KR830006146A - 방향족 이성체의 흡수 분리방법 - Google Patents
방향족 이성체의 흡수 분리방법 Download PDFInfo
- Publication number
- KR830006146A KR830006146A KR1019810002185A KR810002185A KR830006146A KR 830006146 A KR830006146 A KR 830006146A KR 1019810002185 A KR1019810002185 A KR 1019810002185A KR 810002185 A KR810002185 A KR 810002185A KR 830006146 A KR830006146 A KR 830006146A
- Authority
- KR
- South Korea
- Prior art keywords
- hydrochloride
- alkalamine
- improved process
- absorbent
- zeolite
- Prior art date
Links
- 238000010521 absorption reaction Methods 0.000 title claims 3
- 125000003118 aryl group Chemical group 0.000 title claims 2
- 238000000926 separation method Methods 0.000 title 1
- 238000000034 method Methods 0.000 claims 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims 5
- 230000002745 absorbent Effects 0.000 claims 5
- 239000002250 absorbent Substances 0.000 claims 5
- 239000010457 zeolite Substances 0.000 claims 5
- 229910021536 Zeolite Inorganic materials 0.000 claims 4
- 150000001768 cations Chemical group 0.000 claims 4
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims 4
- -1 amine hydrochloride Chemical class 0.000 claims 2
- XHFGWHUWQXTGAT-UHFFFAOYSA-N dimethylamine hydrochloride Natural products CNC(C)C XHFGWHUWQXTGAT-UHFFFAOYSA-N 0.000 claims 2
- IQDGSYLLQPDQDV-UHFFFAOYSA-N dimethylazanium;chloride Chemical group Cl.CNC IQDGSYLLQPDQDV-UHFFFAOYSA-N 0.000 claims 2
- 239000002798 polar solvent Substances 0.000 claims 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims 1
- 150000001805 chlorine compounds Chemical class 0.000 claims 1
- NQMRYBIKMRVZLB-UHFFFAOYSA-N methylamine hydrochloride Chemical group [Cl-].[NH3+]C NQMRYBIKMRVZLB-UHFFFAOYSA-N 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01R—ELECTRICALLY-CONDUCTIVE CONNECTIONS; STRUCTURAL ASSOCIATIONS OF A PLURALITY OF MUTUALLY-INSULATED ELECTRICAL CONNECTING ELEMENTS; COUPLING DEVICES; CURRENT COLLECTORS
- H01R43/00—Apparatus or processes specially adapted for manufacturing, assembling, maintaining, or repairing of line connectors or current collectors or for joining electric conductors
- H01R43/06—Manufacture of commutators
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/16—Alumino-silicates
- B01J20/18—Synthetic zeolitic molecular sieves
- B01J20/186—Chemical treatments in view of modifying the properties of the sieve, e.g. increasing the stability or the activity, also decreasing the activity
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/12—Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers
- C07C7/13—Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers by molecular-sieve technique
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Water Supply & Treatment (AREA)
- Manufacturing & Machinery (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Treatment Of Liquids With Adsorbents In General (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (9)
- 흡수조건에서 공급물을 파라 이성체를 위해 제올라이트 선택성을 만드는 양이온으로 교환될 수 있는 양이온 부분에서 양이온 교환된 형태 X 또는 형태 Y와 혼합하며, 언급한 흡수제에 의해 파라이성체의 선택성 흡수를 수행하며 알칼아민 클로라이드 또는 알칼아민류로 처리된 제올라이트를 사용하는 개량으로 구성되는 파라이성체를 포함하는 방향족 이성체의 혼합물을 포함하는 공급물로부터 방향족 탄화수소류를 분리하는 공정.
- 알칼 아민 하이드로클로라이드가 메탈아민 하이드로클로라이드인 청구범위 1의 개량된 공정
- 알칼아민 하이드로클로라이드가 디메틸 아민 하이드로클로라이드인 청구범위 1의 공정
- 제올라이트를 극성용매에서 알칼아민 하이드로클로라이드를 용해시켜 알킬아민 하이드로클로라이드로 처리하여 교환용액을 형성하고 교환용액을 흡수제상 통과시키는 것으로 구성되는 청구범위 1의 개량된 공정.
