KR870008616A - 신규 촉매 조성물 - Google Patents
신규 촉매 조성물 Download PDFInfo
- Publication number
- KR870008616A KR870008616A KR870001858A KR870001858A KR870008616A KR 870008616 A KR870008616 A KR 870008616A KR 870001858 A KR870001858 A KR 870001858A KR 870001858 A KR870001858 A KR 870001858A KR 870008616 A KR870008616 A KR 870008616A
- Authority
- KR
- South Korea
- Prior art keywords
- catalyst composition
- salts
- acids
- acid
- component
- Prior art date
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G67/00—Macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing oxygen or oxygen and carbon, not provided for in groups C08G2/00 - C08G65/00
- C08G67/02—Copolymers of carbon monoxide and aliphatic unsaturated compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
- B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/824—Palladium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1895—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing arsenic or antimony
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Polyethers (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Endoscopes (AREA)
- Glass Compositions (AREA)
- Paper (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Polyesters Or Polycarbonates (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (10)
- a) 팔라듐 화합물,b) kPa가 2보다 적은 산(단, 할로겐화 수소산이 아니어야 함)의 비-귀금속 전이금속염 또는 그와같은 염과 그와같은 산과의 혼합물,c) 일반식 R1R2-M-R-M-R3R4이좌배위리간드(상기 일반식에서 M은 인, 비소 또는 안티몬을 나타내며, R1,R2,R3와 R4는 극성기로 치환되거나 치환되지 않은 히드로 카르빌기를 나타내고 R은 다리속에 탄소원자 최소한 두개를 갖는 2가의 유기 다리기를 나타낸다), 그리고d) 임의에 따라, 퀴논을 기제로 한 것을 특징으로 하는 신규 촉매 조성물.
- 제 2 항에 있어서, 성분 a)로서 초산 팔라듐과 같은 카르복실산의 팔라듐염을 기제로 한 것을 특징으로 하는 촉매 조성물.
- 제 1 항 또는 2항에 있어서, 성분 b)로서 p-톨루엔설폰산과 같은 설폰산의 염 또는 트리플루오로초산과 같은 카르복실산의 염 또는 그러한 염과 그러한 산의 혼합물을 기제로 한 것을 특징으로 하는 촉매 조성물.
- 제 1 항 내지 제 3 항 중 어느 하나에 있어서, 비-귀금속전이금속이 지르크늄, 바나늄, 크롬, 철, 니켈, 구리, 세륨, 토륨과 우라늄으로 형성된 균으로부터 선택되는 것을 특징으로 하는 촉매 조성물.
- 제 1 항 내지 제 4 항 중 어느 하나에 있어서, M이 인이고, R1,R2,R3와 R4기는 탄소원자 6내지 14를 함유하고 2가의 유기다리기 R은 다리속에 탄소원자 3개를 갖는 성분.c)를 사용함을 특징으로 하는 촉매 조성물
- 제 1 항 내지 제 5 항 중 어느 하나에 있어서, 사용된 성분.d)는 1,4-퀴논, 바람직하게 1,4-벤조퀴논인 것을 특징으로 하는 촉매 조성물.
- 일산화탄소와 하나 또는 그 이상의 올레핀형 불포화 유기 화합물의 혼합물을 제 1 항 내지 제 6 항 중 어느 하나에 따른 촉매 조성물을 사용함으로써 공중합시키는 것을 특징으로 하는 공중합체 제조방법.
- 제 7 항에서와 같은 방법으로 제조된 공중합체.
- 일산화탄소와 옥텐-1과의 신규 신형 교대 공중합체.
