KR900004855A - 무전해도금에 적합한 난연성 폴리페닐렌 에테르 수지 조성물 및 도금물품 - Google Patents

무전해도금에 적합한 난연성 폴리페닐렌 에테르 수지 조성물 및 도금물품 Download PDF

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KR900004855A
KR900004855A KR1019890012963A KR890012963A KR900004855A KR 900004855 A KR900004855 A KR 900004855A KR 1019890012963 A KR1019890012963 A KR 1019890012963A KR 890012963 A KR890012963 A KR 890012963A KR 900004855 A KR900004855 A KR 900004855A
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KR930003693B1 (ko
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쥬로 오오세끼
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에리 마사요시
아사히가세이고오교 가부시끼가이샤
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • C08L71/08—Polyethers derived from hydroxy compounds or from their metallic derivatives
    • C08L71/10—Polyethers derived from hydroxy compounds or from their metallic derivatives from phenols
    • C08L71/12—Polyphenylene oxides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • C08L71/08—Polyethers derived from hydroxy compounds or from their metallic derivatives
    • C08L71/10—Polyethers derived from hydroxy compounds or from their metallic derivatives from phenols
    • C08L71/12—Polyphenylene oxides
    • C08L71/123—Polyphenylene oxides not modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
    • C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S525/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S525/905—Polyphenylene oxide
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31511—Of epoxy ether
    • Y10T428/31529—Next to metal
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31678—Of metal
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31678—Of metal
    • Y10T428/31692—Next to addition polymer from unsaturated monomers
    • Y10T428/31699—Ester, halide or nitrile of addition polymer

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  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Chemically Coating (AREA)

