KR880009001A - 헤테로사이클 유도체, 그 제조방법 및 이를 포함하고 있는 살균제 - Google Patents

헤테로사이클 유도체, 그 제조방법 및 이를 포함하고 있는 살균제 Download PDF

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KR880009001A
KR880009001A KR1019880000425A KR880000425A KR880009001A KR 880009001 A KR880009001 A KR 880009001A KR 1019880000425 A KR1019880000425 A KR 1019880000425A KR 880000425 A KR880000425 A KR 880000425A KR 880009001 A KR880009001 A KR 880009001A
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methyl group
atom
group
general formula
hydrogen atom
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KR1019880000425A
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English (en)
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타다시 오오스미
가조느리 쓰시마
스미오 니시다
기요또 마에다
타다시 오오이시
노리타다 마쯔오
Original Assignee
니시자와 요시히꼬
스미또모 가가꾸 고교 가부시끼가이샤
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Priority claimed from JP62028574A external-priority patent/JP2552846B2/ja
Application filed by 니시자와 요시히꼬, 스미또모 가가꾸 고교 가부시끼가이샤 filed Critical 니시자와 요시히꼬
Publication of KR880009001A publication Critical patent/KR880009001A/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D277/00—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings
    • C07D277/02—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings
    • C07D277/20—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D277/22—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • C07D277/30—Radicals substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D277/00—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings
    • C07D277/02—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings
    • C07D277/20—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D277/32—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D277/56—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D231/16—Halogen atoms or nitro radicals

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  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Dentistry (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Plant Pathology (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)

Abstract

내용 없음.

Description

헤테로사이클 유도체, 그 제조방법 및 이를 포함하고 있는 살균제
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (9)

