KR870006069A - 스피로디포스포아미데이트-타입 화합물 및 그의 제조방법 - Google Patents
스피로디포스포아미데이트-타입 화합물 및 그의 제조방법 Download PDFInfo
- Publication number
- KR870006069A KR870006069A KR860011116A KR860011116A KR870006069A KR 870006069 A KR870006069 A KR 870006069A KR 860011116 A KR860011116 A KR 860011116A KR 860011116 A KR860011116 A KR 860011116A KR 870006069 A KR870006069 A KR 870006069A
- Authority
- KR
- South Korea
- Prior art keywords
- compound
- group
- spirodiphosphoamidate
- sulfur
- aliphatic
- Prior art date
Links
- 150000001875 compounds Chemical class 0.000 title claims 7
- 238000002360 preparation method Methods 0.000 title 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 4
- 125000001931 aliphatic group Chemical group 0.000 claims 4
- 229910052717 sulfur Inorganic materials 0.000 claims 4
- 239000011593 sulfur Substances 0.000 claims 4
- 238000000034 method Methods 0.000 claims 3
- 150000001412 amines Chemical class 0.000 claims 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 2
- 229910052739 hydrogen Inorganic materials 0.000 claims 2
- 239000001257 hydrogen Substances 0.000 claims 2
- 229910052760 oxygen Inorganic materials 0.000 claims 2
- 239000001301 oxygen Substances 0.000 claims 2
- QGLWBTPVKHMVHM-KTKRTIGZSA-N (z)-octadec-9-en-1-amine Chemical group CCCCCCCC\C=C/CCCCCCCCN QGLWBTPVKHMVHM-KTKRTIGZSA-N 0.000 claims 1
- 229940126062 Compound A Drugs 0.000 claims 1
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 claims 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- 125000003118 aryl group Chemical group 0.000 claims 1
- ZJIPHXXDPROMEF-UHFFFAOYSA-N dihydroxyphosphanyl dihydrogen phosphite Chemical compound OP(O)OP(O)O ZJIPHXXDPROMEF-UHFFFAOYSA-N 0.000 claims 1
- 150000002431 hydrogen Chemical class 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 125000003107 substituted aryl group Chemical group 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M137/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus
- C10M137/16—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus having a phosphorus-to-nitrogen bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/22—Amides of acids of phosphorus
- C07F9/24—Esteramides
- C07F9/2404—Esteramides the ester moiety containing a substituent or a structure which is considered as characteristic
- C07F9/2425—Esteramides the ester moiety containing a substituent or a structure which is considered as characteristic containing the structure (RX)(RR'N)P(=Y)-Z-(C)n-Z'-P(=Y)(XR)2 (X = O, S, NR; Y = O, S, electron pair; Z = O, S; Z' = O, S)
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
- C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
- C07F9/657154—Cyclic esteramides of oxyacids of phosphorus
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/047—Thioderivatives not containing metallic elements
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/049—Phosphite
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
- C10N2040/042—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives for automatic transmissions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
- C10N2040/044—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives for manual transmissions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
- C10N2040/046—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives for traction drives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/06—Instruments or other precision apparatus, e.g. damping fluids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/08—Hydraulic fluids, e.g. brake-fluids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Crystallography & Structural Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Lubricants (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 100℉, 200℉ 및 300℉에서 실시예 2에 대해 시험한 결과를 도시한 그래프.
제2도는 100℉, 200℉ 및 300℉에서 대조실시예 C3에 대해 시험한 결과를 도시한 그래프.
제3도는 300℉에서 0,2, 1, 2, 4 및 6시간 후에 실시예 2에 대해 시험한 결과를 도시한 그래프.
Claims (9)
- 하기 일반식(Ⅰ)의 스피로디포스포아미데이트-타입화합물.상기식에서, A 및 A′는 각각 독립적으로 산소 및 황으로 이루어진 그룹중에서 선택되고R1및 R3은 각각 독립적으로 수소, 지방족, 옥시지방족, 폴리옥시지방족, 사이클로지방족 및 방향족 잔기로 구성된 그룹중에서 선택되며;R2및 R4는 각각 독립적으로 C13이상의 지방족, 옥시지방족, 폴리옥시지방족 및 지방족 치환된 아릴그룹으로 구성된 그룹 중에서 선택된다.
- 제1항에 있어서, A 및 A'가 황인 화합물.
- 제1항에 있어서, R1및 R3가 옥시지방족 및 폴리옥시지방족 잔기로 구성된 그룹 중에서 선택되는 화합물.
- 제3항에 있어서, R1및 R3가 수소인 화합물.
- 제1항에 있어서, R2및 R4가 C16이상의 지방족 그룹으로 구성된 그룹중에서 선택되는 화합물.
- 아민을 디할로스피로 디포스파이트와 반응시켜 스피로디포스포아미다이트를 형성시키고, 생성된 스피로 디포스포아미다이트를 산소 및 황중의 적어도 하나와 반응시켜 상응하는 스피로 디포스포아미데이트-타입 화합물을 형성시킴을 특징으로 하여, 스피로디포스포 아미데이트-타입화합물을 제조하는 방법.
- 제6항에 있어서, 디할로스피로포스파이트가 디클로로스피로포스파이트인 방법.
