KR900018046A - 사이클로프로필알킬 또는 사이클로프로필알케닐 화합물, 이들의 제조방법 및 액정 혼합물에서의 용도 - Google Patents
사이클로프로필알킬 또는 사이클로프로필알케닐 화합물, 이들의 제조방법 및 액정 혼합물에서의 용도 Download PDFInfo
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- KR900018046A KR900018046A KR1019900006686A KR900006686A KR900018046A KR 900018046 A KR900018046 A KR 900018046A KR 1019900006686 A KR1019900006686 A KR 1019900006686A KR 900006686 A KR900006686 A KR 900006686A KR 900018046 A KR900018046 A KR 900018046A
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/24—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D213/28—Radicals substituted by singly-bound oxygen or sulphur atoms
- C07D213/30—Oxygen atoms
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
- C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
- C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
- C07D239/26—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C43/00—Ethers; Compounds having groups, groups or groups
- C07C43/02—Ethers
- C07C43/18—Ethers having an ether-oxygen atom bound to a carbon atom of a ring other than a six-membered aromatic ring
- C07C43/184—Ethers having an ether-oxygen atom bound to a carbon atom of a ring other than a six-membered aromatic ring to a carbon atom of a non-condensed ring
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C43/00—Ethers; Compounds having groups, groups or groups
- C07C43/02—Ethers
- C07C43/20—Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring
- C07C43/21—Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring containing rings other than six-membered aromatic rings
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/76—Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring
- C07C69/84—Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring of monocyclic hydroxy carboxylic acids, the hydroxy groups and the carboxyl groups of which are bound to carbon atoms of a six-membered aromatic ring
- C07C69/92—Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring of monocyclic hydroxy carboxylic acids, the hydroxy groups and the carboxyl groups of which are bound to carbon atoms of a six-membered aromatic ring with etherified hydroxyl groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
- C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
- C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
- C07D239/28—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
- C07D239/32—One oxygen, sulfur or nitrogen atom
- C07D239/34—One oxygen atom
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K19/06—Non-steroidal liquid crystal compounds
- C09K19/08—Non-steroidal liquid crystal compounds containing at least two non-condensed rings
- C09K19/30—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing saturated or unsaturated non-aromatic rings, e.g. cyclohexane rings
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K19/06—Non-steroidal liquid crystal compounds
- C09K19/08—Non-steroidal liquid crystal compounds containing at least two non-condensed rings
- C09K19/30—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing saturated or unsaturated non-aromatic rings, e.g. cyclohexane rings
- C09K19/3001—Cyclohexane rings
- C09K19/3066—Cyclohexane rings in which the rings are linked by a chain containing carbon and oxygen atoms, e.g. esters or ethers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K19/06—Non-steroidal liquid crystal compounds
- C09K19/34—Non-steroidal liquid crystal compounds containing at least one heterocyclic ring
- C09K19/3441—Non-steroidal liquid crystal compounds containing at least one heterocyclic ring having nitrogen as hetero atom
- C09K19/3444—Non-steroidal liquid crystal compounds containing at least one heterocyclic ring having nitrogen as hetero atom the heterocyclic ring being a six-membered aromatic ring containing one nitrogen atom, e.g. pyridine
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K19/06—Non-steroidal liquid crystal compounds
- C09K19/34—Non-steroidal liquid crystal compounds containing at least one heterocyclic ring
- C09K19/3441—Non-steroidal liquid crystal compounds containing at least one heterocyclic ring having nitrogen as hetero atom
- C09K19/345—Non-steroidal liquid crystal compounds containing at least one heterocyclic ring having nitrogen as hetero atom the heterocyclic ring being a six-membered aromatic ring containing two nitrogen atoms
- C09K19/3458—Uncondensed pyrimidines
- C09K19/3469—Pyrimidine with a specific end-group other than alkyl, alkoxy or -C*-
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (11)
- 일반식(Ⅰ)의 사이클로프로필알킬 또는 사이클로프로필알케닐 화합물.상기식에서, R1은 탄소수 2 내지 16의 (비대칭 탄소원자가 있거나 없는)직쇄 또는 측쇄 알킬 또는 알케닐(여기에서, 하나 또는 두개의 인접하지 않은 -CH2- 그룹은 -O-, -S-, -CO-, -CO-O-, -O-CO- 또는 -O-CO-O에 의해 치환될 수 있고 H는 F에 의해 치환될 수 있다)이거나 라디칼중의 하나이고, A1, A2및 A3는 동일하거나 상이하고 비치환되거나, 모노-또는 디할로-치환된 1,4-페닐텐, 비치환되거나 1-또는 4-CN-치환된 1,4-사이클로헥실렌, 피라진-2,5-디일, 피리다진-3,6-디일, 피리딘-2,5-디일, 피리미딘-2,5-디일 또는 (1,3,4)-티아디아졸-2,5-디일이며, M1및 M2는 동일하거나 상이하고, CO-O, O-CO, CO-S, S-CO, CH2-O, O-CH2, C=C, CH2-CH2또는 단일 결합이며, G는 탄소수 1 내지 16의 직쇄 또는 측쇄 알킬렌 또는 탄소수 2 내지 16의 알케닐렌 (여기에서, 하나 또는 두개의 인접하지 않는 -CH2- 그룹은 -O-, -S-, -O-CO-, -CO-O-, -S-CO- 또는 -CO-S-에 의하여 치환될 수 있다)이며, R2, R3및 R4은 H이거나 탄소수 1 내지 16의 직쇄 또는 측쇄 알킬 또는 탄소수 2 내지 16의 알케닐(여기에서, 하나의 -CH2- 그룹은 -O-, -CO-O-, 또는 -O-CO-에 의해 치환될 수 있다)이며, k 및 m은 0 또는 1이매, j, ℓ 및 n 0.1 또는 2이다.