- 일산화탄소, 에텐과 도데켄-1과의 신규 선형 교대 삼원공중합체.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL8600564 | 1986-03-05 | ||
NL8600564 | 1986-03-05 |
Publications (1)
Publication Number | Publication Date |
---|---|
KR870008616A true KR870008616A (ko) | 1987-10-19 |
Family
ID=19847665
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR870001858A KR870008616A (ko) | 1986-03-05 | 1987-03-03 | 신규 촉매 조성물 |
Country Status (19)
Country | Link |
---|---|
US (2) | US4824934A (ko) |
EP (1) | EP0235865B1 (ko) |
JP (1) | JPH0822913B2 (ko) |
KR (1) | KR870008616A (ko) |
CN (1) | CN1013374B (ko) |
AT (1) | ATE69454T1 (ko) |
AU (1) | AU590823B2 (ko) |
BR (1) | BR8700951A (ko) |
CA (1) | CA1324456C (ko) |
DE (1) | DE3774456D1 (ko) |
DK (1) | DK109787A (ko) |
ES (1) | ES2026519T3 (ko) |
FI (1) | FI870928A (ko) |
GR (1) | GR3003194T3 (ko) |
IL (1) | IL81972A0 (ko) |
IN (1) | IN168056B (ko) |
NO (1) | NO870876L (ko) |
NZ (1) | NZ219481A (ko) |
ZA (1) | ZA871519B (ko) |
Families Citing this family (34)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IE60363B1 (en) * | 1986-05-27 | 1994-07-13 | Shell Int Research | Process for the preparation of polymers |
CA1305695C (en) * | 1986-08-22 | 1992-07-28 | Eit Drent | Catalyst compositions and process for olefin/co copolymerization |
IN171627B (ko) * | 1986-08-26 | 1992-11-28 | Shell Int Research | |
US4841020A (en) * | 1986-11-27 | 1989-06-20 | Shell Oil Company | Catalytic polymerization of carbon monoxide with functional substituted ethylenically unsaturated monomer |
US4806630A (en) * | 1986-12-01 | 1989-02-21 | Shell Oil Company | Catalytic polymerization of carbon monoxide and olefin, with organo nitro or organo nitrite compound additive |
US4794165A (en) * | 1987-02-23 | 1988-12-27 | Shell Oil Company | Carbon monoxide/olefin polymerization with bidentate ligand containing |
NL8702317A (nl) * | 1987-09-29 | 1989-04-17 | Shell Int Research | Katalysatorcomposities. |
GB8723602D0 (en) * | 1987-10-08 | 1987-11-11 | British Petroleum Co Plc | Polyketones |
AU2663988A (en) * | 1987-12-09 | 1989-06-15 | Shell Internationale Research Maatschappij B.V. | Polyketone polymer preparation |
US4916208A (en) * | 1987-12-18 | 1990-04-10 | Shell Oil Company | Novel polymers |
GB2214917A (en) * | 1988-02-16 | 1989-09-13 | Shell Int Research | Containers for liquid hydrocarbons made of co or so2 copolymer |
EP0376364B1 (en) * | 1988-11-28 | 1996-03-06 | Shell Internationale Researchmaatschappij B.V. | Polymers of carbon monoxide with one or more alpha-olefins |
US5061785A (en) * | 1989-03-29 | 1991-10-29 | Shell Oil Company | Polymerization of carbon monoxide/olefin with tertiary aliphatic monophosphine catalyst |
GB8908869D0 (en) * | 1989-04-19 | 1989-06-07 | Shell Int Research | A process for the preparation of aromatic ureas |
GB8908870D0 (en) * | 1989-04-19 | 1989-06-07 | Shell Int Research | A process for the preparation of carbamates |
US5057599A (en) * | 1989-07-14 | 1991-10-15 | Shell Oil Company | Polymerization of carbon monoxide/olefin with aromatic tetradentate phosphorus ligand |
US5215647A (en) * | 1990-07-25 | 1993-06-01 | Shell Oil Company | Oil compositions |
TW215106B (ko) * | 1990-09-25 | 1993-10-21 | Shell Internat Res Schappej B V | |
WO1992007019A1 (en) * | 1990-10-10 | 1992-04-30 | Akzo N.V. | Copolymer of carbon monoxide and propylene and process for its formation |
US5270441A (en) * | 1990-10-10 | 1993-12-14 | Akzo Nv | Copolymer of carbon monoxide and propylene produced in water/ketone solvent |
NL9002305A (nl) * | 1990-10-23 | 1992-05-18 | Shell Int Research | Werkwijze voor het ontparaffineren. |
