KR860002541A - 불포화 알콜-디오에텔에 의한 새로운 중합체 및 그 제조방법 - Google Patents
불포화 알콜-디오에텔에 의한 새로운 중합체 및 그 제조방법 Download PDFInfo
- Publication number
- KR860002541A KR860002541A KR1019850007033A KR850007033A KR860002541A KR 860002541 A KR860002541 A KR 860002541A KR 1019850007033 A KR1019850007033 A KR 1019850007033A KR 850007033 A KR850007033 A KR 850007033A KR 860002541 A KR860002541 A KR 860002541A
- Authority
- KR
- South Korea
- Prior art keywords
- polymer
- hydroxy
- dia
- alcohol
- unsaturated alcohol
- Prior art date
Links
- 229920000642 polymer Polymers 0.000 title claims 13
- 238000002360 preparation method Methods 0.000 title claims 2
- 238000000034 method Methods 0.000 claims 4
- 239000000203 mixture Substances 0.000 claims 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims 2
- 125000000217 alkyl group Chemical group 0.000 claims 2
- 238000009833 condensation Methods 0.000 claims 2
- 230000005494 condensation Effects 0.000 claims 2
- 239000012948 isocyanate Substances 0.000 claims 2
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 claims 2
- ACIAHEMYLLBZOI-ZZXKWVIFSA-N Unsaturated alcohol Chemical compound CC\C(CO)=C/C ACIAHEMYLLBZOI-ZZXKWVIFSA-N 0.000 claims 1
- 125000003158 alcohol group Chemical group 0.000 claims 1
- 125000003172 aldehyde group Chemical group 0.000 claims 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims 1
- 239000003054 catalyst Substances 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 claims 1
- 230000015271 coagulation Effects 0.000 claims 1
- 238000005345 coagulation Methods 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 229920001577 copolymer Polymers 0.000 claims 1
- 230000008878 coupling Effects 0.000 claims 1
- 238000010168 coupling process Methods 0.000 claims 1
- 238000005859 coupling reaction Methods 0.000 claims 1
- 150000001993 dienes Chemical class 0.000 claims 1
- 239000013536 elastomeric material Substances 0.000 claims 1
- DNJIEGIFACGWOD-UHFFFAOYSA-N ethyl mercaptane Natural products CCS DNJIEGIFACGWOD-UHFFFAOYSA-N 0.000 claims 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 claims 1
- 125000004356 hydroxy functional group Chemical group O* 0.000 claims 1
- -1 isocyanate ester Chemical class 0.000 claims 1
- 150000002513 isocyanates Chemical group 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 238000006068 polycondensation reaction Methods 0.000 claims 1
- 229920005862 polyol Polymers 0.000 claims 1
- 150000003077 polyols Chemical class 0.000 claims 1
- 229920006395 saturated elastomer Polymers 0.000 claims 1
- RVEZZJVBDQCTEF-UHFFFAOYSA-N sulfenic acid Chemical compound SO RVEZZJVBDQCTEF-UHFFFAOYSA-N 0.000 claims 1
- DGVVWUTYPXICAM-UHFFFAOYSA-N β‐Mercaptoethanol Chemical compound OCCS DGVVWUTYPXICAM-UHFFFAOYSA-N 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
- C08G75/12—Polythioether-ethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G85/00—General processes for preparing compounds provided for in this subclass
- C08G85/004—Modification of polymers by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/34—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/34—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives
- C08G65/48—Polymers modified by chemical after-treatment
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polyurethanes Or Polyureas (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Sealing Material Composition (AREA)
- Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (12)
- 다음의 단말 및/또는 싸이드체인를 그 체인에 대동하고, 여기서 R은 H이거나 또는 C1∼C12알킬을 뜻하며, m은 0-6이며, n은 1-10이고 p는 1-10이며 한개, 수개 또는 모든 p 2중 결합이 활성기에 의해 포화될 수 있는 것을 특징으로 하는 중합체 또는공중합체.
- 청구범위 1에 있어서, R은 H이거나 또는 C1∼C6알킬이며, n은 2-6이며 p는 1-3임을 특징으로 하는 중합체.
- 청구범위 1 또는 2에 있어서, 그 체인은 이와 같은 단위의 몇 종류를 대동하며, 특히 p=1, p=2 및 p=3임을 특징으로 하는 중합체.
- 청구범위 1 내지 3에 있어서, 디오디글리콜을 하이드록시에 침하이드록시-유화물 및 불포화, 알콜-디오에텔로 응결시킴으로 결과되며, 이와 같은 것들은 1-하이드록시-3-디아-합텐-5: 1-하이드록시-3-디아-온 데카디엔-5,9 1-하이드록시-3-디아-펜타데카디엔-5,9,13 또는 동시에 이러한 것들의 몇 가지로부터 유도해낸 것을 특징으로 하는 중합체.
