KR880001717A - 에폭사이드-연장 폴리올 에스테르 및 그의 제조 방법 - Google Patents

에폭사이드-연장 폴리올 에스테르 및 그의 제조 방법 Download PDF

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KR880001717A
KR880001717A KR1019870008123A KR870008123A KR880001717A KR 880001717 A KR880001717 A KR 880001717A KR 1019870008123 A KR1019870008123 A KR 1019870008123A KR 870008123 A KR870008123 A KR 870008123A KR 880001717 A KR880001717 A KR 880001717A
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epoxide
mixtures
range
polyol ester
polyol
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에프 화이트 존
아아르 폴라드 마이클
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로드릭 다불류 맥도널드
아트란틱 릿치휘이르드 캄파니
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
    • C07C69/22—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety
    • C07C69/33—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety esterified with hydroxy compounds having more than three hydroxy groups
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L33/00—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof
    • A23L33/20—Reducing nutritive value; Dietetic products with reduced nutritive value
    • A23L33/21—Addition of substantially indigestible substances, e.g. dietary fibres
    • A23L33/25—Synthetic polymers, e.g. vinylic or acrylic polymers
    • A23L33/26—Polyol polyesters, e.g. sucrose polyesters; Synthetic sugar polymers, e.g. polydextrose
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L33/00—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof
    • A23L33/10—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof using additives
    • A23L33/115—Fatty acids or derivatives thereof; Fats or oils
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L33/00—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof
    • A23L33/20—Reducing nutritive value; Dietetic products with reduced nutritive value
    • A23L33/21—Addition of substantially indigestible substances, e.g. dietary fibres
    • A23L33/25—Synthetic polymers, e.g. vinylic or acrylic polymers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S426/00—Food or edible material: processes, compositions, and products
    • Y10S426/804—Low calorie, low sodium or hypoallergic

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Food Science & Technology (AREA)
  • Nutrition Science (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mycology (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Coloring Foods And Improving Nutritive Qualities (AREA)
  • Edible Oils And Fats (AREA)
  • Epoxy Compounds (AREA)

Abstract

내용 없음

Description

에폭사이드-연장 폴리올 에스테르 및 그의 제조 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (49)

