KR920017999A - 제초제 및 식물 성장 조절제로서의 할로알콕시-치환된 벤조일사이클로헥산디온 - Google Patents

제초제 및 식물 성장 조절제로서의 할로알콕시-치환된 벤조일사이클로헥산디온 Download PDF

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KR920017999A
KR920017999A KR1019920003611A KR920003611A KR920017999A KR 920017999 A KR920017999 A KR 920017999A KR 1019920003611 A KR1019920003611 A KR 1019920003611A KR 920003611 A KR920003611 A KR 920003611A KR 920017999 A KR920017999 A KR 920017999A
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haloalkyl
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스타르크 헤르베르트
바우어 클라우스
베링거 헤르만
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엥겔하르트, 라피체
훽스트 아크티엔게젤샤프트
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    • A01N35/06—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical containing keto or thioketo groups as part of a ring, e.g. cyclohexanone, quinone; Derivatives thereof, e.g. ketals
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    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00—Carboxylic acid nitriles
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/22—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and doubly-bound oxygen atoms bound to the same carbon skeleton
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    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/50—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton
    • C07C323/62—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atom of at least one of the thio groups bound to a carbon atom of a six-membered aromatic ring of the carbon skeleton
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
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    • C07C45/54—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition of compounds containing doubly bound oxygen atoms, e.g. esters
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    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C45/72—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups
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    • C07C2601/08—Systems containing only non-condensed rings with a five-membered ring the ring being saturated
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    • C07C2601/14—The ring being saturated

