KR860001008A - 실리카의 제조방법 - Google Patents
실리카의 제조방법 Download PDFInfo
- Publication number
- KR860001008A KR860001008A KR1019850004952A KR850004952A KR860001008A KR 860001008 A KR860001008 A KR 860001008A KR 1019850004952 A KR1019850004952 A KR 1019850004952A KR 850004952 A KR850004952 A KR 850004952A KR 860001008 A KR860001008 A KR 860001008A
- Authority
- KR
- South Korea
- Prior art keywords
- colloid
- silica
- acidifying agent
- volume
- corresponds
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/113—Silicon oxides; Hydrates thereof
- C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/113—Silicon oxides; Hydrates thereof
- C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
- C01B33/18—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof
- C01B33/187—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof by acidic treatment of silicates
- C01B33/193—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof by acidic treatment of silicates of aqueous solutions of silicates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/04—Particle morphology depicted by an image obtained by TEM, STEM, STM or AFM
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/50—Agglomerated particles
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/11—Powder tap density
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/14—Pore volume
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/19—Oil-absorption capacity, e.g. DBP values
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/90—Other properties not specified above
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Nanotechnology (AREA)
- Inorganic Chemistry (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Composite Materials (AREA)
- General Physics & Mathematics (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Physics & Mathematics (AREA)
- Silicon Compounds (AREA)
- Fats And Perfumes (AREA)
- Lubricants (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1,2 및 3도는 응결물의 사진이다.
제6도는 본 발명에 다른 실리카의 유사흡수곡선을 나타낸 것으로서 실선은 흡수된 체적 ㎤/g을 나타내고, 파단선은 그로부터 유도된 것을 나타낸 것이다.
Claims (13)
- 수성물질을 포함하는 히일을 형성하고 산성화제와 알카리성 실리케이트 용액을 동시 첨가하여 알카리성 실리케이트의 수용액과 산성화제를 반응시킴으로써 실리카를 제조하는 방법에 있어서, 하기 단계로 구성됨을 특징으로 하는 실리카의 제조방법.
- a) 일정부피로 반응물을 첨가하고, 직경크기에 있어 단일 분산성인 실리카의 구형콜로이드와 회수 매체중에서 다중 분산성인 실리카의 콜로이드를 일정부피로 얻도록 방응매체를 연속적으로 회수하고, b) 단계a)에서 얻어진 물질중 적어도 일부를 전해질과 반응시키고, c) 실리케이트 용액과 산성화제를 첨가함으로써 단계b)에서 얻어진 물질을 고화합.
- 제1항에 있어서, 단계 b)에서의 콜로이드가 일정부피로 나오는 콜로이드의 1 또는 그 이상의 분획물에 해당하는 것을 특징으로 하는 방법.
- 제1항에 있어서, 단계 b)에서의 콜로이드가 회수물질로부터 나오는 콜로이드의 1 또는 그 이상의 분획물에 해당하는 것을 특징으로 하는 방법.
- 제1항 내지 제3항중 어느 하나에 있어서, 단계 b)에서의 콜로이드가 일정부피의 회수물질로부터 나오는 콜로이드 분획물의 혼합물에 해당하는 것을 특징으로 하는 방법.
- 제1항 내지 제4항중 어느 하나에 있어서, 단계 b)에서의 콜로이드가 안정한 상태에 도달하기 전에 얻어지는 것을 특징으로 하는 방법.
- 제1항 내지 제4항중 어느 하나에 있어서,단계 b)에서의 콜로이드가 안정한 상태에 도달된 후에 얻어지는 것을 특징으로 하는 방법.
- 제1항 내지 제6항중 어느 하나에 있어서, 단계 b)에서의 응결이 알카리금속 및 알카리토금속염의 전해질에 의해 이루어지는 것을 특징으로 하는 방법.
- 제1항 내지 제8항중 어느 하나에 있어서, 운동량이 큰 고온가스로 대칭축 회전류 구조를 형성함으로써 건조조작을 실시하고, 측류를 파괴, 분산, 수집 및 건조하기에 충분한 현탁액의 축류와 관련하여 회전흐름의 대칭축을 따라 건조시킬 현탁액을 도입하는 것을 특징으로 하는 방법.
- 제1항에 있어서, 침강실리카가 다음 특성을 갖는 것을 특징으로 하는 방법:-CTAB표면적: 20 내지 120㎡/g, -DBP오일흡착능:실리카 100g당 250 내지 500㎖ 및 -응결물의 평균 둘출면적 : 8,000nm2이상
- 제9항에 있어서, 침강실리카가 응결물의 평균 둘출면적 15,000nm2이상을 갖는 것을 특징으로 하는 방법.