- 상기 청구범위중 어느 하나에 있어 중합체는 또한 1-하이드록시-3-디아-헵텐-6, 1-하이드록시-3-디아-3-메칠-데카디엔-6,9,1-하이드록시-3-디아-10-메칠-테트라데카디엔-5,10,13, 또는 이러한 화합물 수개로부터 유도해낸 것을 특징으로 하는 중합체.
- 상기 청구범위중 어느 하나에 있어서, 그것은 이소씨아네이트 에스터 또는 알데하이드기를 포함하는 것을 특징으로 하는 중합체.
- 응결촉매 특히 트리페닐포스파이트 및/또는 디오디페놀의 작용하에 100°-200℃에서 알콜관능과 반응을 일으킬 수 있는 기를 대동하는 중합체와 불포화 알콜-디오에텔을 응결시는 중합체 제조방법으로서, 불포화 알콜-디오에텔의 유형은여기서, R은 H나 또는 C1∼C12알킬을 의미하며 바람직하게는 C1∼C6이 좋으며, n은 1-10이며, 바람직하게는 2-6이며, m은 0-6이며, p는 1-10이며 바람직하게는 1-3인 것을 특징으로 하는 중합체 제조방법.
- 청구범위 7에 있어서, 시작중합체는 폴리올, 디아폴리올 및/또는 폴리디올의 다응결로부터 생겨나는 것을 특징으로 하는 제조방법.
- 청구범위 7 또는 8에 있어서, 응결은 몇가지 상이한 불포화 알콜-디오에텔, 특히 상이한 p값을 갖인 이러한 디오에텔의 혼합물의 집합에 의해 달성하는 것을 특징으로 하는 제조방법.
- 청구범위 8에 있어서, 사용한 불포화 알콜 디오에텔의 혼합물은 1-10몰의 활용성디엔, 특히 부타디엔을 머캅토-알콜 특히 머캅토-에타놀과 반응시킨 조제품으로 구성된 것을 특징으로 하는 제조방법.
- 청구범위 7 내지 10중 어느 하나에 있어서 불포화 알콜-디오에텔을 중합체에 결합시키는 수단은 이소씨아네이트, 카복실, 알데하이드, 에텔 또는 염산등임을 특징으로 하는 제조방법.
- 청구범위 1-6중 어느 하나에 있어서, 분말산화체가든 중합체의 혼합물에 의해 경화되고 특히 MnO2및/또는 PbO2에 의해 갱화되고, 또는 메캅탄산화 반응에 의해 갱화된 플라스틱 또는 엘라스토머성물질의 용법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8414666A FR2570709B1 (fr) | 1984-09-25 | 1984-09-25 | Nouveaux polymeres a base d'alcool-thioethers insatures |
| FR8414666 | 1984-09-25 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR860002541A true KR860002541A (ko) | 1986-04-26 |
Family
ID=9308020
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019850007033A KR860002541A (ko) | 1984-09-25 | 1985-09-25 | 불포화 알콜-디오에텔에 의한 새로운 중합체 및 그 제조방법 |
Country Status (20)
| Country | Link |
|---|---|
| US (1) | US4766195A (ko) |
| EP (1) | EP0176439B1 (ko) |
| JP (1) | JPS61190515A (ko) |
| KR (1) | KR860002541A (ko) |
| AU (1) | AU582388B2 (ko) |
| BE (1) | BE903249A (ko) |
| BR (1) | BR8504696A (ko) |
| DE (2) | DE176439T1 (ko) |
| DK (1) | DK434785A (ko) |
| ES (1) | ES8605013A1 (ko) |
| FI (1) | FI853652L (ko) |
| FR (1) | FR2570709B1 (ko) |
| GR (1) | GR852341B (ko) |
| HU (1) | HUT39756A (ko) |
| IT (1) | IT1214631B (ko) |
| LU (1) | LU86092A1 (ko) |
| NO (1) | NO853722L (ko) |
| NZ (1) | NZ213607A (ko) |
| PT (1) | PT81195B (ko) |
| ZA (1) | ZA857325B (ko) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4623711A (en) * | 1985-08-21 | 1986-11-18 | Products Research & Chemical Corp. | Modified disulfide polymer composition and method for making same from mercaptan terminated disulfide polymer and diethyl formal mercaptan terminated polysulfide |
| JP2510912B2 (ja) * | 1991-08-15 | 1996-06-26 | 正幸 小野寺 | 釣用こませの餌まき器 |
| US6262853B1 (en) | 1998-12-25 | 2001-07-17 | Olympus Optical Co., Ltd. | Lens barrel having deformable member |
| DE10025529A1 (de) | 2000-05-23 | 2002-02-14 | Henkel Teroson Gmbh | Zweikomponentiger Polysulfid-Kleb-Dichtstoff |
| JP4817876B2 (ja) * | 2006-02-20 | 2011-11-16 | キヤノン株式会社 | レンズ鏡筒およびカメラシステム |
| US7875666B2 (en) * | 2008-04-24 | 2011-01-25 | Prc-De Soto International, Inc. | Thioethers, methods for their preparation, and compositions including such thioethers |
