KR860008799A - 올레핀의 소중합화 공정 및 그 촉매 조성물 - Google Patents

올레핀의 소중합화 공정 및 그 촉매 조성물 Download PDF

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KR860008799A
KR860008799A KR1019860004022A KR860004022A KR860008799A KR 860008799 A KR860008799 A KR 860008799A KR 1019860004022 A KR1019860004022 A KR 1019860004022A KR 860004022 A KR860004022 A KR 860004022A KR 860008799 A KR860008799 A KR 860008799A
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catalyst composition
group metal
iron group
small polymerization
alkyl aluminum
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KR1019860004022A
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KR890002861B1 (ko
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로이 프레임 로버트
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유오피 인코오포레이티드
마이클 반데케르크호포
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of the platinum group metals, iron group metals or copper
    • B01J31/30—Halides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/30—Catalytic processes with hydrides or organic compounds containing metal-to-carbon bond; Metal hydrides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20—Olefin oligomerisation or telomerisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/06—Halogens; Compounds thereof
    • C07C2527/125—Compounds comprising a halogen and scandium, yttrium, aluminium, gallium, indium or thallium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups C07C2531/02 - C07C2531/24

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

내용 없음

Description

올레핀의 소중합화 공정 및 그 촉매 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (12)

  1. 수화물의 물과 철족 금속의 몰비율이 0.5 : 1이상인 철족 금속 수화물의 촉매량을 함유하는 다공성 지지체상에 촉매량적의 알킬 알루미늄 화합물이 혼합된 것으로 구성된 촉매 조성물.
  2. 제1항에 있어서, 상기 조성물이 촉매량적의 알루미늄 할로겐화물을 함유하는 것을 특징으로 하는 촉매 조성물.
  3. 제1항에 있어서, 상기 조성물내에 원소기준으로 약 1내지 20중량%의 철족 금속을 함유하는 촉매 조성물.
  4. 제1항에 있어서, 상기 조성물 내에, 1몰의 철족 금속에 대하여 몰 비율로 약 0.05 : 1내지 6 : 1몰의 알킬 알루미늄 화합물을 함유하는 촉매 조성물.
  5. 제1항에 있어서, 상기 철족 금속 수화물내의 수화물의 물과 철족 금속의 몰비율이 상기 알킬 알루미늄 화합물과 반응하기에 앞서 약 0.5 : 1내지 6 : 1인 촉매 조성물.
  6. 제3항에 있어서, 철족 금속이 니켈 또는 코발트인 촉매 조성물.
  7. 제1항에 있어서, 알킬 알루미늄 화합물이 알킬 알루미늄 할로겐화물로 구성된 촉매 조성물.
  8. 소중합화 조건하의 제1항에서 7항의 어느 한항의 촉매의 존재하에서 탄화수소를 처리하고 생성된 소중합체를 회수하는 것으로 구성된 올레핀계 탄화수소의 소중합화 공정.
  9. 제8항에 있어서, 상기 소중합화 조건이 약 -20°내지 약 120℃의 온도와 약 350내지 1000psig(2410내지 6895KPag)의 압력인 소중합화 공정.
  10. 제8항에 있어서, 올레핀계 탄화수소가 2내지 8탄소원자를 함유하는 소중합화 공정.
  11. 제8항에 있어서, 올레핀계 탄화수소가 프로필렌이고 소중합체가 헥센, 메틸펜텐 및 디메틸 부텐의 혼합물인 소중합화 공정.
  12. 제8항에 있어서, 올레핀계 탄화수소가 부틸렌이고 소중합체가 옥텐, 메틸 헵텐 및 디메틸 헥센의 혼합물인 소중합화 공정.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019860004022A 1985-05-23 1986-05-23 올레핀의 소중합화 방법 및 그 촉매 조성물 KR890002861B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US06/737,320 US4613580A (en) 1985-05-23 1985-05-23 Process for the oligomerization of olefins and a catalyst thereof
US737320 2000-12-14

Publications (2)

Publication Number Publication Date
KR860008799A true KR860008799A (ko) 1986-12-18
KR890002861B1 KR890002861B1 (ko) 1989-08-05

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KR1019860004022A KR890002861B1 (ko) 1985-05-23 1986-05-23 올레핀의 소중합화 방법 및 그 촉매 조성물

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Country Link
US (1) US4613580A (ko)
EP (1) EP0202670B1 (ko)
JP (1) JPS61278355A (ko)
KR (1) KR890002861B1 (ko)
CN (1) CN1003912B (ko)
AR (1) AR241478A1 (ko)
AT (1) ATE55279T1 (ko)
AU (1) AU577695B2 (ko)
BR (1) BR8602344A (ko)
CA (1) CA1267645A (ko)
DE (1) DE3673238D1 (ko)
EG (1) EG18249A (ko)
FI (1) FI862163A (ko)
ZA (1) ZA863716B (ko)

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EP0333940A1 (en) * 1988-03-17 1989-09-27 Uop Inc. Process and catalyst for the oligomerization of olefins
JPH01242150A (ja) * 1988-03-18 1989-09-27 Uop Inc オレフィンのオリゴメ化方法とその触媒
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CN104001546A (zh) * 2014-06-09 2014-08-27 浙江科技学院 一种丙烯二聚制备六碳烯烃的负载型催化剂及其制备方法
US10882028B2 (en) * 2018-03-14 2021-01-05 Evonik Operations Gmbh Ni-containing catalyst for the oligomerization of olefins
CN108479792B (zh) * 2018-03-23 2020-10-13 安徽理工大学 一种以氧化铝为载体的微波辅助制备高碳烯烃用催化剂及催化工艺
CN110935434A (zh) * 2019-12-09 2020-03-31 北京石油化工学院 丙烯齐聚制备壬烯和十二烯的催化剂及其制备方法与应用

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Publication number Publication date
KR890002861B1 (ko) 1989-08-05
CA1267645A (en) 1990-04-10
EP0202670B1 (en) 1990-08-08
CN86103976A (zh) 1987-03-04
AU5781386A (en) 1986-11-27
AU577695B2 (en) 1988-09-29
EG18249A (en) 1992-12-30
ZA863716B (en) 1986-12-30
US4613580A (en) 1986-09-23
EP0202670A3 (en) 1987-11-19
JPS61278355A (ja) 1986-12-09
FI862163A (fi) 1986-11-24
BR8602344A (pt) 1987-01-21
AR241478A1 (es) 1992-07-31
FI862163A0 (fi) 1986-05-22
ATE55279T1 (de) 1990-08-15
EP0202670A2 (en) 1986-11-26
DE3673238D1 (de) 1990-09-13
CN1003912B (zh) 1989-04-19

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