KR840009318A - 보호피복 또는 부조상의 제조방법 - Google Patents

보호피복 또는 부조상의 제조방법 Download PDF

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KR840009318A
KR840009318A KR1019840002691A KR840002691A KR840009318A KR 840009318 A KR840009318 A KR 840009318A KR 1019840002691 A KR1019840002691 A KR 1019840002691A KR 840002691 A KR840002691 A KR 840002691A KR 840009318 A KR840009318 A KR 840009318A
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파이퍼 요셉
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아놀드 자일러, 에른스트 알더
시바-가이기 에이쥐
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Abstract

내용 없음

Description

보호피복 또는 부조상의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. 중합체를 기준으로 다음 일반식의 구성단위를 적어도 5mol% 이상 함유하는 방사선-감수성 단일중합체 또는 공중합체로 된 캐리어상에 입혀진 코팅위에 전부위에 걸쳐 광을 조사(照射)하여 보초코팅이 생성되게 하거나 또는 차광마스크하에 광을 조사하여 릴리이프상(relief image)이 생성되게 한 후, 비노출부를 현상제로 제거하는 것으로 구성된 캐리어(carrier) 위에 보초코팅 또는 릴리이프상을 만드는 방법.
    상기식에서 R은 헤테로원자 또는 방향족, 헤테고리 또는 고리지방족기가 개재될 수 있는 2가의 비치환 또는 치환된 지방족라디칼, 또는 비치환되거나 치환된 고리지방족 또는 방향족지방족라디칼, 또는 2개의 아릴핵이 지방족기를 통해 연결된 방향족라디칼, 또는 적어도 하나의 알킬, 사이클로알킬, 알콕시, 알콕시알킬, 알킬티오, 알킬티오알킬, 하이드록시알킬, 하이드록시알콕시, 하이드록시알킬티오 또는 아르알킬기에 의해 치환된 방향족라디칼이며 여기서 방향족라디칼의 2개의 인접 탄소원자는 알킬렌에 의해 치환되어 있으며, R′는 독립적으로 R과 동일한 의미를 가지며, q는 0 또는 1이며, 방향족라디칼 R은 q가 0인 경우 질소원자에 대해 양쪽 오르토 위치가 앞서 언급한 라디칼에 의해 또는 알킬렌에 의해 치환되지 않는다.
  2. 제1항에 있어서, 단일중합체 또는 공중합체가 구조식(Ⅰ)의 구성단위를 중합체를 기준으로 5~100몰% 함유하는 방법.
  3. 제1항에 있어서, 방향족라디칼상의 치환분이 1~20개의 탄소원자를 함유하는 방법.
  4. 제1항에 있어서, 지방족라디칼 R이 2~30개의 탄소원자를 함유하거나, 고리지방족라디칼 R이 5~8개의 환탄소원자를 함유하거나, 방향지방족라디칼 R이 7~30개의 탄소원자를 함유하거나 치환된 방향족라디칼 R이 7~30개의 탄소원자를 함유하는 방법.
  5. 제1항에 있어서, 지방족라디칼 R이 산소원자, NH, NRa또는,(Ra는 C1~C12알킬, 환탄소원자를 5 또는 6개 함유하는 사이클로알킬, 페닐 또는 벤질이며,는 양성자산의 음이온임) 사이클로헥실렌나프틸렌, 페닐렌 또는 히단토인이 개재될 수 있는 직쇄 또는 분리쇄 알킬렌이거나, 고리지방족라디칼 R이 5~7개의 환탄소원자를 가지며 알킬에 의해 치환되거나 비치환된 단일고리 또는 두고리 사이클로알킬렌이거나, 방향지방족라디칼 R이 비치환되었거나 또는 아릴 부위가 알킬에 의해 치환된 아르알킬렌이거나(알킬렌라디칼은 직쇄 또는 분리쇄일 수 있음), 또는 방향족라디칼 R이 알킬, 알콕시, 알콕시알킬, 트리메틸렌 또는 테트라메틸렌에 의해 치환된 탄화수소라디칼 또는 피리딘라디칼인 방법.
