KR850006151A - 가스로부터의 황화수소 제거방법 및 그 방법의 사용에 적합한 흡수제 - Google Patents

가스로부터의 황화수소 제거방법 및 그 방법의 사용에 적합한 흡수제 Download PDF

Info

Publication number
KR850006151A
KR850006151A KR1019850001958A KR850001958A KR850006151A KR 850006151 A KR850006151 A KR 850006151A KR 1019850001958 A KR1019850001958 A KR 1019850001958A KR 850001958 A KR850001958 A KR 850001958A KR 850006151 A KR850006151 A KR 850006151A
Authority
KR
South Korea
Prior art keywords
zeolite
absorbent
pore size
hydrogen sulfide
particles
Prior art date
Application number
KR1019850001958A
Other languages
English (en)
Inventor
진 피에르 코넬리스 니이스켄스(외 1) 마아틴
Original Assignee
오노 알버어스
셀 인터나쵸나아래 레사아치 마아츠샤피 비이부이
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 오노 알버어스, 셀 인터나쵸나아래 레사아치 마아츠샤피 비이부이 filed Critical 오노 알버어스
Publication of KR850006151A publication Critical patent/KR850006151A/ko

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B01J20/18—Synthetic zeolitic molecular sieves
    • B01J20/183—Physical conditioning without chemical treatment, e.g. drying, granulating, coating, irradiation
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S502/00—Catalyst, solid sorbent, or support therefor: product or process of making
    • Y10S502/515—Specific contaminant removal
    • Y10S502/517—Sulfur or sulfur compound removal

Landscapes

  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Treating Waste Gases (AREA)
  • Gas Separation By Absorption (AREA)
  • Industrial Gases (AREA)
  • Separation By Low-Temperature Treatments (AREA)

Abstract

내용 없음

Description

가스로부터의 황화수소 제거방법 및 그 방법의 사용에 적합한 흡수제
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (18)

  1. 아연산화물 및 기공 크기가 0.40nm 이상인 제올라이트의 충분한 혼합물로 조성되는 고상의 흡수제에 황화수소-함유가스를 300℃ 이상의 온도에서 접촉시키고, 폐흡수제상에 산소-함유가스를 400℃ 이상의 온도에서 통과시킴으로서 폐흡수제를 재생시킴을 특징으로 하는 가스로부터의 황학수소 제거방법.
