KR870011074A - 프로파르길옥시벤젠 유도체, 그의 제조방법 및 살진균제로서의 용도 - Google Patents

프로파르길옥시벤젠 유도체, 그의 제조방법 및 살진균제로서의 용도 Download PDF

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KR870011074A
KR870011074A KR870004663A KR870004663A KR870011074A KR 870011074 A KR870011074 A KR 870011074A KR 870004663 A KR870004663 A KR 870004663A KR 870004663 A KR870004663 A KR 870004663A KR 870011074 A KR870011074 A KR 870011074A
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radicals
atoms
propargyloxybenzene
hydrogen
same
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삐에르 뽈라스
레기 뻬뼁
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프랑소와 샤르띠앙
롱-뽈랑 아그로쉬미
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C07C43/02—Ethers
    • C07C43/235—Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring and to a carbon atom of a ring other than a six-membered aromatic ring
    • C07C43/243—Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring and to a carbon atom of a ring other than a six-membered aromatic ring having unsaturation outside the six-membered aromatic rings
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    • C07—ORGANIC CHEMISTRY
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    • C07C255/00—Carboxylic acid nitriles
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    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
    • A01N31/08—Oxygen or sulfur directly attached to an aromatic ring system
    • A01N31/16—Oxygen or sulfur directly attached to an aromatic ring system with two or more oxygen or sulfur atoms directly attached to the same aromatic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds containing nitrogen-to-oxygen bonds
    • A01N33/18—Nitro compounds
    • A01N33/20—Nitro compounds containing oxygen or sulfur attached to the carbon skeleton containing the nitro group
    • A01N33/22—Nitro compounds containing oxygen or sulfur attached to the carbon skeleton containing the nitro group having at least one oxygen or sulfur atom and at least one nitro group directly attached to the same aromatic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
    • A01N37/38—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
    • A01N37/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system having at least one carboxylic group or a thio analogue, or a derivative thereof, and one oxygen or sulfur atom attached to the same aromatic ring system
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C205/00—Compounds containing nitro groups bound to a carbon skeleton
    • C07C205/27—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by etherified hydroxy groups
    • C07C205/35—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by etherified hydroxy groups having nitro groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
    • C07C205/36—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by etherified hydroxy groups having nitro groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton to carbon atoms of the same non-condensed six-membered aromatic ring or to carbon atoms of six-membered aromatic rings being part of the same condensed ring system
    • C07C205/37—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by etherified hydroxy groups having nitro groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton to carbon atoms of the same non-condensed six-membered aromatic ring or to carbon atoms of six-membered aromatic rings being part of the same condensed ring system the oxygen atom of at least one of the etherified hydroxy groups being further bound to an acyclic carbon atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C07C43/02—Ethers
    • C07C43/20—Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring
    • C07C43/215—Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring having unsaturation outside the six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C07C43/02—Ethers
    • C07C43/20—Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring
    • C07C43/225—Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring containing halogen
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    • C07—ORGANIC CHEMISTRY
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    • C07C43/00—Ethers; Compounds having groups, groups or groups
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    • C07C43/20—Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring
    • C07C43/23—Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring containing hydroxy or O-metal groups
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    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C07C43/02—Ethers
    • C07C43/257—Ethers having an ether-oxygen atom bound to carbon atoms both belonging to six-membered aromatic rings
    • C07C43/285—Ethers having an ether-oxygen atom bound to carbon atoms both belonging to six-membered aromatic rings having unsaturation outside the six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
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    • C07C43/257—Ethers having an ether-oxygen atom bound to carbon atoms both belonging to six-membered aromatic rings
    • C07C43/29—Ethers having an ether-oxygen atom bound to carbon atoms both belonging to six-membered aromatic rings containing halogen

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Abstract

내용 없음

Description

프로파르길옥시벤젠 유도체, 그의 제조방법 및 살진균제로서의 용도
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (9)

