KR890701519A - 하이드록시 방향족 화합물의 프로파르길 에테르를 제조하는 방법 - Google Patents

하이드록시 방향족 화합물의 프로파르길 에테르를 제조하는 방법

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Publication number
KR890701519A
KR890701519A KR1019890700179A KR890700179A KR890701519A KR 890701519 A KR890701519 A KR 890701519A KR 1019890700179 A KR1019890700179 A KR 1019890700179A KR 890700179 A KR890700179 A KR 890700179A KR 890701519 A KR890701519 A KR 890701519A
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KR
South Korea
Prior art keywords
propargyl
hydroxyaromatic compound
general formula
halide
ether
Prior art date
Application number
KR1019890700179A
Other languages
English (en)
Other versions
KR910003821B1 (ko
Inventor
엔.엔베이즈카렌 뮤티아
케이. 더리코브 스토일
Original Assignee
리차드 지.워터맨
더 다우 케미칼 캄파니
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Publication of KR890701519A publication Critical patent/KR890701519A/ko
Application granted granted Critical
Publication of KR910003821B1 publication Critical patent/KR910003821B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C317/00—Sulfones; Sulfoxides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/16—Preparation of ethers by reaction of esters of mineral or organic acids with hydroxy or O-metal groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C07C43/02—Ethers
    • C07C43/20—Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C45/70—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction with functional groups containing oxygen only in singly bound form
    • C07C45/71—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction with functional groups containing oxygen only in singly bound form being hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/76—Ketones containing a keto group bound to a six-membered aromatic ring
    • C07C49/84—Ketones containing a keto group bound to a six-membered aromatic ring containing ether groups, groups, groups, or groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2603/00—Systems containing at least three condensed rings
    • C07C2603/56—Ring systems containing bridged rings
    • C07C2603/58—Ring systems containing bridged rings containing three rings
    • C07C2603/60—Ring systems containing bridged rings containing three rings containing at least one ring with less than six members
    • C07C2603/66—Ring systems containing bridged rings containing three rings containing at least one ring with less than six members containing five-membered rings

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
  • Steroid Compounds (AREA)

Abstract

내용 없음

Description

하이드록시 방향족 화합물의 프로파르길 에테르를 제조하는 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. 하이드록시방향족 화합물의 프로파르길 에테르를 제조하기에 충분한 반응 조건하에, 상 전이 촉매의 존재하 알카리성 시약의 수용액중에서, 하이드록시방향족 화합물을 프로파르길 할라이드와 접촉시킴을 특징으로 하여, 하이드록시방향족 화합물의 프로파르길 에테르를 제조하는 방법.
  2. 제 1 항에 있어서, 반응을 대기압하에, 0℃ 내지 100℃의 온도에서 수행하는 방법.
  3. 제 1 항에 있어서, 프로파르길 할라이드가 하기 일반식(Ⅶ)으로 나타나며, 상 전이 촉매가 하기 일반식(Ⅷ)의 4급 암모늄, 포스포늄 또는 아르소늄염 ; 분자량이 200 내지 50,000인 일반식 H(OCH2CH2)nOH의 폴리(에틸렌 글리콜) ; 분자량이 200 내지 50,000인 일반식(X)의 폴리(에틸렌 글리콜 알킬 에테르) ; 크라운 에테르 ; 및 크립테이트 중에서 선택되는 방법.
    상기식에서, Hal은 염소, 브롬 또는 요오드이고, Z는 4가의 암모늄, 포스포늄 또는 아르보늄 이온이고, Y는 적합한 모든 짝이온이며, R1,R2,R3및 R4는 독립적으로 탄소수 1 내지 50의 방향족 또는 알칼방향족 잔기이고, R은 탄소수 1 내지 50의 알킬 그룹이다.
  4. 제 1 항에 있어서, 0.001 내지 0.01몰 당량의 상 전이 촉매가 하이드록시방향족 화합물의 각 몰 당량당 사용하는 방법.
  5. 제 1 항에 있어서, 1 내지 1.5몰 당량의 프로파르길 할라이드가 하이드록시방향족 화합물의 각 하이드록실 당량당 사용되는 방법.
  6. 제 1 항에 있어서, 1 내지 10몰 당량의 알카리 시약이 하이드록시방향족 화합물의 각 몰 당량당 사용되는 방법.
  7. 제 1 항에 있어서, 알칼리성 시약이 수산화 나트륨, 수산화 칼륨, 수산화 리튬 또는 이들의 혼합물인 방법.
  8. 제 1 항에 있어서, 프로파르길 할라이드가 프로파르길 클로라이드 또는 프로파르길 브로마이드인 방법.
  9. 제 1 항에 있어서, 상 전의 촉매가 중합체 지지체에 결합되는 방법.
  10. 제 1 항에 있어서, 형성된 하이드록시 방향족 화합물의 고체 프로파르길 에테르를 용액으로부터 여과하고 이 고체 생성물을 몰 및 이소프로판올로 세척하여 95% 이상의 순도를 갖는 이론치 수율 85 내지 97%의 생성물을 회수함을 추가의 특징으로 하느 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890700179A 1987-06-01 1988-05-25 하이드록시방향족 화합물의 프로파르길 에테르를 제조하는 방법 KR910003821B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US5619087A 1987-06-01 1987-06-01
PCT/US1988/001734 WO1988009782A1 (en) 1987-06-01 1988-05-25 Process for making propargyl ethers of hydroxyaromatic compounds
US056,190 1993-05-03

Publications (2)

Publication Number Publication Date
KR890701519A true KR890701519A (ko) 1989-12-20
KR910003821B1 KR910003821B1 (ko) 1991-06-12

Family

ID=22002778

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019890700179A KR910003821B1 (ko) 1987-06-01 1988-05-25 하이드록시방향족 화합물의 프로파르길 에테르를 제조하는 방법

Country Status (14)

Country Link
US (1) US4885403A (ko)
EP (1) EP0293768B1 (ko)
JP (1) JPH01503541A (ko)
KR (1) KR910003821B1 (ko)
AT (1) ATE74344T1 (ko)
AU (1) AU605331B2 (ko)
BR (1) BR8807088A (ko)
CA (1) CA1318688C (ko)
DE (1) DE3869661D1 (ko)
ES (1) ES2030106T3 (ko)
IL (1) IL86547A0 (ko)
NO (1) NO890404L (ko)
WO (1) WO1988009782A1 (ko)
ZA (1) ZA883880B (ko)

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FR2772372B1 (fr) * 1997-12-15 2000-05-19 Rhodia Chimie Sa Procede de o-alkylation de composes aromatiques hydroxyles
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Also Published As

Publication number Publication date
NO890404D0 (no) 1989-01-31
EP0293768A1 (en) 1988-12-07
ES2030106T3 (es) 1992-10-16
CA1318688C (en) 1993-06-01
KR910003821B1 (ko) 1991-06-12
JPH01503541A (ja) 1989-11-30
BR8807088A (pt) 1989-10-17
EP0293768B1 (en) 1992-04-01
US4885403A (en) 1989-12-05
WO1988009782A1 (en) 1988-12-15
IL86547A0 (en) 1988-11-15
AU1936688A (en) 1989-01-04
AU605331B2 (en) 1991-01-10
NO890404L (no) 1989-01-31
ATE74344T1 (de) 1992-04-15
ZA883880B (en) 1990-02-28
DE3869661D1 (de) 1992-05-07

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