KR850005404A - α-시아노-3-펜옥시-4-플루오로벤질 퍼메트레이트의 특정 에난티오머쌍의 제조방법 - Google Patents

α-시아노-3-펜옥시-4-플루오로벤질 퍼메트레이트의 특정 에난티오머쌍의 제조방법 Download PDF

Info

Publication number
KR850005404A
KR850005404A KR1019850000239A KR850000239A KR850005404A KR 850005404 A KR850005404 A KR 850005404A KR 1019850000239 A KR1019850000239 A KR 1019850000239A KR 850000239 A KR850000239 A KR 850000239A KR 850005404 A KR850005404 A KR 850005404A
Authority
KR
South Korea
Prior art keywords
alpha
phenoxy
cyano
fluorobenzyl
mixture
Prior art date
Application number
KR1019850000239A
Other languages
English (en)
Other versions
KR930004358B1 (ko
Inventor
푸흐스(외 1) 라이너
Original Assignee
요아힘 그렘, 귄터 슈마허
바이엘 아크티엔 게젤샤프트
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 요아힘 그렘, 귄터 슈마허, 바이엘 아크티엔 게젤샤프트 filed Critical 요아힘 그렘, 귄터 슈마허
Publication of KR850005404A publication Critical patent/KR850005404A/ko
Application granted granted Critical
Publication of KR930004358B1 publication Critical patent/KR930004358B1/ko

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00—Carboxylic acid nitriles
    • C07C255/01—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms
    • C07C255/32—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms having cyano groups bound to acyclic carbon atoms of a carbon skeleton containing at least one six-membered aromatic ring
    • C07C255/34—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms having cyano groups bound to acyclic carbon atoms of a carbon skeleton containing at least one six-membered aromatic ring with cyano groups linked to the six-membered aromatic ring, or to the condensed ring system containing that ring, by unsaturated carbon chains
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/32—Separation; Purification; Stabilisation; Use of additives
    • C07C253/34—Separation; Purification
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00—Carboxylic acid nitriles
    • C07C255/49—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C255/53—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing cyano groups and hydroxy groups bound to the carbon skeleton

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Steroid Compounds (AREA)

Abstract

내용 없음

Description

α-시아노-3-펜옥시-4-플루오로벤질 퍼메트레이트의 특정 에난티오머쌍의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (3)

  1. 화합물 αR/S-시아노-3-펜옥시-4-플루오로벤질 3R/S-(2,2-디클로로비닐)-2,2-디메틸-클로로프로판-카복실레이트, 모두 8개의 입체이성체의 혼합물을, 각알킬부위에, 2 내지 6개의 탄소위자를 함유하는 2급 또는 3급 알킬 아민중에 용해시킨 다음, 이 용액으로 부터 거울상 이성체쌍(1R-3R-αS+1S-3S-αR) 및 (1R-3R-αS+ 1S-3R-αR)을 결정화시키고 분리시킴을 특징으로 하여, 화합물 αR/S-시아노-3-펜옥시-4-플루오로벤질 3R/S-(2,2-디클로로비닐)-2,2-디메틸-1R/S-클로로프로판-카복실레이트의, 모두 8개의 입체이성체의 혼합물로 부터 에난티오머쌍 (1R-3R-αS+1S-3S-αR) 및 (1R-3R-αS+1S-3S-αR)을 제조하는 방법.
  2. 제1항에 있어서, 아민으로서 알킬부위당 3 내지 4개의 탄소원자를 함유하는 2급 또는 3급 아민을 사용함을 특징으로 하는 방법.
  3. 제1항에 있어서, 아민으로서, 디-이소-부틸아민 및/또는 트리-n-분틸아민을 사용함을 특징으로 하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019850000239A 1984-01-18 1985-01-16 α-시아노-3-펜옥시-4-플루오로벤질 퍼메트레이트의 특정 에난티오머쌍의 제조방법 KR930004358B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE19843401483 DE3401483A1 (de) 1984-01-18 1984-01-18 Verfahren zur herstellung bestimmter enantiomerenpaare von permethrinsaeure-(alpha)-cyano-3-phenoxy-4-fluor-benzyl-ester
DE3401483.7 1984-01-18
DEP3401483.7 1984-01-18

Publications (2)

Publication Number Publication Date
KR850005404A true KR850005404A (ko) 1985-08-26
KR930004358B1 KR930004358B1 (ko) 1993-05-26