US5206342A (en) * | 1991-02-28 | 1993-04-27 | Shell Oil Company | Polymerization of carbon monoxide/non conjugated alkenyl benzene |
US5352767A (en) * | 1992-01-08 | 1994-10-04 | University Of Massachusetts - Amherst | Alpha-olefin/carbon monoxide attenuating copolymers and improved catalyst and method for copolymerizing the same |
US5644023A (en) * | 1992-04-21 | 1997-07-01 | Union Carbide Chemicals & Plastics Technology Corporation | Process for the manufacture of copolymers of ethylene and carbon monoxide |
JPH07508317A (ja) * | 1992-06-26 | 1995-09-14 | アクゾ ノーベル ナムローゼ フェンノートシャップ | ポリケトンヤーン及びそれを製造する方法 |
US5820806A (en) * | 1993-01-13 | 1998-10-13 | Akzo Nobel Nv | Process for the preparation of polyketone fibers |
EP0614928B1 (en) * | 1993-03-12 | 2000-02-02 | Shell Internationale Researchmaatschappij B.V. | Process for the preparation of copolymers of carbon monoxide and ethylenically unsaturated compounds |
GB9307702D0 (en) * | 1993-04-14 | 1993-06-02 | Shell Int Research | Preparation of co-polymers |
GB9506378D0 (en) * | 1995-03-29 | 1995-05-17 | Bp Chem Int Ltd | Catalyst composition and use therefor |
ZA964914B (en) * | 1995-06-12 | 1997-01-08 | Shell Int Research | Catalyst composition and process for the preparation of copolymers of carbon monoxide and an olefinically unsaturated compound |
TR200002321T2 (tr) | 1998-02-12 | 2000-11-21 | Acordis Industrial Fibers B.V. | Poliketon liflerin hazırlanmasına mahsus yöntem |
DE10335990A1 (de) * | 2003-08-01 | 2005-02-24 | Basf Ag | Verfahren zur Emulsionspolymerisation von Olefinen |
SE527742C2 (sv) * | 2004-02-23 | 2006-05-30 | Sandvik Intellectual Property | Ferritiskt stål för högtemperaturtillämpningar, sätt att framställa detta, produkt och användning av stålet |
CN105294638A (zh) * | 2015-10-30 | 2016-02-03 | 成都科创佳思科技有限公司 | 一种去氢α-拉帕醌的催化合成方法 |
Family Cites Families (24)
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US2495286A (en) * | 1949-06-08 | 1950-01-24 | Du Pont | Interpolymers of carbon monoxide and method for preparing the same |
GB1129551A (en) * | 1965-03-18 | 1968-10-09 | Ici Ltd | Process for the manufacture of urethanes |
GB1081304A (en) * | 1965-03-23 | 1967-08-31 | Ici Ltd | Improvements in or relating to chemical compounds |
US3689460A (en) * | 1971-03-04 | 1972-09-05 | Shell Oil Co | Interpolymers of carbon monoxide and process for preparing same |
US3694412A (en) * | 1971-03-04 | 1972-09-26 | Shell Oil Co | Process for preparing interpolymers of carbon monoxide in the presence of aryl phosphine-palladium halide complex |
US3780140A (en) * | 1971-08-06 | 1973-12-18 | Du Pont | Ethylene/carbon monoxide polymer compositions |
US3914391A (en) * | 1973-03-26 | 1975-10-21 | Shell Oil Co | Preparation of HPd(CN){HD 3{B |
US3835123A (en) * | 1973-03-26 | 1974-09-10 | Shell Oil Co | Process for preparing interpolymers of carbon monoxide and ethylenically unsaturated compounds |
US4070532A (en) * | 1975-05-23 | 1978-01-24 | E. I. Du Pont De Nemours And Company | Ethylene carbon monoxide copolymers containing epoxy side groups |
US3984388A (en) * | 1975-06-02 | 1976-10-05 | Shell Oil Company | Process to prepare polyketones |
US4076911A (en) * | 1975-11-05 | 1978-02-28 | Union Oil Company Of California | Ethylene-carbon monoxide copolymers |
GB2058074B (en) * | 1979-08-23 | 1983-10-12 | Secr Defence | Palladium complexes |
EP0086281B2 (en) * | 1981-12-02 | 1988-10-19 | Shell Internationale Researchmaatschappij B.V. | Preparation of carbamates using a palladium-containing catalyst |
US4414409A (en) * | 1981-12-21 | 1983-11-08 | E. I. Du Pont De Nemours & Company | Palladium sulfonate catalyst systems for carbonylation of olefins |
