KR830006163A - 메타아크릴산메틸의 정제방법 - Google Patents
메타아크릴산메틸의 정제방법 Download PDFInfo
- Publication number
- KR830006163A KR830006163A KR1019810002241A KR810002241A KR830006163A KR 830006163 A KR830006163 A KR 830006163A KR 1019810002241 A KR1019810002241 A KR 1019810002241A KR 810002241 A KR810002241 A KR 810002241A KR 830006163 A KR830006163 A KR 830006163A
- Authority
- KR
- South Korea
- Prior art keywords
- distillation column
- methyl methacrylate
- methanol
- methyl
- water
- Prior art date
Links
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 title claims 15
- 238000000034 method Methods 0.000 title claims 6
- 238000000746 purification Methods 0.000 title claims 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims 33
- 238000004821 distillation Methods 0.000 claims 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 12
- 229930195734 saturated hydrocarbon Natural products 0.000 claims 11
- 239000010410 layer Substances 0.000 claims 8
- 239000000203 mixture Substances 0.000 claims 8
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 7
- 125000004432 carbon atom Chemical group C* 0.000 claims 5
- 239000012044 organic layer Substances 0.000 claims 4
- 239000007788 liquid Substances 0.000 claims 2
- 238000000926 separation method Methods 0.000 claims 2
- PKHHQFAULPTXEW-UHFFFAOYSA-N ethane;prop-2-enoic acid Chemical compound CC.OC(=O)C=C PKHHQFAULPTXEW-UHFFFAOYSA-N 0.000 claims 1
- 239000008267 milk Substances 0.000 claims 1
- 210000004080 milk Anatomy 0.000 claims 1
- 235000013336 milk Nutrition 0.000 claims 1
- 150000007523 nucleic acids Chemical class 0.000 claims 1
- 102000039446 nucleic acids Human genes 0.000 claims 1
- 108020004707 nucleic acids Proteins 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
- C07C69/533—Monocarboxylic acid esters having only one carbon-to-carbon double bond
- C07C69/54—Acrylic acid esters; Methacrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/48—Separation; Purification; Stabilisation; Use of additives
- C07C67/52—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
- C07C67/54—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S203/00—Distillation: processes, separatory
- Y10S203/20—Power plant
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S203/00—Distillation: processes, separatory
- Y10S203/22—Accessories
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (6)
- 탄소수 6내지 7의 포화탄화수소가 컬럼에 공급혼합물을 공급한 스테이지 상부에만 전량이 증류하고,상기 포화탄화수소와 메탄올, 포화탄화수소, 메틸이소부티테이트를 증류컬럼의 상부를 통하여 증류하고, 증류컬럼하부로부터 직접 메타크를산메틸을 회수하거나 비닥의 액체를 메타크릴산메틸로 주로 이루어진 유기층과 물로 주로 이루어진 물층으로 분리하고 상기 물층을 분리하여 회수함을 특징으로하여, 메탄올, 메타크릴산메틸, 물 또는 소량의 메틸이소부티테이트를 함유하는 공급혼합물을 증유컬럼에 공급하고, 증류하여 메타크릴산메틸을 정제하는 벙법.
- 메탄올, 메타크릴산메틸, 물을 함유하는 공급혼합물을 증류컬럼에 공급하고, 탄소수 6또는 7의 포화탄화수소를 공급혼합물이 증류컬럼에 공급된 스테이지 상부에만 전량 존재하도록 공급하고 증류컬럼의 상부를 통하여 메탄올 전량과 포화탄화수소를 증류, 그리고 물로서 주로 이루어진 물층과 메타크릴산메틸로서 주로 이루어진 유기층으로 바닥액체를 분리하여 메타크릴산메틸을 회수하고, 상기 물츨을 제거하여 청구범위 제1항에 따른 메타크릴산메틸의 정제방법.
- 메탄올, 메타크릴산메틸, 물, 소량의 메틸이소부티테이트를 함유하는 공급혼합물을 증류컬럼에 공급하고, 탄소수 6 또는 7의 포화탄화수소를 공급혼합물이 증류컬럼에 공급된 스테이지상에만 전량 존재하도록 공급하고, 메타크릴산메틸을 증류컬럼의 하부로부터 직접회수하여, 청구범위 제1항에 따른 메타크릴산메틸의 정제방법.