Abstract

내용 없음

Description

무전해도금에 적합한 난연성 폴리페닐렌 에틸렌 수지 조성물 및 도금물품
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. 하기 성분(A)~(E)로 구성된 무전해 도금에 적합한 난연성 폴리페닐렌 에테르수지 조성물. (A) 성분(A),(B) 및 (C)의 전체 중량을 기준으로 10~60중량%의 폴리페닐렌에테르 수지; (B) 성분(A),(B) 및 (C)의 전체 중량을 기준으로, 아크릴로 니트릴 단위 및 비닐 방향족 화합물 단위로 구성된 그래프트 성분이 그래프트되어 있는 엘라스토머성 고무로 구성된 그래프트화 고수상(α), 및 아크릴로니트릴 단위 및 비닐 방향족 화합물 단위를 포함하는 중합체 또는 중합체 혼합물의 수지상(β)로 구성되어 있는 10~90중량%의 고무-변성수지; 전술한 그래프트화 고무상(α)는 엘라스토머성 고무에 그래프트된 전술한 그래프트 성분 대 전술한 엘라스토머성 고무의 비(%)의 정의되는 바인 그래프트도가 40~300%이고; 전술한 그래프트 성분중의 아크릴로니트릴의 함량 및 수지상(β)중의 아크릴로니트릴의 함량은 각각 10~30중량% 및 3~9중량%이고, 고무-변성 수지(B)중의 모든 아크릴로니트릴의 양은 성분 (A), (B) 및 (C)의 전체 중량을 기준으로 1~7중량%이고, 전술한 엘라스토머성 고무의 양은 성분 (A), (B) 및 (C)의 전체중량을 기준으로 5~20중량%이고; (C) 성분 (A),(B) 및 (C)의 전체 중량을 기준으로 0~80중량%의 폴리스티렌 수지; (D) 성분 (A),(B) 및 (C)의 전체의 100중량부당 1~4 중량부의 적인; 및 (E) 성분 (A),(B) 및 (C)의 전체의 100중량부당 1~12중량부의 인산 에스테르.
  2. 제1항에 있어서, 성분 (A),(B) 및 (C)의 양은 성분(A),(B) 및 (C)의 전체 중량을 기준으로 각각 20~40중량%, 15~70중량% 및 0~65중량%이고;고무-변성수지(B)중의 모든 아크릴로니트릴 단위의 양은 성분(A),(B) 및 (C)의 전체 중량을 기준으로 1~5중량%이고; 전술한 엘라스토머성 고무의 양은 성분 (A),(B) 및 (C)의 전체 중량을 기준으로 1~5중량%이고; 전술한 엘라스토머성 고무의 양은 성분(A),(B) 및 (C)의 전체 중량을 기준으로 5~15중량%이고; 및 적인(D) 및 인산 에스테르(E)의 양은 성분(A),(B) 및 (C)의 전체의 100중량부당 각각 1.5~3.5중량부 및 3~10중량부인 조성물.
  3. 제1항에 있어서, 성분(A)는 폴리(2,6-디메틸-1,4-페닐렌)에테르, 2,6-디메틸페놀과 2,3,6-트리메틸페놀의 공중합체, 및 이들의 혼합물로 구성된 군에서 선택되는 폴리페닐렌 에테르수지인 조성물.
  4. 제1~3항중 어느 한항에 있어서, 성분(B)의 그래프트화고무상(α) 및 수지상(β)의 각각의 비닐 방향족 화합물은 스티렌인 조성물.
  5. 제1~3항중 어느 한항에 있어서, 성분(C)는 폴리스티렌, 고충격 폴리스티렌 및 이들의 혼합물로 구성된 군에서 선택된 폴리스티렌 수지인 조성물.
  6. 제1~3항중 어느 한항에 있어서, 전술한 성분(D)의 인산 에스테르는 방향족 인산 에스테르임을 특징으로 하는 조성물.
  7. 제1~3항중 어느 한항에 있어서, 두께 3.2mm의 샘플로 시험하였을때, 버어티칼 버닝 테스트(Vertical Burning Test)의 UL-94표준에 정의된 V-0등급의 가연성 및 글로잉(glowing)특성을 가지는 조성물.
  8. 제1~3항중 어느 한항에 있어서, 두께 1.6mm의 샘플로 시험하였을때, 버어티칼 버닝 테스트(Vertical Burning Test)의 UL-94표준에 정의된 V-0등급 또는 V-1등급의 가연성 및 글로잉(glowing)특성을 가지는 조성물.
  9. 제1,2 또는 3항에 있어서, 형상품인 조성물.
  10. 제9항에 있어서, 무전해 도금에 의해 형성된 도금을 그 위에 가지는 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890012963A 1988-09-07 1989-09-07 무전해도금에 적합한 난연성 폴리페닐렌 에테르 수지 조성물 및 도금물품 KR930003693B1 (ko)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
JP222518 1988-09-07
JP63222519A JPH0270742A (ja) 1988-09-07 1988-09-07 難燃樹脂組成物
JP222519 1988-09-07
JP63-222518 1988-09-07
JP22251888 1988-09-07
JP63-222519 1988-09-07

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KR900004855A true KR900004855A (ko) 1990-04-13
KR930003693B1 KR930003693B1 (ko) 1993-05-08

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US (1) US4966814A (ko)
EP (1) EP0359469B1 (ko)
KR (1) KR930003693B1 (ko)
CN (1) CN1026704C (ko)
CA (1) CA1334695C (ko)
DE (1) DE68924748T2 (ko)

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KR100453648B1 (ko) * 2000-02-18 2004-10-20 제일모직주식회사 난연성 고무강화 폴리스티렌 수지 조성물
KR100511054B1 (ko) * 2000-05-29 2005-08-31 제일모직주식회사 열가소성 수지 조성물

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EP1497365B1 (en) * 2002-04-16 2011-06-08 Cheil Industries Inc. Thermoplastic flame retardant resin compositions
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KR100511054B1 (ko) * 2000-05-29 2005-08-31 제일모직주식회사 열가소성 수지 조성물

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EP0359469B1 (en) 1995-11-08
DE68924748T2 (de) 1996-07-04
EP0359469A2 (en) 1990-03-21
CN1042371A (zh) 1990-05-23
US4966814A (en) 1990-10-30
EP0359469A3 (en) 1991-12-11
CA1334695C (en) 1995-03-07
KR930003693B1 (ko) 1993-05-08
CN1026704C (zh) 1994-11-23
DE68924748D1 (de) 1995-12-14

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