US4424317A (en) * | 1982-12-06 | 1984-01-03 | Standard Oil Company (Indiana) | Mannich condensation product of ethylene/propylene/carbonyl polymers |
DE3480845D1 (de) * | 1983-04-06 | 1990-02-01 | Shell Int Research | Verfahren zur herstellung von polyketonen. |
US4600614A (en) * | 1983-09-12 | 1986-07-15 | The Dow Chemical Company | High-frequency heatable plastics |
DE3568037D1 (en) * | 1984-07-30 | 1989-03-09 | Shell Int Research | Process for the dimerization of olefins |
GB8428347D0 (en) * | 1984-11-09 | 1984-12-19 | Shell Int Research | Dimerization of olefins |
NL8403035A (nl) * | 1984-10-05 | 1986-05-01 | Shell Int Research | Werkwijze ter bereiding van polyketonen. |
GB8432042D0 (en) * | 1984-12-19 | 1985-01-30 | Shell Int Research | Preparation of dimerization products |
DE3676800D1 (de) * | 1985-11-29 | 1991-02-14 | Shell Int Research | Katalysatorzusammensetzung und verfahren zur copolymerisation von ethen mit kohlenmonoxid. |
JPH0246968A (ja) * | 1988-08-09 | 1990-02-16 | Furukawa Alum Co Ltd | ろう付耐食アルミニウム配管とその製造方法 |
JPH0775042B2 (ja) * | 1990-06-13 | 1995-08-09 | シャープ株式会社 | 光磁気記録再生装置 |
-
1987
- 1987-02-16 CA CA000529757A patent/CA1324456C/en not_active Expired - Fee Related
- 1987-02-16 IN IN132/DEL/87A patent/IN168056B/en unknown
- 1987-02-25 AT AT87200330T patent/ATE69454T1/de not_active IP Right Cessation
- 1987-02-25 ES ES198787200330T patent/ES2026519T3/es not_active Expired - Lifetime
- 1987-02-25 DE DE8787200330T patent/DE3774456D1/de not_active Expired - Fee Related
- 1987-02-25 EP EP87200330A patent/EP0235865B1/en not_active Expired - Lifetime
- 1987-02-27 BR BR8700951A patent/BR8700951A/pt not_active IP Right Cessation
- 1987-03-03 NZ NZ219481A patent/NZ219481A/xx unknown
- 1987-03-03 FI FI870928A patent/FI870928A/fi not_active Application Discontinuation
- 1987-03-03 JP JP62046952A patent/JPH0822913B2/ja not_active Expired - Lifetime
- 1987-03-03 NO NO870876A patent/NO870876L/no unknown
- 1987-03-03 DK DK109787A patent/DK109787A/da not_active Application Discontinuation
- 1987-03-03 AU AU69646/87A patent/AU590823B2/en not_active Ceased
- 1987-03-03 CN CN87101643A patent/CN1013374B/zh not_active Expired
- 1987-03-03 ZA ZA871519A patent/ZA871519B/xx unknown
- 1987-03-03 KR KR870001858A patent/KR870008616A/ko not_active Application Discontinuation
- 1987-03-05 US US07/021,948 patent/US4824934A/en not_active Expired - Lifetime
- 1987-03-23 IL IL81972A patent/IL81972A0/xx unknown
-
1988
- 1988-06-23 US US07/212,030 patent/US4859645A/en not_active Expired - Lifetime
-
1991
- 1991-11-25 GR GR91401813T patent/GR3003194T3/el unknown
Also Published As
Publication number | Publication date |
---|---|
ES2026519T3 (es) | 1992-05-01 |
GR3003194T3 (en) | 1993-02-17 |
DK109787D0 (da) | 1987-03-03 |
EP0235865A2 (en) | 1987-09-09 |
CN87101643A (zh) | 1987-09-30 |
ATE69454T1 (de) | 1991-11-15 |
EP0235865B1 (en) | 1991-11-13 |
EP0235865A3 (en) | 1988-01-27 |
IL81972A0 (en) | 1987-10-20 |
JPH0822913B2 (ja) | 1996-03-06 |
ZA871519B (en) | 1987-08-24 |
FI870928A (fi) | 1987-09-06 |
NO870876D0 (no) | 1987-03-03 |
CN1013374B (zh) | 1991-07-31 |
DK109787A (da) | 1987-09-06 |
AU590823B2 (en) | 1989-11-16 |
NZ219481A (en) | 1989-02-24 |
AU6964687A (en) | 1987-09-10 |
IN168056B (ko) | 1991-01-26 |
DE3774456D1 (de) | 1991-12-19 |
NO870876L (no) | 1987-09-07 |
BR8700951A (pt) | 1987-12-29 |
FI870928A0 (fi) | 1987-03-03 |
US4859645A (en) | 1989-08-22 |
CA1324456C (en) | 1993-11-16 |
JPS62212433A (ja) | 1987-09-18 |
US4824934A (en) | 1989-04-25 |
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Legal Events
Date | Code | Title | Description |
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A201 | Request for examination | ||
WITB | Written withdrawal of application |