  1. 하기 일반식의 에폭사이드-연장 폴리올 에스테르;
    P(OH)a+c(EPO)n(RCOOH)b
    상기 식에서, P(OH)는 a=2-8의 일차 히드록실, c=0-8의 이차+심차 히드록실을 갖는 폴리올이고, a+c 는 3-8의 범위이고, EPO는 C3-C4의 에폭사이드이고 n은 최소 에폭시화 인덱스 평균수 na이고, 상기 폴리올의 일차 히드록실 95% 이상이 이차 또는 심차 히드록실로 전환되기에 충분한 수이며, RCOOH는 R이 C7-C23의 알킬사슬인 지방산 아실 성분이고 b는 2〈ba+c 범위의 평균수이다.
  2. 제1항에 있어서, n이 올리부유와 비교하여 약 10%이하의 리파제 가수분해 속도를 부여하기에 충분한 에폭사이드-연장 폴리올 에스테르.
  3. 제2항에 있어서, R이 소화관 흡수에 대해 본질적으로 저항성 있도록 하기에 충분한 길이를 갖는 에폭사이드-연장 폴리올 에스테트.
  4. 제3항에 있어서, n이 2-8 범위의 평균값을 갖는 에폭사이드-연장 폴리올 에스테르.
  5. 제1항에 있어서, 폴리올이 당, 글리세라이드, 사카라이드 및 그의 혼합물로 부터 선택된 에폭사이드-연장 폴리올 에스테르.
  6. 제5항에 있어서, 당의 글루코오즈, 만노오즈, 갈락토우즈, 아라비노우즈, 크실로즈, 소르비토즈, 아밀로우즈 및 그의 혼합물로부터 선택된 에폭사이드-연장 폴리올 에스테르.
  7. 제5항에 있어서, 에폭사이드가 프로필렌 옥사이드, 펜텐 옥사이드, 1, 2-에폭시부탄, 2, 3-에폭시부탄, 1, 2-에폭시-2-메틸프로판, 1, 2-에폭시시클로헥산, 및 그의 혼합물로부터 선택된 에폭사이드-연장폴리올 에스테르.
  8. 제7항에 있어서, R이 소화관 흡수에 대해 본질적으로 저항성이 있도록 하기에 충분한 길이를 갖는 에폭사이드-연장 폴리올 에스테르.
  9. 제8항에 있어서, R이 C14-18알킬사슬 및 그의 혼합물로부터 선택된 에폭사이드-연장 폴리올 에스테르.
  10. 제9항에 있어서, 폴리올이 당, 글리세라이드, 사카라이드 및 그의 혼합물로 부터 선택된 에폭사이드-연장 폴리올 에스테르.
  11. 제1항에 있어서, P(OH)는 글리세롤, a는 2, c는 1, EPO는 프로필렌 옥사이드, n은 약 2 내지 8의 평균값을 가지며 b는 2〈b3의 평균값을 갖는 에폭사이드-연장 폴리올 에스테르.
  12. 제11항에 있어서, n이 약 2-5의 범위 이고 b가 3인 에폭사이드-연장 폴리올 에스테르.
  13. 제12항에 있어서, n이 약 3-5 범위인 에폭사이드-연장 폴리올 에스테르.
  14. 제12항에 있어서, R이 소화관 흡수에 대해 본질적으로 저항성이 있도록 하기에 충분한 길이를 갖는 에폭사이드-연장 폴리올 에스테르.
  15. 제14항에 있어서, R이 C14-18알킬 사슬과 그의 혼합물로 부터 선택된 에폭사이드-연장 폴리올 에스테르.
  16. 제1항에 있어서,P(OH)가 글리세롤, a는 2, C=1이고, EPO는 부틸렌 옥사이드와 이소부틸렌 옥사이드로 부터 선택되고, n은 2 내지 8사이의 평균 값이고 b는 2〈b3 의 평균값을 갖는 에폭사이드-연장 폴리올 에스테르.
  17. 제16항에 있어서, n이 약 2-5 범위이고 b는 3인 에폭사이드-연장 폴리올 에스테르.
  18. 제17항에 있어서, n이 약 3-6범위인 에폭사이드-연장 폴리올 에스테르.
  19. 제17항에 있어서, R이 소화관 흡수에 대해 본질적으로 저항성이 있도록 하기에 충분한 길이를 갖는 에폭사이드-연장 폴리올 에스테르.
  20. 제19항에 있어서, R이 C14-18알킬 사슬과 그의 혼합물로부터 선택된 에폭사이드-연장 폴리올 에스테르.
  21. 하기 (a)와 (b)의 단계를 포함하는 일반식 P(OH)a+c(EPO)n(RCOOH)b인 에폭사이드-연장 폴리올 에스테르의 제조 방법: a) a=2-8의 일차 히드록실, C=0-8의 이차+삼차 히드록실을 갖고, a+c가 3-8의 범위인 일반식 P(OH)a+c의 폴리올을 염기성 촉매의 존재하에 상기 폴리올의 일차 히드록실 95%이상이 이차 혹은 삼차 히드록실로 전환하기에 충분한 최소 에폭시화 인덱스 편균 수 n=a을 갖는 폴리에폭사이드-연장 폴리올을 제공하기에 충분한 시간동안 C3-C6에폭사이드인 EPO와 반응시키고 : b) 상기 에폭사이드-연장 폴리올 에스테르를 제조하기 위해 R이 C7-C22알킬 사슬이고 b는 2〈ba+c 범위의 평균수인 지방산, RCOOH, 최소한 하나의 사익 에폭사이드-연장 폴리올을 반응시킨다.
  22. 제21항에 있어서, n이 올리브유와 비교하여 약 10% 이하의 리파제 가수분해 속도를 부여하기에 충분한 방법.
  23. 제22항에 있어서, R이 소화관 흡수에 대해 근본적으로 저항성이 있도록 하기에 충분한 길이를 갖는 방법.
  24. 제23항에 있어서, R이 C14-18알킬 사슬과 그의 혼합물로 부터 선택된 방법.
  25. 제23항에 있어서, 폴리올이 당, 글리세라이드, 사카라이드와 그의 혼합물로 부터 선택된 방법.
  26. 제25항에 있어서, 에폭사이드가 프로필렌 옥사이드, 펜텐 옥사이드, 1,2-에폭시부탄, 2, 3-에폭시부탄, 1, 2-에폭시-2-메틸프로판, 1, 2-에폭시시클로헥산, 및 그의 혼합물로 부터 선택된 방법.
  27. 제25항에 있어서, P(OH)가 글리세롤, a는 2, c는 1, EPO는 프로필렌 옥사이드이고, n은 약 2 내지 8사이의 평균값을 가지고 b는 2＜b3의 평균값을 갖는 방법.
  28. 제27항에 있어서, n이 약 2-5의 범위이고 b가 3인 방법.
  29. 제28항에 있어서, n이 약 3-5의 범위인 방법.
  30. 제28항에 있어서, R이 소화관 흡수에 대해 근본적으로 저항성이 있도록 하기에 충분한 길이를 갖는 방법.
  31. 제30항에 있어서, R이 C14-18알킬사슬과 그의 혼합물로 부터 선택된 방법.
  32. 제25항에 있어서, P(OH)가 글리세롤이고, a는 2, c는 1이고, EPO는 부틸렌 옥사이드와 이소부틸렌옥사이드로 부터 선택되고, n은 2내지 8사이의 평균값을 갖고 b는 2〈b3의 평균값을 갖는 방법.
  33. 제32항에 있어서, n이 약 2-5의 범위이고 b가 3인 방법.
  34. 제33항에 있어서, n이 약 3-5의 범위인 방법.
  35. 제33항에 있어서, R이 소화관 흡수에 대해 근본적인 저항성이 있도록 하기에 충분한 길이를 갖는 방법.
  36. 제35항에 있어서, R이 C14-16알킬 사슬과 그의 혼합물로부터 선택된 방법.
  37. 제36항에 있어서, 하기 a)-c)의 단계를 포함하는 방법 : a)대두유, 평지종자유, 수지, 면실유, 코코낫유, 팜유, 바바쑤유, 옥수수유, 라아드, 어유, 올리브유, 낙화생유, 잇꽃종자류, 참기름, 조조바유와 해바라기종자유 및 그의 혼합물로부터 선택된 천연지방 또는 기름을 분열시켜 R이 상기 C7-C23알킬사슬인 하나 또는 그 이상의 지방산 RCO2H 과 글리세롤을 형성하고 :b) 상기 지방산으로부터 글리세율을 분리하고 :c)상기 글리세롤을 상기 염기 촉매 프로폭시화 부가 반응에 제공한다.
  38. 제37항에 있어서, n이 2-8 범위의 평균값을 갖는 방법.
  39. 제38항에 있어서, 에폭사이드가 프로필렌 옥사이드 ,펜텐옥사이드, 1, 2-에폭시부탄, 2, 3-에폭시부탄, 1, 2-에폭시-2-메틸프로판, 1, 2-에폭시시클로헥산과 그의 혼합물로 부터 선택된 방법.
  40. 제39항에 있어서, P(OH)가 글리세롤, a는 2, c는 1이고, EPO는 프로필렌 옥사이드이고, n은 약 2, 2, 이상의 평균값을 가지며 b는 2〈b≤3의 평균값을 갖는 방법.
  41. 제40항에 있어서, n이 약 2-5의 범위이고, b가 3인 방법.
  42. 제41항에 있어서, n이 약 3-5의 범위인 방법.
  43. 제41항에 있어서, R이 소화관 흡수에 대해 근본적으로 저항성이 있도록 하기에 충분한 길이를 갖는 방법.
  44. 제43항에 있어서, R이 C14-18알킬 사슬과 그의 혼합물로 부터 선택된 방법.
  45. 제39항에 있어서, P(OH)가 글리세롤, a는 2, c는 1이고, EPO는 부틸렌 옥사이드와 이소부틸렌 옥사디으로 부터 선택되고, n이 2내지 8사이의 평균값이고 b가 2〈b≤3의 평균값을 갖는 방법.
  46. 제45항에 있어서, n이 약 2-5의 범위이고 b가 3인 방법.
  47. 제46항에 있어서, n이 약 3-5의 범위인 방법.
  48. 제46항에 있어서, R이 소화관 흡수에 대해 근본적으로 저항성이 있도록 하기에 충분한 길이를 갖는 방법.
  49. 제48항에 있어서, R이 C14-18알킬사슬과 그의 혼합물로부터 선택된 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019870008123A 1986-07-25 1987-07-24 에폭사이드-연장 폴리올 에스테르 및 그의 제조방법 KR960004625B1 (ko)

