KR860006430A - 비스(3-아미노펜옥시) 유도체의 제조방법 - Google Patents

비스(3-아미노펜옥시) 유도체의 제조방법 Download PDF

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KR860006430A
KR860006430A KR1019860001263A KR860001263A KR860006430A KR 860006430 A KR860006430 A KR 860006430A KR 1019860001263 A KR1019860001263 A KR 1019860001263A KR 860001263 A KR860001263 A KR 860001263A KR 860006430 A KR860006430 A KR 860006430A
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aminophenoxy
bis
derivative
producing
general formula
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KR1019860001263A
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KR870001062B1 (ko
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유끼히로 요시가와
유끼히로(외 4) 요시가와
게이자부로 야마구찌
겐이찌 스기모또
요시미쯔 다나베
아끼히로 야마구찌
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미쯔이 도아쯔 가가꾸 가부시기 가이샤
도쯔가 야스아끼
미쯔이 도아쯔 가가꾸 가부시기가이샤
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Priority claimed from JP60032568A external-priority patent/JPH06727B2/ja
Priority claimed from JP60113237A external-priority patent/JPH0653710B2/ja
Priority claimed from JP60140408A external-priority patent/JPH06728B2/ja
Priority claimed from JP60183039A external-priority patent/JPH0710814B2/ja
Priority claimed from JP60203557A external-priority patent/JPH06729B2/ja
Priority claimed from JP60210266A external-priority patent/JPH0637444B2/ja
Priority claimed from JP60289334A external-priority patent/JPH0637445B2/ja
Application filed by 미쯔이 도아쯔 가가꾸 가부시기 가이샤, 도쯔가 야스아끼, 미쯔이 도아쯔 가가꾸 가부시기가이샤 filed Critical 미쯔이 도아쯔 가가꾸 가부시기 가이샤
Publication of KR860006430A publication Critical patent/KR860006430A/ko
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Publication of KR870001062B1 publication Critical patent/KR870001062B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C217/00—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton
    • C07C217/78—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the same carbon skeleton
    • C07C217/80—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of non-condensed six-membered aromatic rings
    • C07C217/82—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of non-condensed six-membered aromatic rings of the same non-condensed six-membered aromatic ring
    • C07C217/90—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of non-condensed six-membered aromatic rings of the same non-condensed six-membered aromatic ring the oxygen atom of at least one of the etherified hydroxy groups being further bound to a carbon atom of a six-membered aromatic ring, e.g. amino-diphenylethers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C201/00—Preparation of esters of nitric or nitrous acid or of compounds containing nitro or nitroso groups bound to a carbon skeleton
    • C07C201/06—Preparation of nitro compounds
    • C07C201/12—Preparation of nitro compounds by reactions not involving the formation of nitro groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C205/00—Compounds containing nitro groups bound to a carbon skeleton
    • C07C205/27—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by etherified hydroxy groups
    • C07C205/35—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by etherified hydroxy groups having nitro groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
    • C07C205/36—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by etherified hydroxy groups having nitro groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton to carbon atoms of the same non-condensed six-membered aromatic ring or to carbon atoms of six-membered aromatic rings being part of the same condensed ring system
    • C07C205/38—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by etherified hydroxy groups having nitro groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton to carbon atoms of the same non-condensed six-membered aromatic ring or to carbon atoms of six-membered aromatic rings being part of the same condensed ring system the oxygen atom of at least one of the etherified hydroxy groups being further bound to a carbon atom of a six-membered aromatic ring, e.g. nitrodiphenyl ethers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C213/00—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton
    • C07C213/02—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton by reactions involving the formation of amino groups from compounds containing hydroxy groups or etherified or esterified hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C315/00—Preparation of sulfones; Preparation of sulfoxides
    • C07C315/04—Preparation of sulfones; Preparation of sulfoxides by reactions not involving the formation of sulfone or sulfoxide groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2603/00—Systems containing at least three condensed rings
    • C07C2603/93—Spiro compounds
    • C07C2603/94—Spiro compounds containing "free" spiro atoms

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

내용 없음

Description

비스(3-아미노펜옥시) 유도체의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (15)

