KR870007943A - 인산 에스테르의 제조 방법 - Google Patents
인산 에스테르의 제조 방법 Download PDFInfo
- Publication number
- KR870007943A KR870007943A KR870001108A KR870001108A KR870007943A KR 870007943 A KR870007943 A KR 870007943A KR 870001108 A KR870001108 A KR 870001108A KR 870001108 A KR870001108 A KR 870001108A KR 870007943 A KR870007943 A KR 870007943A
- Authority
- KR
- South Korea
- Prior art keywords
- alkyl
- carbon atoms
- hydrogen
- formula
- alkylthio
- Prior art date
Links
- -1 phosphate ester Chemical class 0.000 title claims abstract 8
- 229910019142 PO4 Inorganic materials 0.000 title claims 3
- 239000010452 phosphate Substances 0.000 title claims 3
- 238000004519 manufacturing process Methods 0.000 title 1
- 125000000217 alkyl group Chemical group 0.000 claims abstract 23
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract 14
- 239000001257 hydrogen Substances 0.000 claims abstract 14
- 150000002431 hydrogen Chemical group 0.000 claims abstract 12
- 125000003118 aryl group Chemical group 0.000 claims abstract 8
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract 7
- 125000003545 alkoxy group Chemical group 0.000 claims abstract 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract 7
- 125000004663 dialkyl amino group Chemical group 0.000 claims abstract 7
- 125000003709 fluoroalkyl group Chemical group 0.000 claims abstract 7
- 229910052736 halogen Inorganic materials 0.000 claims abstract 7
- 150000002367 halogens Chemical group 0.000 claims abstract 7
- 229910052760 oxygen Inorganic materials 0.000 claims abstract 7
- 239000001301 oxygen Substances 0.000 claims abstract 7
- 125000004414 alkyl thio group Chemical group 0.000 claims abstract 6
- 125000000547 substituted alkyl group Chemical group 0.000 claims abstract 5
- 125000004432 carbon atom Chemical group C* 0.000 claims 14
- 150000001875 compounds Chemical class 0.000 claims 7
- 229910052717 sulfur Chemical group 0.000 claims 6
- 239000011593 sulfur Chemical group 0.000 claims 6
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical group [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 4
- 239000002253 acid Substances 0.000 claims 4
- 229910052801 chlorine Inorganic materials 0.000 claims 4
- 239000000460 chlorine Chemical group 0.000 claims 4
- 229910052731 fluorine Inorganic materials 0.000 claims 4
- 239000011737 fluorine Substances 0.000 claims 4
- 125000001153 fluoro group Chemical group F* 0.000 claims 4
- 238000000034 method Methods 0.000 claims 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 4
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims 3
- 241000607479 Yersinia pestis Species 0.000 claims 3
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical group BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims 3
- 229910052794 bromium Inorganic materials 0.000 claims 3
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims 2
- 241000233866 Fungi Species 0.000 claims 2
- 241000238631 Hexapoda Species 0.000 claims 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 2
- 150000002148 esters Chemical class 0.000 claims 2
- 239000002904 solvent Substances 0.000 claims 2
- DUFGYCAXVIUXIP-UHFFFAOYSA-N 4,6-dihydroxypyrimidine Chemical compound OC1=CC(O)=NC=N1 DUFGYCAXVIUXIP-UHFFFAOYSA-N 0.000 claims 1
- CZPWVGJYEJSRLH-UHFFFAOYSA-N Pyrimidine Chemical compound C1=CN=CN=C1 CZPWVGJYEJSRLH-UHFFFAOYSA-N 0.000 claims 1
- 150000001350 alkyl halides Chemical class 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 125000004093 cyano group Chemical group *C#N 0.000 claims 1
- 150000008050 dialkyl sulfates Chemical class 0.000 claims 1
- 239000003085 diluting agent Substances 0.000 claims 1
- 125000004705 ethylthio group Chemical group C(C)S* 0.000 claims 1
- 150000004820 halides Chemical class 0.000 claims 1
- 239000002917 insecticide Substances 0.000 claims 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims 1
- 239000000575 pesticide Substances 0.000 claims 1
- 239000004094 surface-active agent Substances 0.000 claims 1
- 239000005864 Sulphur Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing heterocyclic radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/645—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having two nitrogen atoms as the only ring hetero atoms
- C07F9/6509—Six-membered rings
- C07F9/6512—Six-membered rings having the nitrogen atoms in positions 1 and 3
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Molecular Biology (AREA)
- Pest Control & Pesticides (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Plant Pathology (AREA)
- Dentistry (AREA)
- Engineering & Computer Science (AREA)
- Agronomy & Crop Science (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
- Saccharide Compounds (AREA)
- Cephalosporin Compounds (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (10)
- 다음 일반식 (Ⅰ)의 6-옥소-피리미디닐 (티오노)-포스페이트.상기 식에서,X는 산소 또는 황이고;R은 알킬이며;R1은 플루오로 알킬이고;R2는 수소, 임의로 치환된 알킬, 알콕시, 알킬티오, 디알킬아미노, 또는 아릴이고;R3는 알킬 또는 아릴이며;R4는 수소, 할로겐 또는 알킬이다.