- 제9항에 있어서, 침강실리카가 고기공률(1㎤/g)과 단일성 기공을 갖는 것을 특징으로 하는 방법.
- ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR8411004 | 1984-07-11 | ||
FR84.11004 | 1984-07-11 | ||
FR8411004A FR2567505B1 (fr) | 1984-07-11 | 1984-07-11 | Silice a prise d'huile elevee et a structure primaire controlee et procede pour son obtention |
Publications (2)
Publication Number | Publication Date |
---|---|
KR860001008A true KR860001008A (ko) | 1986-02-22 |
KR910009573B1 KR910009573B1 (ko) | 1991-11-21 |
Family
ID=9306012
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019850004952A KR910009573B1 (ko) | 1984-07-11 | 1985-07-11 | 실리카의 제조방법 |
Country Status (8)
Country | Link |
---|---|
US (3) | US4708859A (ko) |
EP (1) | EP0170579B1 (ko) |
JP (1) | JPS61117113A (ko) |
KR (1) | KR910009573B1 (ko) |
AT (1) | ATE40669T1 (ko) |
CA (1) | CA1285116C (ko) |
DE (1) | DE3568155D1 (ko) |
FR (1) | FR2567505B1 (ko) |
Families Citing this family (51)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2589871B1 (fr) * | 1985-09-13 | 1987-12-11 | Rhone Poulenc Chim Base | Charge renforcante pour elastomere a base de silice |
GB8713263D0 (en) * | 1987-06-05 | 1987-07-08 | Unilever Plc | Spheroidal silica |
US5286478A (en) * | 1987-11-04 | 1994-02-15 | Rhone-Poulenc Chimie | Dentifrice-compatible silica particulates |
US5614177A (en) * | 1987-11-04 | 1997-03-25 | Rhone-Poulenc Chimie | Dentifrice-compatible silica particulates |
FR2631620B1 (fr) * | 1988-05-19 | 1990-07-27 | Rhone Poulenc Chimie | Nouvelle silice precipitee absorbante et composition a base de cette s ilice |
FR2632185B1 (fr) * | 1988-06-01 | 1992-05-22 | Rhone Poulenc Chimie | Silice pour compositions dentifrices compatible notamment avec le zinc |
FR2649089B1 (fr) * | 1989-07-03 | 1991-12-13 | Rhone Poulenc Chimie | Silice a porosite controlee et son procede d'obtention |
US5225177A (en) * | 1990-01-19 | 1993-07-06 | J. M. Huber Corporation | Dentifrice abrasives and compositions |
US5094829A (en) * | 1990-06-21 | 1992-03-10 | Ppg Industries, Inc. | Reinforced precipitated silica |
FR2678259B1 (fr) * | 1991-06-26 | 1993-11-05 | Rhone Poulenc Chimie | Nouvelles silices precipitees sous forme de granules ou de poudres, procedes de synthese et utilisation au renforcement des elastomeres. |
US6001322A (en) | 1993-09-29 | 1999-12-14 | Rhone-Poulenc Chimie | Precipitated silicas |
US6169135B1 (en) | 1993-09-29 | 2001-01-02 | Rhone Poulenc Chimie | Precipitated silica |
CN1047149C (zh) | 1993-09-29 | 1999-12-08 | 罗纳·布朗克化学公司 | 沉淀硅石 |
FR2710630B1 (fr) * | 1993-09-29 | 1995-12-29 | Rhone Poulenc Chimie | Nouvelles silices précipitées, leur procédé de préparation et leur utilisation au renforcement des élastomères. |
WO1995017458A1 (en) * | 1993-12-20 | 1995-06-29 | Ppg Industries, Inc. | Tire tread composition comprising highly reinforcing silica |
WO1995017459A1 (en) * | 1993-12-20 | 1995-06-29 | Ppg Industries, Inc. | Tire tread composition comprising highly reinforcing silica |
FR2714369B1 (fr) * | 1993-12-29 | 1996-01-26 | Rhone Poulenc Chimie | Silices abrasives pour compositions dentifrices. |
JP2908253B2 (ja) * | 1994-09-26 | 1999-06-21 | 日本化学工業株式会社 | 水和珪酸とその製造方法 |
US5846506A (en) * | 1994-10-07 | 1998-12-08 | Degussa Aktiengesellschaft | Precipitated silicas |
US5571494A (en) * | 1995-01-20 | 1996-11-05 | J. M. Huber Corporation | Temperature-activated polysilicic acids |
MY116513A (en) * | 1995-04-19 | 2004-02-28 | Ppg Ind Ohio Inc | Amorphous precipitated silica having large liquid carrying capacity |
US5911963A (en) * | 1995-05-12 | 1999-06-15 | Ppg Industries Ohio, Inc. | Amorphous precipitated silica having a low proportion of small pores |
DE19527278A1 (de) * | 1995-07-26 | 1997-01-30 | Degussa | Fällungskieselsäure |
