KR880008992A - 할로게노알킬-, 알케닐- 및 알키닐-아졸 - Google Patents
할로게노알킬-, 알케닐- 및 알키닐-아졸 Download PDFInfo
- Publication number
- KR880008992A KR880008992A KR1019880000164A KR880000164A KR880008992A KR 880008992 A KR880008992 A KR 880008992A KR 1019880000164 A KR1019880000164 A KR 1019880000164A KR 880000164 A KR880000164 A KR 880000164A KR 880008992 A KR880008992 A KR 880008992A
- Authority
- KR
- South Korea
- Prior art keywords
- halogen
- group
- general formula
- optionally substituted
- compound
- Prior art date
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- 125000001188 haloalkyl group Chemical group 0.000 title claims 3
- 229910052736 halogen Inorganic materials 0.000 claims 13
- 150000002367 halogens Chemical class 0.000 claims 13
- 150000001875 compounds Chemical class 0.000 claims 10
- 229910052739 hydrogen Inorganic materials 0.000 claims 6
- 239000001257 hydrogen Substances 0.000 claims 6
- 150000003839 salts Chemical class 0.000 claims 6
- 229910052801 chlorine Inorganic materials 0.000 claims 5
- 239000000460 chlorine Substances 0.000 claims 5
- 239000000203 mixture Substances 0.000 claims 5
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 4
- 125000003545 alkoxy group Chemical group 0.000 claims 4
- 239000003085 diluting agent Substances 0.000 claims 4
- 229910052757 nitrogen Inorganic materials 0.000 claims 4
- 125000004433 nitrogen atom Chemical group N* 0.000 claims 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 3
- 125000004432 carbon atom Chemical group C* 0.000 claims 3
- 239000003795 chemical substances by application Substances 0.000 claims 3
- 150000002431 hydrogen Chemical class 0.000 claims 3
- 239000000575 pesticide Substances 0.000 claims 3
- 125000005389 trialkylsiloxy group Chemical group 0.000 claims 3
- -1 trimethylsilyloxy Chemical group 0.000 claims 3
- 241000238421 Arthropoda Species 0.000 claims 2
- 241000607479 Yersinia pestis Species 0.000 claims 2
- DKEKURXRUXRNES-UHFFFAOYSA-N bis(1h-pyrrol-2-yl)methanone Chemical compound C=1C=CNC=1C(=O)C1=CC=CN1 DKEKURXRUXRNES-UHFFFAOYSA-N 0.000 claims 2
- 125000005346 substituted cycloalkyl group Chemical group 0.000 claims 2
- GNDDPQONHZKTJA-UHFFFAOYSA-N 2-(2-chloroethenyl)-1h-pyrrole Chemical class ClC=CC1=CC=CN1 GNDDPQONHZKTJA-UHFFFAOYSA-N 0.000 claims 1
- 239000004606 Fillers/Extenders Substances 0.000 claims 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- 229940100198 alkylating agent Drugs 0.000 claims 1
- 239000002168 alkylating agent Substances 0.000 claims 1
- VEMKTZHHVJILDY-UXHICEINSA-N bioresmethrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-UXHICEINSA-N 0.000 claims 1
- 150000004657 carbamic acid derivatives Chemical class 0.000 claims 1
- 150000007942 carboxylates Chemical class 0.000 claims 1
- 125000001309 chloro group Chemical group Cl* 0.000 claims 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 claims 1
- 125000001559 cyclopropyl group Chemical group [H]C1([H])C([H])([H])C1([H])* 0.000 claims 1
- 238000006298 dechlorination reaction Methods 0.000 claims 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 1
- 229910052731 fluorine Inorganic materials 0.000 claims 1
- 239000011737 fluorine Substances 0.000 claims 1
- 150000002366 halogen compounds Chemical class 0.000 claims 1
- 230000002140 halogenating effect Effects 0.000 claims 1
- 239000004009 herbicide Substances 0.000 claims 1
- 238000005984 hydrogenation reaction Methods 0.000 claims 1
- 230000002401 inhibitory effect Effects 0.000 claims 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- 150000003008 phosphonic acid esters Chemical class 0.000 claims 1
- 150000003014 phosphoric acid esters Chemical class 0.000 claims 1
- 150000003018 phosphorus compounds Chemical class 0.000 claims 1
- 230000000243 photosynthetic effect Effects 0.000 claims 1
- 239000004094 surface-active agent Substances 0.000 claims 1
- 150000003573 thiols Chemical class 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/12—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N55/00—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
- C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
- C07D233/56—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
- C07D249/02—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
- C07D249/08—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
- C07F7/1804—Compounds having Si-O-C linkages
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Plural Heterocyclic Compounds (AREA)
Abstract
내용 없음.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (11)
- 일반식 (I)의 할로게노알킬-, 알케닐- 및 알키닐-아졸 및 이의 염.상기식에서, X는 질소원자 또는 CH그룹을 나타내고, R은 임의로 치환된 3급-알킬 또는 임의로 치환된 사이클로알킬을 나타내며, A는 -C C-,또는(여기서, R1은 할로겐, 알콕시 또는 트리알킬실릴옥시를 나타내고, R2는 수소 또는 할로겐을 나타내며, R3는 할로겐을 나타낸다)그룹중의 1개를 나타낸다.