- 제 1 항에 있어서, X가 산소 또는 황이고, R은 탄소수 1 내지 6의 알킬이며, R1은 탄소원자 1 내지 6개와 불소원자 1 내지 6개를 갖는 플루오로알킬이고, R2는 수소;탄소원자 1 내지 6개를 함유하며 불소, 염소, 브롬, 니트로, 시아노, C1-C4-알콕시 또는 C1-C4-알킬티오에 의해 임의로 치환된 알킬; 각 알킬부위의 탄소수가 1 내지 6개인 알콘시, 알킬티오 또는 디알킬아미노;또는 페닐이고, R3는 탄소수 1 내지 6의 알킬, 또는 페닐이며, R4는 수소, 불소, 염소, 브롬, 또는 탄소수 1 내지 6의 알킬인 일반식(Ⅰ)의 화합물.
- 제 1 항에 있어서, X가 산소 또는 황이고, R은 탄소수 1 내지 4의 알킬이며, R1은 탄소원자 1 내지 4개와 불소원자 1 내지 6개를 갖는 플루오로알킬이고, R2는 수소;탄소원자 1 내지 4개를 함유하며 불소, 염소, 메톡시, 에톡시 또는 에틸티오에 의해 임의로 치환된 알킬; 탄소수 1 내지 4개인 알쿠시, 탄소수 1 내지 4의 알킬티오 알킬라디칼당 탄소원자 1 내지 4개의 디알킬아미노; 또는 페닐이고, R3는 탄소수 1 내지 4의 알킬 또는 페닐이며, R4는 수소, 불소, 염소, 브롬, 또는 탄소수 1 내지 4의 알킬인 일반식(Ⅰ)의 화합물.
- (a) 일반식 (Ⅱ)의 라이드를, 경우에 따라 산수용체의 존재하 및 경우에 따라 용매의 존재하에서, 일반식 (Ⅲ)의 1,6-디하이드로-4-하이드록시-6-옥소-피리미딘과 반응시키거나;(b) R3가 알킬인 경우에는, 일반식 (Ⅳ)의 0-(6-하이드록시-피리미딘-4-일) (티오노)-포스페이트를, 경우에 따라 산 수용체의 존재하 및 경우에 따라 용매의 존재하에서, () 일반식 (Ⅴ)의 알킬할라이드와 반응시키거나, () 일반식 (Ⅵ)의 디 알킬 설페이트와 반응 시킴을 특징으로 하는, 일반식 (Ⅰ)의 6-옥소-피리미디닐 (티오노)-포스포르 산 에스테르의 제조 방법.상기 식에서,X는 산소 또는 황을 나타내고;R은 알킬을 나타내며;R1은 플루오로 알킬을 나타내고;R2는 수소, 임의로 치환된 알킬, 알콘시, 알킬티오, 디알킬 아미노, 또는 아릴을 나타내며;R3는 알킬 또는 아릴을 나타내고 단 일반식 (Ⅴ) 및 (Ⅵ)에서는 알킬을 나타내며;R4는 수소, 할로겐 또는 알킬을 나타내고;Hal 및 Hal1은 할로겐을 나타낸다
- 제 1 항 또는 4항에 따르는 일반식 (Ⅰ)의 화합물 적어도 하나를 함유함을 특징으로 하는 살충제.
