KR890017218A - 비스페놀의 제조 방법 - Google Patents
비스페놀의 제조 방법 Download PDFInfo
- Publication number
- KR890017218A KR890017218A KR1019890006270A KR890006270A KR890017218A KR 890017218 A KR890017218 A KR 890017218A KR 1019890006270 A KR1019890006270 A KR 1019890006270A KR 890006270 A KR890006270 A KR 890006270A KR 890017218 A KR890017218 A KR 890017218A
- Authority
- KR
- South Korea
- Prior art keywords
- resin
- mercaptan
- phenol
- catalyst
- reactor
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C39/00—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring
- C07C39/12—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring polycyclic with no unsaturation outside the aromatic rings
- C07C39/15—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring polycyclic with no unsaturation outside the aromatic rings with all hydroxy groups on non-condensed rings, e.g. phenylphenol
- C07C39/16—Bis-(hydroxyphenyl) alkanes; Tris-(hydroxyphenyl)alkanes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/11—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms
- C07C37/20—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms using aldehydes or ketones
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (8)
- 페놀 전부와 메르캅탄의 일부가 반응기 또는 첫번째 반응기 내로 주입되고 나머지 메르캅탄이 반응기 길이를 따라 또는 연이온 반응기들내에 주입되는 반응기 또는 일련의 반응기 내에서 양이온 교환 수지 촉매와 메르캅탄 조-촉매의 존재하에 페놀과 케톤을 반응시키는 것을 포함하는 비스페놀의 제조 방법.
- 제 1 항에 있어서, 조-촉매가 알킬 메르캅탄인 방법.
- 제 2 항에 있어서, 조 촉매가 메틸 메르캅탄 또는 n-펜틸 메르캅탄인 방법.
- 제 1 항 내지 제 3 항중 어느 한 항에 있어서, 산이 산성 양이온 교환 수지인 방법.
- 제 4 항에 있어서, 수지가 술폰화된 스티렌-디비닐벤젠 공중합체, 술폰화된 가교 결합된 스티렌중합체, 페놀-포름알데히드-술폰산 수지 및 벤젠-포름알데히드-술폰산 수지로 부터 선택되는 방법.
- 제 5 항에 있어서, 수지가 마크로 공질 수지(macroreticulat resin)인 방법.
- 제 5 항에 있어서, 수지가 마이크로 공질 수지(microreticular resin) 인 방법.
- 제 1 내지 제 7 중 어느 한 항에 있어서, 페놀이 아세톤과 반응하는 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL194659 | 1988-05-16 | ||
US07/194,659 US4859803A (en) | 1988-05-16 | 1988-05-16 | Preparation of bisphenols |
Publications (2)
Publication Number | Publication Date |
---|---|
KR890017218A true KR890017218A (ko) | 1989-12-15 |
KR0138910B1 KR0138910B1 (ko) | 1998-05-01 |
Family
ID=22718424
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019890006270A KR0138910B1 (ko) | 1988-05-16 | 1989-05-10 | 비스 페놀의 제조 방법 |
Country Status (6)
Country | Link |
---|---|
US (1) | US4859803A (ko) |
EP (1) | EP0342758B1 (ko) |
JP (1) | JP2779952B2 (ko) |
KR (1) | KR0138910B1 (ko) |
CA (1) | CA1320216C (ko) |
DE (1) | DE68922524T2 (ko) |
Families Citing this family (42)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4227520A1 (de) * | 1992-08-20 | 1994-02-24 | Bayer Ag | Verfahren zur Herstellung von Bisphenolen |
US5315042A (en) * | 1993-03-22 | 1994-05-24 | General Electric Company | Use of partial acetone conversion for capacity increase and quality/yield improvement in the bisphenol-A reaction |
TW419458B (en) * | 1994-07-21 | 2001-01-21 | Mitsui Chemicals Inc | Process for preparing bisphenol A |
US5463140A (en) * | 1994-08-31 | 1995-10-31 | The Dow Chemical Company | Process for making polyphenols from ketones or aldehydes and phenols |
CN1137788A (zh) * | 1994-08-31 | 1996-12-11 | 陶氏化学公司 | 由酮或醛和酚制备多酚的方法 |
DE19526088A1 (de) * | 1995-07-18 | 1997-01-23 | Bayer Ag | Verfahren zur Herstellung von Bis(4-hydroxyaryl)alkanen |
