KR870008860A - 설포닐 아졸 및 그의 제조방법 - Google Patents

설포닐 아졸 및 그의 제조방법 Download PDF

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KR870008860A
KR870008860A KR870002343A KR870002343A KR870008860A KR 870008860 A KR870008860 A KR 870008860A KR 870002343 A KR870002343 A KR 870002343A KR 870002343 A KR870002343 A KR 870002343A KR 870008860 A KR870008860 A KR 870008860A
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radical
alkyl
sulfonyl
hydrogen
halogen
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주니찌 사이또
다쯔오 다무라
요시오 구라하시
노보루 마쯔모또
나오꼬 야마구찌
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다떼노 고자부로
니혼 도꾸슈 노야꾸 세이쬬 가부시끼가이샤
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Publication of KR870008860A publication Critical patent/KR870008860A/ko

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    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D233/00Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
    • C07D233/54Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
    • C07D233/64Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms, e.g. histidine
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647Triazoles; Hydrogenated triazoles
    • A01N43/6531,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/713Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with four or more nitrogen atoms as the only ring hetero atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D231/00Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/12Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
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    • C07DHETEROCYCLIC COMPOUNDS
    • C07D233/00Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
    • C07D233/54Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
    • C07D233/56Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring carbon atoms
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    • C07DHETEROCYCLIC COMPOUNDS
    • C07D233/00Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
    • C07D233/54Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
    • C07D233/66Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
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    • C07D233/66Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
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Abstract

내용 없음

Description

설포닐 아졸 및 그의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (12)

  1. 일반식(Ⅰ)의 설포닐 아졸.
    상기 식에서,
    X는 수소, 알킬, 할로겐, 알콕시 또는 릴을 나타내고,
    Y는 수소, 알킬, 할로겐, 니트로 또는 알콕시를 나타내며,
    Z가 수소, 알킬, 할로겐 또는 알콕시이거나,
    Y 및 Z가 함께, 헤테로 원자를 함유할 수 있는 임의로 치환된 사이클릭 환을 나타낼 수 있으며,
    Q는 일반식
    (여기에서, A는
    -N=라디칼 또는
    라디칼을 나타내고, R1은 수소, 알킬 또는 아릴을 나타내며, R2및 R3는 각각 수소, 알킬, 할로겐 또는 니트로이고 단, Y 및 Z가 임의로 치환된 환을 나타내는 경우에만 모든 R-치환체가 동시에 수소일 수 있다)의 라디칼, 1H-벤조트리아졸-1-일 라디칼 또는 1H-테트라졸-1-일 라디칼을 나타낸다.
  2. 제 1 항에 있어서, X가 탄소수 1 내지 4의 알킬을 나타내고, Y가 불소, 염소, 브롬, 니트로, 또는 탄소수 1 내지 4의 알킬을 나타내며, Z는 수소를 나타내고, Q는 일반식
    (여기에서 A는
    라디칼을 나타내고, R1은 수소, 또는 탄소수 1 내지 4의 알킬을 나타내며, R2및 R3는 각각 수소 또는 할로겐을 나타내고 단, R-치환체가 모두 동시에 수소가 아니다)의 라디칼, 1H-벤조트리아졸-1-일-라디칼 또는 1H-테트라졸-1-일 라디칼을 나타내는 일반식(Ⅰ)의 설포닐 아졸.
  3. 제 1 항에 있어서, X가 메틸을 나타내고, Y는 염소, 브로, 니트로, 또는 탄소수 1 내지 3의 알킬을 나타내며, Z는 수소를 나타내고, Q는 2-메틸-이미다졸-1-일 라디칼, 4,5-디클로로이미다졸-1-일 라디칼, 1H-벤조트리아졸-1-일 라디칼 또는1H-테트라졸-1-일-라디칼을 나타내는 일반식(Ⅰ)의 설포닐 아졸.
  4. 제 1 항에 있어서, 구조식
    의 1-(2-클로로-6-메틸-벤젠-설포닐)-2-메틸-이미다졸인 화합물.
  5. 제 1 항에 있어서, 구조식
    1-(2,5-디메틸-벤젠-설포닐)-1H-테트라졸인 화합물.
  6. 제 1 항에 있어서, 구조식
    의 1-(2-메틸-5-니트로-벤젠-설포닐)-4,5-디클로로이미다졸인 화합물.
  7. 제 1 항에 있어서, 구조식
    의 1-(5-클로로-2-메틸-벤젠-설포닐)-1H-벤조트리아졸인 화합물.
  8. 일반식(Ⅱ)의 화합물을 불활성 용매의 존재하에 및 경우에 따라 염기의 존재하에서, 일반식(Ⅲ)의 화합물과 반응시킴을 특징으로 하는 일반식(Ⅰ)의 설포닐 아졸의 제조 방법.
    상기 식에서,
    X는 수소, 알킬, 할로겐, 알콕시 또는 아릴을 나타내고,
    Y는 수소, 알킬, 할로겐, 니트로 또는 알콕시를 나타내며,
    Z가 수소, 알킬, 할로겐 또는 알콕시를 나타내거나
    Y 및 Z가 함게 헤테로원자 예를들면, 산소를 함유할 수 있는 임의로 치환된 사이클릭 환을 나타낼 수 있으며,
    Q는 일반식
    (여기에서 A는 -N= 라디칼 또는
    라디칼을 나타내고, R1은 수소, 알킬 또는 아릴을 나타내며, R2및 R3는 각각 수소, 알릴, 할로겐 또는 니트로이고, 단, Y 및 Z가 임의로 치환된 환을 나타내는 경우에만 모든 R-치환체가 동시에 수소일 수 있다)의 라디칼, 1H-벤조트리아졸-1-일 라디칼 또는 1H-테트라졸-1-일 라디칼을 나타내고,
    Hal은 할로겐을 나타내며,
    M은 수소, 알칼리금속 또는 알칼리토금속 원자를 나타낸다.
  9. 일반식(Ⅰ)의 설포닐 아졸을 적어도 하나 함유하는 농업용 및 원예용 살진균제 조성물.
  10. 일반식(Ⅰ)의 설포닐 아졸을 병원균 및 또는 그의 발생지역 및 식물병해의 발생지역에 자용시킴을 특징으로 하는 식물병해 억제 방법.
  11. 식물병해를 억제하기 위한 일반식(Ⅰ)의 설포닐 아졸의 용도.
  12. 일반식(Ⅰ)의 설포닐 아졸을 증량제 및 또는 계면활성제와 혼합함을 특징으로 하는 농업용 및 원예용 살진균제 조성물의 제조 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR870002343A 1986-03-20 1987-03-16 설포닐 아졸 및 그의 제조방법 KR870008860A (ko)

