KR850007452A - 코폴리에스테르 탄성중합체 방염제 조성물 - Google Patents

코폴리에스테르 탄성중합체 방염제 조성물 Download PDF

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KR850007452A
KR850007452A KR1019850002882A KR850002882A KR850007452A KR 850007452 A KR850007452 A KR 850007452A KR 1019850002882 A KR1019850002882 A KR 1019850002882A KR 850002882 A KR850002882 A KR 850002882A KR 850007452 A KR850007452 A KR 850007452A
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glycol
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block
weight
molecular weight
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KR1019850002882A
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리어포울드 쉐인 앨버어트
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도늘드 에이 호우즈
이 아이 듀우판 디 네모아 앤드 캄파니
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Publication of KR850007452A publication Critical patent/KR850007452A/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00—Use of pretreated ingredients
    • C08K9/04—Ingredients treated with organic substances
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/06—Pretreated ingredients and ingredients covered by the main groups C08K3/00 - C08K7/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/346—Clay

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polyesters Or Polycarbonates (AREA)

Abstract

내용 없음

Description

코폴리에스테르 탄성 중합체 방염제 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. 일반식,으로 표시되는 단쇄에스테르 반복단위(D)는 분자량 250이하의 저분자량 디올로부터 히드록시기를 제거한 후에 잔존하는 2가의 라디칼이고, R은 분자량 300이하의 디카르복실산으로 부터 카르복시기를 제거한 후에 잔존하는 2가의 라디칼이며, D 및 R은 수평균 분자량이 5000이상이고 융점이 150℃이상인 단쇄에스테르 단위들로 중합체가 본질적으로 구성되도록 선택된다)들로 구성되는 고융점 반복 블록(A), 히드록시기 또는 카르복시기 또는 이들의 혼합기들을 함유하며 수평균 분자량이 400내지 4000이고 융점이 약 100℃이하인 화합물들로 부터 유도되는 저융점 반복블록(B), 및 반복블록(A)와 (B)를 결합하여 멀티-블록코폴리에스테르 탄성중합체를 형성하기 위한 충분한 량의 2작용성기들로 본질적으로 구성되며, (A)대 (B)의 중량비율이 약 1 : 0.67내지 1:2인 멀티 블록코폴리에스테르 탄성 중합체(a); 전술한 멀티-블록 코폴리에스테르 탄성 중합체 100부당 공기중에서 가열속도 10℃/분하에 측정한 열중량 분석에 의한 중량손실이 250℃하에 5%이하이고 65중량%이상의 브롬을 함유하는 브롬-함유 방염제 약 25내지 35부(b); 전술한 브롬-함유 방염제 1부당 3산화안티몬 약 0.20내지 0.75부(c); 및 전술한 멀티-블록 코폴리에스테르 탄성중합체 100부당 1종 이상의 일반식,
