KR870002044A - 살 균 제 - Google Patents

살 균 제 Download PDF

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Publication number
KR870002044A
KR870002044A KR1019860006893A KR860006893A KR870002044A KR 870002044 A KR870002044 A KR 870002044A KR 1019860006893 A KR1019860006893 A KR 1019860006893A KR 860006893 A KR860006893 A KR 860006893A KR 870002044 A KR870002044 A KR 870002044A
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South Korea
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optionally substituted
formula
alkyl
compound
plant
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KR1019860006893A
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KR910000249B1 (ko
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마틴 클라우프 존
리차드 아이레스 가드프리 크리스토퍼
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그래함 도날드 아놀드
임페리알 케미칼 인더스트리스 피엘씨
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/612—Esters of carboxylic acids having a carboxyl group bound to an acyclic carbon atom and having a six-membered aromatic ring in the acid moiety
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C321/00—Thiols, sulfides, hydropolysulfides or polysulfides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N39/00—Biocides, pest repellants or attractants, or plant growth regulators containing aryloxy- or arylthio-aliphatic or cycloaliphatic compounds, containing the group or, e.g. phenoxyethylamine, phenylthio-acetonitrile, phenoxyacetone
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N39/00—Biocides, pest repellants or attractants, or plant growth regulators containing aryloxy- or arylthio-aliphatic or cycloaliphatic compounds, containing the group or, e.g. phenoxyethylamine, phenylthio-acetonitrile, phenoxyacetone
    • A01N39/02—Aryloxy-carboxylic acids; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups

Abstract

내용 없음.

Description

살균제
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (11)

  1. 다음 일반식(1)의 화합물 및 그것의 입체이성체 및 그것의 금속 착물.
    식중, V는 산소 또는 황원자; X 및 V는 같거나 다를 수 있는 것으로써, 수소 또는 할로겐원자 또는 임의로 치환된 알킬, 임의로 치환된 알케닐, 임의로 치환된 아틸 임의로 치환된 헤테로아릴, 임의로 치환된 알키닐, 할로알킬, 알콕시, 할로알콕시, 임의로 치환된 아릴옥시, 임의로 치환된 아릴알콕시, 임의로 치환된 아실옥시, 임의로 치환된 아미노, 아실아미노, 니트로, 니트릴, -CO2R3, -CONR4R5, 또는 -COR6그룹 ; 또는 X 및 Y가 페닐환에서 근접한 위치에 있을때, 임의로 하나 또는 그 이상의 헤테로원자를 포함한 방향족 또는 지방족의 붙은 환을 형성하기 위해 결합될 수 있고 ; Z는 임의로 치환된 메틸렌, 임의로 치환된 아미노, 산소 또는 황이고 Z가 치환된 메틸렌 그룹일때 그 치환체는 비방향족 붙은 환을 형성하기 위해 페닐환의 2-위치에 결합될 수 있고 ; R1및 R2는 임의로 하나 또는 그 이상의 할로겐원자로 치환된 C1-4알킬 그룹 ; 및 R3,R4,R5및 R6는 같거나 다를 수 있는 것으로써, 수소원자 또는 임의로 치환된 알킬, 사이클로알킬, 알케닐, 알키닐, 임의로 치환된 아릴, 임의로 치환된 아랄킬, 또는 사이클로알킬 알킬.
  2. 제1항에 있어서, 식중 V가 산소 또는 황 ; X가 H, C1-4알킬, C3-4알케닐, 할로겐, 페닐, 나프틸, 피리딜, 피리미딜, 벤질, 페녹시, 벤질옥시, 피리딜옥시, 퓨릴, 티에닐, 각각 임의로 하나 또는 그 이상의 할로겐원자 또는 C1-4알킬로 치환된 벤조티에닐 또는 피롤릴, C1-4알콕시 또는 할로 C1-4알킬 그룹 ; Y가 수소 또는 할로겐 ; 및 Z가 -CH2-, -CH(CH3)-, -C(CH3)2-, -O-, -S-, -N(CH3)-, 또는 -N(C2H5)-; 및 R1및 R2가 둘다 메틸인 화합물.
  3. 제2항에 있어서, 식중 X가 Z그룹에 대해 메타-(또는 3-)위치에서 페닐환에 결합되고, X가 페닐나프틸, 피리딜, 피리미딜, 퓨릴, 티에닐, 각각 임의로 하나 또는 그 이상의 할로겐 원자 또는 C1-4알킬로 치환되어 링 원자중 어떤 한 원자가 각각 결합된 벤조티에닐 또는 피롤일, C1-4알콕시 또는 할로 C1-4알킬그룹인 화합물.
  4. 전술한 표 1 및 2에 나타낸 특별한 화합물.
  5. 제1항에 있어서, (a) 식중 X,Y,R1및 Z가 제1항에서 전술한 바와 같은 일반식 (2a) 또는 (2b)의 화합물 ;을 산 결합제의 존재하에 식중 R2가 제1항에서 전술한 바와 같고 L이 할로겐 원자 또는 또 다른 좋은 이탈기인 일반식 R2L(3)의 알킬화제와 반응시키거나, (b) 식중 X,Y,Z,R1및 R2가 제1항에서 전술한 바와같은 일반식(13)의 아세탈 ;로부터, 예를들어 리튬 디-이소프로필아미드, 황산수소칼륨, 또는 트리에틸아민과 같은 적당한 산성 또는 염기성 조건하에 타이타늄 테트라클로라이드의 존재하에서, 알콜 R2OH성분을 제거하는 것을 포함하는 일반식 (1)의 화합물의 제조 방법.
  6. 식중 X,Y,Z 및 R1이 제1항에서 전술한 바와 같은 일반식 (4)의 에스테르를염기 및 식중 R3가 알킬 그룹인 염화 트리메틸실릴과 같은 일반식 R3 3SiCl 또는 R3 3SiBr의 트리알킬실 할라이드와 반응시키거나, 염기 및 식중 R3가 알킬 그룹인 일반식 R3 3SiOSO2CF3의 트리알킬실릴 트리플레이트와 반응시킨 다음, 결과의 알킬 실릴 케톤 아세탈을 일반식 (R2O)3CH의 트리알킬올소포메이트로 타이타늄테트라클로라이드와 같은 루이스(Lewis)산의 존재하에서 처리하는 것을 포함하는 식중 X,Y,Z,R1및 R2가 제1항에서 전술한 바와같은 일반식 (13)의 아세틸의 제조방법.
  7. 식중 X,Y,Z 및 R1이 제1항에서 전술한 바와같은 일반식 (4)의 에스테르를 염기 및 포름산 에스테르와 반응시키는 것을 포함하는 식중 X,Y,Z 및 R1이 제1항에서 전술한 바와같은 일반식 (2a)의 화합물 [일반식 (2b)의 화합물과 평형으로 존재할 수 있음]의 제조방법.
  8. 활성 성분으로써 제1항에서 제4항까지의 어느 한 항의 화합물과 그것에 대한 담체로 구성된 살균 또는 식물 생장 조절 조성물.
  9. 제1항에서 제4항까지의 어느 한 항의 화합물 또는 제8항의 조성물을 식물에, 식물의 씨에, 또는 식물 또는 씨의 소재지에 사용하는 것으로 구성된 균 박별법.
  10. 제1항에서 제4항까지의 어느 한 항에 화합물 또는 제8항의 조성물을 식물에, 식물의 씨에, 또는 식물 또는 씨의 소재지에 사용하는 것을 포함하는 식물 생장을 조절하는 방법.
  11. 전술한 일반식 (2a),(2b),(4),(7) 및 (13) 화합물의 신규한 중간생성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019860006893A 1985-08-22 1986-08-21 살균제 KR910000249B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB8521082 1985-08-22
GB858521082A GB8521082D0 (en) 1985-08-22 1985-08-22 Fungicides