  1. 하기 일반식 (I)로 표시되는 것을 특징으로 하는 헤테로 사이클 유도체.
    여기에서 R1은 수소원자 또는 메틸기이고 A는또는인데 여기에서 R2는 메틸기, 에틸기 또는 트리플루오로 메틸기 이고 Y1은 아미노기, 메틸기 또는 염소원자이고 R3는 메틸기 또는 트리플루오로메틸기이고 Z는 수소원자, 할로겐원자 또는 메틸기이고 A가일때 X는 산소원자 또는 황원자이고 A가일때 X는 황원자이다.
  2. 일반식 A1-COOH로 표시되는 헤테로 사이클 카르복실산 또는 그 반응성 유도체를 하기 일반식 (IV)로 표시되는 아미노인단 유도체와 반응시키는 것을 특징으로 하는 다음 식으로 표시되는 헤테로 사이클 유도체를 제조하는 방법.
    여기에서 A1은이며 이 식에서 R2는 메틸기, 에틸기 또는 트리플루오로 메틸기이고 Y1은 아미노기, 메틸기 또는 염소원자 이고 R1은 수소 원자 또는 메틸 그룹이다.
    여기서 R1은 상기 정의한 바와 같다.
  3. 하기 일반식 (II)로 표시되는 헤테로사이클 유도체를 티오화제와 반응시키는 것을 특징으로 하는 하기 일반식 (VIII)로 표시되는 유도체를 제조하는 방법.
    여기에서 A는또는이며 이들 식에서 R2는 메틸기, 에틸기 또는 트리플루오로 메틸기이고 Y1은 아미노기, 메틸기 또는 염소원자이고 R3는 메틸기 또는 트리플루오로 메틸기이고, Z은 수소원자, 할로겐원자 또는 메틸기이고, R1은 수소 원자 또는 메틸기이다.
    여기서 A 및 R1은 상기 정의한 바와 같다.
  4. 제3항에 있어서, 티오화제가 오황화인, 2,4-비스(메틸티오)-1,3,2,4-디티아디포스페탄-2,4-디설파이드 또는 2,4-비스(P-메톡시페닐)-1,3,2,4-디티아디포스페탄-2,4-디설파이드인 것을 특징으로 하는 방법.
  5. 하기 일반식 (VI)으로 표시되는 아미노인단 유도체를 하기 일반식 (VII)로 표시되는 티오아미드 유도체와 반응시키는 것을 특징으로 하는 일반식 (V)로 표시되는 헤테로사이클 유도체를 제조하는 방법.
    여기에서 R1은 수소 원자 또는 메틸기이고 R2는 메틸기, 에틸기 또는 트리플루오로 메틸기이고 Y2는 아미노기 또는 메틸기이다.
    여기에서 R1및 R2는 상기 정의한 바와 같다.
    여기에서 Y2는 상기 정의한 바와 같다.
  6. 활성성분으로서 하기 일반식 (I)로 표시되는 헤테로사이클 유도체를 가지고 있는 것을 특징으로 하는 살균제 조성물.
    여기에서 R1은 수소원자 또는 메틸기이고 A는또는이며 여기에서 R2는 메틸기, 에틸기 또는 트리플루오로 메틸기이고 Y1은 아미노기, 메틸기, 또는 염소원자이고, R3는 메틸기 또는 트리플루오로 메틸기이고 Z는 수소원자, 할로겐원자 또는 메틸기이고 A가일때 X는 산소원자 또는 황원자이고, A가일때 X는 황원자 및 불활성 캐리어 이다.
  7. 하기 일반식 (I)로 표시되는 헤테로사이클 화합물을 살균제 효과를 내는 양만큼 균에 처리하는 것을 특징으로 하는 균을 제어하는 방법.
    여기에서 R1은 수소원자 또는 메틸기이고 A는또는이며 R2는 메틸기, 에틸기 또는 트리플루로오 메틸기 또는 염소원자이고 R3는 메틸기 또는 트리플루오로 메틸기이고 Z은 수소원자, 할로겐원자 또는 메틸기이고 A가일때 X는 산소 원자, 황원자이고 A가일때 X는 황원자이다.
  8. 제7항에 있어서, 균이 식물 병원균인 것을 특징으로 하는 방법.
  9. 제1항에 따른 헤테로 사이클 화합물을 살균제로서 사용하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880000425A 1987-01-20 1988-01-20 헤테로사이클 유도체, 그 제조방법 및 이를 포함하고 있는 살균제 KR880009001A (ko)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
JP?62-11667 1987-01-20
JP1166687 1987-01-20
JP?62-11666 1987-01-20
JP1166787 1987-01-20
JP62028574A JP2552846B2 (ja) 1987-01-20 1987-02-10 置換チアゾールカルボン酸誘導体およびそれを有効成分とする農園芸用殺菌剤
JP?62-28574 1987-02-10

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KR880009001A true KR880009001A (ko) 1988-09-13

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US (1) US4837242A (ko)
EP (1) EP0276177B1 (ko)
KR (1) KR880009001A (ko)
AU (1) AU598624B2 (ko)
DE (1) DE3868076D1 (ko)

