ES8103119A1 - Un metodo para polimerizar continuamente en masa polimezclasque tienen una fase de caucho dienico dispersada en forma departiculas de caucho - Google Patents

Un metodo para polimerizar continuamente en masa polimezclasque tienen una fase de caucho dienico dispersada en forma departiculas de caucho

Info

Publication number
ES8103119A1
ES8103119A1 ES489166A ES489166A ES8103119A1 ES 8103119 A1 ES8103119 A1 ES 8103119A1 ES 489166 A ES489166 A ES 489166A ES 489166 A ES489166 A ES 489166A ES 8103119 A1 ES8103119 A1 ES 8103119A1
Authority
ES
Spain
Prior art keywords
particle size
polyblends
production
polymerization process
mass polymerization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES489166A
Other languages
English (en)
Other versions
ES489166A0 (es
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Monsanto Co
Original Assignee
Monsanto Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Monsanto Co filed Critical Monsanto Co
Publication of ES8103119A1 publication Critical patent/ES8103119A1/es
Publication of ES489166A0 publication Critical patent/ES489166A0/es
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
    • C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Graft Or Block Polymers (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

METODO PARA POLIMERIZAR CONTINUAMENTE EN MASA POLIMEZCLAS QUE TIENEN UNA FASE DE CAUCHO DIENICO DISPERSADA EN FORMA DE PARTICULAS CON UNA DISTRIBUCION POR TAMAÑOS BIMODAL. CONSTA DE LAS SIGUIENTES ETAPAS; PRIMERA, CARGAR CONTINUA Y SIMULTANEAMENTE UNA PRIMERA Y UNA SEGUNDA SOLUCIONES DE MONOMERO-CAUCHO EN UNA PRIMERA ZONA DE REACCION; SEGUNDA, POLIMERIZAR CONTINUAMENTE LA PRIMERA Y SEGUNDA SOLUCIONES BAJO CONDICIONES DE ESTADO ESTABLE HASTA ALCANZAR UNA TRANSFORMACION DE MONOMERO EN POLIMERO DEL 15 AL 50 POR 100, MIENTRAS SE DISPERSAN CONTINUAMENTE EN LA SOLUCION PARCIALMENTE POLIMERIZADA PARTICULAS PROCEDENTES DE LA PRIMERA SOLUCION DE UN TAMAÑO APROXIMADO DE 0,5 A 1 MICRAS Y PARTICULAS PROCEDENTES DE LA SEGUNDA SOLUCION DE UN TAMAÑO APROXIMADO DE 2 A 10 MICRAS; TERCERA, EXTRAER CONTINUAMENTE LA SOLUCION PARCIALMENTE POLIMERIZADA DE LA PRIMERA ZONA DE REACCION Y PASARLA A LA SEGUNDA ZONA DE REACCION DE FLUJO DIRECTO, DONDE SE LA CONTINUA POLIMERIZANDO ADICIONALMENTE HASTA ALCANZAR UNA CONVERSION DE LOS CITADOS MONOMEROS EN POLIMEROS DEL 20 AL 95 POR 100; Y POR ULTIMO, EXTRAER CONTINUAMENTE UN EFLUENTE DE LA SEGUNDA ZONA DE REACCION Y SEPARAR DE DICHO EFLUENTE LA POLIMEZCLA FORMADA. DE USO EN LA PREPARACION DE PLASTICOS MOLDEABLES O EXTRUSIONABLES DE ELEVADA RIGIDEZ. A
ES489166A 1979-03-07 1980-03-04 Un metodo para polimerizar continuamente en masa polimezclasque tienen una fase de caucho dienico dispersada en forma departiculas de caucho Granted ES489166A0 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US06/018,390 US4254236A (en) 1979-03-07 1979-03-07 Process for the continuous mass polymerization of polyblends having a bimodal rubber particle size

Publications (2)

Publication Number Publication Date
ES8103119A1 true ES8103119A1 (es) 1981-02-16
ES489166A0 ES489166A0 (es) 1981-02-16

Family

ID=21787689

Family Applications (1)

Application Number Title Priority Date Filing Date
ES489166A Granted ES489166A0 (es) 1979-03-07 1980-03-04 Un metodo para polimerizar continuamente en masa polimezclasque tienen una fase de caucho dienico dispersada en forma departiculas de caucho

Country Status (9)