  2. 제1항에 있어서, 제올라이트의 기공 크기가 0.5nm이상임을 특징로 하는 방법.
  3. 제2항에 있어서, 제올라이트의 기공 크기가 0.5 내지 1.3nm임을 특징으로 하는 방법.
  4. 제1항 내지 제3항중 어느 하나의 항에 있어서, 제올라이트가 제올라이트 A의 칼슘형임을 특징으로 하는 방법.
  5. 제1항 내지 제3항중 어느 하나의 항에 있어서, 제올라이트 쪼우저사이트(faujasite)임을 특징으로 하는 방법.
  6. 제1항 내지 제5항중 어느 하나의 항에 있어서, 황화수소-함유가스를 500℃ 내지 550℃의 온도에서 흡수제상에 통과시킴을 특징으로 하는 방법.
  7. 제1항 내지 제6항중 어느 하나의 항에 있어서, 흡수제를 500℃ 이상의 온도에서 재생시킴을 특징으로 하는 방법.
  8. 제1항 내지 제7항중 어느 하나의 항에 있어서, 소량의 산소를 폐흡수제의 재샹용 가스기류중에 사용함을 특징으로 하는 방법.
  9. 제1항 내지 제7항중 어느 하나의 항에 있어서, 사용 폐수제 중에 구리, 카드뮴, 티탄, 지르코늄, 바나듐, 크롬, 몰리브덴,텅스텐, 망간, 철, 코발트 및 닉켈로 구성되는 군중에서 선택되는 1종 이상의 금속의 산화물을 추가로 함유시킴을 특징으로 하는 방법.
  10. 제1항 내지 제9항중 어느 하나의 항에 있어서, 흡수제가 아연산화물 및 기공크기가 0.40nm 이상인 제올라이트의 충분한 혼합물로 조성됨을 특징으로 하는 방법의 사용에 적합한 흡수제.
  11. 제10항에 있어서, 제올라이트의 기공 크기가 0.5nm 이상임을 특징으로 하는 방법.
  12. 제11항에 있어서, 제올라이트의 기공크기가 0.5 내지 1.3nm 이상임을 특징으로 하는 흡수제.
  13. 제1항 내지 제12항중 어느 하나의 항에 있어서, 제올라이트가 제올라이트 A의 칼슘형임을 특징으로 흡수제.
  14. 제10항 내지 제12항중 어느 하나의 항에 있어서, 제올라이트가 포우저사이트임을 특징으로 하는 흡수제.
  15. 제10항 내지 제14항 중 어느 하나의 항에 있어서, 아연수산화물 입자들 및 제올라이트 입자들을 충분히 혼합하고, 혼합된 아연수산화물 및 제올라이트의 혼합물을 아연수산화물 및 제올라이트가 실질적으로 완전 균일하게 혼합된 입자들로 펠릿화한 다음, 생성된 펠릿들은 하소를 행하여 황화수소 흡수력이 있는 활성형태의 입자들을 생성시킴으로써 제조함을 특징으로 하는 흡수제.
  16. 제10항 내지 제15항중 어느 하나의 항에 있어서, 흡수제 중에 구리, 카드뮴, 티탄 지르코늄,바나듐, 크롬, 몰리브덴, 텅스텐, 망간, 철, 코발트 및 닉켈로 구성되는 군중에서 선택되는 1종 이상의 금속 산화물을 추가로 함유시킴을 특징으로 하는 흡수제.
  17. 실시예들에 기재된 바와 같이 청구범위 제1항의 방법에 따라 가스로부터의 황화수소 제거방법.
  18. 실시예들에 기재된 바와 같이 가스로부터의 황화수소 제거방법의 사용에 적합한 흡수제.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019850001958A 1984-03-27 1985-03-25 가스로부터의 황화수소 제거방법 및 그 방법의 사용에 적합한 흡수제 KR850006151A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB8407842 1984-03-27
GB848407842A GB8407842D0 (en) 1984-03-27 1984-03-27 Removing hydrogen sulphide from gases