    으로 표시되는 4급 암모늄염(M-은 클로라이드, 브로마이드, 요오다이드, 니트라이트, 히드록사이드, 아세테이트, 메틸셀페이트 및 이들의 혼합으로 구성되는 군중에서 선택되고; R1은 탄소 원자수 12내지 22개의 알킬기이며; R2,R3및 R4는 수소원자, 탄소원자수 1내지 22개의 알킬기, 아릴기 및 알킬 사슬상의 탄소 원자수가 1내지 22개인 아르알킬기로 구성되는 군중에서 선택된다)들과 이온 교환 능력이 점토 100g당 75meg이상인 스멕타이트 점토와의 반응 생성물인 친유기 점토 약 2내지 10부로 구성되는 거의 무적(無滴)의 코폴리에스테르 탄성 중합체 방염제 조성물.
  2. 제1항에 있어서, 고융점 반복 블록이 에틸렌 글리콜 또는 1.4부탄디올과 테레프탈산 또는 30중량%이하의 이소프탈산 또는 프탈산을 함유하는 그의 혼합물로 부터 유도되는 조성물.
  3. 제1항에 있어서, 저융점 반복 블록이 탄소/산소의 원자비율이 약 2.0내지 4.3이고 수평균 분자량이 약 400내지 4000인 폴리(알킬렌옥사이드)글리콜로부터 유도되는 조성물.
  4. 제3항에 있어서, 폴리(알킬렌옥사이드)글리콜이 수평균 분자량이 600내지 1600인 폴리(테트라메틸렌옥사이드)글리콜인 조성물.
  5. 제3항에 있어서, 폴리(알킬렌옥사이드)글리콜이 수평균 분자량이 1500내지 2800이고 에틸렌옥사이드 함량이 15내지 35중량%인 에틸렌옥사이드 말단의폴리(프로필렌옥사이드)글리콜인 조성물.
  6. 제1항에 있어서, 저융점 반복블록이 폴리에스테르글리콜로부터 유도되는 조성물.
  7. 제6항에 있어서, 폴리에스테르글리콜이 수평균 분자량이 800내지 2500인 폴리(테트라메틸렌아디페이트)글리콜 또는 폴리카프로락톤글리콜인 조성물.
  8. 제1항에 있어서, 브롬-함유 방염제가 N,N'-에텔렌비스(테트라브로모프탈이미드)인 조성물.
  9. 제1항에 있어서, 친유기 점토가 디메틸렌벤질(수소첨가탤로우)암모늄클로라이드 10내지 90중량% 및 디메틸디(수소첨가탤로우)암모늄 클로라이드 10내지 90중량%의 혼합물과 벤토나이트 점토의 반응 생성물인 조성물.
  10. 제1항에 있어서, 테레프탈산과 이소프탈산 또는 그의 에스테르의 혼합물과 1,4-부탄디올로 부터 유도되는 고융점 블록과 수평균 분자량이 약 800내지 1200인 폴리(테트라메틸렌옥사이드)글리콜로부터 유도되는 저융점 블록으로 본질적으로 구성되며, 고융점 블록 대 저융점 블록의 중량비율이 1:0.8내지 1:1.1인 멀티-블록 코폴리에스테르 탄성중합체; 전술한 멀티-블록 코폴리에스테르 탄성 중합체 100부당 브롬-함유방염제인 N,N'-에틸렌비스(테트라 브로모프탈이미드) 약 20내지 35부; 전술한 브롬-함유방염제 13부당 3산화안티몬 약 0.3 0.6부; 및 전술한 멀티-블록 코폴리에스테르 탄성중합체 100부당 디메틸벤질(수소첨가 탤로우)암모늄클로라이드 10내지 90중량%와 디메틸디(수소첨가 탤로우)암모늄 놀로라이드 10내지 90중량%의 혼합물과 벤토나이트 점토의 반응 생성물인 친유기 점토 약 3내지 7부로 구성되는 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019850002882A 1984-04-30 1985-04-29 코폴리에스테르 탄성중합체 방염제 조성물 KR850007452A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US06/605,550 US4582866A (en) 1984-04-30 1984-04-30 Flame retardant thermoplastic multi-block copolyester elastomers
US605,550 1984-04-30