| CN107827792B (zh) * | 2017-11-17 | 2019-07-19 | 锦西化工研究院有限公司 | 一种合成1,5,13-三羟基-7-氧杂-3,11-二硫杂十三烷的方法及提纯方法 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4289864A (en) * | 1980-05-19 | 1981-09-15 | Monsanto Company | Oxidative polymerization of monomers having at least two activated unsaturations |
| AU547995B2 (en) * | 1980-12-04 | 1985-11-14 | Courtaulds Aerospace, Inc. | Liquid polythioethers |
| AU7939282A (en) * | 1980-12-04 | 1982-06-17 | Products Research & Chemical Corporation | Linear liquid polythioethers |
| US4366307A (en) * | 1980-12-04 | 1982-12-28 | Products Research & Chemical Corp. | Liquid polythioethers |
-
1984
- 1984-09-25 FR FR8414666A patent/FR2570709B1/fr not_active Expired
-
1985
- 1985-09-17 BE BE0/215591A patent/BE903249A/fr not_active IP Right Cessation
- 1985-09-19 DE DE198585401827T patent/DE176439T1/de active Pending
- 1985-09-19 EP EP85401827A patent/EP0176439B1/fr not_active Expired
- 1985-09-19 DE DE8585401827T patent/DE3562255D1/de not_active Expired
- 1985-09-23 NO NO853722A patent/NO853722L/no unknown
- 1985-09-23 FI FI853652A patent/FI853652L/fi not_active IP Right Cessation
- 1985-09-24 AU AU47829/85A patent/AU582388B2/en not_active Ceased
- 1985-09-24 LU LU86092A patent/LU86092A1/fr unknown
- 1985-09-24 ZA ZA857325A patent/ZA857325B/xx unknown
- 1985-09-24 JP JP60209040A patent/JPS61190515A/ja active Pending
- 1985-09-24 ES ES547249A patent/ES8605013A1/es not_active Expired
- 1985-09-24 IT IT8522260A patent/IT1214631B/it active
- 1985-09-24 HU HU853593A patent/HUT39756A/hu unknown
- 1985-09-25 NZ NZ213607A patent/NZ213607A/xx unknown
- 1985-09-25 KR KR1019850007033A patent/KR860002541A/ko not_active Application Discontinuation
- 1985-09-25 DK DK434785A patent/DK434785A/da not_active Application Discontinuation
- 1985-09-25 PT PT81195A patent/PT81195B/pt not_active IP Right Cessation
- 1985-09-25 GR GR852341A patent/GR852341B/el unknown
- 1985-09-25 BR BR8504696A patent/BR8504696A/pt unknown
-
1986
- 1986-12-15 US US06/942,966 patent/US4766195A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| FR2570709B1 (fr) | 1987-01-02 |
| BE903249A (fr) | 1986-03-17 |
| IT8522260A0 (it) | 1985-09-24 |
| GR852341B (ko) | 1986-01-24 |
| DK434785D0 (da) | 1985-09-25 |
| LU86092A1 (fr) | 1986-03-11 |
| DK434785A (da) | 1986-03-26 |
| AU582388B2 (en) | 1989-03-23 |
| DE3562255D1 (en) | 1988-05-26 |
| BR8504696A (pt) | 1986-07-22 |
| PT81195B (fr) | 1987-07-08 |
| NO853722L (no) | 1986-03-26 |
| EP0176439B1 (fr) | 1988-04-20 |
| FR2570709A1 (fr) | 1986-03-28 |
| HUT39756A (en) | 1986-10-29 |
| NZ213607A (en) | 1988-06-30 |
| PT81195A (fr) | 1985-10-01 |
| ES8605013A1 (es) | 1986-03-16 |
| JPS61190515A (ja) | 1986-08-25 |
| ZA857325B (en) | 1986-05-28 |
| IT1214631B (it) | 1990-01-18 |
| US4766195A (en) | 1988-08-23 |
| ES547249A0 (es) | 1986-03-16 |
| AU4782985A (en) | 1986-04-10 |
| FI853652L (fi) | 1986-03-26 |
| EP0176439A1 (fr) | 1986-04-02 |
| FI853652A0 (fi) | 1985-09-23 |
| DE176439T1 (de) | 1987-01-15 |
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| A201 | Request for examination | ||
| E902 | Notification of reason for refusal | ||
| E601 | Decision to refuse application |