Publications (1)

Publication Number Publication Date
KR850006151A true KR850006151A (ko) 1985-10-02

Family

ID=10558713

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019850001958A KR850006151A (ko) 1984-03-27 1985-03-25 가스로부터의 황화수소 제거방법 및 그 방법의 사용에 적합한 흡수제

Country Status (15)

Country Link
US (1) US4673557A (ko)
EP (1) EP0159056B1 (ko)
JP (1) JPS60232234A (ko)
KR (1) KR850006151A (ko)
AT (1) ATE45513T1 (ko)
AU (1) AU570101B2 (ko)
BR (1) BR8501341A (ko)
CA (1) CA1230107A (ko)
DE (1) DE3572310D1 (ko)
DK (1) DK165280C (ko)
ES (1) ES8608328A1 (ko)
GB (1) GB8407842D0 (ko)
NO (1) NO163558C (ko)
NZ (1) NZ211554A (ko)
ZA (1) ZA852219B (ko)

Families Citing this family (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB8517333D0 (en) * 1985-07-09 1985-08-14 Ici Plc Purification of hydrocarbon mixture
US4732888A (en) * 1986-05-15 1988-03-22 Amax Inc. Durable zinc ferrite sorbent pellets for hot coal gas desulfurization
GB8630846D0 (en) * 1986-12-24 1987-02-04 Ici Plc Desulphurisation
US4830733A (en) * 1987-10-05 1989-05-16 Uop Integrated process for the removal of sulfur compounds from fluid streams
US5114689A (en) * 1987-10-05 1992-05-19 Uop Integrated process for the removal of sulfur compounds from fluid streams
US4830734A (en) * 1987-10-05 1989-05-16 Uop Integrated process for the removal of sulfur compounds from fluid streams
US5252528A (en) * 1987-11-19 1993-10-12 California Institute Of Technology Hot gas, regenerative, supported H2 S sorbents
JPH01203040A (ja) * 1988-02-05 1989-08-15 Teikoku Kako Co Ltd 吸着剤およびその製造方法
JPH01297142A (ja) * 1988-05-24 1989-11-30 Teika Corp 酸性および塩基性ガスに対する両用吸着剤およびその樹脂成型体
DE3825169A1 (de) * 1988-07-23 1990-02-01 Huels Chemische Werke Ag Verfahren zur feinentschwefelung von kohlenwasserstoffen
US4990318A (en) * 1989-06-07 1991-02-05 Phillips Petroleum Company Selective removal of hydrogen sulfide over a nickel-promoted absorbing composition
US5057473A (en) * 1990-04-12 1991-10-15 The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration Regenerative Cu La zeolite supported desulfurizing sorbents
US5178843A (en) * 1991-03-08 1993-01-12 Phillips Petroleum Company Removal of hydrogen sulfide from fluid streams
US5227351A (en) * 1991-03-13 1993-07-13 The United States Of America As Represented By The United States Department Of Energy Sorbent for use in hot gas desulfurization
ZA93401B (en) * 1992-01-27 1993-08-24 Phillips Petroleum Co Composition useful as sulfur absorption for fluid streams.
US5512260A (en) * 1994-03-04 1996-04-30 Mobil Oil Corporation Reduction of sulfur content in a gaseous stream
WO1996022160A1 (en) * 1995-01-17 1996-07-25 E.I. Du Pont De Nemours And Company Sulfide scavenging packaging materials
AU5975496A (en) * 1995-06-07 1996-12-30 E.I. Du Pont De Nemours And Company Sulfide scavenging packaging materials
US6579347B1 (en) * 1998-04-28 2003-06-17 Matsushita Electric Industrial Co., Ltd. Method for removing sulfur compound present in city gas
US6274533B1 (en) * 1999-12-14 2001-08-14 Phillips Petroleum Company Desulfurization process and novel bimetallic sorbent systems for same
US7427581B2 (en) * 1999-12-14 2008-09-23 China Petroleum & Chemical Corporation Desulfurization process and novel bimetallic sorbent systems for same
US6544410B1 (en) 2001-12-19 2003-04-08 Phillips Petroleum Company Desulfurization with improved sorbent regeneration
US6649555B2 (en) 2001-12-19 2003-11-18 Conocophillips Company Reactivation of deactivated sorbents
US6635795B2 (en) 2001-12-19 2003-10-21 Conocophillips Company Desulfurization with improved sorbent regeneration
JP4776985B2 (ja) * 2005-06-01 2011-09-21 石油コンビナート高度統合運営技術研究組合 低硫黄軽質炭化水素油の製造方法
US7959720B2 (en) * 2007-05-18 2011-06-14 Exxonmobil Research And Engineering Company Low mesopore adsorbent contactors for use in swing adsorption processes
US8529663B2 (en) 2007-05-18 2013-09-10 Exxonmobil Research And Engineering Company Process for removing a target gas from a mixture of gases by swing adsorption
US8444750B2 (en) * 2007-05-18 2013-05-21 Exxonmobil Research And Engineering Company Removal of CO2, N2, or H2S from gas mixtures by swing adsorption with low mesoporosity adsorbent contactors
JP6163719B2 (ja) * 2012-08-31 2017-07-19 三菱ケミカル株式会社 硫化水素の分離方法
US10384197B2 (en) 2016-07-26 2019-08-20 Saudi Arabian Oil Company Additives for gas phase oxidative desulfurization catalysts
JP2019171234A (ja) * 2018-03-27 2019-10-10 東ソー株式会社 硫化水素分離用ゼオライト膜の再生方法