- 해충, 특히 곤충 및 진균을 퇴치하기 위한 제 1 항 또는 4항에 따르는 일반식 (Ⅰ) 화합물의 용도.
- 제 1 항 또는 4항에 따르는 일반식 (Ⅰ)의 화합물을 해충, 바람직하게는 곤충 및 진균 또는 이들의 서식지에 작용 시킴을 특징으로 하여, 해충을 구제하는 방법.
- 제 1 항 또는 4항에 따르는 일반식 (Ⅰ)의 화합물을 중량제 및/또는 계면활성제와 혼합함을 특징으로 하는 살충제의 제조 방법.
- 다음 일반식 (Ⅳ)의 0-(6-하이드록시피리미딘-4-일) (티오노)-포스포로 산 에스테르.상기 식에서,X는 산소 또는 황이고;R은 알킬이며;R1은 플루오알킬이고;R2는 수소, 임의로 치환된 알킬, 알콘시, 알킬티오, 디알킬아미노, 또는 아릴이며;R4는 수소, 할로겐 또는 알킬이다.
- 일반식 (Ⅸ)의 4,6-디하이드록시피리미딘을, 경우에 따라 산 수용체, 예를 들면 트리에틸아민의 존재하 및 경우에 따라 희석제의 존재하에서, 일반식 (Ⅱ)의 할라이드와 반응 시킴을 특징으로 하는 일반식 (Ⅳ)의 0-(6-하이드록시피리미딘-4-일) (티오노)-포스포로 산 에스테르의 제조 방법.상기 식에서,X는 산소 또는 황이고;R은 알킬이며;R1은 플루오로알킬이고;R2는 수소, 임의로 치환된 알킬, 알콘시, 알킬티오, 디알킬아미노, 또는 아릴이며;R4는 수소, 할로겐 또는 알킬이고,Hal은 할로겐을 나타낸다.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19863605002 DE3605002A1 (de) | 1986-02-18 | 1986-02-18 | Phosphorsaeureester |
| DE3605002.4 | 1986-02-18 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR870007943A true KR870007943A (ko) | 1987-09-23 |
Family
ID=6294291
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR870001108A KR870007943A (ko) | 1986-02-18 | 1987-02-11 | 인산 에스테르의 제조 방법 |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US4771040A (ko) |
| EP (1) | EP0234356B1 (ko) |
| JP (1) | JPS62192392A (ko) |
| KR (1) | KR870007943A (ko) |
| AT (1) | ATE44960T1 (ko) |
| AU (1) | AU6916687A (ko) |
| BR (1) | BR8700710A (ko) |
| DD (1) | DD256643A5 (ko) |
| DE (2) | DE3605002A1 (ko) |
| DK (1) | DK79587A (ko) |
| HU (1) | HUT45541A (ko) |
| IL (1) | IL81589A0 (ko) |
| ZA (1) | ZA871131B (ko) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5453414A (en) * | 1993-05-20 | 1995-09-26 | Rohm And Haas Company | 2-arylpyrimidines and herbicidal use thereof |
| US5300477A (en) * | 1992-07-17 | 1994-04-05 | Rohm And Haas Company | 2-arylpyrimidines and herbicidal use thereof |
| US5726124A (en) * | 1992-07-17 | 1998-03-10 | Rohm And Haas Company | 2-arylpyrimidines and herbicidal use thereof |
| US5629264A (en) * | 1995-03-23 | 1997-05-13 | Rohm And Haas Company | 2-aryl-5,6-dihydropyrimidinones and herbicidal use thereof |
| WO2003084936A2 (en) * | 2002-04-10 | 2003-10-16 | Orchid Chemicals & Pharmaceuticals Limited | Amino substituted pyrimidinone derivatives useful in the treatment of inflammation and immunological |
| ES2365011T3 (es) * | 2002-07-22 | 2011-09-20 | Orchid Research Laboratories Limited | Nuevas moléculas bioactivas. |
| US20090163521A1 (en) * | 2005-06-28 | 2009-06-25 | Orchid Research Laboratories Limited | Novel Pyrazolopyrimidinone Derivatives |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1369062A (fr) * | 1962-08-24 | 1964-08-07 | Bayer Ag | Nouvelles compositions insecticides et acaricides et leur procédé de fabrication |
