KR840007532A - 펠릿형 제올라이트 흡착제에 대한 기체 분리 카이네틱스를 향상시키는 방법 - Google Patents

펠릿형 제올라이트 흡착제에 대한 기체 분리 카이네틱스를 향상시키는 방법 Download PDF

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KR840007532A
KR840007532A KR1019840000652A KR840000652A KR840007532A KR 840007532 A KR840007532 A KR 840007532A KR 1019840000652 A KR1019840000652 A KR 1019840000652A KR 840000652 A KR840000652 A KR 840000652A KR 840007532 A KR840007532 A KR 840007532A
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pelletized
zeolite
adsorbent
acid solution
acid
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KR1019840000652A
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KR870000267B1 (ko
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시르카 쉬바지 (외 2)
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이. 유진 이니스
에어 프로덕츠 앤드 케미칼즈 인코오포레이티드
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B01J20/18—Synthetic zeolitic molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/0462—Temperature swing adsorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/047—Pressure swing adsorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B01J20/18—Synthetic zeolitic molecular sieves
    • B01J20/186—Chemical treatments in view of modifying the properties of the sieve, e.g. increasing the stability or the activity, also decreasing the activity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/106—Silica or silicates
    • B01D2253/108—Zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/0407—Constructional details of adsorbing systems
    • B01D53/0423—Beds in columns
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S95/00—Gas separation: processes
    • Y10S95/90—Solid sorbent
    • Y10S95/902—Molecular sieve

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  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Separation Of Gases By Adsorption (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)

Abstract

내용 없음.

Description

펠릿형 제올라이트 흡착제에 대한 기체 분리 카이네틱스를 향상시키는 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (11)

  1. 0.3N이 넘지 않는 무기산으로 펠릿형 소듐 알루미노실리케이트 제올라이트를 처리하는 것을 특징으로 하는, 기체분리에 사용되는 펠릿형 소듐 알루미노 실리케이트 제올라이트의 동력학적 흡착성을 향상시키는 방법.
  2. 제1항에 있어서, 상기 산은 약 0.1N의 염산인 것을 특징으로 하는 방법.
  3. 제2항에 있어서, 상기 산의 처리방식은 계속적 처리방식인 것을 특징으로 하는 방법.
  4. 제2항에 있어서, 산의 사용량은 1파운드의 흡착제당 0.5-3ℓ인 것을 특징으로 하는 방법.
  5. 제2항에 있어서, 상기 펠릿형 제올라이트는 실질적으로 소듐 모오데나이트로 구성되는 것을 특징으로 하는 방법.
  6. 제1항에 있어서, 상기 펠릿형 제올라이트는 실질적으로 소듐 모오데나이트로 구성되는 것을 특징으로 하는 방법.
  7. 제1항에 있어서, 상기 펠릿형 제올라이트가 13X인 것을 특징으로 하는 방법.
  8. 혼합 기체 성분에 대한 선택적 압력 스윙 흡착 또는 선택적 열적 스윙 흡착에 의해 기체를 분리하는 방법에 있어서, 0.3N이 넘지 않는 묽은 산용액에 세척된 펠릿형 소듐 알루미노실리케이트 제올라이트 흡착제로 구성된 흡착베드에 혼합기체를 통과시키는 것을 특징으로 하는 방법.
  9. 제8항에 있어서, 상기 제올라이트 흡착제는 실질적으로 소듐 모오데나이트로 구성되는 것을 특징으로 하는 방법.
  10. 제8항에 있어서, 상기 산용액은 약 0.1N의 염산 용액인 것을 특징으로 하는 방법.
  11. 제8항에 있어서, 상기 제올라이트 흡착제는 흡착제 1파운당 0.5-3ℓ의 염산용액으로 세척된 흡착제인 것을 특징으로 하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019840000652A 1983-02-11 1984-02-11 펠릿형 제올라이트 흡착제에 대한 기체 분리 카이네틱스를 향상시키는 방법 KR870000267B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US465845 1983-02-11
US06/465,845 US4529416A (en) 1983-02-11 1983-02-11 Gas separation kinetics in commercial pellets

Publications (2)

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KR840007532A true KR840007532A (ko) 1984-12-08
KR870000267B1 KR870000267B1 (ko) 1987-02-23

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US (1) US4529416A (ko)
EP (1) EP0128998B1 (ko)
JP (1) JPS59154136A (ko)
KR (1) KR870000267B1 (ko)
BR (1) BR8400575A (ko)
CA (1) CA1210748A (ko)
DE (1) DE3472218D1 (ko)
ES (2) ES8602538A1 (ko)
MX (1) MX166613B (ko)
ZA (1) ZA84970B (ko)

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ES8607748A1 (es) 1986-06-01
CA1210748A (en) 1986-09-02
JPS59154136A (ja) 1984-09-03
KR870000267B1 (ko) 1987-02-23
ES529627A0 (es) 1985-12-01
DE3472218D1 (en) 1988-07-28
ES544168A0 (es) 1986-06-01
BR8400575A (pt) 1984-09-18
ES8602538A1 (es) 1985-12-01
EP0128998B1 (en) 1988-06-22
EP0128998A3 (en) 1985-04-17
ZA84970B (en) 1985-10-30
US4529416A (en) 1985-07-16
EP0128998A2 (en) 1984-12-27
MX166613B (es) 1993-01-21

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