- 메탄올, 메타크릴산메틸, 물, 소량의 메틸이소부티테이트를 함유하는 공급혼합물을 제1증류컬럼에 공급하고, 탄소수 6 또는 7의 포화탄화수소를 공급혼합물이 증류컬럼에 공급된 스테이지상에만 전량 존재하도록 공급하고, 제1증류컬럼의 상부를 통하여 메탄올전량과 메틸이소부티테이트, 포화탄화수소를 증류하고 물층과 유기층으로 분리한 후 물층을 제거하여 미타크릴산메틸을 회수하여, 청구범위 제1항에 따른 메타크릴산메틸의 정제방법.
- 증류컬럼의 상부로부터의 증류액을 분리용기 내에서 물층과 유기층으로 분리하고, 상기 포화탄화수소층은 증류컬럼에서 환류하고, 상기 메탄올층은 제2증류컬럼에 공급하고, 메틸이소부티테이트와 메탄올의 조합 또는 공급에서 함유된 메탄올량에 상당하는 메탄올량을 제2증류컬럼바닥으로부터 제거하고, 포화탄화수소는 제2증류컬럼의 상부를 통하여 메탄올 일부를 회수하고 상기 분리용기에 재순환시키는 청구범위 제1항에 따른 메탄크릴산메틸의 정제방법.
- 탄소수 6또는 7의 포화탄화수소가 핵산인 청구범위 제1,2,3,4 또는 5항에 따른 메타크릴산메틸의 정제방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP83542 | 1980-06-20 | ||
JP8354380A JPS579740A (en) | 1980-06-20 | 1980-06-20 | Purification of methyl methacrylate |
JP8354280A JPS579739A (en) | 1980-06-20 | 1980-06-20 | Purification of methyl methacrylate |
JP83543 | 1980-06-20 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR830006163A true KR830006163A (ko) | 1983-09-17 |
KR840001899B1 KR840001899B1 (ko) | 1984-10-24 |
Family
ID=26424573
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019810002241A KR840001899B1 (ko) | 1980-06-20 | 1981-06-19 | 메틸 메타아크릴레이트의 정제방법 |
Country Status (4)
Country | Link |
---|---|
US (1) | US4518462A (ko) |
EP (1) | EP0044409B1 (ko) |
KR (1) | KR840001899B1 (ko) |
DE (1) | DE3161884D1 (ko) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20180094935A (ko) * | 2015-12-18 | 2018-08-24 | 롬 앤드 하아스 컴패니 | 메틸 메타크릴레이트의 정제 방법 |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3211901A1 (de) * | 1982-03-31 | 1983-10-13 | Basf Ag, 6700 Ludwigshafen | Verfahren zur abtrennung von methanol aus wasser enthaltenden mischungen von methylmethacrylat und methanol |
DE3211851A1 (de) * | 1982-03-31 | 1983-10-06 | Basf Ag | Dihydrothiophen-carbonester, verfahren zu ihrer herstellung und ihre verwendung zur bekaempfung unerwuenschten pflanzenwuchses |
FR2584711B1 (fr) * | 1985-07-11 | 1987-10-30 | Organo Synthese Ste Fse | Procede de preparation d'esters methacrylique par transesterification |
DE3606121A1 (de) * | 1986-02-26 | 1987-08-27 | Texaco Ag | Verfahren zur kontinuierlichen abtrennung von wasser aus gemischen mit organischen substanzen |
CA2012935A1 (en) * | 1989-03-31 | 1990-09-30 | Hirozo Segawa | Purification and preparation processes for methyl methacrylate |
FR2650587B1 (fr) * | 1989-08-03 | 1991-10-18 | Norsolor Sa | Procede de preparation en continu d'acrylates legers |
EP0571044B1 (en) * | 1992-05-20 | 1997-04-09 | Shell Internationale Researchmaatschappij B.V. | Recovery of carboxylate ester reaction products |
KR930023324A (ko) * | 1992-05-20 | 1993-12-18 | 알베르투스 빌헬무스 요아네스 쩨스트 라텐 | 카르복실산 에스테르 반응 생성물의 회수방법 |
US5435892A (en) * | 1993-08-30 | 1995-07-25 | Mitsubishi Rayon Co., Ltd. | Process for separating methanol and methyl acrylate or methyl methacrylate |
SG71815A1 (en) * | 1997-07-08 | 2000-04-18 | Asahi Chemical Ind | Method of producing methyl methacrylate |
CN107074729B (zh) | 2014-10-31 | 2020-08-04 | 陶氏环球技术有限责任公司 | 分离方法 |
