KR840004702A - 올레핀 결합 이성질화 방법 - Google Patents

올레핀 결합 이성질화 방법 Download PDF

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Publication number
KR840004702A
KR840004702A KR1019830002257A KR830002257A KR840004702A KR 840004702 A KR840004702 A KR 840004702A KR 1019830002257 A KR1019830002257 A KR 1019830002257A KR 830002257 A KR830002257 A KR 830002257A KR 840004702 A KR840004702 A KR 840004702A
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moles
sio
olefin
catalyst
formula
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KR1019830002257A
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KR870000055B1 (ko
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훠라니(외 2) 오르훼오
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칼로 시오니
스남프로게티 쏘시에떼 퍼 아찌오니
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/23—Rearrangement of carbon-to-carbon unsaturated bonds
    • C07C5/25—Migration of carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/23—Rearrangement of carbon-to-carbon unsaturated bonds
    • C07C5/25—Migration of carbon-to-carbon double bonds
    • C07C5/2506—Catalytic processes
    • C07C5/2512—Catalytic processes with metal oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/08—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of gallium, indium or thallium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of rare earths
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

내용 없음

Description

올레핀 결합 이성질화 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. 아래식(1)과 같은 일반식을 가지는 촉매존재하에 올레핀을 이성질화함을 특징으로하는 감마알루미나로 된 촉매 존재하의 올레핀 결합 이성질화 방법.
    aAl2O3·bSiO2·cMexOy(1)
    단 (1)식에 있어서 MexOy는 ⅡA족과/또는Ⅷ족과/또는 ⅢB족과/또는 란탄족 원소등의 2가 또는 3가 금속(들)의 산화물이고, a,b,c는 각각 Al2O3,SiO2및 MexOy의 몰수이며 b와 c는 다음식(2)과 같은 관계를 가짐.
    c≥mb+B (2)
    식 (2)에 있어서 B는 0.01과 같거나 이보다 큰 수이고 b는 0-0.300사이의 수인데 특히 0.020-0.0250사이의 수이고(b+c)/a의 비는 0.01-9.0사이이며 m은 0.7-0.1사이의 수임.
  2. 청구범위 제1항에 있어서 올레핀의 이성질화 온도를 350-550℃로 함을 특징으로 하는 방법.
  3. 청구범위 제2항에 있어서 올레핀의 이성질화 온도를 450-500℃로 함을 특징으로 하는 방법.
  4. 청구범위 제1항에 있어서 올레핀의 이성질화 온도를 0.1-10ata로 함을 특징으로 하는 방법.
  5. 청구범위 제4항에 있어서 올레핀의 이성질화 압력을 0.5-3ata로 함을 특징으로 하는 방법.
  6. 청구범위 제1항에 있어서 ⅡA족 금속으로서는 칼슘을 사용하고 촉매중의 CaO의 몰수가 다음식과 같이 SiO2의 몰수와 관계를 가짐을 특징으로 하는 방법.
    Ca0몰수≥0.500×SiO2몰수+0.030
    단 위의 식에서 SiO2의 몰수는 0-0.300, 특히 0.020≥0.250의 범위로 함.
  7. 청구범위 제1항에 있어서 ⅡA족 금속으로서는 바륨을 사용하고 촉매중의 BaO의 몰수가 다음식과 같이 SiO2의 몰수와 관계를 가짐을 특징으로 하는 방법.
    BaO몰수≥0.500×SiO2몰수+0.020
    단 위의식에서 SiO2의 몰수는 0-0.300, 특히 0.020-0.250의 범위로 함.
  8. 청구범위 제1항에 있어서 금속으로서는 란탄 또는 란탄족 원소를 사용하고 촉매중의 La2O3또는 산화란탄의 몰수가 다음식과 같이 SiO2의 몰수와 관계를 가짐을 특징으로 하는 방법
    La2O3몰수≥0.257×SiO2몰수+0.014
    단, 위의 식에서 SiO2의 몰수는 0-0.300, 특히 0.020-0.250의 범위로 함.
  9. 청구범위 제1항에 있어서 Ⅷ족 금속으로서는 철을 사용하고 촉매중의 Fe2O3의 몰수가 다음식과 같이 SiO2의 몰수와 관계를 가짐을 특징으로 하는 방법.
    Fe2O3몰수≥0.290×SiO2몰수+0.018
    단, 위의 식에서 SiO2의 몰수는 0-0.300, 특히 0.020-0.250의 범위로 함.
  10. 앞에나온 청구범위들에 있어서 올레핀의 공간 속도를 2-20h-1, 특히 4-8h-1의 범위로 함을 특징으로 하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019830002257A 1982-05-27 1983-05-23 올레핀 결합 이성화방법 KR870000055B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IT21511A/82 1982-05-27
IT21511/82A IT1190839B (it) 1982-05-27 1982-05-27 Procedimento per la isomerizzazione di legame delle olefine