  1. 하기 일반식 I의 프로파르길옥시벤젠 유도체 :
    [상기 식중, X는 동일하거나 다른 라디칼로서 이하(수소원자 및 할로겐원자, 필요하다면 모노-또는 디알킬화될 수도 있는 시아노, 니트로 및 아미노기, 알킬부분의 탄소원자수가 1∼12이며 모노-또는 폴리할로겐화될 수도 있는 알킬, 알콕시 또는 알킬티오 라디칼로서, 알킬 라디칼에 있어서는, 탄소원자수가 1∼4일때, 히드록시, 저급알콕시 또는 벤족시 또는 필요하다면 모노-또는 디알킬화될 수도 있는 아미노 라디칼로 치환되는 것이 가능하며, 탄소원자수 2∼5의 알케닐 또는 알켄옥시 라디칼, 필요하다면 치환될 수도 있는 페닐, 페녹시 라디칼)로 구성된 군으로부터 선택되며; m은 0∼5-n의 정수이고 ; Y 및 Z는 동인하거나 다를 수 있으며, 수소 또는 할로겐원자를 나타내고 ; n은 1 또는 2의 정수이며 ; 및 R1,R2R3및 R4는 동일하거나 다를 수 있고, 각각 수소원자 또는 저급알킬 라디칼로서, 단, R1, R2, R3, R4 및 X가 각각 수소원자이고 n이 1일 때, Y 및 Z가 모두 수소원자는 아니다.]
  2. 제1항에 있어서, 식중 n이 1이고 -O-C(R3,R4)-C=C-Z기가 페닐 고리상에 있으며, -O-C(R1,R2)-C=C-Y기에 대해 오르토-위치에 있는 프로파르길옥시벤젠 유도체.
  3. 제1항에 있어서, 식중 Y 및 Z가 동일하거나 다를 수 있으며, 브롬 또는 요오드 원자인 프로파르길옥시벤젠 유도체.
  4. 제1항에 있어서, 식중 n이 1이고 Y 및 Z가 수소원자일 때, X가 모두 수소원자는 아닌 프로파르길옥시벤젠 유도체를 제조하는 방법으로서, 하기의 반응도식과 같이 산수용체의 존재하에 디-또는 트리페놀을 프로파르길할라이드와 반응시키는 프로파르길옥시벤젠유도체의 제조방법.
  5. 제1항에 있어서, 식중 Y 또는 Z가운데 최소한 하나가 할로겐원자인 프로파르길옥시벤젠 유도체를 제조하는 방법으로서, 상수용체의 존재하에 하기의 반응을 수행하는 프로파르길옥시벤젠 유도체의 제조방법
    (상기 식중, Hal은 할로겐원자이다.)
  6. 제5항에 있어서, 식중 Hal이 요오드 또는 브롬원자인 프로파르길옥시벤젠 유도체의 제조방법.
  7. 하기 일반식 I의 화합물을 활성물질로서 함유하는 진균원인성 식물질병을 억제하는 살진균 조성물 :
    [상기 식중, X는 동일하거나 다른 라디칼로서 이하(수소원자 및 할로겐원자, 필요하다면 모노-또는 디알킬화될 수도 있는 시아노, 니트로 및 아미노기, 알킬부분의 탄소원자수가 1∼12이며 모노-또는 폴리할로겐화될 수도 있는 알킬, 알콕시 또는 알킬티오라디칼로서, 알킬 라디칼에 있어서는, 탄소원자수가 1∼4일때, 히드록실, 저급알콕시 또는 벤족시 또는 필요하다면 모노-또는 디알킬화될 수도 있는 아미노 라디칼로 치환되는 것이 가능하며, 탄소원자수 2∼5의 알케닐 또는 알켄옥시 라디칼, 필요하다면 치환될 수도 있는 페닐, 페녹시 라디칼)로 구성된 군으로부터 선택되며 ; m은 0∼5-n의 정수이고 ; Y 및 Z는 동일하거나 다를 수 있으며, 수소 또는 할로겐원자를 나타내고, n은 1 또는 2의 정수이며, R1,R2,R3및 R4는 동일하거나 다를 수 있고, 각각 수소원자 또는 저급알킬 라디칼이다.]
  8. 제7항에 있어서, 식중 치환기는 상기에서 정의한 바와 동일하며, 단, R1,R2,R3,R4 및 X가 각각 수소원자이고 n이 1일 때, Y 및 Z가 모두 수소원자는 아닐 살진균 조성물.
  9. 활성물질로서 제7항의 화합물을 함유하는 조성물을 사용하여 진균 원인성 식물질병을 억제하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR870004663A 1986-05-12 1987-05-12 프로파르길옥시벤젠 유도체, 그의 제조방법 및 살진균제로서의 용도 KR870011074A (ko)

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FR8606959 1986-05-12
FR8606959A FR2598408A1 (fr) 1986-05-12 1986-05-12 Derives propargyloxybenzenes : leur preparation et compositions fongicides les contenant

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KR870011074A true KR870011074A (ko) 1987-12-19

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EP (1) EP0249567A3 (ko)
JP (1) JPS62273931A (ko)
KR (1) KR870011074A (ko)
CN (1) CN87103507A (ko)
AU (1) AU7268387A (ko)
BG (1) BG79667A (ko)
BR (1) BR8702392A (ko)
DK (1) DK237287A (ko)
FI (1) FI872073A (ko)
FR (1) FR2598408A1 (ko)
HU (1) HUT46641A (ko)
IL (1) IL82312A0 (ko)
MA (1) MA20974A1 (ko)
OA (1) OA08595A (ko)
PL (1) PL265648A1 (ko)
PT (1) PT84859B (ko)
TN (1) TNSN87066A1 (ko)
ZA (1) ZA873357B (ko)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0749379B2 (ja) * 1985-12-27 1995-05-31 住友化学工業株式会社 置換ベンゼン誘導体およびそれを有効成分とする農園芸用殺菌剤
JPH0825944B2 (ja) * 1986-08-12 1996-03-13 住友化学工業株式会社 置換ベンゼン誘導体およびそれを有効成分とする農園芸用殺菌剤
MX2016013636A (es) * 2014-04-17 2017-02-28 Basf Se Nuevos inhibidores de la nitrificacion.
US10676408B2 (en) * 2014-12-18 2020-06-09 Basf Se Alkynylpyrazoles as nitrification inhibitors

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU3576571A (en) * 1970-11-16 1973-05-24 Stauffer Chemical Company Aryl acetylene ethers

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AU7268387A (en) 1987-11-19
DK237287D0 (da) 1987-05-11
FI872073A (fi) 1987-11-13
HUT46641A (en) 1988-11-28
BG79667A (bg) 1993-12-24
DK237287A (da) 1987-11-13
OA08595A (fr) 1988-11-30
JPS62273931A (ja) 1987-11-28
FI872073A0 (fi) 1987-05-11
MA20974A1 (fr) 1987-12-31
EP0249567A3 (fr) 1988-03-30
ZA873357B (en) 1987-11-03
TNSN87066A1 (fr) 1990-01-01
PT84859B (fr) 1989-07-06
BR8702392A (pt) 1988-02-17
PL265648A1 (en) 1988-08-18
CN87103507A (zh) 1988-01-13
EP0249567A2 (fr) 1987-12-16
IL82312A0 (en) 1987-10-30
PT84859A (fr) 1987-06-01
FR2598408A1 (fr) 1987-11-13

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