WO2016069198A1 (en) | 2014-10-31 | 2016-05-06 | Dow Global Technologies Llc | Breaking a methanol/methyl methacrylate azeotrope using pressure swing distillation |
TW201739730A (zh) | 2015-12-18 | 2017-11-16 | 陶氏全球科技責任有限公司 | 用於純化甲基丙烯酸甲酯之方法 |
EP3798202A1 (de) | 2019-09-25 | 2021-03-31 | Röhm GmbH | Verfahren zur aufreinigung von methylmethacrylat von leichtsiedenden komponenten |
JP6889322B1 (ja) | 2020-09-30 | 2021-06-18 | 住友化学株式会社 | 組成物 |
CN115819231B (zh) * | 2021-10-31 | 2024-06-25 | 浙江新和成股份有限公司 | 甲基丙烯酸甲酯的制备方法和装置 |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2406561A (en) * | 1943-12-27 | 1946-08-27 | Nasa | Azeotropic distillation of methanol from admixture with acrylic esters |
US2476206A (en) * | 1945-08-04 | 1949-07-12 | Skelly Oil Co | Purification of methanol by azeotropic distillation |
GB668285A (en) * | 1948-02-09 | 1952-03-12 | Goodrich Co B F | Improvements in or relating to method of producing alkyl esters of alpha-beta unsaturated monocarboxylic acids |
US2591877A (en) * | 1948-09-21 | 1952-04-08 | Celanese Corp | Purification of alcohols by azeotropic distillation |
US2581789A (en) * | 1949-04-11 | 1952-01-08 | Nat Distillers Prod Corp | Azeotropic distillation of methanol and acetone with hexane |
US2561680A (en) * | 1949-07-20 | 1951-07-24 | Cities Service Oil Co | Purification of methanol by azeotropic distillation |
US2916512A (en) * | 1953-08-27 | 1959-12-08 | Celanese Corp | Esterification of acrylic acid with methanol |
CH400107A (de) * | 1961-10-11 | 1965-10-15 | Lonza Ag | Verfahren zur Gewinnung von Methanol durch Verseifung von Methylacetat |
DE1296623B (de) * | 1963-05-09 | 1969-06-04 | Wacker Chemie Gbmh | Verfahren zur fortlaufenden oder ansatzweisen Trennung von azeotropen Gemischen aus Estern, aliphatischer, gesaettigter und ungesaettigter Carbonsaeuren |
FR1490688A (fr) * | 1966-06-22 | 1967-08-04 | Melle Usines Sa | Procédé pour séparer les constituants de mélanges azéotropiques de méthanol et d'ester aliphatique inférieur |
JPS51146418A (en) * | 1975-06-10 | 1976-12-16 | Nippon Zeon Co Ltd | Purification of methacrylic esters |
NL7807420A (nl) * | 1977-07-22 | 1979-01-24 | Mitsubishi Chem Ind | Werkwijze voor het afscheiden van methacrylzuur uit een mengsel, dat water, methanol, methacrylzuur en methylmethacrylaat bevat. |
-
1981
- 1981-06-17 EP EP81104673A patent/EP0044409B1/en not_active Expired
- 1981-06-17 DE DE8181104673T patent/DE3161884D1/de not_active Expired
- 1981-06-19 KR KR1019810002241A patent/KR840001899B1/ko active
-
1983
- 1983-05-25 US US06/497,783 patent/US4518462A/en not_active Expired - Lifetime
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20180094935A (ko) * | 2015-12-18 | 2018-08-24 | 롬 앤드 하아스 컴패니 | 메틸 메타크릴레이트의 정제 방법 |
Also Published As
Publication number | Publication date |
---|---|
EP0044409B1 (en) | 1984-01-11 |
US4518462A (en) | 1985-05-21 |
KR840001899B1 (ko) | 1984-10-24 |
DE3161884D1 (en) | 1984-02-16 |
EP0044409A1 (en) | 1982-01-27 |
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