- 제7항에 있어서, 스피로디포스포아미다이트를 황과 반응시키는 방법.
- 제8항에 있어서, 치환된 아민이 올레일아민인 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US81316185A | 1985-12-24 | 1985-12-24 | |
US813161 | 1985-12-24 | ||
US813,161 | 1985-12-24 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR870006069A true KR870006069A (ko) | 1987-07-09 |
KR940009032B1 KR940009032B1 (ko) | 1994-09-29 |
Family
ID=25211620
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019860011116A KR940009032B1 (ko) | 1985-12-24 | 1986-12-23 | 스피로디포스포아미데이트형 화합물 및 이의 제조방법 |
Country Status (6)
Country | Link |
---|---|
US (1) | US4758683A (ko) |
EP (1) | EP0232536B1 (ko) |
JP (1) | JPS62158294A (ko) |
KR (1) | KR940009032B1 (ko) |
CA (1) | CA1293737C (ko) |
DE (2) | DE3688287D1 (ko) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4778613A (en) * | 1985-12-24 | 1988-10-18 | Borg-Warner Chemicals, Inc. | Spirodiphosphate-containing working substances |
US8466096B2 (en) * | 2007-04-26 | 2013-06-18 | Afton Chemical Corporation | 1,3,2-dioxaphosphorinane, 2-sulfide derivatives for use as anti-wear additives in lubricant compositions |
Family Cites Families (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3192243A (en) * | 1962-04-10 | 1965-06-29 | Delaware Chemicals Inc | Phosphorous derivatives of pentaerythritol |
US3141032A (en) * | 1963-01-23 | 1964-07-14 | Union Carbide Corp | Dialkyl pentaerythritol diphosphonates and phosphite phosphonates |
US3325566A (en) * | 1964-04-20 | 1967-06-13 | Olin Mathieson | Diphosphaspiro compound and process of making same |
US3597503A (en) * | 1967-12-06 | 1971-08-03 | Hooker Chemical Corp | Cyclic phosphoroamidates and process for making same |
FR2125442B1 (ko) * | 1971-02-16 | 1974-06-28 | Shell Int Research | |
US3819748A (en) * | 1972-05-05 | 1974-06-25 | Texaco Nv Sa | Phosphorus derivatives of tetrafunctional aromatic compounds |
US3839506A (en) * | 1973-04-16 | 1974-10-01 | Borg Warner | Hindered phenol pentaerythritol phosphonate |
US3978167A (en) * | 1974-01-02 | 1976-08-31 | Michigan Chemical Corporation | Pentaerythritol cyclic diphosphates and diphosphoramidates |
US4290976A (en) * | 1975-03-24 | 1981-09-22 | Borg-Warner Chemicals, Inc. | Process for the preparation of phenol-free phosphites |
GB1517652A (en) * | 1976-01-13 | 1978-07-12 | Velsicol Chemical Corp | Cyclic phosphorus-containing pentaerythritol derivatives and their use as flame retardants for polymers |
US4086205A (en) * | 1976-09-03 | 1978-04-25 | Monsanto Company | Hydrogen phosphonates |
US4154721A (en) * | 1976-09-21 | 1979-05-15 | Borg-Warner Corporation | Flame-retardant phosphonate compositions |
US4130540A (en) * | 1977-11-25 | 1978-12-19 | Borg-Warner Corporation | Olefin polymers stable to copper |
US4348291A (en) * | 1979-07-02 | 1982-09-07 | Stauffer Chemical Company | Novel phosphoramides, lubricating compositions and method of improving wear and extreme pressure characteristics of lubricating oil |
US4341722A (en) * | 1979-07-06 | 1982-07-27 | Ciba-Geigy Corporation | 2-Thiono-(2H) [1,3,2] dioxaphosphorinanes (phospholanes) |
US4664828A (en) * | 1985-04-25 | 1987-05-12 | Stauffer Chemical Company | Antiwear additives for functional fluids |
US4778613A (en) * | 1985-12-24 | 1988-10-18 | Borg-Warner Chemicals, Inc. | Spirodiphosphate-containing working substances |
-
1986
- 1986-12-11 CA CA000525102A patent/CA1293737C/en not_active Expired - Fee Related
- 1986-12-23 EP EP86117944A patent/EP0232536B1/en not_active Expired - Lifetime
- 1986-12-23 DE DE8686117944A patent/DE3688287D1/de not_active Expired - Fee Related
- 1986-12-23 DE DE86117944T patent/DE3688287T4/de not_active Expired - Lifetime
- 1986-12-23 KR KR1019860011116A patent/KR940009032B1/ko not_active IP Right Cessation
- 1986-12-24 JP JP61315958A patent/JPS62158294A/ja active Pending
-
1987
- 1987-09-25 US US07/102,270 patent/US4758683A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
DE3688287T2 (de) | 1993-08-19 |
JPS62158294A (ja) | 1987-07-14 |
EP0232536B1 (en) | 1993-04-14 |
KR940009032B1 (ko) | 1994-09-29 |
EP0232536A2 (en) | 1987-08-19 |
DE3688287D1 (de) | 1993-05-19 |
DE3688287T4 (de) | 1993-12-02 |
EP0232536A3 (en) | 1989-05-31 |
US4758683A (en) | 1988-07-19 |
CA1293737C (en) | 1991-12-31 |
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