  6. 제5항에 있어서, 방향족라디칼이 하기 구조식을 가지며
    단일치환의 경우엔 하나의 라디칼 R4가 C1_6알킬이고 나머지 라디칼 R4이 수소이며, 디-트리, 또는 테트라-치환의 경우엔, 2개의 라디칼 R4가 알킬이고 나머지 라디칼 R4가 수소원자 또는 C1_6알킬이거나 또는 디-트리-테트라-치환의 경우 페닐환상에 있는 2개의 인접한 라디칼 R4가 트리메틸렌 또는 테트라메틸렌이고 나머지 R4가 수소원자 또는 C1_6알킬이며, Y가 O,S,NH,CO 또는 CH2이며, R5가 수소원자, C1_5알킬이며, R6가 C1_5알킬이며, Z가 직접 결합을 나타내거나 또는 O,S,SO,SO2,CO,,NR7,CONH,NH,R7SiR8,R7OSiOR8,
    C1_6알킬렌, C2_6알케닐렌 또는 알킬리덴, 페닐렌 또는 페닐디옥시이며 여기서 R7과 R8가 각기 독립적으로 C1_6알킬 또는 페닐이며 j가 1~10인 방법.
  7. 제1항에 있어서, 단일중합체 또는 공중합체가 폴리이미드, 폴리아미드, 포화폴리에스테르, 폴리카보네이트, 폴리아미드-이미드, 폴리에스테르-아미드폴리실옥산, 불포화폴리에스테르, 에폭시수지, 방향족폴리에테르, 방향족 폴리에테르-케톤, 방향족 폴리에테르-설폰, 방향족폴리케톤, 방향족폴리티오에테르 및 이들 중합체의 혼합물로 구성된 군으로부터 선택되는 방법.
  8. 제7항에 있어서, 중합체가 q가 0인 구조식(I)의 반복되는 구성요소를 함유하는 폴리이미드이거나 또는 q가 0인 구조식(I)의 반복되는 구성요소와 구조식(Ⅱ)의 반복되는 구성요소를 함유하는 코폴리이미드인 방법.
    상기식에서 A는 4가 유기라디칼이며 R10은 2가 유기라디칼이다.
  9. 제7항에 있어서, 중합체가 유기디아민, 디카르복실산, w-아미노카르복실산, q가 1이며 아민기 또는 카르복실기가 R 및 R1기에 결합된 구조식(I)의 구성요소를 함유한 디카르복실산 또는 디아민 및 단량체 혼합물로 된 폴리아미드 또는 코폴리아미드인 방법.
  10. 제7항에 있어서, 중합체가 유기디올, 디카르복실산, 하이드록시카르복실산, q가 1이며 하이드록시 또는 카르복실기가 R 및 R′기에 결합되어 있는 구조식(I)의 구성요소를 함유한 디카르복실산 또는 디올 및 단량체 혼합물로 된 폴리에스테르 또는 코폴리에스테르인 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019840002691A 1983-05-18 1984-05-17 보호용 피복물 또는 릴리이프상의 제조방법 KR920008723B1 (ko)

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US4696890A (en) * 1985-04-11 1987-09-29 Ciba-Geigy Corporation Processes for preparing protective coatings and relief structures
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US4847359A (en) * 1986-06-30 1989-07-11 Ciba-Geigy Corporation Diamino-9,10-dihydroanthracenes and polyamide acid (esters) and polyimides derived therefrom
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DE3469073D1 (en) 1988-03-03
EP0134752A1 (de) 1985-03-20
US4657832A (en) 1987-04-14
EP0134752B1 (de) 1988-01-27
CA1256759A (en) 1989-07-04
KR920008723B1 (ko) 1992-10-08

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