- 제1항에 있어서, X가 질소원자 또는 CH그룹을 나타내고, R이 임의로 할로겐-치환된 탄소원자 4 내지 8개의 3급-알킬, 또는 탄소원자 1 내지 4개의 알킬 및/또는 할로겐에 의하여 임의로 치환된 탄소원자 3 내지 6개의 사이클로알킬을 나타내며, A가 그룹또는 -C C- (여기서, R1은 할로겐, 탄소원자 1 내지 4개의 알콕시, 또는 트리메틸실릴옥시를 나타내고, R2는 수소 또는 할로겐을 나타내며 R3는 할로겐을 나타낸다)를 나타내는 화합물.
- 제1항에 있어서, X가 질소원자 또는 CH그룹을 나타내고, R이 염소 및/또는 불소에 의해 임의로 치환된 탄소원자 4 내지 8개의 3급-알킬을 나타내거나, 또는 각기 염소, 메틸, 에틸 및/또는 이소프로필에 의하여 임의로 치환된 사이클로프로필, 사이클로펜틸 또는 사이클로헥실을 나타내며, A가 -C C- 그룹을 나타내거나, A가그룹(여기서, (a) R1은 염소, 메톡시, 에톡시 또는 트리메틸실릴옥시를 나타내고, R2는 수소를 나타내거나, 또는 (b) R1및 R2가 염소를 나타냄)을 나타내거나, 또는 A가그룹(여기서, R1, R2및 R3는 염소를 나타냄)을 나타내는 화합물.
- 다음 구조식의 화합물.
- (a) X 및 R이 상술한 의미를 갖고, A가그룹(여기서, R1은 할로겐을 나타내고 R2는 수소를 나타낸다)을 나타내는 경우에는, 다음 일반식 (II)의 아졸릴 케톤을 적합한 할로겐화제와 반응시키거나, (b) X 및 R이 상술한 바와 같은 의미를 갖고, A가그룹(여기서, R1은 알콕시 또는 트리알킬실릴옥시를 나타내고 R2는 수소를 나타낸다)을 나타내는 경우에는, 다음 일반식 (II)의 아졸릴 케톤을 강염기 및 희석제의 존재하에 알킬화제 또는 실릴화제와 반응시키거나, (c) X 및 R이 상술한 바와 같은 의미를 갖고, A가 -C C- 그룹을 나타내는 경우에는, 일반식 (Ia)의 클로로비닐-아졸 유도체를 희석제의 존재하에 강염기와 반응시켜 탈염산화시키거나, (d) X 및 R이 상술한 바와 같은 의미를 갖고, A가그룹(여기서, R1, R2및 R3은 상술한 바의 의미를 갖는다)을 나타내는 경우에는, 다음 일반식 (Ib)의 알케닐-아졸을 희석제의 존재하에 일반식 (III)의 할로겐 화합물과 반응시키거나, 또는 (e) X 및 R이 상술한 바와 같은 의미를 갖고, A가그룹(여기서, R1은 상술한 바와 같은 의미를 갖고 R2는 할로겐을 나타낸다)을 나타내는 경우에는, 일반식 (Ic)의 할로게노알킬-아졸을 희석제의 존재하에 강염기와 반응시켜 탈할로겐화 수소화시키며, 경우에 따라 산 또는 금속 염을 수득된 일반식 (I)의 화합물에 통상적인 방법으로 첨가함을 특징으로 하여 일반식 (I)의 할로게노알킬-, 알케닐- 및 알키닐-아졸 및 이의 염을 제조하는 방법.상기식에서, X는 질소원자 또는 CH그룹을 나타내고, R은 임의로 치환된 3급-알킬 또는 임의로 치환된 사이클로알킬을 나타내며, A는 그룹 -C C-,또는를 나타내고, R1은 할로겐, 알콕시 또는 트리알킬실릴옥시를 나타내며, R2는 수소 또는 할로겐을 나타내고, R3는 할로겐을 나타내나, 단, 일반식 (Ic)에서 R2및 R3는 할로겐을 나타낸다.
- 제1항 또는 제5항에 따른 일반식 (I) 화합물 및 이들 염의 해충 방제용 상승제로서의 용도.
- 광합성-억제 제초제 또는 절지류 방제제와 제1항 또는 제5항에 따른 일반식 (I) 화합물 및 이들 염의 혼합물.