Families Citing this family (45)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4914097A (en) * 1987-02-25 1990-04-03 Mitsubishi Kasei Corporation N-indanyl carboxamide derivative and agricultural/horticultural fungicide containing the derivative as active ingredient
DE3805058A1 (de) * 1988-02-18 1989-08-31 Bayer Ag N-sulfenylierte 2-amino-4-chlor-thiazol-sulfonamide, ihre verwendung, verfahren zu ihrer herstellung und die dabei auftretenden zwischenprodukte 2,4-dichlor-thiazol-sulfonsaeurechlorid und 2-amino-4-chlor-thiazol-sulfonsaeureamid
US5049575A (en) * 1988-11-10 1991-09-17 Sumitomo Chemical Company Substituted carboxylic acid, fungicidal compositions and use
US5045554A (en) * 1988-11-29 1991-09-03 Monsanto Company Substituted thiazoles and their use as fungicides
US5258397A (en) * 1988-11-30 1993-11-02 Novapharme 3-Isoxazoyl derivatives endowed with anticonvulsant activity, procedure for their preparation and their pharmaceutical compositions
FR2662692B1 (fr) * 1990-05-30 1995-04-28 Novapharme Derives heterocycliques doues d'activite anticonvulsivante, procede de preparation et composition pharmaceutique.
US5464860A (en) * 1988-11-30 1995-11-07 Novapharme N(pyrazol-3-yl) benzamides and pharmaceutical compositions
JPH066234B2 (ja) 1989-07-04 1994-01-26 日本鋼管株式会社 チタンクラッド材の製造方法
US5210205A (en) * 1989-12-21 1993-05-11 Ciba-Geigy Corporation Pesticidal compositions
US5256670A (en) * 1990-12-10 1993-10-26 Rohm And Haas Company N-aryl-3-aryl-4-substituted-2,3,4,5-tetrahydro-1H-pyrazole-1-carboxamides, insecticidal compositions containing such compounds and methods of controlling insects such compounds
US5093347A (en) * 1991-01-28 1992-03-03 Monsanto Company 3-difluoromethylpyrazolecarboxamide fungicides, compositions and use
IL103614A (en) * 1991-11-22 1998-09-24 Basf Ag Carboxamides for controlling botrytis and certain novel such compounds
US5880288A (en) * 1992-08-11 1999-03-09 Rohm And Haas Company Process for the preparation of 2-methylthiazole-5-carboxylates
DE4301356A1 (de) * 1993-01-20 1994-07-21 Basf Ag Verfahren zur Herstellung von 2-Alkyl-4-fluormethyl-thiazolcarbonsäure-alkylestern
CA2108864C (en) * 1993-10-20 2004-11-30 Aggie Hoobler Hollis Improved process for the preparation of 2-methylthiazole-5-carboxylates
EP0654464A1 (en) * 1993-10-22 1995-05-24 Shell Internationale Researchmaatschappij B.V. Processes for the preparation of pesticides and intermediates
US5521317A (en) * 1993-10-22 1996-05-28 American Cyanamid Co. Processes for the preparation of pesticides and intermediates
JP3726306B2 (ja) * 1994-04-27 2005-12-14 日産化学工業株式会社 ピラゾールカルボン酸誘導体および植物病害防除剤
DE19735224A1 (de) * 1997-08-15 1999-02-18 Basf Ag Biphenylamide
US7125875B2 (en) 1999-04-15 2006-10-24 Bristol-Myers Squibb Company Cyclic protein tyrosine kinase inhibitors
JP3989175B2 (ja) 1999-04-15 2007-10-10 ブリストル−マイヤーズ スクイブ カンパニー 環状タンパク質チロシンキナーゼ阻害剤
DE10204390A1 (de) * 2002-02-04 2003-08-14 Bayer Cropscience Ag Disubstituierte Thiazolylcarboxanilide
DE10204391A1 (de) * 2002-02-04 2003-08-14 Bayer Cropscience Ag Difluormethylthiazolylcarboxanilide
US7186862B2 (en) 2002-02-23 2007-03-06 Bayer Cropscience Ag Microbicidal agents on the basis of biphenylbenzamide derivatives