Publications (2)

Publication Number Publication Date
KR870002044A true KR870002044A (ko) 1987-03-28
KR910000249B1 KR910000249B1 (ko) 1991-01-23

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US (3) US4802913A (ko)
EP (1) EP0212859B1 (ko)
JP (1) JPH0819047B2 (ko)
KR (1) KR910000249B1 (ko)
AU (1) AU598741B2 (ko)
BR (1) BR8603992A (ko)
CA (1) CA1280417C (ko)
DE (1) DE3674114D1 (ko)
DK (1) DK173341B1 (ko)
ES (1) ES2001880A6 (ko)
GB (2) GB8521082D0 (ko)
HU (1) HU201726B (ko)
IE (1) IE59221B1 (ko)
MY (1) MY100929A (ko)
NZ (1) NZ217048A (ko)
PT (1) PT83233B (ko)
ZA (1) ZA865792B (ko)

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CA1280417C (en) 1991-02-19
DK173341B1 (da) 2000-07-31
KR910000249B1 (ko) 1991-01-23
MY100929A (en) 1991-05-31
DK394586A (da) 1987-02-23
AU6109986A (en) 1987-02-26
ES2001880A6 (es) 1988-07-01
HU201726B (en) 1990-12-28
PT83233B (pt) 1989-03-30
HUT41597A (en) 1987-05-28
US4913721A (en) 1990-04-03
EP0212859B1 (en) 1990-09-12
GB8521082D0 (en) 1985-09-25
BR8603992A (pt) 1987-04-07
AU598741B2 (en) 1990-07-05
DK394586D0 (da) 1986-08-19
PT83233A (en) 1986-09-01
IE59221B1 (en) 1994-01-26
US4802913A (en) 1989-02-07
GB2179346A (en) 1987-03-04
IE861986L (en) 1987-02-22
GB2179346B (en) 1989-08-02
NZ217048A (en) 1989-11-28
US5124353A (en) 1992-06-23
EP0212859A2 (en) 1987-03-04
DE3674114D1 (de) 1990-10-18
EP0212859A3 (en) 1988-05-04
GB8617984D0 (en) 1986-08-28
JPS6248649A (ja) 1987-03-03
ZA865792B (en) 1987-04-29
JPH0819047B2 (ja) 1996-02-28

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