DE19701278A1 (de) | 1997-01-16 | 1998-07-23 | Bayer Ag | Verfahren zur Herstellung von Bis-(4-hydroxyaryl)-alkanen |
DE19720541A1 (de) | 1997-05-16 | 1998-11-19 | Bayer Ag | Verfahren zur kontinuierlichen Herstellung von Dihydroxydiphenylalkanen |
DE19720540A1 (de) | 1997-05-16 | 1998-11-19 | Bayer Ag | Verfahren zur Aufarbeitung von Mutterlaugen aus der Bisphenolsynthese |
DE19720539A1 (de) | 1997-05-16 | 1998-11-19 | Bayer Ag | Verfahren zur kontinuierlichen Herstellung von Dihydroxydiarylalkanen |
DE19756771A1 (de) | 1997-12-19 | 1999-06-24 | Bayer Ag | Verfahren zur Herstellung von Bis(4-hydroxyaryl)alkanen |
US6133190A (en) * | 1998-04-27 | 2000-10-17 | The Dow Chemical Company | Supported mercaptosulfonic acid compounds useful as catalysts for phenolation reactions |
DE19840110C1 (de) | 1998-09-03 | 2000-02-17 | Bayer Ag | Verfahren zur Herstellung von Bis(4-hydroxyaryl)alkanen |
DE19848026A1 (de) | 1998-10-17 | 2000-04-20 | Bayer Ag | Verfahren zur Herstellung von Bis(4-hydroxyaryl)alkanen |
JP4093655B2 (ja) * | 1998-10-22 | 2008-06-04 | 出光興産株式会社 | ビスフェノールaの製造法 |
DE19860144C1 (de) * | 1998-12-24 | 2000-09-14 | Bayer Ag | Verfahren zur Herstellung von Bisphenol A |
TW530045B (en) * | 1999-04-13 | 2003-05-01 | Idemitsu Petrochemical Co | Method of producing bisphenol A |
DE19962530A1 (de) | 1999-12-23 | 2001-07-05 | Bayer Ag | Fluidisierter Bisphenol-Staub |
US6429343B1 (en) | 2000-01-07 | 2002-08-06 | Idemitsu Petrochemical Co., Ltd. | Process for producing bisphenol a |
DE10015014A1 (de) * | 2000-03-27 | 2001-10-04 | Bayer Ag | Verfahren zur Herstellung von Bisphenolen |
DE10015864A1 (de) | 2000-03-30 | 2001-10-11 | Bayer Ag | Stoffgemisch enthaltend Bisphenol A |
JP2002193862A (ja) * | 2000-12-28 | 2002-07-10 | Idemitsu Petrochem Co Ltd | ビスフェノールaの製造方法 |
US6730816B2 (en) * | 2000-12-29 | 2004-05-04 | Rohm And Haas Company | High productivity bisphenol-A catalyst |
JP2002265402A (ja) | 2001-03-08 | 2002-09-18 | Idemitsu Petrochem Co Ltd | ビスフェノールaの製造方法 |
US6465697B1 (en) | 2001-04-13 | 2002-10-15 | Resolution Performance Products Llc | Catalyst promotor for the manufacture of polyphenols |
US6620939B2 (en) * | 2001-09-18 | 2003-09-16 | General Electric Company | Method for producing bisphenol catalysts and bisphenols |
US6703530B2 (en) | 2002-02-28 | 2004-03-09 | General Electric Company | Chemical reactor system and process |
US6960697B2 (en) | 2002-03-13 | 2005-11-01 | Mitsubishi Chemical Corporation | System and method of producing bisphenol-A (BPA) |
US20050075520A1 (en) * | 2002-03-13 | 2005-04-07 | O'young Drow Lionel | System and method of producing bisphenol-A (BPA) using two stage crystallization |
US7112702B2 (en) * | 2002-12-12 | 2006-09-26 | General Electric Company | Process for the synthesis of bisphenol |
US7132575B2 (en) * | 2003-07-01 | 2006-11-07 | General Electric Company | Process for the synthesis of bisphenol |
US7015365B2 (en) * | 2003-12-19 | 2006-03-21 | General Electric Company | Methods for preparing cycloalkylidene bisphenols |
DE102007021935A1 (de) | 2007-05-10 | 2008-11-20 | Bayer Materialscience Ag | Verfahren und Herstellung von Bisphenol A mit verlängerter Standzeit in der Kristallisation |
