KR900000699A - 이온크로마토그라피용 이온교환조성물 및 이를 채운 크로마토그라프관 - Google Patents

이온크로마토그라피용 이온교환조성물 및 이를 채운 크로마토그라프관 Download PDF

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KR900000699A
KR900000699A KR1019890007735A KR890007735A KR900000699A KR 900000699 A KR900000699 A KR 900000699A KR 1019890007735 A KR1019890007735 A KR 1019890007735A KR 890007735 A KR890007735 A KR 890007735A KR 900000699 A KR900000699 A KR 900000699A
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ion exchange
exchange composition
particles
monomer
derived
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오토 나플 죤
엠. 워스 린다
에스 프리쯔 제임스
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윌리엄. 이 렘베르트 3세
롬 앤드 하스 캄파니
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Abstract

내용 없음

Description

이온크로마토그라피용 이온교환조성물 및 이를 채운 크로마토그라프관
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 본 발명과 관련하여 이온교환용량과 NaCl 농도의 관계를 나타내는 그래프,
제2도 내지 제3도는 본 발명의 이온교환 조성물로된 관층전물(column packing)을 통하여 음이온 혼합물을 용리시킬 때 얻어지는 크로마토그람이다.

Claims (20)

  1. 평균입자크기가 약 2-50미크론이며 분질적으로 이온교환 용량을 갖지 않은 물불용성 소수성 지지입자 및 상기 지지입자의 표면에 소수결합되며, 평균입자크기가 상기 지지입자의 크기보다 작으며 약 0.01-10미크론 범위며, 물불용성 소수성 이온교환 관능화된 입자로 된, 코팅제를 포함하는 복합 이온교환 조성물.
  2. 1항에 있어서, 상기 지지입자는 유기 혹은 무기물질에서 선택되고 상기 표면입자는 수지라텍스에서 유도됨을 특징으로 하는 이온교환 조성물.
  3. 1항에 있어서, 상기 지지입자는 단순분산 수지라텍스에서 유도되며 상기 표면입자는 스티렌 혹은 아크릴 수지 라텍스에서 유도됨을 특징으로 하는 이온교환 조성물.
  4. 1항에 있어서, 상기 지지입자는 평균입자크기가 약 3-12미크론인 수지라텍스에서 유도되며, 상기 표면입자는 평균입자크기가 약 0.05-1.2미크론인 수지라텍스에서 유도됨을 특징으로 하는 이온교환 조성물.
  5. 1항에 있어서, 상기 지지입자 겔상(gelular) 혹은 큰 그물상 수지를 포함하며, 상기 표면입자는 하나 혹은 그 이상의 모노에틸렌계 불포화 단량체 및 이에 대한 교차결합단량체의 라텍스에서 유도됨을 특징으로 하는 이온교환 조성물.
  6. 5항에 있어서, 상기 모노에틸렌계 불포화 단량체는 비닐방향족, 단량체, 아크릴 단량체 혹은 그 혼합물에서 선택됨을 특징으로 하는 이온교환 조성물.
  7. 5항에 있어서, 상기 모노에틸렌계 불포화 단량체는 스티렌 단량체 이며, 교차결합 단량체는 디비닐벤젠임을 특징으로 하는 이온교환 조성물.
  8. 5항에 있어서, 상기 모노에틸렌계 불포화 단량체는 아크릴 단량체이며, 상기 교차결합단량체는 디비닐벤젠임을 특징으로 하는 이온교환 조성물.
  9. 5항에 있어서, 상기 표면입자를 포함하는 라텍스는 스티렌계 단량체, 아크릴 단량체 및 디비닐벤젠의 혼합물에서 유도됨을 특징으로 하는 이온교환 조성물.
  10. 9항에 있어서, 상기 스틸렌 단량체는 스틸렌이며, 아크릴 단량체는 디메틸 아미노에틸 메타크릴레이트임을 특징으로 하는 이온교환 조성물.
  11. 1항에 있어서, 상기 지지입자는, 초기단계 중합물(polymerizarte)이 1 혹은 그 이상의 에틸렌계 불포화 단량체를 에멀션 중합시킴으로써 제조된 종자(seed) 입자를 포함하며, 하나 혹은 그 이상의 연속단계는 상기 초기단계의 종자입자의 존재하에 하나 혹은 그 이상의 에틸렌계 불포화 단량체를 중합시킴으로써 제조되는 입자를 포함하는 연쇄중합에 의한 다단계 수지 라텍스로부터 유도됨을 특징으로 하는 이온교환 조성물.
  12. 11항에 있어서, 상기 초기단계 단량체는 스티렌계 단량체, 아크릴 단량체 혹은 그 혼합물로부터 선택됨을 특징으로 하는 이온교환 조성물.
  13. 청구범위 1항의 복합 이온교환 조성물을 채운 튜브형 본체를 포함하는 크로마토그라프관(chromatographic column).
  14. 청구범위 2항의 복합 이온교환 조성물을 채운 튜브형 본체를 포함하는 크로마토그라프관.
  15. 청구범위 3항의 복합 이온교환 조성물을 채운 튜브형 본체를 포함하는 크로마토그라프관.
  16. 청구범위 4항의 복합 이온교환 조성물을 채운 튜브형 본체를 포함하는 크로마토그라프관.
  17. 청구범위 6항의 복합 이온교환 조성물을 채운 튜브형 본체를 포함하는 크로마토그라프관.
  18. 청구범위 9항의 복합 이온교환 조성물을 채운 튜브형 본체를 포함하는 크로마토그라프관.
  19. 청구범위 10항의 복합 이온교환 조성물을 채운 튜브형 본체를 포함하는 크로마토그라프관.
  20. 청구범위 11항의 복합 이온교환 조성물을 채운 튜브형 본체를 포함하는 크로마토그라프관.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890007735A 1988-06-07 1989-06-05 이온 크로마토그라피용 이온교환조성물 및 이를 채운 크로마토그라프관 KR0140099B1 (ko)