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KR850007452A true KR850007452A (ko) 1985-12-04

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US (1) US4582866A (ko)
EP (1) EP0163427B1 (ko)
JP (1) JPS60235858A (ko)
KR (1) KR850007452A (ko)
AU (1) AU4173685A (ko)
BR (1) BR8501998A (ko)
CA (1) CA1225182A (ko)
DE (1) DE3565272D1 (ko)
ES (1) ES8609413A1 (ko)

Families Citing this family (43)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4639486A (en) * 1985-10-08 1987-01-27 General Electric Company Flame retardant elastomeric compositions
US4708975A (en) * 1986-04-02 1987-11-24 E. I. Du Pont De Nemours And Company Low smoke generating, high char forming, flame retardant thermoplastic multi-block copolyesters
US4826899A (en) * 1987-06-15 1989-05-02 E. I. Du Pont De Nemours And Company Low smoke generating, high char forming, flame resistant thermoplastic multi-block copolyesters
US4908260A (en) * 1988-09-07 1990-03-13 E. I. Du Pont De Nemours And Company Flame-retardant, vapor-permeable waterproof structure
JPH02112178A (ja) * 1988-10-20 1990-04-24 Sumitomo Wiring Syst Ltd コネクター
DE19642491A1 (de) * 1996-10-15 1998-04-16 Basf Ag Flammwidrige thermoplastische Formmassen auf Basis von Polyphenylenethern und vinylaromatischen Polymeren
EP0950076A4 (en) * 1997-01-03 2000-09-13 Lawrence A Acquarulo FLAME RETARDANT NYLON ELASTOMERS
US5773502A (en) * 1997-10-14 1998-06-30 General Electric Company Fire retardant blends
GB9807180D0 (en) 1998-04-04 1998-06-03 Ecc Int Ltd Pigment products
US6541557B1 (en) 1999-03-23 2003-04-01 Kabushiki Kaisha Toyota Chuo Kenkyusho Resin composite material
DE10084441T1 (de) 1999-04-01 2002-03-21 Imerys Pigments Inc Koalinton-Pigmente, ihre Herstellung und Verwendung
DE10084442T1 (de) 1999-04-01 2002-05-02 Imerys Pigments Inc Kaolin-Pigmente, ihre Herstellung und Verwendung
US6350804B2 (en) 1999-04-14 2002-02-26 General Electric Co. Compositions with enhanced ductility
PT1177252E (pt) 1999-04-30 2005-08-31 Sued Chemie Ag Composicoes retardadoras das chamas
US6554892B1 (en) 1999-07-02 2003-04-29 Imerys Kaolin, Inc. Compositions and methods for making a coarse platey, high brightness kaolin product
US6610770B1 (en) * 1999-10-04 2003-08-26 Elementis Specialties, Inc. Organoclay/polymer compositions with flame retardant properties
US6579926B2 (en) * 1999-11-15 2003-06-17 General Electric Company Fire retardant polyphenylene ether-organoclay composition and method of making same
US6414070B1 (en) 2000-03-08 2002-07-02 Omnova Solutions Inc. Flame resistant polyolefin compositions containing organically modified clay
FR2809499B1 (fr) 2000-05-29 2003-10-03 Cit Alcatel Peau de protection pour fibres optiques
GB0020182D0 (en) 2000-08-17 2000-10-04 Imerys Minerals Ltd Particulate kaolin
GB0020180D0 (en) 2000-08-17 2000-10-04 Imerys Minerals Ltd Kaolin products and their production
GB0020179D0 (en) * 2000-08-17 2000-10-04 Imerys Minerals Ltd Kaolin products and their use
US20030085012A1 (en) * 2001-09-07 2003-05-08 Jones J Philip E Hyperplaty clays and their use in paper coating and filling, methods for making same, and paper products having improved brightness
US6808559B2 (en) 2002-02-26 2004-10-26 Imerys Pigments, Inc. Kaolin clay pigments suited to rotogravure printing applications and method for preparing the same
JP2005521767A (ja) * 2002-03-28 2005-07-21 イメリーズ ミネラルズ リミテッド 粒状粘土鉱物を含む難燃性ポリマー組成物
US20040074847A1 (en) * 2002-10-16 2004-04-22 Jaquess Percy A. Stable N-bromo-2-pyrrolidone and methods to make the same
DK1581588T3 (da) * 2003-01-08 2007-04-02 Sued Chemie Ag Sammensætning på basis af præeksfolierede nanoclays og anvendelse heraf
PL1560879T3 (pl) 2003-06-12 2006-08-31 Sued Chemie Ag Sposób wytwarzania dodatku nanokompozytowego o polepszonym rozwarstwieniu w polimerach
GB0315409D0 (en) * 2003-07-01 2003-08-06 Imerys Minerals Ltd Particulate clay materials and polymer compositions incorporating the same
US7148282B2 (en) * 2003-12-19 2006-12-12 Cornell Research Foundations, Inc. Composite of high melting polymer and nanoclay with enhanced properties
DE102004039451A1 (de) * 2004-08-13 2006-03-02 Süd-Chemie AG Polymerblend aus nicht verträglichen Polymeren
CN101072837A (zh) * 2004-10-06 2007-11-14 英默里斯高岭土公司 用在硅橡胶基配方中的有机中和的煅烧高岭土
KR101108242B1 (ko) 2005-02-15 2012-01-31 에스케이케미칼주식회사 난연성 폴리에스테르 엘라스토머 조성물
US20060202177A1 (en) * 2005-03-11 2006-09-14 Taiwan Textile Research Institute Flame retardant composition
US7888419B2 (en) * 2005-09-02 2011-02-15 Naturalnano, Inc. Polymeric composite including nanoparticle filler
US8124678B2 (en) * 2006-11-27 2012-02-28 Naturalnano, Inc. Nanocomposite master batch composition and method of manufacture
US8648132B2 (en) * 2007-02-07 2014-02-11 Naturalnano, Inc. Nanocomposite method of manufacture
US20090326133A1 (en) * 2007-05-23 2009-12-31 Naturalnano Research, Inc. Fire and flame retardant polymer composites
TWI379860B (en) 2008-06-24 2012-12-21 Univ Chung Yuan Christian Modified clay and clay-polymer composite
WO2010039616A2 (en) * 2008-09-30 2010-04-08 Polyone Corporation Flame retardant thermoplastic elastomers
JP5854095B1 (ja) * 2014-07-25 2016-02-09 横浜ゴム株式会社 耐熱コンベヤベルト用ゴム組成物および耐熱コンベヤベルト
WO2019140165A1 (en) * 2018-01-11 2019-07-18 Celanese International Corporation Copolyester polymer composition with enhanced elastic properties
US20210277160A1 (en) * 2020-01-08 2021-09-09 Northrop Grumman Systems Corporation Precursor compositions for an insulation, insulated rocket motors, and related methods