  1. m-디니트로벤젠을 일반식 HO-X-OH의 방향족 또는 브리지된 방향족 탄화수소의 디히드록시-유도체와 쌍극성 중성용매 중에서 염기 존재하에 축합반응시킨 후 생성된 다음 일반식 (Ⅱ)의 방향족 또는 브리지된 방향족 탄화수소의 비스(3-니트르펜옥시) 유도체를 환원시키는 것을 특징으로 하는 다음 일반식(Ⅰ)의 방향족 또는 브리지된 방향족 탄화수소의 비스(3-아미노펜옥시) 유도체의 제조방법.
    상기 일반식에서,
    Y는 C1-C10, -C(CF3)2, -CO-, -S-, -SO-, -SO2- 또는 -O-의 탄화수소이고, R1,R2및 R3는 H 또는 CH3이다.
  2. 제 1 항에 있어서, 축합반응을 반응촉진제로서 다음 일반식의 질소 함유 지방족 폴리에테르 존재하에 수행하는 것을 특징으로 하는 비스(3-아미노펜옥시) 유도체의 제조방법.
    N[-CH2-CH2-O(-CH2-CH2-O)n-R]3
    R은 C1-C4알킬이고, n은 1 또는 2이다.
  3. 제 1 항에 있어서, 염기가 알카리 금속의 탄산염 또는 중탄산염인 것을 특징으로 하는 비스(3-아미노펜옥시) 유도체의 제조방법.
  4. 제 1 항에 있어서, 환원반응을 히드라진으로 수행하는 것을 특징으로 하는 비스(3-아미노펜옥시) 유도체의 제조방법.
  5. 제 1 항에 있어서, 환원반응을 촉매 존재하에 수소로 수행하는 것을 특징으로 하는 비스(3-아미노펜옥시) 유도체의 제조방법.
  6. 제 1 항에 있어서, 디히드록시 유도체가 다음 일반식을 갖는 것을 특징으로 하는 비스(3-아미노펜옥시) 유도체의 제조방법.
    상기 일반식에서, Y는 C1-C10, -C(CF3)2, -CO-, -S-, -SO-, -SO2- 또는 -O-의 탄화수소이다.
  7. 제 1 항에 있어서, 디히드록시 유도체가 히드로퀴논인 것을 특징으로 하는 비스(3-아미노펜옥시) 유도체의 제조방법.
  8. 제 1 항에 있어서, 디히드록시 유도체가 4,4'-디히드록시비페닐인 것을 특징으로 하는 비스(3-아미노펜옥시) 유도체의 제조방법.
  9. 제 1 항에 있어서, 디히드록시 유도체가 1-(4-히드록시페닐) -1,3,3-트리메틸-6-히드록시인단인 것을 특징으로 하는 비스(3-아미노펜옥시) 유도체의 제조방법.
  10. 제 1 항에 있어서, 디히드록시 유도체가 6,6-디히드록시-3,3,3',3' -트리메틸-1,1'-스피로비인단인 것을 특징으로 하는 비스(3-아미노펜옥시) 유도체의 제조방법.
  11. 제 1 항에 있어서, 디히드록시 유도체가 다음 일반식의 2,2-비스(4-히드록시페닐)프로판 유도체인 것을 특징으로 하는 비스(3-아미노펜옥시) 유도체의 제조방법.
    상기 일반식에서, R1,R2및 R3는 H 또는 CH3이다.
  12. 제 1 항에 있어서, 최종 생성물이 4,4'-비스(3-아미노펜옥시) 비페닐인 것을 특징으로 하는 비스(3-아미노펜옥시) 유도체의 제조방법.
  13. 제 1 항에 있어서, 최종 생성물이 1-[4-(3-아미노펜옥시)페닐]-1,3,3-트리메틸-6-(-3-아미노펜옥시)인단인 것을 특징으로 하는 비스(3-아미노펜옥시) 유도체의 제조방법.
  14. 제 1 항에 있어서, 최종생성물이 6,6'-비스(3-아미노펜옥시)-3,3,3',3'-테트라메틸-1,1'-스피로비인단인 것을 특징으로 하는 비스(3-아미노펜옥시) 유도체의 제조방법.
  15. 제 1 항에 있어서, 최종 생성물이 다음 일반식의 메틸 치환된 2,2-비스[4-(3-아미노펜옥시)페닐]프로판인 것을 특징으로 하는 비스(3-아미노펜옥시) 유도체의 제조방법.
    상기 일반식에서, R1,R2및 R3는 H 또는 CH3이다.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019860001263A 1985-02-22 1986-02-21 비스(3-아미노펜옥시) 유도체의 제조방법 KR870001062B1 (ko)

Applications Claiming Priority (15)

Application Number Priority Date Filing Date Title
JP85-32568 1985-02-22
JP60032568A JPH06727B2 (ja) 1985-02-22 1985-02-22 ビス（３−アミノフエノキシ）化合物の製造方法
JP85-113237 1985-05-28
JP60113237A JPH0653710B2 (ja) 1985-05-28 1985-05-28 １，４−ビス（３−アミノフエノキシ）ベンゼンの製造方法
JP60140408A JPH06728B2 (ja) 1985-06-28 1985-06-28 １−〔４−（３−アミノフエノキシ）フエニル〕−１，３，３−トリメチル−６−（３−アミノフエノキシ）インダンおよびその製造方法
JP85-140408 1985-06-28
JP60183039A JPH0710814B2 (ja) 1985-08-22 1985-08-22 ビス（３−ニトロフエノキシ）化合物の製造方法
JP85-183039 1985-08-22
JP60203557A JPH06729B2 (ja) 1985-09-17 1985-09-17 ６，６′−ビス（３−アミノフエノキシ）−３，３，３′，３′−テトラメチル−１，１′−スピロビインダンおよびその製造方法
JP85-203557 1985-09-17
JP60210266A JPH0637444B2 (ja) 1985-09-25 1985-09-25 ４，４′−ビス（３−アミノフエノキシ）ビフエニル
JP85-210266 1985-09-25
JP85-2102566 1985-09-25
JP85-289334 1985-12-24
JP60289334A JPH0637445B2 (ja) 1985-12-24 1985-12-24 ２，２−ビス〔４−（３−アミノフエノキシ）フエニル〕プロパンのメチル置換体およびその製造方法

