KR840004702A - 올레핀 결합 이성질화 방법 - Google Patents
올레핀 결합 이성질화 방법 Download PDFInfo
- Publication number
- KR840004702A KR840004702A KR1019830002257A KR830002257A KR840004702A KR 840004702 A KR840004702 A KR 840004702A KR 1019830002257 A KR1019830002257 A KR 1019830002257A KR 830002257 A KR830002257 A KR 830002257A KR 840004702 A KR840004702 A KR 840004702A
- Authority
- KR
- South Korea
- Prior art keywords
- moles
- sio
- olefin
- catalyst
- formula
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
- C07C5/23—Rearrangement of carbon-to-carbon unsaturated bonds
- C07C5/25—Migration of carbon-to-carbon double bonds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
- C07C5/23—Rearrangement of carbon-to-carbon unsaturated bonds
- C07C5/25—Migration of carbon-to-carbon double bonds
- C07C5/2506—Catalytic processes
- C07C5/2512—Catalytic processes with metal oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/08—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of gallium, indium or thallium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of rare earths
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (10)
- 아래식(1)과 같은 일반식을 가지는 촉매존재하에 올레핀을 이성질화함을 특징으로하는 감마알루미나로 된 촉매 존재하의 올레핀 결합 이성질화 방법.aAl2O3·bSiO2·cMexOy(1)단 (1)식에 있어서 MexOy는 ⅡA족과/또는Ⅷ족과/또는 ⅢB족과/또는 란탄족 원소등의 2가 또는 3가 금속(들)의 산화물이고, a,b,c는 각각 Al2O3,SiO2및 MexOy의 몰수이며 b와 c는 다음식(2)과 같은 관계를 가짐.c≥mb+B (2)식 (2)에 있어서 B는 0.01과 같거나 이보다 큰 수이고 b는 0-0.300사이의 수인데 특히 0.020-0.0250사이의 수이고(b+c)/a의 비는 0.01-9.0사이이며 m은 0.7-0.1사이의 수임.
- 청구범위 제1항에 있어서 올레핀의 이성질화 온도를 350-550℃로 함을 특징으로 하는 방법.
- 청구범위 제2항에 있어서 올레핀의 이성질화 온도를 450-500℃로 함을 특징으로 하는 방법.
- 청구범위 제1항에 있어서 올레핀의 이성질화 온도를 0.1-10ata로 함을 특징으로 하는 방법.
- 청구범위 제4항에 있어서 올레핀의 이성질화 압력을 0.5-3ata로 함을 특징으로 하는 방법.
- 청구범위 제1항에 있어서 ⅡA족 금속으로서는 칼슘을 사용하고 촉매중의 CaO의 몰수가 다음식과 같이 SiO2의 몰수와 관계를 가짐을 특징으로 하는 방법.Ca0몰수≥0.500×SiO2몰수+0.030단 위의 식에서 SiO2의 몰수는 0-0.300, 특히 0.020≥0.250의 범위로 함.
- 청구범위 제1항에 있어서 ⅡA족 금속으로서는 바륨을 사용하고 촉매중의 BaO의 몰수가 다음식과 같이 SiO2의 몰수와 관계를 가짐을 특징으로 하는 방법.BaO몰수≥0.500×SiO2몰수+0.020단 위의식에서 SiO2의 몰수는 0-0.300, 특히 0.020-0.250의 범위로 함.
- 청구범위 제1항에 있어서 금속으로서는 란탄 또는 란탄족 원소를 사용하고 촉매중의 La2O3또는 산화란탄의 몰수가 다음식과 같이 SiO2의 몰수와 관계를 가짐을 특징으로 하는 방법La2O3몰수≥0.257×SiO2몰수+0.014단, 위의 식에서 SiO2의 몰수는 0-0.300, 특히 0.020-0.250의 범위로 함.
- 청구범위 제1항에 있어서 Ⅷ족 금속으로서는 철을 사용하고 촉매중의 Fe2O3의 몰수가 다음식과 같이 SiO2의 몰수와 관계를 가짐을 특징으로 하는 방법.Fe2O3몰수≥0.290×SiO2몰수+0.018단, 위의 식에서 SiO2의 몰수는 0-0.300, 특히 0.020-0.250의 범위로 함.