Family

ID=6225185

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019850000239A KR930004358B1 (ko) 1984-01-18 1985-01-16 α-시아노-3-펜옥시-4-플루오로벤질 퍼메트레이트의 특정 에난티오머쌍의 제조방법

Country Status (22)

Country Link
US (1) US4544508A (ko)
EP (1) EP0150006B1 (ko)
JP (1) JPH0788345B2 (ko)
KR (1) KR930004358B1 (ko)
AT (1) ATE22070T1 (ko)
AU (1) AU565238B2 (ko)
BR (1) BR8500212A (ko)
CA (1) CA1249841A (ko)
CS (1) CS253716B2 (ko)
DD (1) DD232037A5 (ko)
DE (2) DE3401483A1 (ko)
DK (1) DK173881B1 (ko)
ES (1) ES8603385A1 (ko)
GR (1) GR850124B (ko)
HU (1) HU193919B (ko)
IL (1) IL74053A (ko)
MA (1) MA20327A1 (ko)
NZ (1) NZ210853A (ko)
PH (1) PH20448A (ko)
TR (1) TR22462A (ko)
ZA (1) ZA85382B (ko)
ZW (1) ZW22384A1 (ko)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB8422872D0 (en) * 1984-09-11 1984-10-17 Ici Plc Insecticidal product
CA1275108A (en) * 1985-01-16 1990-10-09 Laszlo Pap Insecticidal composition comprising more than one active ingredients
DE3522629A1 (de) * 1985-06-25 1987-01-08 Bayer Ag Verfahren zur herstellung bestimmter enantiomerenpaare von permethrinsaeure-(alpha)-cyano-3-phenoxy-4-fluor-benzyl -ester
GB2187385A (en) * 1986-03-07 1987-09-09 Shell Int Research Method of combatting colorado beetles using chemical compounds and compositions containing the chemical compounds
US4717050A (en) * 1986-05-19 1988-01-05 Sunbeam Plastics Corporation Multiple orifice dispensing closure
US4997970A (en) * 1987-06-15 1991-03-05 Fmc Corporation Conversion of pyrethroid isomers to move active species
US5128497A (en) * 1990-01-03 1992-07-07 Fmc Corporation Conversion of pyrethroid isomers to more active species
GB9127355D0 (en) * 1991-12-24 1992-02-19 Ici Plc Isomerisation process

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2375161A1 (fr) * 1976-04-23 1978-07-21 Roussel Uclaf Procede de transformation d'un ester d'acide chiral d'alcool secondaire a-cyane optiquement actif de structure (r) en ester d'acide chiral d'alcool secondaire a-cyane de structure (s)
FR2348901A1 (fr) * 1976-04-23 1977-11-18 Roussel Uclaf Procede de transformation d'un ester d'acide chiral d'alcool secondaire alpha-cyane optiquement actif en ester d'acide chiral d'alcool secondaire alpha-cyane racemique
DE2709264C3 (de) * 1977-03-03 1982-01-21 Bayer Ag, 5090 Leverkusen Substituierte Phenoxybenzyloxycarbonylderivate, Verfahren zu ihrer Herstellung und ihre Verwendung als Insektizide und Akarizide sowie neue Zwischenprodukte
US4308279A (en) * 1979-06-06 1981-12-29 Fmc Corporation Crystalline, insecticidal pyrethroid
DE2938112A1 (de) * 1979-09-20 1981-04-16 Bayer Ag, 5090 Leverkusen Verfahren zur herstellung von (alpha) -cyano-phenoxy-benzyl-estern
CA1150730A (en) * 1980-04-23 1983-07-26 Michael J. Bull Process for preparing cyclopropane carboxylic acid ester derivatives
CA1162560A (en) * 1980-04-23 1984-02-21 Ronald F. Mason Process for preparing cyclopropane carboxylic acid ester derivatives

