KR850002257A - 1-아조릴-치환된 옥심 에테르의 제조방법 - Google Patents
1-아조릴-치환된 옥심 에테르의 제조방법 Download PDFInfo
- Publication number
- KR850002257A KR850002257A KR1019840005787A KR840005787A KR850002257A KR 850002257 A KR850002257 A KR 850002257A KR 1019840005787 A KR1019840005787 A KR 1019840005787A KR 840005787 A KR840005787 A KR 840005787A KR 850002257 A KR850002257 A KR 850002257A
- Authority
- KR
- South Korea
- Prior art keywords
- alkyl
- moiety
- substituted
- alkenyl
- phenyl
- Prior art date
Links
- 238000004519 manufacturing process Methods 0.000 title 1
- SQDFHQJTAWCFIB-UHFFFAOYSA-N n-methylidenehydroxylamine Chemical class ON=C SQDFHQJTAWCFIB-UHFFFAOYSA-N 0.000 title 1
- 125000000217 alkyl group Chemical group 0.000 claims 14
- 125000003342 alkenyl group Chemical group 0.000 claims 5
- 125000003118 aryl group Chemical group 0.000 claims 5
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 5
- -1 1-azolyl Chemical group 0.000 claims 4
- 125000003710 aryl alkyl group Chemical group 0.000 claims 4
- 150000001875 compounds Chemical class 0.000 claims 4
- 229910052736 halogen Inorganic materials 0.000 claims 4
- 150000002367 halogens Chemical group 0.000 claims 4
- 125000004183 alkoxy alkyl group Chemical group 0.000 claims 3
- 125000003545 alkoxy group Chemical group 0.000 claims 3
- 125000000304 alkynyl group Chemical group 0.000 claims 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 3
- 125000005359 phenoxyalkyl group Chemical group 0.000 claims 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims 2
- 229910052794 bromium Inorganic materials 0.000 claims 2
- 229910052801 chlorine Inorganic materials 0.000 claims 2
- 239000000460 chlorine Substances 0.000 claims 2
- 125000000753 cycloalkyl group Chemical group 0.000 claims 2
- 125000004475 heteroaralkyl group Chemical group 0.000 claims 2
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims 1
- 125000001494 2-propynyl group Chemical group [H]C#CC([H])([H])* 0.000 claims 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims 1
- 239000011230 binding agent Substances 0.000 claims 1
- 125000001246 bromo group Chemical group Br* 0.000 claims 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 1
- 229910052731 fluorine Inorganic materials 0.000 claims 1
- 239000011737 fluorine Substances 0.000 claims 1
- 125000001153 fluoro group Chemical group F* 0.000 claims 1
- 125000001072 heteroaryl group Chemical group 0.000 claims 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 1
- 229910052757 nitrogen Inorganic materials 0.000 claims 1
- 125000004433 nitrogen atom Chemical group N* 0.000 claims 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims 1
- 150000002923 oximes Chemical class 0.000 claims 1
- 125000004430 oxygen atom Chemical group O* 0.000 claims 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 239000002904 solvent Substances 0.000 claims 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
- C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
- C07D233/66—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D233/90—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/12—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C259/00—Compounds containing carboxyl groups, an oxygen atom of a carboxyl group being replaced by a nitrogen atom, this nitrogen atom being further bound to an oxygen atom and not being part of nitro or nitroso groups
- C07C259/02—Compounds containing carboxyl groups, an oxygen atom of a carboxyl group being replaced by a nitrogen atom, this nitrogen atom being further bound to an oxygen atom and not being part of nitro or nitroso groups with replacement of the other oxygen atom of the carboxyl group by halogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
- C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
- C07D233/56—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
- C07D249/02—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
- C07D249/08—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
Landscapes
- Organic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Environmental Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Plant Pathology (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
- Plural Heterocyclic Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (3)
- 일반식(Ⅱ)의 옥심을 일반식(Ⅲ)의 알킬, 알케닐 또는 알키닐 할라이드와 경우에 따라서 용매 및 산－결합제의 존재하에 반응시킴을 특징으로 하는 일반식(Ⅰ)의 1－아조릴－치환된 옥심 에테르의 제조방법.상기식에서, R은 알킬, 알콕시알킬, 알케닐, 사이클로알킬, 아르알킬, 페녹시알킬 또는 페닐을 나타내고 전술한 마지막 세개의 라디칼은 발향족 부위에서 치환될 수 있으며; R1은 알킬, 알케닐, 알키닐, 임의로 치환된 아르알킬 또는 헤테로아르알킬을 나타내고; X는 질소 또는 CH그룹을 나타내며; HaL은 염소 또는 브롬을 나타낸다.