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JP60642 1986-03-20
JP61060642A JPS62221672A (ja) 1986-03-20 1986-03-20 新規スルホニルアゾ−ル

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KR870008860A true KR870008860A (ko) 1987-10-21

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US (1) US4804673A (ko)
EP (1) EP0237912A1 (ko)
JP (1) JPS62221672A (ko)
KR (1) KR870008860A (ko)
AU (1) AU7045687A (ko)
BR (1) BR8701241A (ko)
DK (1) DK141387A (ko)
HU (1) HUT43922A (ko)
IL (1) IL81909A0 (ko)
PT (1) PT84455B (ko)
ZA (1) ZA872014B (ko)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0284277A1 (en) * 1987-03-21 1988-09-28 AgrEvo UK Limited Cyanoimidazole fungicides
DE3833549A1 (de) * 1988-10-01 1990-04-12 Bayer Ag Substituierte phenoxyphenylsulfonylazole, verfahren zu ihrer herstellung sowie ihre verwendung als herbizide und pflanzenwuchsregulatoren
AU5772196A (en) * 1995-05-19 1996-11-29 Chiroscience Limited 3,4-disubstituted-phenylsulphonamides and their therapeutic use
DE19623207A1 (de) * 1996-06-11 1997-12-18 Bayer Ag Imidazolderivate
WO1999006380A1 (fr) * 1997-08-01 1999-02-11 Nissan Chemical Industries, Ltd. Composes de tetrazole et agent de controle des parasites
EP3735398B1 (en) 2018-01-03 2022-02-16 Ecolab Usa Inc. Benzotriazole derivatives as corrosion inhibitors
EP4061363A1 (en) * 2019-11-20 2022-09-28 Institut National de la Santé et de la Recherche Médicale (INSERM) Inhibitors of hsp70 protein

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4115060A (en) * 1977-10-03 1978-09-19 Fmc Corporation N-sulfonylimidazoles as peroxygen activators
DE3021834A1 (de) * 1980-06-11 1982-03-04 Basf Ag, 6700 Ludwigshafen Azolyl-4-nitro-2-trichlormethyl-benzolsulfone, ihre herstellung und verwendung
US4434288A (en) * 1982-04-08 1984-02-28 Eli Lilly And Company Preparation of substituted 1-thiazinyl or 1-thiazolyl-2-aminobenzimidazoles
JPS6160659A (ja) * 1984-09-03 1986-03-28 Nippon Tokushu Noyaku Seizo Kk 置換フエニルスルホニルアゾ−ル、その製法及び農園芸用殺菌剤

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AU7045687A (en) 1987-09-24
HUT43922A (en) 1988-01-28
DK141387A (da) 1987-09-21
DK141387D0 (da) 1987-03-19
US4804673A (en) 1989-02-14
IL81909A0 (en) 1987-10-20
EP0237912A1 (de) 1987-09-23
JPS62221672A (ja) 1987-09-29
PT84455A (en) 1987-04-01
ZA872014B (en) 1987-11-25
PT84455B (en) 1989-03-29

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