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Abstract

내용 없음

Description

제조제 및 식물 성장 조절제로서의 할로알콕시-치환된 벤조일사이클로헥산디온
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. 하기 일반식(Ⅰ)의 화합물 또는 그의 염.
    상기식에서, n은 0내지 6의 정수이고, R1은 직쇄 C1-C4-알킬, 분지된 C3-C4알킬, C3-C6사이클로알킬 및 페닐(이들 라디칼은 비치환되거나 하나 이상의 할로겐 원자로 치환된다)을 포함하는 그룹중에서 선택된 같거나 다른 치환체를 나타내고, R2는 할로겐, NO2, CN, C1-C3-알킬, C1-C3-할로알킬, C1-C3-알콕시, C1-C3-할로알콕시, C1-C3티오알킬, RaSO2-, RaSO2-O- 또는 RaSO2NRb-(여기서, Ra및 Rb는 서로 독립적으로 C1-C2-알킬 또는 C1-C2-알킬 또는 C1-C2-할로알킬이다)이며, R3는 수소, 할로겐, C1-C3-알킬, C1-C3-할로알킬, C1-C3-알콕시, C1-C3-할로알콕시 또는 C1-C3-알킬티오이고, R4는 C1-C3-할로알킬이다.
  2. 제1항에 있어서, n은 0 내지 4의 정수이고, R1이 직쇄 C1-C3-알킬, i-프로필, C4-C6-사이클로알킬 및 페닐(이드 4개의 라디칼은 비치환되거나 염소 및 불소를 포함한 그룹중에서 선택된 하나 이상의 라디칼로 치환된다)을 포함하는 그룹중에서 선택된 같거나 다른 치환체를 나타내며, R2가 할로겐, NO2, CN, C1-C3-알킬, C1-C|3-할로알킬, C1-C2-알콕시, C1-C2-할로알콕시 또는 RaSO|2-(여기서, Ra는 전술한 의미를 갖는다)이고, R3가 H, 할로겐, C1-C2-알킬, C1-C2-할로알킬, C|1-C2-알콕시, C1-C2-할로알콕시 또는 C1-C2-알킬티오이며, R4가 C1-C3-할로알킬인 일반식(Ⅰ)의 화합물 또는 그의 염.
  3. 제1항 또는 제2항에 있어서, n이 0 내지 3이고, R1이 C1-C3-알킬, 사이클로펜틸 또는 페닐이고, R2가 불소, 염소, NO2, CN, 메틸, 트리플루오로메틸, 메톡시, 디플루오로메톡시, 트리플루오로메톡시 또는 메틸설포닐이며, R3가 수소, 할로겐, 메틸, CF3, 메톡시, 디플루오로메톡시, 트리플루오로메톡시 또는 메틸티오이고, R4가 CH2F, CHF2, CH2Cl, CHCl2, CCl3, CH2CH|2Cl, CH2CH2F, CH2CHF2, CH2CF3, CHFCH3, CHFCH2F, CHFCHF2, CF2CH3, CF2CH2F, CF2CHF2, CF2CF3, CF2CHFCl, CHFCHFCl, CH2CCl3, CH2CHCl2, CHFCHCl2, CF2CHCl2, CHFCH2Cl 또는 CF2CH2Cl인 일반식(Ⅰ)의 화합물 또는 그의 염.
  4. a)하기 일반식(Ⅱ)의 사이클로헥산디온을 하기 일반식(Ⅲ)의 산 클로라이드와 반응시켜 하기 일반식(Ⅳ)의 엔올 에테르를 수득하고, 상기 엔올 에테르를 시아나이드 공급원 또는 루이스산의 존재하에서 전위시켜 제1항에서 언급한 일반식(Ⅰ)의 화합물을 수득하거나, 또는 b)하기 일반식(Ⅱ)의 사이클로헥산디온을 하기 일반식(Ⅴ)의 벤조일 시아나이드와 반응시킴을 포함하는, 제1항에 따른 일반식(Ⅰ)의 화합물 또는 그의 염의 제조방법.
    상기식에서, R1, R2, R3, R4및 n은 제1항의 일반식(Ⅰ)에서 언급한 의미를 갖는다.
  5. 제1항 내지 제3항중 어느 한 항에 따른 일반식(Ⅰ)의 화합물 또는 그의 염 및 통상적인 제형화 보조제를 포함하는 제초제 또는 식물 성장 조절제.
  6. 제1항 내지 제3항중 어느 한 항에 따른 일반식(Ⅰ)의 화합물 또는 그의 염의 제초제 또는 식물 성장 조절제로서의 용도.
  7. 제1항 내지 제3항중 어느 한 항에 정의된 일반식(Ⅰ)의 화합물중 하나 또는 그의 염 효과량을 식물, 식물의 종자 또는 경작지에 적용시킴을 포함하는, 유해식물을 선택적으로 방제하는 방법.
  8. 제1항 내지 제3항중 어느 한 항에 정의된 일반식(Ⅰ)의 화합물중 하나 또는 그의 염 효과량을 식물, 식물의 종자 또는 경작지에 적용시킴을 포함하는, 식물의 성장을 조절하는 방법.
  9. 하기 일반식(Ⅷ)의 화합물.
    상기식에서, Q는 Cl, CN, OH 또는 O-Me+(Me+는 무기 또는 유기 양이온이다)이고, R2, R3및 R4는 제1항 내지 제3항중 어느 한 항에 따른 일반식(Ⅰ)에서 정의한 바와 같다.
  10. 하기 일반식(Ⅷ)의 상응하는 톨루엔을 과망간산 칼륨 또는 질산으로 산화시켜 일반식(Ⅷ) (여기서, Q는 OH이다)의 화합물을 수득하고, Q는 Cl인 화합물을 제조할 경우에는 생성물을 할로겐화시키거나, 또는 Q가 CN인 화합물을 제조할 경우에는 생성물을 벤조일 시아나이드로 전환시킴을 포함하는, 제9항에 따른 일반식(Ⅷ)의 화합물의 제조방법.
    상기식에서, R2, R3및 R4는 제1항 내지 제3항중 어느 한 항에 따른 일반식(Ⅰ)의 정의한 바와 같다.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019920003611A 1991-03-06 1992-03-05 제초제 및 식물 성장 조절제로서의 할로알콕시-치환된 벤조일사이클로헥산디온 KR920017999A (ko)

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US (1) US5306695A (ko)
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JP (1) JPH04338356A (ko)
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AU (1) AU1145092A (ko)
BR (1) BR9200766A (ko)
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HU (1) HUT61434A (ko)
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DE10117503A1 (de) * 2001-04-07 2002-10-17 Bayer Cropscience Gmbh Derivate von Benzoylcyclohexandionen und ihre Verwendung als Herbizide
EA024266B1 (ru) 2009-03-11 2016-09-30 Байер Интеллектуэль Проперти Гмбх Кетоенолы, замещенные галоидалкилметиленоксифенилом, и их применение
WO2011101321A1 (de) 2010-02-19 2011-08-25 Bayer Cropscience Ag 3-aminocarbonyl substituierte benzoylcyclohexandione und ihre verwendung als herbizide

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JPH04338356A (ja) 1992-11-25
AU1145092A (en) 1992-09-10
CA2062440A1 (en) 1992-09-07
US5306695A (en) 1994-04-26
MX9200956A (es) 1993-09-01
ZA921642B (en) 1992-10-28
HU9200770D0 (en) 1992-05-28
EP0502492A2 (de) 1992-09-09
BR9200766A (pt) 1992-11-10
EP0502492A3 (en) 1992-11-25

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