- (1) 카바메이트 및/또는 (2) 카복실레이트 (천연 및 합성 피레트로이드 포함) 및/또는 (3) 포스포르산 에스테르 및 포스폰산 에스테르와 같은 인 화합물(티올 및 티오노 화합물 포함)로 이루어진 그룹으로 부터의 절지류 방제활성 화합물과 제1항 또는 제5항에 따른 일반식 (I) 화합물 및 이들 염의 혼합물.
- 제7항 또는 제8항의 혼합물을 1개 이상 함유하는 살충제.
- 해충 방제용으로서, 제7항 또는 8항에 따른 혼합물 및 제9항에 따른 살충제의 용도.
- 제7항 또는 제8항의 혼합물 1개 이상을 증량제 및/또는 계면-활성제와 혼합함을 특징으로 하는 살충제의 제조방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19873700916 DE3700916A1 (de) | 1987-01-14 | 1987-01-14 | Halogenalkyl-, alkenyl- und alkinyl-azole |
| DEP3700916.8 | 1987-01-14 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR880008992A true KR880008992A (ko) | 1988-09-13 |
Family
ID=6318820
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019880000164A KR880008992A (ko) | 1987-01-14 | 1988-01-13 | 할로게노알킬-, 알케닐- 및 알키닐-아졸 |
Country Status (10)
| Country | Link |
|---|---|
| EP (1) | EP0275866A1 (ko) |
| JP (1) | JPS63208577A (ko) |
| KR (1) | KR880008992A (ko) |
| AU (1) | AU1015088A (ko) |
| BR (1) | BR8800112A (ko) |
| DD (1) | DD273969A5 (ko) |
| DE (1) | DE3700916A1 (ko) |
| DK (1) | DK14288A (ko) |
| IL (1) | IL85059A0 (ko) |
| ZA (1) | ZA88206B (ko) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3819903A1 (de) * | 1988-06-11 | 1989-12-21 | Basf Ag | 1-halogen-1-azolyl-ethan-derivate und diese enthaltende fungizide |
| DE3923151A1 (de) * | 1989-07-13 | 1991-01-24 | Basf Ag | 1,2-dihalogenazolylethanderivate und diese enthaltende pflanzenschutzmittel |
| DE3913725A1 (de) * | 1989-04-26 | 1990-10-31 | Basf Ag | 1-halogenvinyl-azole und diese enthaltende fungizide und wachstumsregulatoren |
| IL111118A (en) * | 1993-10-07 | 2000-07-26 | Shell Int Research | Pesticidal compositions comprising a substituted 1,2,4-triazole compound and a pyrethroid insecticide and the use thereof in combating pests |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NZ192941A (en) * | 1979-02-22 | 1984-10-19 | Wellcome Found | 1-substituted imidazoles;pharmaceutical compositions |
| DE3362868D1 (en) * | 1982-02-19 | 1986-05-15 | Ciba Geigy Ag | Microbicidal and plant-growth regulating agents |
| DE3417468A1 (de) * | 1984-05-11 | 1985-11-14 | Bayer Ag, 5090 Leverkusen | Azolylvinylether |
| DE3525978A1 (de) * | 1985-07-20 | 1987-01-29 | Bayer Ag | Azolyl-alkene und -alkine |
-
1987
- 1987-01-14 DE DE19873700916 patent/DE3700916A1/de not_active Withdrawn
-
1988
- 1988-01-05 EP EP88100037A patent/EP0275866A1/de not_active Withdrawn
- 1988-01-08 AU AU10150/88A patent/AU1015088A/en not_active Abandoned
- 1988-01-11 IL IL85059A patent/IL85059A0/xx unknown
- 1988-01-11 JP JP63002657A patent/JPS63208577A/ja active Pending
- 1988-01-12 DD DD88312190A patent/DD273969A5/de unknown
- 1988-01-13 ZA ZA880206A patent/ZA88206B/xx unknown
- 1988-01-13 DK DK014288A patent/DK14288A/da not_active Application Discontinuation
- 1988-01-13 BR BR8800112A patent/BR8800112A/pt unknown
- 1988-01-13 KR KR1019880000164A patent/KR880008992A/ko not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| DE3700916A1 (de) | 1988-07-28 |
| IL85059A0 (en) | 1988-06-30 |
| ZA88206B (en) | 1988-06-30 |
| AU1015088A (en) | 1988-07-21 |
| DD273969A5 (de) | 1989-12-06 |
| EP0275866A1 (de) | 1988-07-27 |
| DK14288A (da) | 1988-07-15 |
| DK14288D0 (da) | 1988-01-13 |
| BR8800112A (pt) | 1988-08-23 |
| JPS63208577A (ja) | 1988-08-30 |
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| Publication | Publication Date | Title |
|---|---|---|
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