KR850004255A - 탄화수소류의 정제방법 - Google Patents
탄화수소류의 정제방법 Download PDFInfo
- Publication number
- KR850004255A KR850004255A KR1019840007659A KR840007659A KR850004255A KR 850004255 A KR850004255 A KR 850004255A KR 1019840007659 A KR1019840007659 A KR 1019840007659A KR 840007659 A KR840007659 A KR 840007659A KR 850004255 A KR850004255 A KR 850004255A
- Authority
- KR
- South Korea
- Prior art keywords
- contact material
- liquid
- hydrocarbon
- stream
- column
- Prior art date
Links
- 150000002430 hydrocarbons Chemical class 0.000 title claims 19
- 229930195733 hydrocarbon Natural products 0.000 title claims 18
- 238000000034 method Methods 0.000 title claims 17
- 239000000463 material Substances 0.000 claims 13
- 239000004215 Carbon black (E152) Substances 0.000 claims 10
- 239000007788 liquid Substances 0.000 claims 10
- 238000000926 separation method Methods 0.000 claims 7
- 239000003054 catalyst Substances 0.000 claims 6
- 230000003647 oxidation Effects 0.000 claims 5
- 238000007254 oxidation reaction Methods 0.000 claims 5
- -1 phthalocyanine compound Chemical class 0.000 claims 5
- 230000005526 G1 to G0 transition Effects 0.000 claims 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 3
- 239000003795 chemical substances by application Substances 0.000 claims 3
- 239000001301 oxygen Substances 0.000 claims 3
- 229910052760 oxygen Inorganic materials 0.000 claims 3
- 239000007787 solid Substances 0.000 claims 3
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 claims 2
- 238000009835 boiling Methods 0.000 claims 2
- 239000003610 charcoal Substances 0.000 claims 2
- 238000006243 chemical reaction Methods 0.000 claims 2
- 239000005745 Captan Substances 0.000 claims 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 claims 1
- 229940117949 captan Drugs 0.000 claims 1
- 125000004122 cyclic group Chemical group 0.000 claims 1
- 239000007789 gas Substances 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 239000011236 particulate material Substances 0.000 claims 1
- 239000002994 raw material Substances 0.000 claims 1
- 238000004064 recycling Methods 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G17/00—Refining of hydrocarbon oils in the absence of hydrogen, with acids, acid-forming compounds or acid-containing liquids, e.g. acid sludge
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
- C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
- C10G27/06—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen in the presence of alkaline solutions
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Seasonings (AREA)
- Medicines That Contain Protein Lipid Enzymes And Other Medicines (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Saccharide Compounds (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (16)
- 메르캅탄을 함유하는 액층탄화수소원료류와 산소공급류를 혼합하고 알카리제 및 용해성 산화촉매를 함유하는 액층 제1수성류와 혼합하여 반응대역 충진류를 형성하고 ; 수직배향탑내에 위치하고 있으며 탑상부진로부터 적어도 탑 최하부 1/4까지 하방으로 뻗어있는 고정상 접촉물질을 통해 산화촉진조건에서 반응대역 충진류를 하방으로 통과시키고 ; 수직다공벽을 통해 액체를 탑하부에 위치하여 접촉물질의 고정성 하부를 둘러싸고 있는 환형분리대역으로 회수하고, 다공벽위에 위치하고 비침투성 상측벽에 의해 접촉물질의 고정상과 분리된 하부 개방형 챔버로 올라오는 이황화물로 구성되는 탄화수소층과 탑저부로 침강되는 알카리제로 구성되는 수성층으로 액체를 옮기고; 처리된 탄화수소 생성류를 하부 개방형 챔버로부터 회수하고; 수성액의 제2류를 탑저부로 부터 회수하고 ;전술한 바와같은 적어도 일부 제2수성류를 제1수성류에 사용하는 단계로 구성됨을 특징으로 하는 탄화수소류의 정제방법.
- 제1항에 있어서,탄화수소원료류의 초기비점이 약 430 ℉이하임을 특징으로 하는 탄화수소류의 정제 방법.
- 제2항에 있어서, 산화촉매가 프탈로시아닌 화합물로 구성됨을 특징으로 하는 탄화수소류의 정제방법.
- 제3항에 있어서, 접촉물질의 고정상이 비교적 불활성인 고체미세물질의 상임을 특징으로 하는 탄화수소류의 정제방법.
