KR830006351A - 폴리프로필렌의 제조방법 - Google Patents

폴리프로필렌의 제조방법 Download PDF

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Publication number
KR830006351A
KR830006351A KR1019810002829A KR810002829A KR830006351A KR 830006351 A KR830006351 A KR 830006351A KR 1019810002829 A KR1019810002829 A KR 1019810002829A KR 810002829 A KR810002829 A KR 810002829A KR 830006351 A KR830006351 A KR 830006351A
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KR
South Korea
Prior art keywords
polymerization
producing polypropylene
solvent
organoaluminum
catalyst system
Prior art date
Application number
KR1019810002829A
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English (en)
Other versions
KR840001787B1 (ko
Inventor
스즈끼다께시
Original Assignee
노기 사다오
짓소 가부시끼 가이샤
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by 노기 사다오, 짓소 가부시끼 가이샤 filed Critical 노기 사다오
Publication of KR830006351A publication Critical patent/KR830006351A/ko
Application granted granted Critical
Publication of KR840001787B1 publication Critical patent/KR840001787B1/ko

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04Monomers containing three or four carbon atoms
    • C08F10/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C08F297/08Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

내용 없음

Description

폴리프로필렌의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도, 제2도는 중합용제를 완전 순환하여 사용하는 프로필렌 연속중합 프로세스이며, 도면중의 7은 촉매계를 만드는 교반기가 부착된 반응조, 9는 중합기 15는 후랏 슈드럼, 17은 원심분리기, 23, 38은 사이크론 26은 안정화조, 28은 유동건조기, 30은 스크라버를 나타냄.

Claims (1)

  1. 삼연화티탄 및 유기알루미늄으로 부터 되는 촉매계를 사용하여 프로필렌의 단독중합 혹은 공중합을 행하여, 상기 중합의 슬러리에서 용제불용성 중합체를 제거 분리시킨 용제의 일부 혹은 전량을 정제하지 않고 중합공정에 순환시켜 재사용하여 폴리프로필렌을 제조하는 방법에 있어서, 삼염화티탄 조성물 및 유기알루미늄으로 부터 촉매에 삼염화 티탄 조성물 1g당 0.1g 이상의 프로필렌중합체를 형성시키는 중합전 처리를 실시하여 되는 촉매계를 사용하는것을 특징으로 하는 폴리프로필렌의 제조법.
    ※참고사항:최초출원 내용에 의하여 공개하는 것임.
KR1019810002829A 1980-08-05 1981-08-04 폴리프로필렌의 제조방법 KR840001787B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP10748780A JPS5731910A (en) 1980-08-05 1980-08-05 Production of polypropylene
JP107,487 1980-08-05
JP55-107487 1980-08-05

Publications (2)

Publication Number Publication Date
KR830006351A true KR830006351A (ko) 1983-09-24
KR840001787B1 KR840001787B1 (ko) 1984-10-20

Family

ID=14460454

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019810002829A KR840001787B1 (ko) 1980-08-05 1981-08-04 폴리프로필렌의 제조방법

Country Status (5)

Country Link
JP (1) JPS5731910A (ko)
KR (1) KR840001787B1 (ko)
BE (1) BE889854A (ko)
CS (1) CS235518B2 (ko)
IT (1) IT1143218B (ko)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57172904A (en) * 1981-04-18 1982-10-25 Mitsui Toatsu Chem Inc Production of propylene/ethylene copolymer
JPS6198705A (ja) * 1984-10-20 1986-05-17 Mitsui Petrochem Ind Ltd ポリオレフインの連続的製造法
IN168452B (ko) * 1985-09-18 1991-04-06 Uniroyal Chem Co Inc
JPH0735410B2 (ja) * 1986-01-31 1995-04-19 三菱油化株式会社 オレフィンの立体規則性重合用触媒
ES2157911T3 (es) * 1987-02-02 2001-09-01 Fina Technology Procedimiento para aumentar la eficacia de un catalizador prepolimerizado.

Also Published As

Publication number Publication date
IT1143218B (it) 1986-10-22
JPH0128051B2 (ko) 1989-05-31
JPS5731910A (en) 1982-02-20
KR840001787B1 (ko) 1984-10-20
CS235518B2 (en) 1985-05-15
IT8149044A0 (it) 1981-08-04
BE889854A (fr) 1981-12-01

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