KR870010033A - 살 균 제 - Google Patents

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KR870010033A
KR870010033A KR870003674A KR870003674A KR870010033A KR 870010033 A KR870010033 A KR 870010033A KR 870003674 A KR870003674 A KR 870003674A KR 870003674 A KR870003674 A KR 870003674A KR 870010033 A KR870010033 A KR 870010033A
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KR950004002B1 (ko
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마가렛트 안토니 비비엔
마틴 클라우 존
디 프레인 폴
뷰트먼트 케빈
리차드 엘리스 고프레이 크리스토퍼
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알란 브라이안 벡
임페리알 케미칼 인더스트리스 피엘씨
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D207/30—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
    • C07D207/32—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • C07D207/33—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms with substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • C07D207/337—Radicals substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
    • A01N43/38—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings condensed with carbocyclic rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/58—1,2-Diazines; Hydrogenated 1,2-diazines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D209/02—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom condensed with one carbocyclic ring
    • C07D209/04—Indoles; Hydrogenated indoles
    • C07D209/10—Indoles; Hydrogenated indoles with substituted hydrocarbon radicals attached to carbon atoms of the hetero ring
    • C07D209/18—Radicals substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/54—Radicals substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/77—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom ortho- or peri-condensed with carbocyclic rings or ring systems
    • C07D307/78—Benzo [b] furans; Hydrogenated benzo [b] furans
    • C07D307/79—Benzo [b] furans; Hydrogenated benzo [b] furans with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to carbon atoms of the hetero ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
    • C07D333/02—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings
    • C07D333/04—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom
    • C07D333/06—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to the ring carbon atoms
    • C07D333/24—Radicals substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
    • C07D333/50—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom condensed with carbocyclic rings or ring systems
    • C07D333/52—Benzo[b]thiophenes; Hydrogenated benzo[b]thiophenes
    • C07D333/54—Benzo[b]thiophenes; Hydrogenated benzo[b]thiophenes with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to carbon atoms of the hetero ring
    • C07D333/60—Radicals substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals

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  • Organic Chemistry (AREA)
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  • Environmental Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
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  • Pest Control & Pesticides (AREA)
  • Health & Medical Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Pyrrole Compounds (AREA)
  • Heterocyclic Compounds Containing Sulfur Atoms (AREA)
  • Furan Compounds (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Pyridine Compounds (AREA)

Abstract

내용 없음

Description

살균제
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (12)