- 제4항에 있어서, 환형분리대역이 고체미세물질을 함유하지 않음을 특징으로 하는 탄화수소류의 정제방법.
- 제5항에 있어서, 고체미립자 물질이 목탄으로 구성됨을 특징으로 하는 탄화수소류의 정제방법.
- 제6항에 있어서, 수성류의 유속의 15부피%이하임을 특징으로 하는 탄화수소류의 정제방법.
- 메르캅탄류를 구성하는 액층탄화수소원료류, 알카리제를 구성하는 액층 제1수성류, 산화촉진조건으로 유지되고 수직일련탑내에 위치한 고정상 접촉물질내에 존재하는 산화촉매의 산소공급류를 촉진시키는 것으로 상기 액체는 탑상부로부터 탑하부 1/3지점까지 접촉물질상을 통해 하향공류하고 ; 수성층과 덜 조밀한 탄화수소층으로 나누어지는 액체함유탑 저부의 1/3에 위치한 정지분리대역내로 접촉물질상의 저부를 에워싸는 다공성 수직스크린을 통해 적어도 액체의 탄화수소부를 수평으로 통과시키는 방법에 의해서 접촉물질상을 통해 하향통과한 액체를 분리하는 것으로 상기 덜 조밀한 탄화수소층은 분리대역 정부를 형성하는 하부 개방형 챔버에 포집되고 ; 이황화물을 구성하는 처리된 탄화수소 생성류를 분리대역으로부터 회수하고 ; 하부개방형 챔버아래의 탑의 소정지점에서 제2 수성류를 회수하고; 전술한 액층 제1수성류에 대해 언급한 용도를 위해 적어도 일부의 제2수성류를 탑내로 재순환시킴을 특징으로 하는 탄화수소류의 메르캅탄화합물 노도를 감소시키는 방법.
- 제8항에 있어서, 산화촉매가 수성류에 존재함을 특징으로 하는 탄화수소류의 메르캅탄화합물 농도를 감소시키는 방법.
- 제9항에 있어서, 촉매가 프탈로시아닌 화합물로 구성된 특징으로 하는 탄화수소류의 메르캅탄 화합물 농도를 감소시키는 방법.
- 제10항에 있어서, 촉매가 금속 프탈로시아닌 화합물로 구성됨을 특징으로 하는탄화수소류의 메르갑탄화합물 농도를 감소시키는 방법.
- 제11항에 있어서, 접촉물질의 고정상이 목탄으로 구성됨을 특징으로 하는 탄화수소류의 메르캅탄 화합물 농도를 감소시키는 방법.
- 제12항에 있어서, 분리대역은 환형이고, 탑내부면과 원통벽사이에 위치하고, 원통벽의 하부는 상기 다공스크린에 의해 형성되고, 원통벽의 상부는 비침투성임을 특징으로 하는 탄화수소류의 메르캅탄 화합물 농도를 감소시키는 방법.
- 제13항에 있어서, 원통벽내의 원통실이 접촉물질로 채워지고, 접촉물질의 고정상은 분리대역위의 상방으로 계속됨을 특징으로 한는 탄화수소류의 메르캅탄화합물 농도를 감소시키는 방법.
- 제14항에 있어서, 탄화수소원료류의 초기비점이 약 43°임을 특징으로 하는 탄화수소류의 메르캅탄화합물 농도를 감소시키는 방법.