- 앞에나온 청구범위들에 있어서 올레핀의 공간 속도를 2-20h-1, 특히 4-8h-1의 범위로 함을 특징으로 하는 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT21511A/82 | 1982-05-27 | ||
IT21511/82A IT1190839B (it) | 1982-05-27 | 1982-05-27 | Procedimento per la isomerizzazione di legame delle olefine |
Publications (2)
Publication Number | Publication Date |
---|---|
KR840004702A true KR840004702A (ko) | 1984-10-24 |
KR870000055B1 KR870000055B1 (ko) | 1987-02-09 |
Family
ID=11182885
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019830002257A KR870000055B1 (ko) | 1982-05-27 | 1983-05-23 | 올레핀 결합 이성화방법 |
Country Status (33)
Country | Link |
---|---|
US (1) | US4814542A (ko) |
JP (1) | JPS58219128A (ko) |
KR (1) | KR870000055B1 (ko) |
AT (1) | AT382864B (ko) |
AU (1) | AU552806B2 (ko) |
BE (1) | BE896849A (ko) |
CA (1) | CA1199041A (ko) |
CS (1) | CS244933B2 (ko) |
DD (1) | DD209801A5 (ko) |
DE (1) | DE3319171A1 (ko) |
DK (1) | DK234583A (ko) |
ES (1) | ES8500201A1 (ko) |
FR (1) | FR2527596A1 (ko) |
GB (1) | GB2121430B (ko) |
GR (1) | GR81339B (ko) |
HU (1) | HUT34419A (ko) |
IN (2) | IN158661B (ko) |
IT (1) | IT1190839B (ko) |
LU (1) | LU84823A1 (ko) |
MW (1) | MW2283A1 (ko) |
NL (1) | NL8301872A (ko) |
NO (1) | NO831847L (ko) |
NZ (1) | NZ204340A (ko) |
PH (1) | PH17965A (ko) |
PL (1) | PL141424B1 (ko) |
PT (1) | PT76764B (ko) |
RO (1) | RO86409B (ko) |
SE (1) | SE8302849L (ko) |
SU (1) | SU1333231A3 (ko) |
YU (1) | YU113083A (ko) |
ZA (1) | ZA833396B (ko) |
ZM (1) | ZM3683A1 (ko) |
ZW (1) | ZW11283A1 (ko) |
Families Citing this family (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT1190839B (it) * | 1982-05-27 | 1988-02-24 | Anic Spa | Procedimento per la isomerizzazione di legame delle olefine |
EP0225407A1 (en) * | 1985-01-25 | 1987-06-16 | Council of Scientific and Industrial Research | Lanthanum silicate materials, their production and use |
FR2584388B1 (fr) * | 1985-07-03 | 1991-02-15 | Rhone Poulenc Spec Chim | Composition a base d'oxyde cerique, sa preparation et ses utilisations |
AU591208B2 (en) * | 1985-12-23 | 1989-11-30 | Nippon Shokubai Kagaku Kogyo Co. Ltd. | Catalyst for vapor-phase intramolecular dehydration reaction of alkanolamines |
CA1276615C (en) * | 1985-12-27 | 1990-11-20 | Yuuji Shimasaki | Catalyst for vapor-phase intermolecular dehydration reaction of alkanolamines |
US5507940A (en) * | 1991-08-30 | 1996-04-16 | Shell Oil Company | Hydrodenitrification catalyst and process |
DE4445680A1 (de) * | 1994-12-21 | 1996-06-27 | Huels Chemische Werke Ag | Katalysator und Verfahren zur Isomerisierung von aliphatischen C¶4¶-C¶1¶¶0¶-Monoolefinen |
US6875901B2 (en) * | 2001-05-23 | 2005-04-05 | Abb Lummus Global Inc. | Olefin isomerization process |
US6777582B2 (en) * | 2002-03-07 | 2004-08-17 | Abb Lummus Global Inc. | Process for producing propylene and hexene from C4 olefin streams |
DE10311139A1 (de) | 2003-03-14 | 2004-09-23 | Basf Ag | Verfahren zur Herstellung von 1-Buten |
US7638573B2 (en) * | 2006-04-07 | 2009-12-29 | Exxonmobil Chemical Patents Inc. | Butyl nanocomposite via low Mw elastomer pre-blend |
CA2670935A1 (en) | 2006-11-30 | 2008-06-05 | Basf Se | Process for the hydroformylation of olefins |
DE102008036295A1 (de) * | 2008-08-04 | 2010-02-11 | Bayer Technology Services Gmbh | Katalysatorzusammensetzung zur Umesterung |