- 알칼아민이 메틸아민 하이드로클로라이드인 청구범위 1의 개량된 공정.
- 알칼아민 디메틸 아민 하이드로클로라이드인 청구범위 1의 개량된 공정.
- 제올라이트를 극성용매에서 알칼아민 또는 이들의 유도체를 용해시켜 교환용액을 형성하고 교환용액을 흡수제상 통과시켜 알칼아민 또는 이들의 유도체로 처리하는 청구범위 1의 개량된 공정.
- 알칼아민 하이드로클로라이드 또는 이들 유도체의 0.004 내지 0.121 당량을 제올라이트에 첨가하는 청구범위 1의 개량된 공정.
- 형태 X 또는 형태 Y 제올라이트를 교환할 수 있는 양이온 부분에서 교환하고 여기에 알칼아민 하이드로클로라이드 또는 이들 유도체의 0.004 내지 0.121 당량을 갖는 흡수제를 첨가하는 것으로 구성되는 흡수제.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US06/160,053 US4283587A (en) | 1980-06-16 | 1980-06-16 | Adsorptive separation of aromatic isomers |
US160053 | 1980-06-16 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR830006146A true KR830006146A (ko) | 1983-09-17 |
KR830002427B1 KR830002427B1 (ko) | 1983-10-26 |
Family
ID=22575318
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019810002185A KR830002427B1 (ko) | 1980-06-16 | 1981-06-16 | 방향족 이성체의 흡착 분리방법 |
Country Status (14)
Country | Link |
---|---|
US (1) | US4283587A (ko) |
EP (1) | EP0042164B1 (ko) |
JP (1) | JPS6043047B2 (ko) |
KR (1) | KR830002427B1 (ko) |
AU (1) | AU537685B2 (ko) |
BR (1) | BR8103791A (ko) |
CA (1) | CA1153745A (ko) |
DE (1) | DE3161883D1 (ko) |
ES (1) | ES503057A0 (ko) |
MX (1) | MX158089A (ko) |
PT (1) | PT73194B (ko) |
RO (1) | RO82404A (ko) |
SU (1) | SU1097191A3 (ko) |
YU (1) | YU42720B (ko) |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4393266A (en) * | 1980-05-23 | 1983-07-12 | Texaco Inc. | Separation of para-xylene |
US4423279A (en) * | 1982-02-25 | 1983-12-27 | Uop Inc. | Separation of bi-alkyl substituted monocyclic aromatic isomers with pyrolyzed adsorbent |
US4778946A (en) * | 1982-09-28 | 1988-10-18 | Exxon Research And Engineering Company | Process for separating ethylbenzene from feedstream containing metaxylene using a zeolite adsorbent |
US4554398A (en) * | 1984-10-29 | 1985-11-19 | Exxon Research & Engineering Co. | Process for the separation of C9 aromatic isomers |
US4593150A (en) * | 1984-11-23 | 1986-06-03 | Exxon Research And Engineering Co. | Process for enhancing the separation of paraxylene from a feedstream containing other xylenes and ethylbenzene using a zeolite adsorbent |
JPS6369335A (ja) * | 1986-09-11 | 1988-03-29 | Nippon Denzai Kogyo Kenkyusho:Kk | 非接触伝送装置 |
US5202516A (en) * | 1987-11-23 | 1993-04-13 | The Dow Chemical Company | Process of recovering monoalkylbenzene and pure 1,3,5-trialkylbenzene from a mixture of dialkyl- and trialkylbenzenes |
CA2428749A1 (en) | 2000-11-16 | 2002-05-23 | Uop Llc | Adsorptive separation process for recovery of para-xylene |
US6627084B2 (en) * | 2001-04-24 | 2003-09-30 | Polymer Ventures, Inc. | Organoclay compositions for purifying contaminated liquids and methods for making and using them |
CN101497022B (zh) * | 2008-01-31 | 2011-06-15 | 中国石油化工股份有限公司 | 聚结型沸石吸附剂及其制备方法 |
US7728187B2 (en) * | 2008-06-30 | 2010-06-01 | Uop Llc | Adsorbent and process for the separation of meta-xylene from aromatic hydrocarbons |
US8704031B2 (en) * | 2010-06-30 | 2014-04-22 | Uop Llc | Adsorptive process for separation of C8 aromatic hydrocarbons |