- 제1항에 있어서, R은 C1－C12의 직쇄 또는 분지된 알킬, 각 알킬부위가 C1－C4인 알콕시알킬, 각 경우에 있어서 C2－C5인 알키닐 또는 알케닐, 환에서 C6까지를 갖는 사이클로알킬, 알킬부위가 C1－C4이고 및 아릴부위가 C6－C10인 아르알킬(여기에서 아릴부위는 할로겐, 또는 각 경우에 있어서 C4까지를 갖는 알킬 및/또는 알콕시그룹으로 임의 치환될 수 있다), 직쇄 또는 분지된 알킬부위가 C3까지를 갖는 페녹시알킬 또는 페닐을 나타내고, 여기에서 전술한 마지막 두개의 라디칼이 할로겐 또는 각 경우에 있어서 C1－C4의 알킬 및/또는 알콕시 그룹에 의해서 페닐상에 치환될 수 있으며; R1은 C1－C6의 알킬, 각 경우에 있어서 C3－C5인 알키닐 또는 알케닐, 알킬 부위가 C1－C3이고 아릴부위가 C6－C10인 아르알킬(여기에서 아릴부위는 할로겐 또는 각 경우에 있어서 C4까지를 갖는 알콕시 및/또는 알킬에 의해서 치환될 수 있다) 또는 R1은 알킬 부위가 C1－C2이고 헤테로아릴 부위가 질소원자 1 내지 3개 및 적절하게는 1개의 산소 원자를 갖는 5원 방향족 헤테로환을 갖는 헤테로아르알킬을 나타내고, X는 제1항에서 기술한 바와 같은 일반식(Ⅰ)의 화합물을 제조하는 방법.
- 제1항에 있어서, R은 3급－부틸, 각 알킬부위가 C1－C3인 알콕시알킬, 또는 알킬부위가 C3까지를 갖는 페녹시알킬을 나타내고, 여기에서 페닐 부위는 불소, 염소, 브롬, 메틸 및/또는 메톡시에 의해서 단일－, 이－또는 삼치환될 수 있으며; R1은 메틸, 에틸, 프로필, 부틸, 알릴, 프로파길 또는 벤질을 나타내고, 여기에서 페닐 부위는 할로겐, 메틸 및 메톡시에 의해서 단일－, 이－, 삼－치환될 수 있으며, 또는 R1은 트리아졸메틸 또는 이미다조릴메틸을 나타내고; X는 제1항에 기술한 바와 같은 일반식(Ⅰ)의 화합물을 제조하는 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEP3334220,2 | 1983-09-22 | ||
| DE19833334220 DE3334220A1 (de) | 1983-09-22 | 1983-09-22 | 1-azolyl-substituierte oximether |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR850002257A true KR850002257A (ko) | 1985-05-10 |
Family
ID=6209739
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019840005787A KR850002257A (ko) | 1983-09-22 | 1984-09-21 | 1-아조릴-치환된 옥심 에테르의 제조방법 |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US4599348A (ko) |
| EP (1) | EP0142653A1 (ko) |
| JP (1) | JPS6087269A (ko) |
| KR (1) | KR850002257A (ko) |
| AU (1) | AU3323384A (ko) |
| BR (1) | BR8404764A (ko) |
| DE (1) | DE3334220A1 (ko) |
| DK (1) | DK453184A (ko) |
| ES (1) | ES536136A0 (ko) |
| GR (1) | GR80433B (ko) |
| HU (1) | HUT36806A (ko) |
| IL (1) | IL72994A0 (ko) |
| PH (1) | PH19450A (ko) |
| ZA (1) | ZA847445B (ko) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4857649A (en) * | 1988-07-21 | 1989-08-15 | Uniroyal Chemical Company, Inc. | Azole derivatives of naphthalenone oxime esters |
| US5006153A (en) * | 1989-11-29 | 1991-04-09 | Uniroyal Chemical Company, Inc. | Azole derivatives of naphthalenone oxime ethers |
| IL97144A (en) * | 1990-02-27 | 1994-11-28 | Erba Carlo Spa | History of 1-) Alkoxy-Iminoalkyl (Imidazole Transformed Preparation and Pharmaceutical Preparations Containing Them |
| DE69131125T2 (de) * | 1990-11-29 | 1999-09-30 | Kumiai Chemical Industry Co | Benzohydroxyimoylazolderivat, herstellung und insektizid |
| GB9116470D0 (en) * | 1991-07-30 | 1991-09-11 | Erba Carlo Spa | 2-(imidazol-1-yl)-benzylethylidene-aminoxyalkanoic acid derivatives |
| EP0633252A1 (en) * | 1993-07-09 | 1995-01-11 | Shionogi & Co., Ltd. | Benzaldehyde oxime derivatives, production and use thereof |
| GB9315058D0 (en) * | 1993-07-20 | 1993-09-01 | Erba Carlo Spa | 2-(imidazol-1-yl)benzylethylidene-aminooxylkyl-hydroxamic acid derivatives |