Also Published As

Publication number Publication date
TR22462A (tr) 1987-07-17
NZ210853A (en) 1987-05-29
KR930004358B1 (ko) 1993-05-26
DK22885A (da) 1985-07-19
CS33385A2 (en) 1987-05-14
ES539647A0 (es) 1985-12-16
IL74053A (en) 1988-03-31
BR8500212A (pt) 1985-08-27
PH20448A (en) 1987-01-09
CA1249841A (en) 1989-02-07
JPS60161958A (ja) 1985-08-23
DE3401483A1 (de) 1985-07-25
DD232037A5 (de) 1986-01-15
DE3560001D1 (en) 1986-10-16
EP0150006B1 (de) 1986-09-10
MA20327A1 (fr) 1985-10-01
AU3776585A (en) 1985-07-25
AU565238B2 (en) 1987-09-10
US4544508A (en) 1985-10-01
IL74053A0 (en) 1985-04-30
ZW22384A1 (en) 1985-09-25
CS253716B2 (en) 1987-12-17
JPH0788345B2 (ja) 1995-09-27
ZA85382B (en) 1985-09-25
HU193919B (en) 1987-12-28
EP0150006A1 (de) 1985-07-31
DK173881B1 (da) 2002-01-28
GR850124B (ko) 1985-05-08
DK22885D0 (da) 1985-01-17
ES8603385A1 (es) 1985-12-16
HUT39420A (en) 1986-09-29
ATE22070T1 (de) 1986-09-15

Similar Documents

Publication Publication Date Title
KR870000287A (ko) α-시아노-3-펜옥시-4-플루오로벤질 퍼메트레이트의 특정 에난티오머쌍의 제조방법
KR890002030A (ko) 메데토 미딘의 d 및 1 에난티오머, 그 분리 방법 및 이를 포함하는 제약학적 조성물
BR8304343A (pt) Processo para recuperacao de pentitois anidros puros cristalinos, hexitois mono e/ou dianidros por cristalizacao de uma solucao e processo para recuperacao de no minimo dois alcoois de acucar anidro c5/6 cristalinos
DE3586017D1 (de) Stabiles glukose-isomerase-konzentrat und verfahren zu dessen herstellung.
KR850005404A (ko) α-시아노-3-펜옥시-4-플루오로벤질 퍼메트레이트의 특정 에난티오머쌍의 제조방법
ATE1997T1 (de) Verfahren zur gewinnung der enantiomeren formen von 4-cyan-1-(n-methyl-n-(2'-((3'',4''dimethoxyphenyl))-ethyl)-amino)-5-methyl-4(3',4',5'-trimethoxyphenyl)-hexan und dessen salzen.
DE3060670D1 (en) Process for the separation of the two optical isomers of 1-(o-methoxyphenoxy)-3-isopropylamino-propan-2-ol, optical isomers obtained thereby and pharmaceutical compositions of the levorotatory antipode thereof
TH2533A (th) ขบวนการผลิตอีแนนทีโอเมอร์เป็นคู่ๆ ที่เฉพาะเจาะจงของสาร อัลฟา-ไชยาโน-3-พีนอกซี-4-ฟลูออโร-เบนซลเพอร์มีเธรท
TH2533EX (th) ขบวนการผลิตอีแนนทีโอเมอร์เป็นคู่ๆ ที่เฉพาะเจาะจงของสาร อัลฟา-ไชยาโน-3-พีนอกซี-4-ฟลูออโร-เบนซลเพอร์มีเธรท
ATE61346T1 (de) Synthese von 3s, 4s-boc-statin.
ES2003994A6 (es) Procedimiento de preparacion de nuevas 2-cloro-12-(3-dimetilamino-2-metilpropil)-12h-dibenzo(d,g) (i,3,6) dioxazocinas opticamente activas y de sus sales de adicion acidas farmaceuticamente aceptables
TH4094B (th) กระบวนการเตรียมเอนแอทิโอเมอร์บางคู่ของแอลฟา-ไซยาโน-3-เฟนนอกซิ-4-ฟลูออโรเบนซิลเปอร์มีเธรท
DE69017145D1 (de) Verfahren zur Trennung von R und S-2, 2-R1,R2-1,3-Dioxolan-4-Carbonsäure.
UA19064A1 (uk) Спосіб одержаhhя суміші ізомерів сиhтетичhих піретроїдів
TH3796A (th) กระบวนการเตรียมเอนแอทิโอเมอร์บางคู่ของแอลฟา-ไซยาโน-3-เฟนนอกซิ-4-ฟลูออโรเบนซิลเปอร์มีเธรท
JPS56122329A (en) Resolving method of dl-mandelic acid

Legal Events

Date Code Title Description
A201 Request for examination
G160 Decision to publish patent application
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
FPAY Annual fee payment

Payment date: 20030430

Year of fee payment: 11

LAPS Lapse due to unpaid annual fee