US5804293A (en) * | 1995-12-08 | 1998-09-08 | Ppg Industries, Inc. | Coating composition for recording paper |
WO1997045365A1 (en) * | 1996-05-31 | 1997-12-04 | Ppg Industries, Inc. | Amorphous precipitated silica |
DE69714727T2 (de) * | 1996-05-31 | 2003-04-03 | Ppg Ind Ohio Inc | Amorphe fällungskieselsäure |
FR2750692B1 (fr) * | 1996-07-05 | 1998-10-16 | Rhone Poulenc Chimie | Nouvelle silice abrasive, utilisable dans les dentifrices, son procede de preparation et compositions dentifrices la contenant |
FR2762611B1 (fr) * | 1997-04-29 | 1999-06-11 | Atochem Elf Sa | Silice poreuse modifiee, son procede de fabrication et son utilisation dans les peintures et comme vecteur de pigments et colorants |
US5891949A (en) * | 1997-05-02 | 1999-04-06 | J.M. Huber Corporation | Natural rubber compound |
US5929156A (en) * | 1997-05-02 | 1999-07-27 | J.M. Huber Corporation | Silica product for use in elastomers |
FR2763581B1 (fr) * | 1997-05-26 | 1999-07-23 | Rhodia Chimie Sa | Silice precipitee utilisable comme charge renforcante pour elastomeres |
AU1614700A (en) * | 1998-11-10 | 2000-05-29 | Integrity Technologies, Llc | Method of generating aqueous silica network particles and compositions includingthe silica network particles |
US6573032B1 (en) | 1999-04-22 | 2003-06-03 | J. M. Huber Corporation | Very high structure, highly absorptive hybrid silica and method for making same |
AU5527300A (en) * | 1999-05-31 | 2000-12-18 | Pirelli Pneumatici S.P.A. | Low rolling resistance tire for vehicles |
US6624233B2 (en) | 1999-05-31 | 2003-09-23 | Pirelli Pneumatici S.P.A. | Low rolling resistance tire for vehicles |
CA2292819A1 (en) * | 1999-12-22 | 2001-06-22 | Bayer Inc. | Process for the production of a precipitated silica slurry with a controlled aggregate particle size distribution |
AU2002211736A1 (en) * | 2000-10-13 | 2002-04-22 | University Of Cincinnati | Methods for synthesizing precipitated silica and use thereof |
ATE280203T1 (de) * | 2001-08-08 | 2004-11-15 | Degussa | Mit siliziumdioxid umhüllte metalloxidpartikel |
US20030096900A1 (en) * | 2001-11-16 | 2003-05-22 | Holden Brian David | Organic plant derived precipitated silica aggregates, elastomers reinforced therewith and articles such as tires with component thereof |
FR2833937B1 (fr) * | 2001-12-26 | 2004-11-12 | Rhodia Chimie Sa | Silices a faible reprise en eau |
US7682738B2 (en) * | 2002-02-07 | 2010-03-23 | Kvg Technologies, Inc. | Lead acid battery with gelled electrolyte formed by filtration action of absorbent separators and method for producing it |
JP2005053728A (ja) * | 2003-08-01 | 2005-03-03 | Dsl Japan Co Ltd | 高吸油性および高い構造性を有する非晶質シリカ粒子 |
CN101679050B (zh) * | 2007-05-03 | 2012-11-28 | 科学与工业研究委员会 | 制备微细的沉淀二氧化硅的方法 |
FR2928363B1 (fr) * | 2008-03-10 | 2012-08-31 | Rhodia Operations | Nouveau procede de preparation de silices precipitees, silices precipitees a morphologie, granulometrie et porosite particulieres et leurs utilisations, notamment pour le renforcement de polymeres |
US8790608B2 (en) * | 2008-09-12 | 2014-07-29 | Nalco Company | Siliceous materials having tunable porosity and surface morphology and methods of synthesizing same |
US8529787B2 (en) | 2008-09-26 | 2013-09-10 | Fuso Chemical Co., Ltd. | Colloidal silica containing silica secondary particles having bent structure and/or branched structure, and method for producing same |
US8609068B2 (en) | 2010-02-24 | 2013-12-17 | J.M. Huber Corporation | Continuous silica production process and silica product prepared from same |
JP5495880B2 (ja) * | 2010-03-25 | 2014-05-21 | 扶桑化学工業株式会社 | コロイダルシリカの二次粒子径調整方法 |
WO2011155536A1 (ja) * | 2010-06-09 | 2011-12-15 | 日揮触媒化成株式会社 | 蛋白質固定化用担体、固定化蛋白質及びそれらの製造方法 |
US9028605B2 (en) | 2011-02-25 | 2015-05-12 | J.M. Huber Corporation | Coating compositions comprising spheroid silica or silicate |