  1. 일반식(1)의화합물 및 그의 입체이성체
    [식중,W는 R1O2C-C=CH-ZR2(서로 동일 또는 상이한 R1 및 R2는 알킬 또는 플루오로 알킬 그룹이고, Z는 산소 또는 황원자);
    A는 산수 또는 황원자, -NR3- 또는 -CR4R5;
    X,Y 및 Z1은 (동일 또는 상이함)수소 또는 할로겐 원자, 또는 하이드록시, 임의 치환된 알킬, 임의 치환된 사이클로알킬, 임의 치환된 사이클로알킬알킬, 임의 치환된 아랄킬, 임의 치환된 헤테로아릴알킬, 임의 치환된 아릴옥시알킬, 임의 치환된 헤테로아릴옥시알킬, 임의 치환된 알케닐, 임의 치환된 알키닐, 임의 치환된 아릴, 임의 치환된 헤테로아릴, 임의치환된 알콕시, 임의 치환된 아릴알콕시, 임의 치환된 아릴옥시, 임의 치환된 헤테로아릴옥시, 임의 치환된 아실옥시, 임의치환된 아미노, 임의 치환된 아실아미노, 임의 치환된 아릴아조, 니트로, 시아노, -CO2R6,-CONR7R8,-COR9,-CR=NR10,-CR=NOR10또는 -N=CR11R12그룹,
    또는 그룹 X 및 Y는 환상에서 인접위치에 있을 경우, 임의 결함하여 융합환을 마들며 방향족 또는 지방족이되며 임의로 한개 또는 그 이상의 헤테로원자를 함유한다;
    R,R3,R4,R5,R6,R7,R8,R9,R10,R11및 R12은 (서로 동일 또는 상이함), 수소원자(단 R4및 R5가 수소가아닐 경우) 또는 임의 치환 알킬, 임의 치환사이클로알킬, 임의 치환 사이클로 알킬알킬, 임의 치환 아랄킬, 임의 치환헤테로아릴알킬, 임의 치환 아릴옥시알킬, 임의 치환 헤테로아릴옥시알킬, 임의 치환 알케닐, 임의 치환 알키닐, 임의 치환 헤테로아릴 그룹];
  2. 제1항에 있어서, X,Y 및 Z1은 수소, 할로겐, C1-4알킬 C1-4)아릴, 알킬헤테로아릴 C1-4알킬, 헤테로아릴옥시 C1-4알킬, 헤테로아릴옥시, 아릴옥시 C1-4알킬, 알콕시, 아릴 C1-4알콕시, 아리옥시, 아릴 C1-4알케닐, 헤테로아릴 C1-4알케닐, 아릴 C2-4알키닐, 헤테로아릴 C2-4알키닐, 시아노 C2-4알콕시카보닐 및 아릴옥시카보닐로 구성된 그룹으로부터 선택되며, X,Y 및 Z1중 하나는 수소가 아니며 그 수소가 그룹 W에 인접한 헤테로싸클이환상에 있지 않는 화합물.
  3. 제1항 또는 제2항에 있어서, R1및 R2가 둘다메틸인 화합물.
  4. 일반식(1a)의 화합물:
    [식중, X는 (아실레이트 그룹에 인접한 위치에 있음)할로겐, C1-4알킬, 할로 C1-4알킬, 아릴C1-4알킬, 아릴옥시C1-4알킬, 아릴C1-4알케닐, 아릴옥시 또는 아실].
  5. 일반식(1b)의 화합물.
    [식중, R1은 수소, C1-4알킬 또는 아릴(C1-4)알킬;
    X는 수소, (C1-4)알킬, 아릴(C1-4)알킬, 아릴(C2-4)알케닐 eh는 아실; 및
    Y 및 Z1은 수소이고; X가 수소일때 Y 및 Z1은 함께 융합 벤젠환을 형성한다].
  6. (i)일반식(2)의 케토에스테르를 통상의 용매내에서 일반식 Ph3P+, -CH(ZR2)의 포소포란과 처리하거나;
    (ii)산성 또는 염기성 조건하에서 일반식(10)의 아세탈로부터 알콜 R2ZH를 방출하거나;
    Z가 산소일 경우,
    (ⅲ)일반식(13)의 화합물(R13은 금속원자)을 R2Q로 처리하거나 R13이 수소인 경우 연속적으로 염기 및 R2Q로 리하거나;
    (ⅳ)일반식(12)의 아크릴산 유도체를 브롬, 시약 R2OM 및 나트륨 수소 황산염으로 연속 처리하거나;
    Z가 황일 경우,
    (ⅴ)일반식(2)의 케토에스테르를 일반식(CH3)3SiCH(Li)SR2의 리티오종으로 처리하거나;
    (ⅵ)임의적으로 탈수소제의 조건하에서 산성 조건하에서 일반식(13)의 에놀 (R13은 수소)을 일반식 R2SH의 티올과 반응시키거나;
    (ⅶ)일반식(15)의 베타 클로로아크릴레이트를 일반식 R2SM의 티올레이트와 반응시키거나;
    (ⅷ)다음 일반식(16)의 베타-설포닐옥시아크릴레이트를 일반식 R2SM의 티올레이트로 처리하는 것으로 구성되는,
    [식중, A, X, Y, Z, Z1, R1및 R2는 제1항에 기술된 바와 같으며;
    Ph는 페닐;
    R13은 수소 또는 금속원자;
    Q는 이탈그룹;
    M은 금속원자 또는 결합 할로겐을 가지는 금속원자, 제1항의 일반식(Ⅰ)화합물의 제조방법.
  7. 본 원에 기술된 일반식(2) 및 (9) 내지 (17)의 화학중간 물질.
  8. 활성성분으로서, 살균 효과량의 제1항의 화합물 및 살균에 허용 가능한 담체 또는 희석제를 포함하는 살균조성물.
  9. 식물 또는 종자 또는 그의 국부에 제1항의 화합물 또는 제8항의 조성물을 가하는 것을 포함하는, 살충 또는 식물 성장 조절용 조성물.
  10. 활성 성분으로서, 효과량 만큼의 제1항의 화합물 및 허용 가능한 EKAC 또는 희석제를 포함하는 살충 또는 식물 성장 조절용 조성물.
  11. 곤충 또는 그의 국부에, 일반식(1)의 살충 화합물을 효과량 만큼 투여하는 것으로 구성되는 곤충 페스트 퇴치 방법.
  12. 식물에, 제1항에 따르는 일반식(1)의 식물 성장 조절용 화합물을 효과량 만큼 투여하는 것으로 구성되는 식물 성장 조절 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019870003674A 1986-04-17 1987-04-17 살균제의 제조방법 KR950004002B1 (ko)

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GB8609452 1986-04-17
GB868609452A GB8609452D0 (en) 1986-04-17 1986-04-17 Fungicides
US8609452 1986-04-17

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AT (1) ATE61363T1 (ko)
AU (1) AU611387B2 (ko)
BR (1) BR8701891A (ko)
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US5679967A (en) * 1985-01-20 1997-10-21 Chip Express (Israel) Ltd. Customizable three metal layer gate array devices
GB8609452D0 (en) * 1986-04-17 1986-05-21 Ici Plc Fungicides
GB8619236D0 (en) * 1986-08-06 1986-09-17 Ici Plc Fungicides
FR2604173B1 (fr) * 1986-09-18 1988-12-30 Roussel Uclaf Nouveaux derives de l'indole, leur procede de preparation et leur application comme pesticide
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DE3768314D1 (de) 1991-04-11
NZ219871A (en) 1989-09-27
US4863503A (en) 1989-09-05
CN87103543A (zh) 1988-02-24
GB8609452D0 (en) 1986-05-21
JPS62258344A (ja) 1987-11-10
AU7111087A (en) 1987-10-22
JP2591743B2 (ja) 1997-03-19
EP0243014A1 (en) 1987-10-28
ZA872504B (en) 1987-12-30
GR3001563T3 (en) 1992-11-23
US5160364A (en) 1992-11-03
CN1021403C (zh) 1993-06-30
ATE61363T1 (de) 1991-03-15
IL82128A (en) 1994-05-30
DK187787D0 (da) 1987-04-10
US5053073A (en) 1991-10-01
BR8701891A (pt) 1988-02-02
DK187787A (da) 1987-10-18
AU611387B2 (en) 1991-06-13
ES2039235T3 (es) 1993-09-16
HUT43234A (en) 1987-10-28
EP0243014B1 (en) 1991-03-06
CA1297871C (en) 1992-03-24
KR950004002B1 (ko) 1995-04-22
US5073184A (en) 1991-12-17
HU203884B (en) 1991-10-28

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