- 제1항에 있어서, 일반식(Ⅰ)에서 그룹 (-A1)J(-M1)K(-A2)I(-M2)M(-A3)M-이 하기의 그룹인 화합물.
- 제1항에 있어서, 일반식(Ⅰ)에서 그룹 R1(-A1)J(-M1)K(-A2)I(-M2)M(-A3)M-이 하기의 그룹인 화합물.
- 제1항 내지 3항중 어느 한 항에 있어서, 일반식(Ⅰ)에서, A1, A2및 A3가 동일하거나 상이하고 모노- 또는 디플루오로-치환된 1,4-페닐렌, 비치환된 1,4-페닐렌, 1,4-사이클로헥실렌, 피리딘-2,5-디일 또는 피리미딘-2,5-디일인 화합물.
- 일반식(Ⅱ)의 메소제닉, 일작용성의 반응성 모(母)화합물을 일반식(Ⅲ)의 일작용성이 반응성 사이 클로로프로필알킬 화합물과 반응시킬을 특징으로 하여 제1항 내지 3항중 어느 한 항에 따른 일반식(Ⅰ)의 사이클로프로필알킬 또는 사이클로로프로필알케닐 화합물을 제조하는 방법.R1(-A1)J(-M1)K(-A2)I(-M2)M(-A3)M-X상기식에서, R1,R2,R3,R4,A1,A2,A3,M1,M2,G,k,m,f,ℓ 및 n은 전술한 바와 같고, X는 OH, O-(알칼리금속), COOH 또는 CCO-(알칼리금속)이며, Y는 H,OH,알칼리금속, 할로겐, 톨루엔설포닐옥시 또는 메틸설포닐옥시와 같은, 반응도중에 방출되는 치환체이다.
- 올레핀을 출발물질로 사용하여 시몬스-스미드(Simmons-Smith) 반응에 의해 제1항 내지 3항줄 어느 한항에 따른 일반식(Ⅰ)의 사이클로프로필알킬 또는 사이클로프로필알케닐 화합물을 제조하는 방법.
- 액정 혼합물중의 성분으로서, 제1항 내지 3항중 어느 한 항에 따른 일반식(Ⅰ)의 사이클로프로필알킬 또는 사이클로프로필알케닐 화합물의 용도.
- 제7항에 있어서, 액정 혼합물이 네마틱인 용도.
- 제7항에 있어서, 액정 혼합물이 스메틱, 특히 키랄 스메틱, 바람직하게는 강유전성인 용도.
- 제1항 내지 3항중 어느 한 항에 따른 일반식(Ⅰ)의 사이클로프로필알킬 또는 사이클로프로필알케닐 화합물을 적어도 하나 함유하는 액정 혼합물.