WO2024100081A1 (en) | 2022-11-08 | 2024-05-16 | Evonik Operations Gmbh | Precipitated silica and methods thereof |
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US2466842A (en) * | 1945-11-15 | 1949-04-12 | Davison Chemical Corp | Method for making silica hydrosol |
US2577485A (en) * | 1950-09-08 | 1951-12-04 | Du Pont | Process of making stable silica sols and resulting composition |
GB710015A (en) * | 1950-12-02 | 1954-06-02 | Degussa | An improved process for the production of finely divided silica |
CH341802A (de) * | 1955-02-03 | 1959-10-31 | Basf Ag | Verfahren zur kontinuierlichen Herstellung kieselsäurehaltiger Hydrogele |
US2956957A (en) * | 1956-04-02 | 1960-10-18 | Grace W R & Co | Method for producing clear, homogeneous silica hydrosols |
GB1044019A (en) * | 1963-10-17 | 1966-09-28 | Permutit Co Ltd | Improvements relating to the production of silica sol |
DE1299617B (de) * | 1965-01-13 | 1969-07-24 | Degussa | Verfahren zur Herstellung von feinverteiltem gefaelltem Siliciumdioxid |
US3337299A (en) * | 1965-05-24 | 1967-08-22 | Jr Oliver W Burke | Silica pigments and process for producing same |
US4001379A (en) * | 1968-04-27 | 1977-01-04 | Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler | Process of making superfine amorphous high structural silicic acid |
US3954944A (en) * | 1973-03-08 | 1976-05-04 | Joseph Crosfield & Sons, Ltd. | Fine silicas |
US4191742A (en) * | 1974-05-22 | 1980-03-04 | J. M. Huber Corporation | Amorphous precipitated siliceous pigments and methods for their production |
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FR2353486A1 (fr) * | 1976-06-04 | 1977-12-30 | Rhone Poulenc Ind | Nouvelle silice de synthese amorphe, procede pour son obtention et application de ladite silice dans les vulcanisats |
FR2444700A1 (fr) * | 1978-12-20 | 1980-07-18 | Rhone Poulenc Ind | Nouvel agent recurant non abrasif et composition lessivielle le renfermant |
US4243428A (en) * | 1979-01-24 | 1981-01-06 | Donnet Jean Baptise | Processes for the manufacturing of precipitated silica |
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JPS59163306A (ja) * | 1983-03-08 | 1984-09-14 | Taki Chem Co Ltd | 歯磨用シリカ基剤及びその製法 |
FR2562534B1 (fr) * | 1984-04-06 | 1986-06-27 | Rhone Poulenc Chim Base | Nouvelle silice precipitee a caracteres morphologiques ameliores, procede pour son obtention et application, notamment comme charge |
-
1984
- 1984-07-11 FR FR8411004A patent/FR2567505B1/fr not_active Expired
-
1985
- 1985-07-08 EP EP85401379A patent/EP0170579B1/fr not_active Expired
- 1985-07-08 AT AT85401379T patent/ATE40669T1/de not_active IP Right Cessation
- 1985-07-08 DE DE8585401379T patent/DE3568155D1/de not_active Expired
- 1985-07-09 CA CA000486487A patent/CA1285116C/en not_active Expired - Fee Related
- 1985-07-10 JP JP60152150A patent/JPS61117113A/ja active Granted
- 1985-07-11 KR KR1019850004952A patent/KR910009573B1/ko not_active IP Right Cessation
-
1986
- 1986-06-24 US US06/879,492 patent/US4708859A/en not_active Expired - Lifetime
-
1987
- 1987-01-16 US US07/005,012 patent/US4842838A/en not_active Expired - Lifetime
- 1987-08-05 US US07/081,980 patent/US4874594A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
EP0170579A1 (fr) | 1986-02-05 |
KR910009573B1 (ko) | 1991-11-21 |
US4874594A (en) | 1989-10-17 |
FR2567505A1 (fr) | 1986-01-17 |
JPH0130764B2 (ko) | 1989-06-21 |
US4708859A (en) | 1987-11-24 |
DE3568155D1 (en) | 1989-03-16 |
CA1285116C (en) | 1991-06-25 |
FR2567505B1 (fr) | 1986-11-21 |
JPS61117113A (ja) | 1986-06-04 |
EP0170579B1 (fr) | 1989-02-08 |
US4842838A (en) | 1989-06-27 |
ATE40669T1 (de) | 1989-02-15 |
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