US8586813B2 (en) * | 2009-07-21 | 2013-11-19 | Lummus Technology Inc. | Catalyst for metathesis of ethylene and 2-butene and/or double bond isomerization |
US8704028B2 (en) * | 2010-03-30 | 2014-04-22 | Uop Llc | Conversion of acyclic symmetrical olefins to higher and lower carbon number olefin products |
DE102013226370A1 (de) | 2013-12-18 | 2015-06-18 | Evonik Industries Ag | Herstellung von Butadien durch oxidative Dehydrierung von n-Buten nach vorhergehender Isomerisierung |
DE102015200702A1 (de) | 2015-01-19 | 2016-07-21 | Evonik Degussa Gmbh | Herstellung von Butadien aus Ethen |
JP6571392B2 (ja) | 2015-05-29 | 2019-09-04 | Jxtgエネルギー株式会社 | 異性化触媒、直鎖オレフィンの製造方法及び化合物の製造方法 |
JP6736017B2 (ja) * | 2015-11-05 | 2020-08-05 | Eneos株式会社 | 異性化触媒、直鎖オレフィンの製造方法及び化合物の製造方法 |
KR102210178B1 (ko) * | 2016-07-28 | 2021-02-02 | 라이온델 케미칼 테크놀로지, 엘.피. | C4 함유 스트림으로부터의 파라핀 제거 |
US10550048B2 (en) * | 2017-01-20 | 2020-02-04 | Saudi Arabian Oil Company | Multiple-stage catalyst system for self-metathesis with controlled isomerization and cracking |
JP2020097544A (ja) * | 2018-12-18 | 2020-06-25 | Jxtgエネルギー株式会社 | 直鎖モノオレフィンの製造方法及び化合物の製造方法 |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3313858A (en) * | 1965-02-12 | 1967-04-11 | Phillips Petroleum Co | Isomerization of non-terminal olefins |
US3467727A (en) * | 1966-10-10 | 1969-09-16 | Universal Oil Prod Co | Isomerization of 2,3-dimethylbutenes |
US3479415A (en) * | 1967-05-12 | 1969-11-18 | Air Prod & Chem | Isomerization of olefinic hydrocarbons |
GB1267719A (en) * | 1969-12-05 | 1972-03-22 | Exxon Research Engineering Co | Isomerization of olefins |
US3864424A (en) * | 1973-04-30 | 1975-02-04 | Universal Oil Prod Co | Isomerization process |
US4217244A (en) * | 1978-05-11 | 1980-08-12 | Phillips Petroleum Company | Regeneration of isomerization catalysts containing magnesium oxide |
US4229610A (en) * | 1978-11-03 | 1980-10-21 | Phillips Petroleum Company | Olefin double bond isomerization |
FR2506297B1 (fr) * | 1981-05-21 | 1986-05-02 | Inst Francais Du Petrole | Procede d'isomerisation d'olefines |
IT1190839B (it) * | 1982-05-27 | 1988-02-24 | Anic Spa | Procedimento per la isomerizzazione di legame delle olefine |
-
1982
- 1982-05-27 IT IT21511/82A patent/IT1190839B/it active
-
1983
- 1983-05-11 ZA ZA833396A patent/ZA833396B/xx unknown
- 1983-05-12 ZW ZW112/83A patent/ZW11283A1/xx unknown
- 1983-05-13 AU AU14535/83A patent/AU552806B2/en not_active Ceased
- 1983-05-16 GR GR71362A patent/GR81339B/el unknown
- 1983-05-17 GB GB08313561A patent/GB2121430B/en not_active Expired
- 1983-05-18 PH PH28925A patent/PH17965A/en unknown
- 1983-05-19 SE SE8302849A patent/SE8302849L/ not_active Application Discontinuation
- 1983-05-20 YU YU01130/83A patent/YU113083A/xx unknown
- 1983-05-23 KR KR1019830002257A patent/KR870000055B1/ko active IP Right Grant
- 1983-05-24 RO RO111051A patent/RO86409B/ro unknown
- 1983-05-24 NZ NZ204340A patent/NZ204340A/en unknown
- 1983-05-25 FR FR8308648A patent/FR2527596A1/fr active Granted
- 1983-05-25 NO NO831847A patent/NO831847L/no unknown
- 1983-05-25 DK DK234583A patent/DK234583A/da not_active Application Discontinuation
- 1983-05-26 PL PL1983242214A patent/PL141424B1/pl unknown
- 1983-05-26 SU SU833598342A patent/SU1333231A3/ru active
- 1983-05-26 CA CA000428977A patent/CA1199041A/en not_active Expired
- 1983-05-26 AT AT0192583A patent/AT382864B/de not_active IP Right Cessation