RU2670962C2 (ru) * | 2014-09-05 | 2018-10-26 | ЭсСиДжи КЕМИКАЛЗ КОМПАНИ ЛИМИТЕД | Способ отделения смеси c8 ароматических соединений |
EP3189023B1 (en) * | 2014-09-05 | 2021-08-04 | SCG Chemicals Company Limited | Process for the enhanced separation of ethylbenzene |
CN112759502B (zh) * | 2019-10-21 | 2023-08-29 | 中国石油化工股份有限公司 | 一种抑制临氢反应体系中芳环损失的方法及其应用与系统 |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2930447A (en) * | 1955-07-29 | 1960-03-29 | Union Carbide Corp | Adsorption process |
NL112918C (ko) * | 1957-08-28 | |||
US3306848A (en) * | 1964-05-27 | 1967-02-28 | Universal Oil Prod Co | Zeolite and zeolite separation process |
US3558732A (en) * | 1969-05-12 | 1971-01-26 | Universal Oil Prod Co | Aromatic hydrocarbon separation by adsorption |
US3804746A (en) * | 1970-04-23 | 1974-04-16 | Mobil Oil Corp | Hydrocarbon conversion using crystalline zeolite zsm-11 catalyst |
US3686342A (en) * | 1970-09-18 | 1972-08-22 | Universal Oil Prod Co | Aromatic hydrocarbon separation by adsorption |
US3855333A (en) * | 1973-03-19 | 1974-12-17 | Universal Oil Prod Co | Adsorptive separation of aromatic isomers with adsorbents containing an alcohol substrate |
US3998901A (en) * | 1975-07-14 | 1976-12-21 | Universal Oil Products Company | Separation of ethylbenzene with an adsorbent comprising sr and k exchanged x or y zeolite |
DD123189A1 (ko) * | 1976-02-04 | 1976-12-05 |
-
1980
- 1980-06-16 US US06/160,053 patent/US4283587A/en not_active Expired - Lifetime
-
1981
- 1981-06-11 CA CA000379542A patent/CA1153745A/en not_active Expired
- 1981-06-13 EP EP81104566A patent/EP0042164B1/en not_active Expired
- 1981-06-13 DE DE8181104566T patent/DE3161883D1/de not_active Expired
- 1981-06-15 BR BR8103791A patent/BR8103791A/pt unknown
- 1981-06-15 SU SU813308437A patent/SU1097191A3/ru active
- 1981-06-15 PT PT73194A patent/PT73194B/pt unknown
- 1981-06-15 ES ES503057A patent/ES503057A0/es active Granted
- 1981-06-15 JP JP56090999A patent/JPS6043047B2/ja not_active Expired
- 1981-06-16 YU YU1518/81A patent/YU42720B/xx unknown
- 1981-06-16 AU AU71875/81A patent/AU537685B2/en not_active Ceased
- 1981-06-16 RO RO81104588A patent/RO82404A/ro unknown
- 1981-06-16 KR KR1019810002185A patent/KR830002427B1/ko active
- 1981-06-16 MX MX187830A patent/MX158089A/es unknown
Also Published As
Publication number | Publication date |
---|---|
RO82404B (ro) | 1983-08-30 |
ES8204610A1 (es) | 1982-05-01 |
ES503057A0 (es) | 1982-05-01 |
YU42720B (en) | 1988-12-31 |
YU151881A (en) | 1983-12-31 |
JPS5762226A (en) | 1982-04-15 |
KR830002427B1 (ko) | 1983-10-26 |
JPS6043047B2 (ja) | 1985-09-26 |
DE3161883D1 (en) | 1984-02-16 |
CA1153745A (en) | 1983-09-13 |
EP0042164A1 (en) | 1981-12-23 |
AU7187581A (en) | 1981-12-24 |
RO82404A (ro) | 1983-09-26 |
PT73194A (en) | 1981-07-01 |
AU537685B2 (en) | 1984-07-05 |
MX158089A (es) | 1989-01-06 |
PT73194B (en) | 1982-07-16 |
US4283587A (en) | 1981-08-11 |
EP0042164B1 (en) | 1984-01-11 |
BR8103791A (pt) | 1982-03-09 |
SU1097191A3 (ru) | 1984-06-07 |
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