- 제15항에 있어서, 산소공급류는 공기이고 탄화수소류의 잔류기체 용액 용량이하의 속도로 공정에 충전됨을 특징으로 하는 탄화수소류의 메르캅탄화합물 농도를 감소시키는방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/558,243 US4481106A (en) | 1983-12-05 | 1983-12-05 | Hydrocarbon treating process |
| US558,243 | 1983-12-05 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR850004255A true KR850004255A (ko) | 1985-07-11 |
| KR900000892B1 KR900000892B1 (ko) | 1990-02-17 |
Family
ID=24228751
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019840007659A KR900000892B1 (ko) | 1983-12-05 | 1984-12-05 | 탄화수소류의 정제방법 |
Country Status (20)
| Country | Link |
|---|---|
| US (1) | US4481106A (ko) |
| EP (1) | EP0145439B1 (ko) |
| JP (1) | JPS60137994A (ko) |
| KR (1) | KR900000892B1 (ko) |
| AT (1) | ATE33145T1 (ko) |
| AU (1) | AU559760B2 (ko) |
| BR (1) | BR8406193A (ko) |
| CA (1) | CA1209514A (ko) |
| CS (1) | CS264323B2 (ko) |
| DD (1) | DD237181A5 (ko) |
| DE (1) | DE3470056D1 (ko) |
| DZ (1) | DZ710A1 (ko) |
| EG (1) | EG17094A (ko) |
| ES (1) | ES538237A0 (ko) |
| GR (1) | GR81083B (ko) |
| IL (1) | IL73519A (ko) |
| IN (1) | IN162878B (ko) |
| MY (1) | MY101734A (ko) |
| TR (1) | TR22117A (ko) |
| YU (1) | YU201084A (ko) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4490246A (en) * | 1983-11-18 | 1984-12-25 | Uop Inc. | Process for sweetening petroleum fractions |
| US4604261A (en) * | 1984-06-29 | 1986-08-05 | Mobil Oil Corporation | Hydroprocessing reactor for catalytically dewaxing liquid petroleum feedstocks |
| US4746494A (en) * | 1985-05-30 | 1988-05-24 | Merichem Company | Treatment of sour hydrocarbon distillate |
| US4675100A (en) * | 1985-05-30 | 1987-06-23 | Merichem Company | Treatment of sour hydrocarbon distillate |
| US4753722A (en) | 1986-06-17 | 1988-06-28 | Merichem Company | Treatment of mercaptan-containing streams utilizing nitrogen based promoters |
| US5264187A (en) * | 1990-10-15 | 1993-11-23 | Phillips Petroleum Company | Treatment of hydrocarbons |
| US5741415A (en) * | 1994-09-27 | 1998-04-21 | Chevron U.S.A. Inc. | Method for the demercaptanization of petroleum distillates |
| US5858212A (en) * | 1996-07-03 | 1999-01-12 | Interglobal Desulfuruzations Systems, Inc. | Desulfurization and hydrocarbon quality enhancement process |
| US5961819A (en) * | 1998-02-09 | 1999-10-05 | Merichem Company | Treatment of sour hydrocarbon distillate with continuous recausticization |
| KR100566487B1 (ko) * | 1998-06-25 | 2006-07-14 | 에스케이 주식회사 | 석유계 탄화수소의 스위트닝 공정 |
| GB0226178D0 (en) | 2002-11-11 | 2002-12-18 | Johnson Matthey Plc | Desulphurisation |
| US7223332B1 (en) | 2003-10-21 | 2007-05-29 | Uop Llc | Reactor and process for mercaptan oxidation and separation in the same vessel |
| US8900446B2 (en) * | 2009-11-30 | 2014-12-02 | Merichem Company | Hydrocarbon treatment process |
| WO2011114352A2 (en) | 2010-03-17 | 2011-09-22 | Indian Oil Corporation Limited | Process for selective removal of mercaptan from aviation turbine fuel (atf) |
| US20140353209A1 (en) * | 2013-05-29 | 2014-12-04 | Uop, Llc | Process for treating a naphtha stream |
| US8999149B2 (en) | 2013-06-28 | 2015-04-07 | Uop Llc | Process for removing gases from a sweetened hydrocarbon stream, and an appartus relating thereto |
| US9393526B2 (en) | 2013-06-28 | 2016-07-19 | Uop Llc | Process for removing one or more sulfur compounds and an apparatus relating thereto |
| US9914886B2 (en) * | 2014-06-10 | 2018-03-13 | Uop Llc | Apparatuses and methods for conversion of mercaptans |
| US10774274B2 (en) | 2018-04-27 | 2020-09-15 | Uop Llc | Process and apparatus for a settler and first stage water wash in a caustic free kerosene sweetening reactor |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA625756A (en) * | 1961-08-15 | K. T. Gleim William | Process for sweetening sour hydrocarbon distillates | |