| DE2630054A1 (de) * | 1976-07-03 | 1978-01-12 | Bayer Ag | 6-oxo-pyrimidinyl(thiono)(thiol)- phosphor(phosphon)-saeureester bzw. -esteramide, verfahren zu ihrer herstellung und ihre verwendung als insektizide und akarizide |
| DE2722402A1 (de) * | 1977-05-17 | 1978-11-30 | Bayer Ag | 1-phenyl-6-oxo-pyrimidinyl(thiono) (thiol)-phosphor(phosphon)-saeureester bzw. -esteramide, verfahren zu ihrer herstellung und ihre verwendung als insektizide und akarizide |
| US4575499A (en) * | 1982-11-22 | 1986-03-11 | The Dow Chemical Company | Phosphorus derivatives of 4-pyrimidinols |
| DE3317824A1 (de) * | 1983-05-17 | 1984-11-22 | Bayer Ag, 5090 Leverkusen | Phosphorsaeureester |
| DE3445465A1 (de) * | 1984-12-13 | 1986-06-19 | Bayer Ag, 5090 Leverkusen | Pyrimidinyl-thionophosphorsaeureester |
| DE3527861A1 (de) * | 1985-08-02 | 1987-02-05 | Bayer Ag | Phosphorsaeureester |
-
1986
- 1986-02-18 DE DE19863605002 patent/DE3605002A1/de not_active Withdrawn
-
1987
- 1987-02-05 EP EP87101560A patent/EP0234356B1/de not_active Expired
- 1987-02-05 AT AT87101560T patent/ATE44960T1/de not_active IP Right Cessation
- 1987-02-05 DE DE8787101560T patent/DE3760363D1/de not_active Expired
- 1987-02-10 US US07/013,081 patent/US4771040A/en not_active Expired - Fee Related
- 1987-02-11 KR KR870001108A patent/KR870007943A/ko not_active Application Discontinuation
- 1987-02-11 AU AU69166/87A patent/AU6916687A/en not_active Abandoned
- 1987-02-16 JP JP62031650A patent/JPS62192392A/ja active Pending
- 1987-02-16 IL IL81589A patent/IL81589A0/xx unknown
- 1987-02-17 DD DD87299966A patent/DD256643A5/de unknown
- 1987-02-17 HU HU87617A patent/HUT45541A/hu unknown
- 1987-02-17 ZA ZA871131A patent/ZA871131B/xx unknown
- 1987-02-17 BR BR8700710A patent/BR8700710A/pt unknown
- 1987-02-17 DK DK079587A patent/DK79587A/da not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| AU6916687A (en) | 1987-08-20 |
| ZA871131B (en) | 1987-08-11 |
| JPS62192392A (ja) | 1987-08-22 |
| DE3605002A1 (de) | 1987-08-20 |
| DK79587A (da) | 1987-08-19 |
| ATE44960T1 (de) | 1989-08-15 |
| IL81589A0 (en) | 1987-09-16 |
| DD256643A5 (de) | 1988-05-18 |
| EP0234356A1 (de) | 1987-09-02 |
| DE3760363D1 (en) | 1989-08-31 |
| BR8700710A (pt) | 1987-12-22 |
| US4771040A (en) | 1988-09-13 |
| HUT45541A (en) | 1988-07-28 |
| EP0234356B1 (de) | 1989-07-26 |
| DK79587D0 (da) | 1987-02-17 |
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