Country Link
US (1) US4254236A (es)
EP (1) EP0015752B1 (es)
JP (1) JPS55120616A (es)
AR (1) AR224759A1 (es)
AU (1) AU530676B2 (es)
BR (1) BR8001347A (es)
CA (1) CA1124432A (es)
DE (1) DE3062861D1 (es)
ES (1) ES489166A0 (es)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5919576B2 (ja) * 1979-11-01 1984-05-07 三井東圧化学株式会社 ゴム変性スチレン系樹脂の製造方法
US4417030A (en) * 1981-05-20 1983-11-22 Monsanto Company Mass polymerization process for ABS polyblends
US4385157A (en) * 1981-11-27 1983-05-24 Monsanto Company Emulsion polymerization process for ABS polyblends
US4598124A (en) * 1982-02-12 1986-07-01 Monsanto Company Mass polymerization process for ABS polyblends
US4476283A (en) * 1982-11-12 1984-10-09 Uniroyal, Inc. Graft copolymerization process
NL8304029A (nl) * 1983-11-23 1985-06-17 Dow Chemical Nederland Met rubber versterkte polymeren van monovinylideen-aromatische verbindingen met een zeer goede verhouding tussen glans en sterkteeigenschappen en een werkwijze voor hun bereiding.
AU559998B2 (en) * 1984-02-21 1987-03-26 Dow Chemical Company, The Mineral fiber rubber reinforced resins
AT384430B (de) * 1985-11-27 1987-11-10 Vianova Kunstharz Ag Verfahren zur herstellung von copolymerisaten
IT1230085B (it) * 1989-05-24 1991-10-05 Montedipe Spa Processo per la produzione in massa e in continuo di (co) polimeri vinil aromatici antiurto.
GB8918157D0 (en) * 1989-08-09 1989-09-20 Dow Benelux A process for the preparation of rubber-reinforced monovinylidene aromatic polymers
GB8920574D0 (en) * 1989-09-12 1989-10-25 Dow Benelux Monovinylidene aromatic polymers with improved properties and a process for their preparation
US5264492A (en) * 1989-09-12 1993-11-23 The Dow Chemical Company Monovinylidene aromatic polymers with improved properties
US5166261A (en) * 1990-09-04 1992-11-24 Monsanto Company High gloss ABS made by continuous process
US5414045A (en) * 1993-12-10 1995-05-09 General Electric Company Grafting, phase-inversion and cross-linking controlled multi-stage bulk process for making ABS graft copolymers
DE19631925B4 (de) * 1995-08-10 2004-04-15 Toyoda Gosei Co., Ltd. Formkörper
DE19610931A1 (de) * 1996-03-20 1997-09-25 Bayer Ag Verfahren zur Herstellung von ABS-Formmassen
ES2150239T3 (es) * 1996-04-12 2000-11-16 Dow Chemical Co Procedimiento bimodal simplificado.
CA2391210C (en) 1999-12-23 2010-01-26 Dow Global Technologies Inc. Monovinylidene aromatic polymers with improved properties and a process for their preparation
WO2003011928A1 (en) 2001-08-02 2003-02-13 Dow Global Technologies Inc. Monovinylidene aromatic polymers based on highly linear high molecular weight polybutadiene rubbers and a process for their preparation
KR100671135B1 (ko) * 2004-09-08 2007-01-17 주식회사 엘지화학 고충격 고광택 고무변성 스티렌계 공중합 수지의 제조방법
US11292855B2 (en) 2016-11-08 2022-04-05 Ddp Specialty Electronic Materials Us, Llc Controlled particle size distribution

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA832523A (en) 1970-01-20 A. Walker Dale High impact polystyrene composition containing bimodal rubber particles
US3144420A (en) * 1961-12-18 1964-08-11 Koppers Co Inc High impact polystyrene
GB1047073A (en) * 1964-09-07 1966-11-02 Shell Int Research Improvements in or relating to polymers of monovinylaromatic compounds
US3509237A (en) * 1966-03-21 1970-04-28 Monsanto Co Abs graft polyblends containing two graft polymers having different particle sizes
US3509238A (en) * 1966-03-21 1970-04-28 Monsanto Co Abs graft polyblends containing two graft polymers with different degrees of grafting
US3511895A (en) * 1966-04-01 1970-05-12 Union Carbide Corp Polymerization process and product thereof
FR1542175A (fr) * 1966-11-01 1968-10-11 Shell Int Research Compositions polymères tirées de composés vinylaromatiques et procédé pour leurpréparation
US3945976A (en) * 1968-09-30 1976-03-23 Standard Oil Company Process for producing impact resistant polymer
US3652721A (en) * 1970-07-24 1972-03-28 Monsanto Co Novel graft copolymer blends with two different particle sizes and method of making same
US3660535A (en) * 1970-09-23 1972-05-02 Dow Chemical Co Process for the production of alkenyl aromatic polymers containing a reinforcing polymer therein
US3676527A (en) * 1970-10-26 1972-07-11 Shell Oil Co Process for preparation of high impact polystyrene
US3903202A (en) * 1973-09-19 1975-09-02 Monsanto Co Continuous mass polymerization process for polyblends
US4012462A (en) * 1975-05-15 1977-03-15 Arco Polymers, Inc. High impact graft copolymers
US4146589A (en) * 1978-05-19 1979-03-27 Monsanto Company Method for preparing a monoalkenyl aromatic polyblend having a dispersed rubber phase as particles with a bimodal particle size distribution

Also Published As

Publication number Publication date
JPS55120616A (en) 1980-09-17
EP0015752A3 (en) 1980-11-26
AU530676B2 (en) 1983-07-28
CA1124432A (en) 1982-05-25
DE3062861D1 (en) 1983-06-01
BR8001347A (pt) 1980-11-11
AU5622080A (en) 1980-09-11
EP0015752A2 (en) 1980-09-17
EP0015752B1 (en) 1983-04-27
ES489166A0 (es) 1981-02-16
US4254236A (en) 1981-03-03
AR224759A1 (es) 1982-01-15

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