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KR840004702A true KR840004702A (ko) 1984-10-24
KR870000055B1 KR870000055B1 (ko) 1987-02-09

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US (1) US4814542A (ko)
JP (1) JPS58219128A (ko)
KR (1) KR870000055B1 (ko)
AT (1) AT382864B (ko)
AU (1) AU552806B2 (ko)
BE (1) BE896849A (ko)
CA (1) CA1199041A (ko)
CS (1) CS244933B2 (ko)
DD (1) DD209801A5 (ko)
DE (1) DE3319171A1 (ko)
DK (1) DK234583A (ko)
ES (1) ES8500201A1 (ko)
FR (1) FR2527596A1 (ko)
GB (1) GB2121430B (ko)
GR (1) GR81339B (ko)
HU (1) HUT34419A (ko)
IN (2) IN158661B (ko)
IT (1) IT1190839B (ko)
LU (1) LU84823A1 (ko)
MW (1) MW2283A1 (ko)
NL (1) NL8301872A (ko)
NO (1) NO831847L (ko)
NZ (1) NZ204340A (ko)
PH (1) PH17965A (ko)
PL (1) PL141424B1 (ko)
PT (1) PT76764B (ko)
RO (1) RO86409B (ko)
SE (1) SE8302849L (ko)
SU (1) SU1333231A3 (ko)
YU (1) YU113083A (ko)
ZA (1) ZA833396B (ko)
ZM (1) ZM3683A1 (ko)
ZW (1) ZW11283A1 (ko)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1190839B (it) * 1982-05-27 1988-02-24 Anic Spa Procedimento per la isomerizzazione di legame delle olefine
EP0225407A1 (en) * 1985-01-25 1987-06-16 Council of Scientific and Industrial Research Lanthanum silicate materials, their production and use
FR2584388B1 (fr) * 1985-07-03 1991-02-15 Rhone Poulenc Spec Chim Composition a base d'oxyde cerique, sa preparation et ses utilisations
AU591208B2 (en) * 1985-12-23 1989-11-30 Nippon Shokubai Kagaku Kogyo Co. Ltd. Catalyst for vapor-phase intramolecular dehydration reaction of alkanolamines
CA1276615C (en) * 1985-12-27 1990-11-20 Yuuji Shimasaki Catalyst for vapor-phase intermolecular dehydration reaction of alkanolamines
US5507940A (en) * 1991-08-30 1996-04-16 Shell Oil Company Hydrodenitrification catalyst and process
DE4445680A1 (de) * 1994-12-21 1996-06-27 Huels Chemische Werke Ag Katalysator und Verfahren zur Isomerisierung von aliphatischen C¶4¶-C¶1¶¶0¶-Monoolefinen
US6875901B2 (en) * 2001-05-23 2005-04-05 Abb Lummus Global Inc. Olefin isomerization process
US6777582B2 (en) * 2002-03-07 2004-08-17 Abb Lummus Global Inc. Process for producing propylene and hexene from C4 olefin streams
DE10311139A1 (de) 2003-03-14 2004-09-23 Basf Ag Verfahren zur Herstellung von 1-Buten
US7638573B2 (en) * 2006-04-07 2009-12-29 Exxonmobil Chemical Patents Inc. Butyl nanocomposite via low Mw elastomer pre-blend
CA2670935A1 (en) 2006-11-30 2008-06-05 Basf Se Process for the hydroformylation of olefins
DE102008036295A1 (de) * 2008-08-04 2010-02-11 Bayer Technology Services Gmbh Katalysatorzusammensetzung zur Umesterung
US8586813B2 (en) * 2009-07-21 2013-11-19 Lummus Technology Inc. Catalyst for metathesis of ethylene and 2-butene and/or double bond isomerization
US8704028B2 (en) * 2010-03-30 2014-04-22 Uop Llc Conversion of acyclic symmetrical olefins to higher and lower carbon number olefin products
DE102013226370A1 (de) 2013-12-18 2015-06-18 Evonik Industries Ag Herstellung von Butadien durch oxidative Dehydrierung von n-Buten nach vorhergehender Isomerisierung
DE102015200702A1 (de) 2015-01-19 2016-07-21 Evonik Degussa Gmbh Herstellung von Butadien aus Ethen
JP6571392B2 (ja) 2015-05-29 2019-09-04 Ｊｘｔｇエネルギー株式会社 異性化触媒、直鎖オレフィンの製造方法及び化合物の製造方法
JP6736017B2 (ja) * 2015-11-05 2020-08-05 Ｅｎｅｏｓ株式会社 異性化触媒、直鎖オレフィンの製造方法及び化合物の製造方法
KR102210178B1 (ko) * 2016-07-28 2021-02-02 라이온델 케미칼 테크놀로지, 엘.피. C4 함유 스트림으로부터의 파라핀 제거
US10550048B2 (en) * 2017-01-20 2020-02-04 Saudi Arabian Oil Company Multiple-stage catalyst system for self-metathesis with controlled isomerization and cracking
JP2020097544A (ja) * 2018-12-18 2020-06-25 Ｊｘｔｇエネルギー株式会社 直鎖モノオレフィンの製造方法及び化合物の製造方法