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3078640A (en) * 1959-12-18 1963-02-26 Union Carbide Corp Separation of sulfur compounds from vapor mixtures
FR85066E (fr) * 1964-01-07 1965-06-04 Aquitaine Petrole Procédé de récupération de composés sulfurés gazeux contenus en faibles concentrations dans les gaz résiduaires et fumées
DE2424818A1 (de) * 1974-05-22 1975-12-04 Basf Ag Verfahren zur herstellung von zinkoxid enthaltenden entschwefelungsmassen
FR2295782A1 (fr) * 1974-12-27 1976-07-23 Inst Francais Du Petrole Procede d'epuration d'un gaz contenant du sulfure d'hydrogene et masses de contact utilisables a cet effet
BE873505A (fr) * 1979-01-16 1979-05-16 Catalysts & Chem Europ Procede d'absorption de composes sulfures et masse absorbante mise en oeuvre dans ce procede
US4358297A (en) * 1980-01-02 1982-11-09 Exxon Research And Engineering Company Removal of sulfur from process streams
US4371507A (en) * 1980-09-23 1983-02-01 Phillips Petroleum Company Catalytic hydrogenation of olefins, hydrodesulfurization of organic sulfur compounds and/or selective removal of hydrogen sulfide from fluid streams
US4363790A (en) * 1981-08-14 1982-12-14 Institute Of Gas Technology Desulfurization of H2 S containing gas streams with production of elemental sulfur
US4455286A (en) * 1982-07-07 1984-06-19 The United States Of America As Represented By The United States Department Of Energy High-temperature sorbent method for removal of sulfur containing gases from gaseous mixtures

Also Published As

Publication number Publication date
CA1230107A (en) 1987-12-08
DK132885D0 (da) 1985-03-25
EP0159056A3 (en) 1986-04-02
EP0159056B1 (en) 1989-08-16
NO851187L (no) 1985-09-30
GB8407842D0 (en) 1984-05-02
AU570101B2 (en) 1988-03-03
DK132885A (da) 1985-09-28
NZ211554A (en) 1987-07-31
EP0159056A2 (en) 1985-10-23
US4673557A (en) 1987-06-16
ATE45513T1 (de) 1989-09-15
ZA852219B (en) 1985-11-27
DE3572310D1 (en) 1989-09-21
ES8608328A1 (es) 1986-06-16
DK165280C (da) 1993-03-22
ES541546A0 (es) 1986-06-16
AU4032585A (en) 1985-10-03
NO163558C (no) 1990-06-20
BR8501341A (pt) 1985-11-19
DK165280B (da) 1992-11-02
NO163558B (no) 1990-03-12
JPS60232234A (ja) 1985-11-18

Similar Documents

Publication Publication Date Title
KR850006151A (ko) 가스로부터의 황화수소 제거방법 및 그 방법의 사용에 적합한 흡수제
Swisher et al. Review of metals and binary oxides as sorbents for removing sulfur from coal-derived gases
ATE162102T1 (de) Verfahren zur hochselektiven katalytischen direktoxidation von in niedriger konzentrationen in einem gas vorhandenem h2s
JPS6014928A (ja) 汚染空気の浄化方法
KR850006152A (ko) 배기가스로 부터 황 화합물의 제거방법
KR850001200B1 (ko) 배연탈황법
JPH03186317A (ja) ガス中の硫黄化合物の除去方法および該方法に用いられる脱硫剤
WO2010048201A2 (en) Sulfur removal from gases
SE8307237L (sv) Avsvavling av reducerande gas under anvendning av ett atercirkulerande kalciumoxidsystem
JPH02107313A (ja) 硫黄化合物の除去方法および該方法に用いられる脱硫剤
JPS5395872A (en) Treating method for tail gas
JPS61245819A (ja) 高温還元性ガスの精製法
JP2000515807A (ja) 触媒組成物、その調製、及び接触灰化におけるその使用
JP2575771B2 (ja) 高温ガスの乾湿式脱硫方法
GB2152489A (en) Method for purifying gases from sulphurous compounds
JPS61185334A (ja) 脱硫剤
JPH07118668A (ja) 硫黄含有ガス中の硫黄化合物の除去方法
Munidasa et al. Technical Means to Reduce Air Pollution
JPS60166033A (ja) 脱硫剤
JPS59139934A (ja) 乾式脱硫剤
Stiles Catalytic process for removing SO/sub 2/from sulfuric acid plant off gases
Klein et al. Process for H/sub 2/S removal employing a regenerable polyalkanolamine adsorbent.[6 claims; Claus process]
JPS59139933A (ja) 乾式脱硫剤
JPS59166241A (ja) 脱硫剤
JPS60102935A (ja) 脱硫剤

Legal Events

Date Code Title Description
A201 Request for examination