| US6048885A (en) * | 1994-04-01 | 2000-04-11 | Shionogi & Co., Ltd. | Oxime derivative and bactericide containing the same as active ingredient |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH617427A5 (ko) * | 1975-12-24 | 1980-05-30 | Siegfried Ag | |
| DE2723942C2 (de) * | 1977-05-27 | 1982-11-11 | Basf Ag, 6700 Ludwigshafen | ω-(1,2,4-Triazol-1-yl) acetophenonoximäther |
| DE2816817A1 (de) * | 1978-04-18 | 1979-10-31 | Bayer Ag | Oximino-triazolyl-aethane, verfahren zu ihrer herstellung sowie ihre verwendung als fungizide |
| US4347372A (en) * | 1978-09-01 | 1982-08-31 | Ciba-Geigy Corporation | Benzoxazolyl-glyoxylonitrile-2-oxime ether derivatives |
| BR8008467A (pt) * | 1979-04-20 | 1981-03-31 | Ciba Geigy Ag | Derivados de 1-triazo-n-(fenil)-azometina |
| DE3005899A1 (de) * | 1980-02-16 | 1981-09-03 | Hoechst Ag, 6000 Frankfurt | Derivate des 1,2,4-triazols und imidazols, verfahren zu ihrer herstellung und ihre verwendung als schaedlingsbekaempfungsmittel |
| DE3016569A1 (de) * | 1980-04-30 | 1981-11-05 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von alkylarylketoximethern |
| DE3150984A1 (de) * | 1981-12-23 | 1983-06-30 | Bayer Ag, 5090 Leverkusen | Oximcarbamate, verfahren zu ihrer herstellung und ihre verwendung als schaedlingsbekaempfungsmittel |
| DE3220183A1 (de) * | 1982-05-28 | 1983-12-01 | Basf Ag, 6700 Ludwigshafen | Triazolyl-ketonoxime und -dioxime, verfahren zu ihrer herstellung und ihre verwendung als pflanzenwachstumsregulatoren |
-
1983
- 1983-09-22 DE DE19833334220 patent/DE3334220A1/de not_active Withdrawn
-
1984
- 1984-09-07 US US06/648,910 patent/US4599348A/en not_active Expired - Fee Related
- 1984-09-08 EP EP84110733A patent/EP0142653A1/de not_active Withdrawn
- 1984-09-17 PH PH31217A patent/PH19450A/en unknown
- 1984-09-18 AU AU33233/84A patent/AU3323384A/en not_active Abandoned
- 1984-09-19 IL IL72994A patent/IL72994A0/xx unknown
- 1984-09-19 JP JP59194922A patent/JPS6087269A/ja active Pending
- 1984-09-20 GR GR80433A patent/GR80433B/el unknown
- 1984-09-21 ES ES536136A patent/ES536136A0/es active Granted
- 1984-09-21 ZA ZA847445A patent/ZA847445B/xx unknown
- 1984-09-21 BR BR8404764A patent/BR8404764A/pt unknown
- 1984-09-21 KR KR1019840005787A patent/KR850002257A/ko not_active Application Discontinuation
- 1984-09-21 HU HU843582A patent/HUT36806A/hu unknown
- 1984-09-21 DK DK453184A patent/DK453184A/da unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DK453184A (da) | 1985-03-23 |
| AU3323384A (en) | 1985-03-28 |
| BR8404764A (pt) | 1985-08-13 |
| EP0142653A1 (de) | 1985-05-29 |
| ES8505662A1 (es) | 1985-06-01 |
| HUT36806A (en) | 1985-10-28 |
| ES536136A0 (es) | 1985-06-01 |
| GR80433B (en) | 1985-01-18 |
| DE3334220A1 (de) | 1985-04-11 |
| DK453184D0 (da) | 1984-09-21 |
| JPS6087269A (ja) | 1985-05-16 |
| ZA847445B (en) | 1985-05-29 |
| PH19450A (en) | 1986-04-18 |
| IL72994A0 (en) | 1984-12-31 |
| US4599348A (en) | 1986-07-08 |
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