DE102007026548A1 (de) | 2007-06-08 | 2008-12-18 | Bayer Materialscience Ag | Vermeidung von Feststoffablagerungen in Tropfenabscheidern durch Eindüsung von geeigneten Flüssigkeiten |
US8735634B2 (en) | 2011-05-02 | 2014-05-27 | Sabic Innovative Plastics Ip B.V. | Promoter catalyst system with solvent purification |
EP2606973A1 (de) * | 2011-12-22 | 2013-06-26 | LANXESS Deutschland GmbH | Thiolgruppenhaltiges Acrylatharz |
EP4298080A1 (en) | 2021-02-23 | 2024-01-03 | Covestro Deutschland AG | Process for preparing bisphenol a (bpa) in the presence of alpha-methylstyrene |
CN116917260A (zh) | 2021-02-23 | 2023-10-20 | 科思创德国股份有限公司 | 在至少两种杂质存在下制备双酚a(bpa)的方法 |
US20240076257A1 (en) | 2021-02-23 | 2024-03-07 | Covestro Deutschland Ag | Process for preparing bisphenol a (bpa) in the presence of 2-methyl benzofuran |
JP2024508774A (ja) | 2021-02-23 | 2024-02-28 | コベストロ、ドイチュラント、アクチエンゲゼルシャフト | ベンゼンの存在下でビスフェノールa(bpa)を作製するプロセス |
EP4298084A1 (en) | 2021-02-23 | 2024-01-03 | Covestro Deutschland AG | Process for preparing bisphenol a (bpa) in the presence of cumene |
EP4298083A1 (en) | 2021-02-23 | 2024-01-03 | Covestro Deutschland AG | Process for preparing bisphenol a (bpa) in the presence of acetophenone |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2730552A (en) * | 1956-01-10 | williamson | ||
GB785079A (en) * | 1954-07-12 | 1957-10-23 | Bataafsche Petroleum | Improvements in or relating to the preparation of bis(hydroxyaryl) compounds |
DE1618016A1 (de) * | 1966-03-09 | 1972-04-13 | Union Carbide Corp | Verfahren zur Herstellung von Bisphenolen |
GB1410750A (en) * | 1974-05-13 | 1975-10-22 | Combinaturl Petrochemic Borzes | Process for bisphenol production |
GB1539463A (en) * | 1976-07-26 | 1979-01-31 | Shell Int Research | Preparation of a fixed bed catalyst |
DE2860850D1 (en) * | 1977-11-09 | 1981-10-22 | Shell Int Research | Preparation of bisphenols |
US4423252A (en) * | 1980-08-07 | 1983-12-27 | Mitsubishi Chemical Industries Limited | Process for preparing bisphenols |
US4365099A (en) * | 1981-05-12 | 1982-12-21 | General Electric Company | Process for the production of bisphenols |
-
1988
- 1988-05-16 US US07/194,659 patent/US4859803A/en not_active Expired - Lifetime
-
1989
- 1989-05-03 CA CA000598573A patent/CA1320216C/en not_active Expired - Fee Related
- 1989-05-10 KR KR1019890006270A patent/KR0138910B1/ko not_active IP Right Cessation
- 1989-05-11 JP JP1116246A patent/JP2779952B2/ja not_active Expired - Lifetime
- 1989-05-16 EP EP89201241A patent/EP0342758B1/en not_active Expired - Lifetime
- 1989-05-16 DE DE68922524T patent/DE68922524T2/de not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
KR0138910B1 (ko) | 1998-05-01 |
DE68922524D1 (de) | 1995-06-14 |
US4859803A (en) | 1989-08-22 |
EP0342758A1 (en) | 1989-11-23 |
JP2779952B2 (ja) | 1998-07-23 |
DE68922524T2 (de) | 1995-12-21 |
EP0342758B1 (en) | 1995-05-10 |
JPH0217144A (ja) | 1990-01-22 |
CA1320216C (en) | 1993-07-13 |
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E902 | Notification of reason for refusal | ||
E701 | Decision to grant or registration of patent right | ||
GRNT | Written decision to grant | ||
FPAY | Annual fee payment |
Payment date: 20011226 Year of fee payment: 5 |
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LAPS | Lapse due to unpaid annual fee |