GB0224316D0 (en) 2002-10-18 2002-11-27 Syngenta Participations Ag Chemical compounds
DE10250110A1 (de) * 2002-10-28 2004-05-13 Bayer Cropscience Ag Thiazol-(bi)cycloalkyl-carboxanilide
GB0716592D0 (en) * 2007-08-24 2007-10-03 Syngenta Ltd Improvements in or relating to organic compounds
IT1403275B1 (it) 2010-12-20 2013-10-17 Isagro Ricerca Srl Indanilanilidi ad elevata attività fungicida e loro composizioni fitosanitarie
CN103145639B (zh) * 2011-12-07 2016-01-06 中化蓝天集团有限公司 2-甲基-4-(三氟甲基)噻唑-5-甲酸的制备方法
EP2662361A1 (en) 2012-05-09 2013-11-13 Bayer CropScience AG Pyrazol indanyl carboxamides
WO2013167548A1 (en) * 2012-05-09 2013-11-14 Bayer Cropscience Ag Pyrazole tetrahydronaphthyl carboxamides
EP2662360A1 (en) 2012-05-09 2013-11-13 Bayer CropScience AG 5-Halogenopyrazole indanyl carboxamides
EP2662364A1 (en) 2012-05-09 2013-11-13 Bayer CropScience AG Pyrazole tetrahydronaphthyl carboxamides
US9199941B2 (en) * 2012-05-09 2015-12-01 Bayer Cropscience Ag Pyrazole indanyl carboxamides
MX2014013489A (es) * 2012-05-09 2015-02-12 Bayer Cropscience Ag 5-halogenopirazolindanil carboxamidas.
EP2662362A1 (en) 2012-05-09 2013-11-13 Bayer CropScience AG Pyrazole indanyl carboxamides
EP2847170B1 (en) 2012-05-09 2017-11-08 Bayer CropScience AG Pyrazole indanyl carboxamides
ITMI20121045A1 (it) 2012-06-15 2013-12-16 Isagro Ricerca Srl Composizioni sinergiche per la protezione di colture agrarie e relativo uso
CN104870426B (zh) 2012-12-19 2018-02-09 拜耳作物科学股份公司 四氢萘基(硫代)羧酰胺
EP3062617B1 (en) 2013-10-30 2017-12-06 Bayer CropScience Aktiengesellschaft Benzocyclobutane(thio) carboxamides
CN104945350A (zh) * 2014-03-25 2015-09-30 中国科学院生态环境研究中心 简捷合成高光学纯度噻唑氨基酸的新方法
CN106316978A (zh) * 2015-07-06 2017-01-11 英德广农康盛化工有限责任公司 一种合成2-甲基-4-三氟甲基-5-噻唑甲酸的优化工艺
ES2806460T3 (es) 2016-04-15 2021-02-17 Stichting I F Product Collaboration Proceso para la preparación de derivados de 4-aminoindano y amidas de aminoindano relacionadas
CN106349183B (zh) * 2016-08-29 2018-06-05 青岛瀚生生物科技股份有限公司 2-甲基-4-三氟甲基-5-噻唑甲酸的制备方法
IT201900017330A1 (it) 2019-09-26 2021-03-26 Isagro Spa Processo per la preparazione di (r)-4-amminoindani e corrispondenti ammidi.

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3505055A (en) * 1966-12-07 1970-04-07 Uniroyal Inc Method of controlling plant growth with carboxamidothiazoles
US4134987A (en) * 1976-01-14 1979-01-16 Huppatz John L Compounds and compositions
JPS58140054A (ja) * 1982-02-10 1983-08-19 Sumitomo Chem Co Ltd インダニルベンツアミド誘導体、その製造法およびこれらを有効成分として含有する農園芸用殺菌剤
IL73419A (en) * 1983-11-07 1988-02-29 Lilly Co Eli 1h-pyrazole-4-(thio)carboxamide derivatives,their preparation and herbicidal compositions containing them
KR920003893B1 (ko) * 1984-10-29 1992-05-18 스미또모가가꾸고오교 가부시끼가이샤 피라졸 카르복스아미드 유도체의 제조방법
DE3875750D1 (de) * 1987-01-30 1992-12-17 Ciba Geigy Ag Mikrobizide mittel.

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EP0276177B1 (en) 1992-01-29
AU1037388A (en) 1988-07-21
EP0276177A1 (en) 1988-07-27
US4837242A (en) 1989-06-06
DE3868076D1 (de) 1992-03-12
AU598624B2 (en) 1990-06-28

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