US5015511A (en) | 1988-05-12 | 1988-05-12 | Linear low density ethylene interpolymers for injection molding |
US?193,433? | 1988-05-12 | ||
US193,433 | 1988-05-12 | ||
PCT/US1989/002083 WO1989010943A1 (en) | 1988-05-12 | 1989-05-12 | Linear low density ethylene interpolymers for injection molding |
Publications (2)
Publication Number | Publication Date |
---|---|
KR900701871A true KR900701871A (ko) | 1990-12-04 |
KR0137650B1 KR0137650B1 (ko) | 1998-04-30 |
Family
ID=22713618
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019900700055A KR0137650B1 (ko) | 1988-05-12 | 1989-05-12 | 사출형성용의 선형 저밀도 에틸렌 인터폴리머 |
Country Status (10)
Country | Link |
---|---|
US (1) | US5015511A (ko) |
EP (1) | EP0342032B1 (ko) |
JP (1) | JPH02504167A (ko) |
KR (1) | KR0137650B1 (ko) |
AR (1) | AR248033A1 (ko) |
AU (1) | AU609623B2 (ko) |
CA (1) | CA1321694C (ko) |
DE (1) | DE68918985T2 (ko) |
ES (1) | ES2063128T3 (ko) |
WO (1) | WO1989010943A1 (ko) |
Families Citing this family (31)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6025448A (en) | 1989-08-31 | 2000-02-15 | The Dow Chemical Company | Gas phase polymerization of olefins |
MY107639A (en) * | 1990-04-18 | 1996-05-30 | Mitsui Chemicals Incorporated | Process for the preparation of an ethylene copolymer and an olefin polymer, and catalyst for olefin polymeri -zation |
US6538080B1 (en) | 1990-07-03 | 2003-03-25 | Bp Chemicals Limited | Gas phase polymerization of olefins |
JPH0519421A (ja) * | 1991-07-15 | 1993-01-29 | Konica Corp | フイルム収納容器本体 |
US5582923A (en) | 1991-10-15 | 1996-12-10 | The Dow Chemical Company | Extrusion compositions having high drawdown and substantially reduced neck-in |
US5783638A (en) | 1991-10-15 | 1998-07-21 | The Dow Chemical Company | Elastic substantially linear ethylene polymers |
US5525695A (en) | 1991-10-15 | 1996-06-11 | The Dow Chemical Company | Elastic linear interpolymers |
US5674342A (en) | 1991-10-15 | 1997-10-07 | The Dow Chemical Company | High drawdown extrusion composition and process |
US5278272A (en) | 1991-10-15 | 1994-01-11 | The Dow Chemical Company | Elastic substantialy linear olefin polymers |
US5395471A (en) | 1991-10-15 | 1995-03-07 | The Dow Chemical Company | High drawdown extrusion process with greater resistance to draw resonance |
US5346732A (en) * | 1992-08-04 | 1994-09-13 | The Dow Chemical Company | Performance super high flow ethylene polymer compositions |
US5773106A (en) | 1994-10-21 | 1998-06-30 | The Dow Chemical Company | Polyolefin compositions exhibiting heat resistivity, low hexane-extractives and controlled modulus |
KR20000064477A (ko) * | 1995-12-21 | 2000-11-06 | 그래햄 이. 테일러 | 라미네이트의제조방법 |
FR2759085B1 (fr) * | 1997-02-04 | 2002-09-06 | Oreal | Materiau plastique presentant une bonne resistance au stress-cracking et conditionnement constitue de ce materiau |
AUPO617497A0 (en) | 1997-04-14 | 1997-05-08 | Jacobs, Ian Orde Michael | Injection moulding |
JP4620260B2 (ja) * | 1998-04-14 | 2011-01-26 | イアン オード マイケル ヤコブズ | 射出成形法 |
GB0014547D0 (en) * | 2000-06-14 | 2000-08-09 | Borealis Tech Oy | Improvements in or relating to polymers |
US20020107343A1 (en) * | 2001-02-08 | 2002-08-08 | Mitsui Chemicals, Inc. | Ethylene polymer, preparation process thereof and molded articles of the same |
US7396878B2 (en) * | 2002-10-01 | 2008-07-08 | Exxonmobil Chemical Patents Inc. | Polyethylene compositions for injection molding |
DE60331562D1 (ko) * | 2002-10-01 | 2010-04-15 | Exxonmobil Chem Patents Inc | |
US7943700B2 (en) * | 2002-10-01 | 2011-05-17 | Exxonmobil Chemical Patents Inc. | Enhanced ESCR of HDPE resins |
US7396881B2 (en) * | 2002-10-01 | 2008-07-08 | Exxonmobil Chemical Patents Inc. | Polyethylene compositions for rotational molding |
AU2012206982B2 (en) * | 2003-01-16 | 2013-12-05 | Viva Healthcare Packaging Limited | Methods, compositions and blends for forming articles having improved environmental stress crack resistance |
BRPI0406793A (pt) | 2003-01-16 | 2006-02-07 | Ian Orde Michael Jacobs | Processo para a fabricação de artigos de parede fina flexìveis, mistura polimérica, e, uso das nanopartìculas |
DE602004004277T2 (de) * | 2004-11-03 | 2007-05-24 | Borealis Technology Oy | Multimodale Polyethylenzusammensetzung für durch Spritzgussverfahren hergestellte Kappen und Verschlussvorrichtungen |