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KR860006430A true KR860006430A (ko) 1986-09-11
KR870001062B1 KR870001062B1 (ko) 1987-05-27

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EP (1) EP0192480B1 (ko)
KR (1) KR870001062B1 (ko)
AU (1) AU566103B2 (ko)
CA (1) CA1256451A (ko)
DE (1) DE3650142T2 (ko)

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JPS6250375A (ja) * 1985-08-30 1987-03-05 Mitsui Toatsu Chem Inc 耐熱性接着剤
CA1270998A (en) * 1986-07-15 1990-06-26 Akihiro Yamaguchi Thermosetting resin composition
US4808754A (en) * 1987-02-27 1989-02-28 General Electric Company Spirobiindane bis-aminophenoxy ethers
EP0294931B1 (en) * 1987-05-06 1992-09-02 MITSUI TOATSU CHEMICALS, Inc. Self-lubricating thermosetting resin composition
EP0294930B1 (en) * 1987-05-06 1992-09-02 MITSUI TOATSU CHEMICALS, Inc. Thermosetting resin composition
DE3739795A1 (de) * 1987-11-24 1989-06-08 Hoechst Ag Teilfluorierte diphenylether, verfahren zu ihrer herstellung und ihre verwendung
EP0317882B1 (de) * 1987-11-24 1993-07-28 Hoechst Aktiengesellschaft Fluorhaltige Verbindungen auf Basis von 4,4'-Bis [2-(4-hydroxy-phenyl) hexafluorisopropyl] diphenylether, Verfahren zu ihrer Herstellung und ihre Verwendung
US4814496A (en) * 1988-02-18 1989-03-21 General Electric Company Spiro(bis)indane bis(carboxyphenyl ethers) and derivatives thereof
DE68919786T2 (de) * 1988-08-15 1995-07-20 Mitsui Toatsu Chemicals Geruchlose von polyvalenten Metallen modifizierte Salizylsäurecopolymere, deren Herstellungsverfahren und ihre Verwendung als Farbentwicklungsmittel für druckempfindliche Aufzeichnungspapierschichten.
DE58906877D1 (de) * 1988-09-02 1994-03-17 Ciba Geigy Bisimide der Allyl- oder Methallylbicyclo[2,2,1]hept-5-en-2,3-dicarbonsäure.
JP2854959B2 (ja) * 1989-12-28 1999-02-10 三井化学株式会社 ビス（３―ニトロフェノキシ）化合物の製造法
DE4001821A1 (de) * 1990-01-23 1991-07-25 Huels Chemische Werke Ag Verfahren zur herstellung von 4,4'-bis-(4-aminophenoxy)-diphenylsulfon
DE4035882A1 (de) * 1990-11-12 1992-05-14 Huels Chemische Werke Ag Verfahren zur herstellung von 4,4'-bis(4-aminophenoxy)diphenylsulfon
AU1186092A (en) * 1991-01-10 1992-08-17 E.I. Du Pont De Nemours And Company Bis(aminophenoxy)naphthalenes and bis(nitrophenoxy)naphthalenes
US5354839A (en) * 1992-04-07 1994-10-11 Mitsui Toatsu Chemicals, Incorporated Polyimide and preparation process of same
TW260682B (ko) * 1992-10-28 1995-10-21 Sumitomo Chemical Co
US5977413A (en) * 1997-08-04 1999-11-02 Nippon Kayaku Kabushiki Kaisha Method for producing bis(3-amino-4-hydroxyphenyl) compounds
RU2656270C1 (ru) * 2017-04-17 2018-06-04 Вадим Григорьевич Хозин Цемент низкой водопотребности и способ его получения
CN113563240A (zh) * 2021-06-28 2021-10-29 常州市阳光药业有限公司 4,4`-双（3-氨基苯氧基）二苯砜的合成方法

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US4196144A (en) * 1976-06-15 1980-04-01 Ciba-Geigy Corporation Aromatic diamines and their use as polycondensation components for the manufacture of polyamide, polyamide-imide and polyimide polymers
US4203922A (en) * 1976-07-19 1980-05-20 Trw Inc. Fluorinated aromatic diamine
US4222962A (en) * 1978-12-11 1980-09-16 Gulf Research & Development Company Process for preparing a substituted diphenoxybenzene

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AU5378586A (en) 1986-09-04
EP0192480A1 (en) 1986-08-27
AU566103B2 (en) 1987-10-08
DE3650142T2 (de) 1995-05-04
KR870001062B1 (ko) 1987-05-27
EP0192480B1 (en) 1994-11-23
CA1256451A (en) 1989-06-27
DE3650142D1 (de) 1995-01-05

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