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Application Number Priority Date Filing Date Title
US06/889552 1986-07-25
US06/889,552 US4861613A (en) 1986-07-25 1986-07-25 Non-digestible fat substitutes of low-caloric value
US06/889,552 1986-07-25

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KR880001717A true KR880001717A (ko) 1988-04-26
KR960004625B1 KR960004625B1 (ko) 1996-04-09

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US (3) US4861613A (ko)
EP (1) EP0254547B1 (ko)
JP (1) JP2518649B2 (ko)
KR (1) KR960004625B1 (ko)
CA (1) CA1311238C (ko)
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AU7600587A (en) 1988-01-28
JPS6335568A (ja) 1988-02-16
DE3784195T2 (de) 1993-06-03
US5603978A (en) 1997-02-18
GR3007102T3 (ko) 1993-07-30
KR960004625B1 (ko) 1996-04-09
IN167650B (ko) 1990-12-01
JP2518649B2 (ja) 1996-07-24
CA1311238C (en) 1992-12-08
EP0254547A3 (en) 1989-05-24
DD287484A5 (de) 1991-02-28
EP0254547A2 (en) 1988-01-27
AU606348B2 (en) 1991-02-07
US4861613A (en) 1989-08-29
ES2044935T3 (es) 1994-01-16
EP0254547B1 (en) 1993-02-17
US5641534A (en) 1997-06-24
DE3784195D1 (de) 1993-03-25

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