US7456244B2 (en) * | 2006-05-23 | 2008-11-25 | Dow Global Technologies | High-density polyethylene compositions and method of making the same |
CN101516931B (zh) * | 2006-06-27 | 2015-08-26 | 尤尼威蒂恩技术有限责任公司 | 用于滚塑和注塑制品的以茂金属催化剂制备的聚合物 |
BRPI0713012B1 (pt) | 2006-06-27 | 2018-05-08 | Univation Tech Llc | copolímero de etileno alfa-olefina, composição, artigo obtido através de moldagem rotativa e processo para a produção de um copolímero de etileno alfa-olefina |
RU2446179C2 (ru) | 2006-06-27 | 2012-03-27 | ЮНИВЕЙШН ТЕКНОЛОДЖИЗ, ЭлЭлСи | Усовершенствованные способы полимеризации с использованием металлоценовых катализаторов, полимерные продукты и их применение |
EP2328968B1 (en) | 2008-08-29 | 2017-05-03 | Basell Polyolefine GmbH | Polyethylene for injection moldings |
AR109705A1 (es) | 2016-09-30 | 2019-01-16 | Dow Global Technologies Llc | Composiciones de polietileno de alta procesabilidad para artículos moldeados por inyección |
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US4076698A (en) * | 1956-03-01 | 1978-02-28 | E. I. Du Pont De Nemours And Company | Hydrocarbon interpolymer compositions |
US3703565A (en) * | 1971-02-22 | 1972-11-21 | Dow Chemical Co | Blends of ethylene polymers having improved stress crack resistance |
US4314912A (en) * | 1977-02-03 | 1982-02-09 | The Dow Chemical Company | High efficiency, high temperature catalyst for polymerizing olefins |
US4250288A (en) * | 1977-02-03 | 1981-02-10 | The Dow Chemical Company | High efficiency, high temperature catalyst for polymerizing olefins |
US4192935A (en) * | 1978-01-06 | 1980-03-11 | DuPont of Canada Limited | Ethylene polymers of high melt index |
DE2964517D1 (en) * | 1978-01-06 | 1983-02-24 | Du Pont Canada | Ethylene copolymers with a high melt index and manufacture of containers with these |
US4390677A (en) * | 1978-03-31 | 1983-06-28 | Karol Frederick J | Article molded from ethylene hydrocarbon copolymer |
JPS5846212B2 (ja) * | 1979-05-18 | 1983-10-14 | 旭化成株式会社 | ポリエチレン組成物 |
CA1218181A (en) * | 1983-04-21 | 1987-02-17 | Asahi Kasei Kogyo Kabushiki Kaisha | Polyethylene composition |
US4525322A (en) * | 1983-06-28 | 1985-06-25 | E. I. Du Pont De Nemours And Company | Ethylene polymer composition for blow molding |
JPS60195108A (ja) * | 1984-03-16 | 1985-10-03 | Mitsui Petrochem Ind Ltd | オレフイン重合用チタン触媒成分 |
US4672096A (en) * | 1984-04-04 | 1987-06-09 | Mobil Oil Corporation | Catalyst composition for polymerizing alpha-olefins |
US4593009A (en) * | 1984-04-04 | 1986-06-03 | Mobil Oil Corporation | Catalyst composition for polymerizing alpha-olefins |
IT1176299B (it) * | 1984-06-22 | 1987-08-18 | Anic Spa | Metodo per la preparazione di un catalizzatore a base di zirconio o afnio e processo di polimerizzazione o copolimerizzazione di composti insaturi impiegante lo stesso |
JPS61246209A (ja) * | 1985-04-24 | 1986-11-01 | Mitsubishi Chem Ind Ltd | 射出成形用ポリエチレンの製造方法 |
US4612300A (en) * | 1985-06-06 | 1986-09-16 | The Dow Chemical Company | Novel catalyst for producing relatively narrow molecular weight distribution olefin polymers |
-
1988
- 1988-05-12 US US07/193,433 patent/US5015511A/en not_active Expired - Lifetime
-
1989
- 1989-05-11 CA CA000599483A patent/CA1321694C/en not_active Expired - Fee Related
- 1989-05-11 EP EP89304775A patent/EP0342032B1/en not_active Expired - Lifetime
- 1989-05-11 DE DE68918985T patent/DE68918985T2/de not_active Expired - Fee Related
- 1989-05-11 ES ES89304775T patent/ES2063128T3/es not_active Expired - Lifetime
- 1989-05-12 AR AR89313913A patent/AR248033A1/es active
- 1989-05-12 AU AU37458/89A patent/AU609623B2/en not_active Ceased
- 1989-05-12 WO PCT/US1989/002083 patent/WO1989010943A1/en unknown
- 1989-05-12 KR KR1019900700055A patent/KR0137650B1/ko not_active IP Right Cessation
- 1989-05-12 JP JP1506328A patent/JPH02504167A/ja active Pending
Also Published As
Publication number | Publication date |
---|---|
AR248033A1 (es) | 1995-05-31 |
CA1321694C (en) | 1993-08-31 |
AU609623B2 (en) | 1991-05-02 |
JPH02504167A (ja) | 1990-11-29 |
ES2063128T3 (es) | 1995-01-01 |
EP0342032A3 (en) | 1991-03-20 |
EP0342032B1 (en) | 1994-10-26 |
WO1989010943A1 (en) | 1989-11-16 |
DE68918985D1 (de) | 1994-12-01 |
AU3745889A (en) | 1989-11-29 |
EP0342032A2 (en) | 1989-11-15 |
KR0137650B1 (ko) | 1998-04-30 |
DE68918985T2 (de) | 1995-03-02 |
US5015511A (en) | 1991-05-14 |
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