- 제10항에 따른 액정 혼합물을 함유하는 전자광학 성분.※ 참고사항 : 최초출원내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3915804A DE3915804A1 (de) | 1989-05-13 | 1989-05-13 | Cyclopropylalkyl- oder -alkenylverbindungen, verfahren zu ihrer herstellung und ihre verwendung in fluessigkristallinen mischungen |
DEP3915804.7 | 1989-05-13 |
Publications (1)
Publication Number | Publication Date |
---|---|
KR900018046A true KR900018046A (ko) | 1990-12-20 |
Family
ID=6380682
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019900006686A KR900018046A (ko) | 1989-05-13 | 1990-05-11 | 사이클로프로필알킬 또는 사이클로프로필알케닐 화합물, 이들의 제조방법 및 액정 혼합물에서의 용도 |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP0398155B1 (ko) |
JP (1) | JP2753113B2 (ko) |
KR (1) | KR900018046A (ko) |
CA (1) | CA2016632A1 (ko) |
DE (2) | DE3915804A1 (ko) |
NO (1) | NO902111L (ko) |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9923148B2 (en) | 2002-10-30 | 2018-03-20 | Udc Ireland Limited | Electroluminescent device |
KR101027635B1 (ko) | 2002-10-30 | 2011-04-07 | 시바 홀딩 인크 | 전계 발광 디바이스 |
CN104531166B (zh) * | 2014-12-12 | 2016-09-07 | 石家庄诚志永华显示材料有限公司 | 含有环丙基的液晶化合物以及液晶混合物 |
CN104593004B (zh) * | 2015-02-15 | 2017-05-24 | 石家庄诚志永华显示材料有限公司 | 液晶组合物 |
CN104593007B (zh) * | 2015-02-15 | 2017-10-20 | 石家庄诚志永华显示材料有限公司 | 液晶组合物及其应用 |
CN104650925B (zh) * | 2015-02-15 | 2017-10-20 | 石家庄诚志永华显示材料有限公司 | 液晶介质 |
CN104650924B (zh) * | 2015-02-15 | 2017-10-20 | 石家庄诚志永华显示材料有限公司 | 含有环丙基的负介电各向异性液晶介质及其应用 |
CN107267158A (zh) * | 2015-02-15 | 2017-10-20 | 石家庄诚志永华显示材料有限公司 | 含有环丙基的负介电各向异性液晶介质及其应用 |
CN107286951B (zh) * | 2016-04-01 | 2019-01-29 | 北京八亿时空液晶科技股份有限公司 | 一种环丙基类负介电各向异性的液晶化合物及其应用 |
CN107286952B (zh) * | 2016-04-01 | 2019-01-29 | 北京八亿时空液晶科技股份有限公司 | 一种环丙基类负介电各向异性的液晶化合物及其应用 |
CN107345142B (zh) * | 2016-05-06 | 2020-02-21 | 北京八亿时空液晶科技股份有限公司 | 一种含有萘环的负介电各向异性液晶组合物及其应用 |
CN107400516B (zh) * | 2016-05-19 | 2019-01-29 | 北京八亿时空液晶科技股份有限公司 | 一种环丙基类负介电各向异性的液晶化合物及其应用 |
CN106010579B (zh) * | 2016-05-23 | 2019-01-04 | 石家庄诚志永华显示材料有限公司 | 一种液晶组合物 |
CN107446592B (zh) * | 2016-05-31 | 2019-08-27 | 北京八亿时空液晶科技股份有限公司 | 一种含有环丙基化合物的液晶组合物及其应用 |
CN107446593A (zh) * | 2016-06-01 | 2017-12-08 | 北京八亿时空液晶科技股份有限公司 | 一种含有环丙基和甲氧基的化合物的液晶组合物及其应用 |
CN107523314B (zh) * | 2016-06-20 | 2019-09-20 | 北京八亿时空液晶科技股份有限公司 | 一种含有环丙基醚类负介电液晶组合物及其应用 |
CN107586545B (zh) * | 2016-07-06 | 2019-08-23 | 北京八亿时空液晶科技股份有限公司 | 一种快响应负介电各向异性液晶组合物及其应用 |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3782531T2 (de) * | 1986-04-21 | 1993-05-06 | Ajinomoto Kk | Optisch aktive verbindung und fluessigkristalline zusammensetzung. |
CN1022409C (zh) * | 1987-11-25 | 1993-10-13 | 赫彻斯特股份公司 | 液晶环丙基烷基杂环化合物制备方法 |
-
1989
- 1989-05-13 DE DE3915804A patent/DE3915804A1/de not_active Withdrawn
-
1990
- 1990-05-10 DE DE59010108T patent/DE59010108D1/de not_active Expired - Lifetime
- 1990-05-10 EP EP90108802A patent/EP0398155B1/de not_active Expired - Lifetime
- 1990-05-11 CA CA002016632A patent/CA2016632A1/en not_active Abandoned
- 1990-05-11 KR KR1019900006686A patent/KR900018046A/ko not_active Application Discontinuation
- 1990-05-11 NO NO90902111A patent/NO902111L/no unknown
- 1990-05-14 JP JP2123960A patent/JP2753113B2/ja not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
NO902111D0 (no) | 1990-05-11 |
NO902111L (no) | 1990-11-14 |
EP0398155A2 (de) | 1990-11-22 |
CA2016632A1 (en) | 1990-11-13 |
EP0398155B1 (de) | 1996-02-07 |
EP0398155A3 (de) | 1992-02-26 |
DE59010108D1 (de) | 1996-03-21 |
JP2753113B2 (ja) | 1998-05-18 |
DE3915804A1 (de) | 1990-11-15 |
JPH03115241A (ja) | 1991-05-16 |
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