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US3313858A (en) * 1965-02-12 1967-04-11 Phillips Petroleum Co Isomerization of non-terminal olefins
US3467727A (en) * 1966-10-10 1969-09-16 Universal Oil Prod Co Isomerization of 2,3-dimethylbutenes
US3479415A (en) * 1967-05-12 1969-11-18 Air Prod & Chem Isomerization of olefinic hydrocarbons
GB1267719A (en) * 1969-12-05 1972-03-22 Exxon Research Engineering Co Isomerization of olefins
US3864424A (en) * 1973-04-30 1975-02-04 Universal Oil Prod Co Isomerization process
US4217244A (en) * 1978-05-11 1980-08-12 Phillips Petroleum Company Regeneration of isomerization catalysts containing magnesium oxide
US4229610A (en) * 1978-11-03 1980-10-21 Phillips Petroleum Company Olefin double bond isomerization
FR2506297B1 (fr) * 1981-05-21 1986-05-02 Inst Francais Du Petrole Procede d'isomerisation d'olefines
IT1190839B (it) * 1982-05-27 1988-02-24 Anic Spa Procedimento per la isomerizzazione di legame delle olefine

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NL8301872A (nl) 1983-12-16
CA1199041A (en) 1986-01-07
FR2527596A1 (fr) 1983-12-02
JPS58219128A (ja) 1983-12-20
AU1453583A (en) 1983-12-01
NZ204340A (en) 1986-01-24
PT76764A (en) 1983-06-01
DK234583D0 (da) 1983-05-25
KR870000055B1 (ko) 1987-02-09
ES523076A0 (es) 1984-10-01
MW2283A1 (en) 1985-02-13
NO831847L (no) 1983-11-28
GR81339B (ko) 1984-12-11
GB2121430B (en) 1986-09-24
ZM3683A1 (en) 1984-01-23
CS244933B2 (en) 1986-08-14
SE8302849L (sv) 1983-11-28
PT76764B (en) 1986-03-27
IT1190839B (it) 1988-02-24
US4814542A (en) 1989-03-21
ZW11283A1 (en) 1983-07-27
DD209801A5 (de) 1984-05-23
ATA192583A (de) 1986-09-15
IN159131B (ko) 1987-03-28
DE3319171C2 (ko) 1989-01-26
ES8500201A1 (es) 1984-10-01
SU1333231A3 (ru) 1987-08-23
GB8313561D0 (en) 1983-06-22
ZA833396B (en) 1984-05-30
AT382864B (de) 1987-04-27
HUT34419A (en) 1985-03-28
YU113083A (en) 1986-02-28
FR2527596B1 (ko) 1985-04-19
PL141424B1 (en) 1987-07-31
PL242214A1 (en) 1984-07-02
IT8221511A0 (it) 1982-05-27
PH17965A (en) 1985-02-22
RO86409A (ro) 1985-03-15
GB2121430A (en) 1983-12-21
AU552806B2 (en) 1986-06-19
DK234583A (da) 1983-11-28
DE3319171A1 (de) 1983-12-01
SE8302849D0 (sv) 1983-05-19
LU84823A1 (fr) 1984-03-07
BE896849A (fr) 1983-11-28
RO86409B (ro) 1985-04-01
IN158661B (ko) 1987-01-03

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