KR870007096A - 글리옥실 에스테르의 단리방법 - Google Patents
글리옥실 에스테르의 단리방법 Download PDFInfo
- Publication number
- KR870007096A KR870007096A KR870000569A KR870000569A KR870007096A KR 870007096 A KR870007096 A KR 870007096A KR 870000569 A KR870000569 A KR 870000569A KR 870000569 A KR870000569 A KR 870000569A KR 870007096 A KR870007096 A KR 870007096A
- Authority
- KR
- South Korea
- Prior art keywords
- ester
- glyoxyl
- alcohol
- water
- roh
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/48—Separation; Purification; Stabilisation; Use of additives
- C07C67/52—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
- C07C67/54—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (5)
- C1내지 C4에스테르 그룹을 갖는 글리옥실에스테르, 물 및/또는 C1내지 C|4알코올 ROH를 함유하고 이때 글리옥실 에스테르, 물 및/또는 알코올이 부분적으로 또는 완전히 화학적으로 결합된 형태로 존재하는 혼합물에 비등점이 180℃이상인 고급 알코올 R"OH를 가하고, 800mbar를 초과하지 않는 압력하에 우선 물 및/또는 알코올 ROH를 증류, 이어서 글리옥실 에스테르를 증류시킴을 특징으로 하여, C1내지 C4에스테르 그룹을 갖는 글리옥실 에스테르, 물 및/또는 C1내지 C4알코올 ROH를 함유하고 이때 글리옥실 에스테르와 물 및/또는 알코올이 부분적으로 또는 완전히 화학적으로 결합된 형태로 존재하는 혼합물로부터 C1내지 C4에스테르 그룹을 갖는 글리옥실에스테르를 수득하는 방법.
- 제1항에 있어서, 비등점이 200℃이상인 고급 알코올 R'OH를 사용하는 방법.
- 제1 또는 2항에 있어서, 하기 3가지 종류 중하나에 속하는 고급 알코올 R'OH를 사용하는 방법 : a) 탄소수 최대치 16인 직쇄 또는 측쇄알칸올, b) n=2내지 24인 폴리글리콜 HO-(-CH2CH2O-)nH. c) n=2내지 24이고, R"이 탄소수 최대의 4의 직쇄 또는 측쇄 알킬라디칼인 폴리글리콜 모노에스테르 HO-(-CH2CH2O-)nR".
- 제1 내지 3항 중 어느 한 항에 있어서, 약 15내지 약 530mbar의 압력하에 수행하는 방법.
- 제1 내지 4항중 어느 한 항에 있어서, 글리옥실 에스테르가 메틸 에스테르의 형태이고 저급 알코올 ROH가 메탄올의 형태인 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEP3602274.8 | 1986-01-25 | ||
DE19863602274 DE3602274A1 (de) | 1986-01-25 | 1986-01-25 | Halbacetale von glyoxylsaeureestern sowie verfahren zur isolierung von glyoxylsaeureestern |
Publications (1)
Publication Number | Publication Date |
---|---|
KR870007096A true KR870007096A (ko) | 1987-08-14 |
Family
ID=6292648
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR870000569A KR870007096A (ko) | 1986-01-25 | 1987-01-24 | 글리옥실 에스테르의 단리방법 |
Country Status (8)
Country | Link |
---|---|
US (1) | US4814491A (ko) |
EP (1) | EP0230951B1 (ko) |
JP (1) | JPS62178541A (ko) |
KR (1) | KR870007096A (ko) |
CN (1) | CN87100429A (ko) |
BR (1) | BR8700302A (ko) |
DE (2) | DE3602274A1 (ko) |
ZA (1) | ZA87505B (ko) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4820385A (en) * | 1988-02-18 | 1989-04-11 | Monsanto Company | Purification of alkyl glyoxylate in a continuous column by azeotropic distillation |
US4867849A (en) * | 1988-07-25 | 1989-09-19 | Cova Dario R | Purification of alkyl glyoxylate |
AT396589B (de) * | 1990-06-05 | 1993-10-25 | Chemie Linz Gmbh | Verfahren zur herstellung von allantoin |
US5217582A (en) * | 1990-06-20 | 1993-06-08 | E. I. Du Pont De Nemours And Company | Process for the isolation of alkyl glyoxylate |
DE4020536A1 (de) * | 1990-06-28 | 1992-01-02 | Chemie Linz Deutschland | Verfahren zur herstellung von allantoin |
JP3150909B2 (ja) * | 1996-09-05 | 2001-03-26 | 株式会社日本触媒 | グリオキシル酸エステル類の精製方法 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA517825A (en) * | 1955-10-25 | P. Mcdermott John | Hydroxy ester derivatives | |
DE1004158B (de) * | 1955-12-08 | 1957-03-14 | Basf Ag | Verfahren zur Herstellung von Oxyalkoxyessigsaeureestern |
FR2383911A1 (fr) * | 1977-03-17 | 1978-10-13 | Hoechst France | Procede permettant d'augmenter les rendements en hemiacetal-esters de l'acide glyoxylique au cours de leur obtention ou leurs taux de recuperation dans les milieux les contenant |
US4443623A (en) * | 1982-05-12 | 1984-04-17 | American Cyanamid Company | Preparation of predominately methyl acrylamidoglycolate methyl ether in a normally liquid product |
US4502923A (en) * | 1983-10-06 | 1985-03-05 | Monsanto Company | Production of high purity alkyl glyoxylate by plural stage distillation |
DE3401115A1 (de) * | 1984-01-14 | 1985-07-18 | Hoechst Ag, 6230 Frankfurt | Verfahren zur herstellung eines glyoxylsaeureesters |
DE3446528A1 (de) * | 1984-12-20 | 1986-06-26 | Hoechst Ag, 6230 Frankfurt | Verfahren zur herstellung von glyoxylsaeurehemiacetalestern |
JP3453158B2 (ja) * | 1992-11-05 | 2003-10-06 | 三菱電線工業株式会社 | ゲル状電解質 |
-
1986
- 1986-01-25 DE DE19863602274 patent/DE3602274A1/de not_active Withdrawn
-
1987
- 1987-01-19 EP EP87100637A patent/EP0230951B1/de not_active Expired - Lifetime
- 1987-01-19 DE DE8787100637T patent/DE3770177D1/de not_active Expired - Fee Related
- 1987-01-23 BR BR8700302A patent/BR8700302A/pt unknown
- 1987-01-23 JP JP62012641A patent/JPS62178541A/ja active Pending
- 1987-01-23 ZA ZA87505A patent/ZA87505B/xx unknown
- 1987-01-24 KR KR870000569A patent/KR870007096A/ko not_active Application Discontinuation
- 1987-01-24 CN CN198787100429A patent/CN87100429A/zh active Pending
-
1988
- 1988-05-11 US US07/193,225 patent/US4814491A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
EP0230951B1 (de) | 1991-05-22 |
BR8700302A (pt) | 1987-12-01 |
ZA87505B (en) | 1987-09-30 |
EP0230951A2 (de) | 1987-08-05 |
CN87100429A (zh) | 1987-11-11 |
JPS62178541A (ja) | 1987-08-05 |
EP0230951A3 (en) | 1988-07-20 |
DE3770177D1 (de) | 1991-06-27 |
US4814491A (en) | 1989-03-21 |
DE3602274A1 (de) | 1987-07-30 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
WITN | Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid |