KR830010061A - 페녹시벤조산 유도체의 제조방법 - Google Patents
페녹시벤조산 유도체의 제조방법 Download PDFInfo
- Publication number
- KR830010061A KR830010061A KR1019820001911A KR820001911A KR830010061A KR 830010061 A KR830010061 A KR 830010061A KR 1019820001911 A KR1019820001911 A KR 1019820001911A KR 820001911 A KR820001911 A KR 820001911A KR 830010061 A KR830010061 A KR 830010061A
- Authority
- KR
- South Korea
- Prior art keywords
- carbon atoms
- group
- alkyl group
- halogen atom
- groups
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 6
- PKRSYEPBQPFNRB-UHFFFAOYSA-N 2-phenoxybenzoic acid Chemical class OC(=O)C1=CC=CC=C1OC1=CC=CC=C1 PKRSYEPBQPFNRB-UHFFFAOYSA-N 0.000 title description 2
- 125000000217 alkyl group Chemical group 0.000 claims 7
- 125000004432 carbon atom Chemical group C* 0.000 claims 7
- 125000005843 halogen group Chemical group 0.000 claims 5
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 5
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims 3
- 229910052783 alkali metal Inorganic materials 0.000 claims 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 2
- 125000004093 cyano group Chemical group *C#N 0.000 claims 2
- 238000010438 heat treatment Methods 0.000 claims 2
- 230000007062 hydrolysis Effects 0.000 claims 2
- 238000006460 hydrolysis reaction Methods 0.000 claims 2
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- -1 alkali metal cation Chemical class 0.000 claims 1
- 150000001340 alkali metals Chemical group 0.000 claims 1
- 125000003545 alkoxy group Chemical group 0.000 claims 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 150000001768 cations Chemical class 0.000 claims 1
- 125000001309 chloro group Chemical group Cl* 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 230000032050 esterification Effects 0.000 claims 1
- 238000005886 esterification reaction Methods 0.000 claims 1
- 125000001188 haloalkyl group Chemical group 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 239000003960 organic solvent Substances 0.000 claims 1
- 238000002360 preparation method Methods 0.000 claims 1
- 125000001424 substituent group Chemical group 0.000 claims 1
- 125000000547 substituted alkyl group Chemical group 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
- C07C303/36—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of amides of sulfonic acids
- C07C303/40—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of amides of sulfonic acids by reactions not involving the formation of sulfonamide groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D275/00—Heterocyclic compounds containing 1,2-thiazole or hydrogenated 1,2-thiazole rings
- C07D275/04—Heterocyclic compounds containing 1,2-thiazole or hydrogenated 1,2-thiazole rings condensed with carbocyclic rings or ring systems
- C07D275/06—Heterocyclic compounds containing 1,2-thiazole or hydrogenated 1,2-thiazole rings condensed with carbocyclic rings or ring systems with hetero atoms directly attached to the ring sulfur atom
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
- A01N41/04—Sulfonic acids; Derivatives thereof
- A01N41/06—Sulfonic acid amides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Environmental Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Plant Pathology (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
페녹시벤조산 유도체의 제조방법
Claims (4)
- 하기식(Ⅱ)의 생성물을 가수분해시키고, 만약 적당하다면 이를 산성화시킨 다음, 가수분해 생성물을 에스테르화 시킴을 특징으로 하는 하기식(Ⅰ)의 제조방법.(Ⅰ)여기서, W는 할로겐원자, 니트로 또는 시아노기 또는 수소원자를 나타내고, X는 할로겐원자 또는 할로게노알킬기를 나타내고, Y는 할로겐원자 또는 CF3, CN 또는 NO2기를 나타내고, Z는 할로겐원자 또는 수소원자를 나타내고, R1은 수소원자, 탄소원자수 1∼6의 알킬기, 알칼리금속원자 또는 암모늄기를 나타내고, R2는 COOR7기(여기서, R7은 탄소원자수가 1∼6인 것이 바람직한 알킬기, 수소원자 또는 금속 양이온 또는 암모늄 양이온, 특히 알칼리 금속 양이온임)를 나타내고, R3, R4, R5및 R6은 동일 또는 상이하며, 할로겐 원자, 알킬기(특히, 탄소원자수 1∼6의 알킬기) 또는 수소원자, 시아노, 니트로 또는 CF3기, CO-OR7또는 OR8, 또는 치환된 알킬기(특히, 1개 이상의 염소원자, NO2기 또는 탄소원자수 1∼4의 알콕시기, 또는 탄소원자수 1∼4의 알킬카르복실레이트로 치환된 탄소원자수 1∼4의 알킬기)를 나타내고, R8은 탄소원자수 1∼6의 알킬기를 나타낸다.여기서, 각 치환체는 상기 정의한 바와 같다.
- 제1항에 있어서, 물 및/또는 유기용매존재하 알칼리 매질중에서, 40∼140℃로 가열시킴으로써 가수분해가 수행됨을 특징으로 하는 방법.
- 제2항에 있어서, 가수분해가, 구조식(Ⅱ)화합물 1몰에 대해 1∼3몰의 수산화칼륨 또는 수산화나트륨존재하, 수행됨을 특징으로 하는 방법.
- 제1 내지 3항에 있어서, 에스테르화가, 과량의 알코올 및 산존재하, 40∼120℃로 가열시킴으로써 수행됨을 특징으로 하는 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/259,336 US4447634A (en) | 1981-04-30 | 1981-04-30 | Herbicidal arylsulfonamide derivatives of phenoxybenzoic acids |
| US259336 | 1981-04-30 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR830010061A true KR830010061A (ko) | 1983-12-24 |
Family
ID=22984519
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019820001911A KR830010061A (ko) | 1981-04-30 | 1982-04-30 | 페녹시벤조산 유도체의 제조방법 |
Country Status (25)
| Country | Link |
|---|---|
| US (1) | US4447634A (ko) |
| JP (1) | JPS57185258A (ko) |
| KR (1) | KR830010061A (ko) |
| AU (1) | AU8306282A (ko) |
| BE (1) | BE893028A (ko) |
| BR (1) | BR8202523A (ko) |
| CS (1) | CS228925B2 (ko) |
| DD (1) | DD202088A5 (ko) |
| DE (1) | DE3215991A1 (ko) |
| DK (1) | DK191482A (ko) |
| ES (1) | ES8306717A1 (ko) |
| GB (1) | GB2098207A (ko) |
| GR (1) | GR75424B (ko) |
| IL (1) | IL65628A0 (ko) |
| IT (1) | IT1153498B (ko) |
| LU (1) | LU84116A1 (ko) |
| MA (1) | MA19459A1 (ko) |
| NL (1) | NL8201783A (ko) |
| OA (1) | OA07087A (ko) |
| PL (1) | PL236203A1 (ko) |
| PT (1) | PT74826B (ko) |
| RO (1) | RO83848B (ko) |
| SE (1) | SE8202423L (ko) |
| TR (1) | TR21156A (ko) |
| ZA (1) | ZA822910B (ko) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH658453A5 (fr) * | 1982-12-17 | 1986-11-14 | Rhone Poulenc Agrochimie | Procede pour la preparation d'acides aryloxybenzoiques a groupe sulfonamide. |
| DE4427995A1 (de) * | 1994-08-08 | 1996-02-15 | Basf Ag | Saccharinderivate |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3317540A (en) * | 1964-07-30 | 1967-05-02 | Milimaster Onyx Corp | Microbiocidal quaternary ammonium aromatic sulfonamides |
| US3622626A (en) * | 1968-12-18 | 1971-11-23 | Minnesota Mining & Mfg | N-acylated perfluoroalkanesulfonamides |
| US3641114A (en) * | 1969-06-03 | 1972-02-08 | American Home Prod | 2-lower alkanoyloxy-n-sulfonylbenzamides |
| US3663615A (en) * | 1970-03-02 | 1972-05-16 | Merck & Co Inc | Nuclear sulfamoyl n-organosulfonyl benzamides |
| US3906024A (en) * | 1971-02-24 | 1975-09-16 | Minnesota Mining & Mfg | Perfluoroalkanesulfonamidoaryl compounds |
| US4063929A (en) * | 1973-02-12 | 1977-12-20 | Rohm And Haas Company | Herbicidal 4-trifluoromethyl-4'nitrodiphenyl ethers |
| GR65995B (ko) * | 1978-01-19 | 1981-01-13 | Ici Ltd |
-
1981
- 1981-04-30 US US06/259,336 patent/US4447634A/en not_active Expired - Fee Related
-
1982
- 1982-04-19 SE SE8202423A patent/SE8202423L/xx not_active Application Discontinuation
- 1982-04-22 MA MA19664A patent/MA19459A1/fr unknown
- 1982-04-26 RO RO107369A patent/RO83848B/ro unknown
- 1982-04-27 IL IL65628A patent/IL65628A0/xx unknown
- 1982-04-27 JP JP57071126A patent/JPS57185258A/ja active Pending
- 1982-04-28 PL PL23620382A patent/PL236203A1/xx unknown
- 1982-04-28 LU LU84116A patent/LU84116A1/fr unknown
- 1982-04-28 ZA ZA822910A patent/ZA822910B/xx unknown
- 1982-04-28 DD DD82239384A patent/DD202088A5/de unknown
- 1982-04-28 AU AU83062/82A patent/AU8306282A/en not_active Abandoned
- 1982-04-28 GB GB8212295A patent/GB2098207A/en not_active Withdrawn
- 1982-04-29 TR TR21156A patent/TR21156A/xx unknown
- 1982-04-29 BE BE0/207970A patent/BE893028A/fr not_active IP Right Cessation
- 1982-04-29 GR GR68023A patent/GR75424B/el unknown
- 1982-04-29 DE DE19823215991 patent/DE3215991A1/de not_active Withdrawn
- 1982-04-29 ES ES511809A patent/ES8306717A1/es not_active Expired
- 1982-04-29 DK DK191482A patent/DK191482A/da not_active Application Discontinuation
- 1982-04-29 NL NL8201783A patent/NL8201783A/nl not_active Application Discontinuation
- 1982-04-29 PT PT74826A patent/PT74826B/pt unknown
- 1982-04-30 CS CS823126A patent/CS228925B2/cs unknown
- 1982-04-30 OA OA57673A patent/OA07087A/xx unknown
- 1982-04-30 IT IT21031/82A patent/IT1153498B/it active
- 1982-04-30 KR KR1019820001911A patent/KR830010061A/ko unknown
- 1982-04-30 BR BR8202523A patent/BR8202523A/pt unknown
Also Published As
| Publication number | Publication date |
|---|---|
| ES511809A0 (es) | 1983-06-01 |
| LU84116A1 (fr) | 1984-03-02 |
| GB2098207A (en) | 1982-11-17 |
| BE893028A (fr) | 1982-10-29 |
| CS228925B2 (en) | 1984-05-14 |
| PT74826A (fr) | 1982-05-01 |
| MA19459A1 (fr) | 1982-12-31 |
| IT1153498B (it) | 1987-01-14 |
| US4447634A (en) | 1984-05-08 |
| ZA822910B (en) | 1983-12-28 |
| ES8306717A1 (es) | 1983-06-01 |
| BR8202523A (pt) | 1983-04-19 |
| GR75424B (ko) | 1984-07-17 |
| DD202088A5 (de) | 1983-08-31 |
| RO83848A (ro) | 1984-04-12 |
| IT8221031A0 (it) | 1982-04-30 |
| IL65628A0 (en) | 1982-07-30 |
| JPS57185258A (en) | 1982-11-15 |
| DK191482A (da) | 1982-10-31 |
| RO83848B (ro) | 1984-05-30 |
| AU8306282A (en) | 1982-11-04 |
| PT74826B (fr) | 1985-01-07 |
| NL8201783A (nl) | 1982-11-16 |
| DE3215991A1 (de) | 1982-11-18 |
| OA07087A (fr) | 1984-01-31 |
| SE8202423L (sv) | 1982-10-31 |
| TR21156A (tr) | 1983-11-28 |
| PL236203A1 (en) | 1983-02-28 |
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