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WO1992009889A1 (fr) * 1990-11-21 1992-06-11 Sekisui Kagaku Kogyo Kabushiki Kaisha Procede de preparation d'un porteur pour la chromatographie liquide a echange de cations, et procede de determination quantitative de l'hemoglobine saccharifiee a l'aide dudit porteur
US5292818A (en) * 1982-07-20 1994-03-08 Sekisui Kagaku Kogyo Kabushiki Kaisha Method for producing a carrier for cation exchange liquid chromatography and a method for determining glycosylated hemoglobins using the carrier
DE69022250D1 (de) * 1990-11-21 1995-10-12 Sekisui Chemical Co Ltd Verfahren zur herstellung von trägern für die kationenaustausch-flüssigchromatographie sowie verfahren zur quantitativen bestimmung von glucose-hämoglobin unter benutzung dieses trägers.
AU639959B2 (en) * 1990-11-21 1993-08-12 Sekisui Kagaku Kogyo Kabushiki Kaisha Process for preparing carrier for cation exchange liquid chromatography and method of quantitatively determining saccharified hemoglobin using said carrier
DE4038109C2 (de) * 1990-11-29 1994-07-07 Fraunhofer Ges Forschung Verfahren zur Herstellung von Formkörpern mit poröser Oberfläche und enger Oberflächenporenradienverteilung, nach dem Verfahren hergestellte Formkörper und Verwendung dieser Formkörper
US5652059A (en) * 1991-11-20 1997-07-29 Bar Ilan University Method for attaching microspheres to a substrate
IL100105A (en) * 1991-11-20 1996-01-19 Univ Bar Ilan Supported microspheres
EP0758261B1 (en) * 1994-05-05 1998-08-26 Minnesota Mining And Manufacturing Company Chemically modified solid phase extraction particles and articles containing same
JP6251978B2 (ja) * 2013-01-25 2017-12-27 日立化成株式会社 カラム用コアシェル型粒子及びその製造方法
CN103197022A (zh) * 2013-04-25 2013-07-10 山西省食品质量安全监督检验研究所 一种检测食醋中所含氨基酸的方法
US11988649B2 (en) * 2020-10-06 2024-05-21 Board Of Regents, The University Of Texas System On-line suppressor

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US4383047A (en) * 1981-02-17 1983-05-10 The Dow Chemical Company High performance anion-exchange chromatographic packing composition
AU7976082A (en) * 1981-02-17 1982-08-26 Dionex Corporation Analytical column for anion determination
US4376047A (en) * 1981-06-18 1983-03-08 Dionex Corporation Coated resin ion exchange composition
JPS5820235A (ja) * 1981-07-30 1983-02-05 Yokogawa Hokushin Electric Corp イオン交換クロマトグラフ用イオン交換体及びその作製方法
AU3097084A (en) * 1983-08-12 1985-02-14 Dionex Corporation Coated cation exchange resin
JPS6354948A (ja) * 1986-08-25 1988-03-09 Yokogawa Electric Corp 陽イオン交換樹脂の製造方法
JPS63126548A (ja) * 1986-11-14 1988-05-30 Koken Co Ltd 吸着剤

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JPH0285758A (ja) 1990-03-27
KR0140099B1 (ko) 1998-06-01
DE68900216D1 (de) 1991-09-26
NZ229430A (en) 1992-03-26
EP0346037B1 (en) 1991-08-21
ES2024710B3 (es) 1992-03-01
AU3603789A (en) 1989-12-14
SG94391G (en) 1992-01-17
CA1336973C (en) 1995-09-12
EP0346037A1 (en) 1989-12-13
AU605986B2 (en) 1991-01-24

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