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2531396A (en) * 1947-03-29 1950-11-28 Nat Lead Co Elastomer reinforced with a modified clay
US3023192A (en) * 1958-05-29 1962-02-27 Du Pont Segmented copolyetherester elastomers
GB1114174A (en) * 1964-12-18 1968-05-15 Berk Ltd Synthetic thermoplastic polymer composition
US4374220A (en) * 1968-09-18 1983-02-15 Raychem Corporation Imide flame retardants and compositions containing them
US3624024A (en) * 1970-02-24 1971-11-30 Eastman Kodak Co Flame retardant poly(tetramethylene terephthalate) molding compositions
US3833535A (en) * 1971-08-30 1974-09-03 Gen Electric Non-dripping flame retardant glass reinforced polyester resins
JPS5645942B2 (ko) * 1973-01-18 1981-10-29
US4031165A (en) * 1974-09-30 1977-06-21 Teijin Limited Process for preparing polyester elastomers
FR2322900A1 (fr) * 1975-09-04 1977-04-01 Rhone Poulenc Ind Compositions ignifugees de polyesters
GB1592271A (en) * 1977-03-23 1981-07-01 Exxon Research Engineering Co Overtreated higher dialkyl dimethyl ammonium clay gellants and their use in greases
US4216135A (en) * 1978-03-27 1980-08-05 Nl Industries, Inc. Organophilic clays and thixotropic polyester compositions containing the same
US4467057A (en) * 1978-12-06 1984-08-21 General Electric Company Modified polyester composition
GB2042560A (en) * 1979-01-12 1980-09-24 Gen Electric Non-blooming flame retardant thermoplastic compositions
EP0029930B1 (de) * 1979-11-19 1984-02-15 Bayer Ag Verwendung von Formmassen aus Polyethylenterephthalat und einem organischen Imid zur Herstellung von kristallinen Formkörpern durch Spritzguss bei niedriger Formtemperatur
DE3362141D1 (en) * 1982-03-16 1986-03-27 Ciba Geigy Ag Flame-resistant reinforced thermoplastic polyester moulding compounds, and their use
US4521557A (en) * 1983-06-23 1985-06-04 E. I. Du Pont De Nemours And Company Flame retardant copolyetheresters
CA1225653A (en) * 1983-07-07 1987-08-18 Thomas D. Thompson, Iii Organoclay-antiozonant complex

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JPH0133500B2 (ko) 1989-07-13
ES542686A0 (es) 1986-07-16
EP0163427B1 (en) 1988-09-28
AU4173685A (en) 1985-11-07
BR8501998A (pt) 1985-12-31
US4582866A (en) 1986-04-15
JPS60235858A (ja) 1985-11-22
ES8609413A1 (es) 1986-07-16
DE3565272D1 (en) 1988-11-03
CA1225182A (en) 1987-08-04
EP0163427A1 (en) 1985-12-04

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