- 1983-05-26 MW MW22/83A patent/MW2283A1/xx unknown
- 1983-05-26 PT PT76764A patent/PT76764B/pt unknown
- 1983-05-26 CS CS833719A patent/CS244933B2/cs unknown
- 1983-05-26 LU LU84823A patent/LU84823A1/fr unknown
- 1983-05-26 DE DE19833319171 patent/DE3319171A1/de active Granted
- 1983-05-26 BE BE0/210852A patent/BE896849A/fr not_active IP Right Cessation
- 1983-05-26 HU HU831864A patent/HUT34419A/hu unknown
- 1983-05-26 NL NL8301872A patent/NL8301872A/nl not_active Application Discontinuation
- 1983-05-27 IN IN669/CAL/83A patent/IN158661B/en unknown
- 1983-05-27 JP JP58092563A patent/JPS58219128A/ja active Pending
- 1983-05-27 DD DD83251340A patent/DD209801A5/de unknown
- 1983-05-27 IN IN671/CAL/83A patent/IN159131B/en unknown
- 1983-05-27 ES ES523076A patent/ES8500201A1/es not_active Expired
- 1983-05-27 ZM ZM36/83A patent/ZM3683A1/xx unknown
-
1988
- 1988-07-26 US US07/224,359 patent/US4814542A/en not_active Expired - Fee Related
Also Published As
Similar Documents
Publication | Publication Date | Title |
---|---|---|
KR840004702A (ko) | 올레핀 결합 이성질화 방법 | |
US2404788A (en) | Polymerizing olefins | |
KR840004150A (ko) | 알칸을 탈수소 환식화하는 방법 | |
KR860000234A (ko) | 에탄올 에틸렌으로 산화탈수소화하는 방법 | |
TR22002A (tr) | Kraking katalizatoerue oktan randiman performansinin artirilmasi | |
ES2076943T3 (es) | Componente catalitico liquido, sistema catalitico que contiene dicho componente y procedimiento para producir copolimeros de etileno-alfa-olefina utilizando dicho sistema catalitico. | |
GB1148907A (en) | Purification of phenol | |
AR013373A1 (es) | Procedimiento para la obtencion de olefinas livianas mediante la deshidrogenacion de las correspondientes parafinas | |
KR850001499A (ko) | 탄화수소 전환촉매의 제조방법 | |
GB1323913A (en) | Catalytic composite of platinum tin and germanium with carrier material and use thereof for the conversion of hydrocarbon | |
MX166693B (es) | Composicion catalizadora y metodo para convertir hicrocarburos | |
KR850004789A (ko) | 열접착성 수지 조성물 및 열봉함용 알루미-시이트 | |
ATE67467T1 (de) | Zeolith mit hohem siliziumgehalt (ecr-17), dieses zeolith enthaltender katalysator und umwandlung von kohlenwasserstoffen mit einem solchen katalysator. | |
KR840004521A (ko) | 감마 알루미나로된 촉매 제조방법 | |
ATE81606T1 (de) | Traegerkatalysatoren und ihre verwendung zur umwandlung von methan und zur dehydrogenierung von kohlenwasserstoffen. | |
ATE213775T1 (de) | Rekombinante thermostabile dna-polymerase von archaebakterie | |
GB1327738A (en) | Catalyst for the conversion of hydrocarbons and its manufacture and use | |
ATE24187T1 (de) | Katalysator zuer polymersation von olefinen. | |
NO862959L (no) | Fremgangsmaate til omdannelse av hydrokarboner. | |
KR920019670A (ko) | 결정성 실리콘 강화 알루미나류 및 그것의 제조방법 | |
GB1338342A (en) | Episulphide preparation process | |
FR2119624A5 (en) | Defluorescence of cresol - for tricresyl phosphate prepn by treatment with acid and distillation | |
DE3683631D1 (de) | Verfahren zur herstellung fluessiger kohlenwasserstoffe. | |
DE3676659D1 (de) | Isomerisierung von epoxiden im fallstromverfahren. | |
KR940007785A (ko) | 자기기록매체 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
E902 | Notification of reason for refusal | ||
G160 | Decision to publish patent application | ||
E701 | Decision to grant or registration of patent right | ||
NORF | Unpaid initial registration fee |