| US2176806A (en) * | 1938-01-24 | 1939-10-17 | Skelly Oil Co | Method and apparatus for contacting immiscible liquids |
| BE512549A (ko) * | 1951-07-04 | |||
| NL235884A (ko) * | 1958-02-13 | |||
| US2988500A (en) * | 1959-03-13 | 1961-06-13 | Universal Oil Prod Co | Treatment of hydrocarbon distillates |
| US3413215A (en) * | 1966-05-16 | 1968-11-26 | Universal Oil Prod Co | Oxidation of mercapto compounds |
| US3445380A (en) * | 1967-07-07 | 1969-05-20 | Universal Oil Prod Co | Treating sour hydrocarbon distillates containing mercapto compounds and acidic,surface-active materials |
| US3547354A (en) * | 1968-09-06 | 1970-12-15 | Continental Oil Co | Gas flow diffuser |
| US3574093A (en) * | 1969-01-22 | 1971-04-06 | Universal Oil Prod Co | Combination process for treatment of hydrocarbon streams containing mercapto compounds |
| US3923645A (en) * | 1973-09-07 | 1975-12-02 | Ashland Oil Inc | Method for oxidizing mercaptans occurring in petroleum refining streams |
| US4039389A (en) * | 1975-11-03 | 1977-08-02 | Uop Inc. | Liquid-liquid extraction apparatus |
| US4019869A (en) * | 1975-11-10 | 1977-04-26 | Uop Inc. | Combination reactor-separator apparatus |
| US4100057A (en) * | 1977-08-01 | 1978-07-11 | Uop Inc. | Method of treating a sour petroleum distillate |
| US4248694A (en) * | 1979-05-17 | 1981-02-03 | Uop Inc. | Process for treating a sour petroleum distillate |
| US4392947A (en) * | 1981-09-30 | 1983-07-12 | Mobil Oil Corporation | Integrated refining process |
-
1983
- 1983-12-05 US US06/558,243 patent/US4481106A/en not_active Expired - Lifetime
-
1984
- 1984-11-06 IN IN851/DEL/84A patent/IN162878B/en unknown
- 1984-11-06 CA CA000467138A patent/CA1209514A/en not_active Expired
- 1984-11-13 AU AU35366/84A patent/AU559760B2/en not_active Expired
- 1984-11-14 IL IL73519A patent/IL73519A/xx not_active IP Right Cessation
- 1984-11-27 YU YU02010/84A patent/YU201084A/xx unknown
- 1984-11-28 DZ DZ847344A patent/DZ710A1/fr active
- 1984-11-28 GR GR81083A patent/GR81083B/el unknown
- 1984-11-30 TR TR22117A patent/TR22117A/xx unknown
- 1984-12-04 ES ES538237A patent/ES538237A0/es active Granted
- 1984-12-04 AT AT84308398T patent/ATE33145T1/de not_active IP Right Cessation
- 1984-12-04 EG EG746/84A patent/EG17094A/xx active
- 1984-12-04 CS CS849319A patent/CS264323B2/cs unknown
- 1984-12-04 DE DE8484308398T patent/DE3470056D1/de not_active Expired
- 1984-12-04 BR BR8406193A patent/BR8406193A/pt not_active IP Right Cessation
- 1984-12-04 EP EP84308398A patent/EP0145439B1/en not_active Expired
- 1984-12-04 DD DD84270267A patent/DD237181A5/de not_active IP Right Cessation
- 1984-12-05 JP JP59255880A patent/JPS60137994A/ja active Granted
- 1984-12-05 KR KR1019840007659A patent/KR900000892B1/ko not_active IP Right Cessation
-
1987
- 1987-05-14 MY MYPI87000654A patent/MY101734A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| ES8600371A1 (es) | 1985-09-16 |
| DZ710A1 (fr) | 2004-09-13 |
| CS931984A2 (en) | 1988-12-15 |
| MY101734A (en) | 1992-01-17 |
| EP0145439A2 (en) | 1985-06-19 |
| YU201084A (en) | 1987-02-28 |
| TR22117A (tr) | 1986-04-28 |
| EP0145439A3 (en) | 1985-12-04 |
| DD237181A5 (de) | 1986-07-02 |
| EP0145439B1 (en) | 1988-03-23 |
| CS264323B2 (en) | 1989-07-12 |
| JPS60137994A (ja) | 1985-07-22 |
| DE3470056D1 (en) | 1988-04-28 |
| IL73519A0 (en) | 1985-02-28 |
| JPH0121198B2 (ko) | 1989-04-20 |
| ES538237A0 (es) | 1985-09-16 |
| US4481106A (en) | 1984-11-06 |
| EG17094A (en) | 1991-12-30 |
| CA1209514A (en) | 1986-08-12 |
| IL73519A (en) | 1988-03-31 |
| KR900000892B1 (ko) | 1990-02-17 |
| GR81083B (en) | 1985-03-29 |
| BR8406193A (pt) | 1985-09-24 |
| IN162878B (ko) | 1988-07-16 |
| AU3536684A (en) | 1985-06-13 |
| AU559760B2 (en) | 1987-03-19 |
| ATE33145T1 (de) | 1988-04-15 |
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