KR850008100A - 질소 흡착방법 - Google Patents

질소 흡착방법 Download PDF

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Publication number
KR850008100A
KR850008100A KR1019850003603A KR850003603A KR850008100A KR 850008100 A KR850008100 A KR 850008100A KR 1019850003603 A KR1019850003603 A KR 1019850003603A KR 850003603 A KR850003603 A KR 850003603A KR 850008100 A KR850008100 A KR 850008100A
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South Korea
Prior art keywords
polyvalent cation
nitrogen
type
fusersite
mixtures
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KR1019850003603A
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English (en)
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KR890003431B1 (ko
Inventor
제이. 코우(외 1) 챨스
Original Assignee
원본미기재
에어 프로덕츠 앤드 케미칼스 인코오포레이티드
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Publication of KR850008100A publication Critical patent/KR850008100A/ko
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Publication of KR890003431B1 publication Critical patent/KR890003431B1/ko

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/0454—Controlling adsorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B01J20/18—Synthetic zeolitic molecular sieves
    • B01J20/186—Chemical treatments in view of modifying the properties of the sieve, e.g. increasing the stability or the activity, also decreasing the activity
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B13/00—Oxygen; Ozone; Oxides or hydroxides in general
    • C01B13/02—Preparation of oxygen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/106—Silica or silicates
    • B01D2253/108—Zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/106—Silica or silicates
    • B01D2253/108—Zeolites
    • B01D2253/1085—Zeolites characterized by a silicon-aluminium ratio
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/10—Nitrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/12—Oxygen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/10—Single element gases other than halogens
    • B01D2257/102—Nitrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/10—Single element gases other than halogens
    • B01D2257/104—Oxygen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S95/00—Gas separation: processes
    • Y10S95/90—Solid sorbent
    • Y10S95/902—Molecular sieve

Abstract

내용 없음

Description

질소 흡착방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 GC 설택도에 대한 이온교환량의 효과를 도시한 그래프이며,
제2도 및 3도는 본 실시예의 여러 비교실시예와 실시예에 대한 질소등온을 도시한 그래프이며.

Claims (10)

  1. 질소가 함유된 기체를 적어도 50중량퍼센트의 포우저사이트가 함유된 다가 양이온 교환 제올라이트 홈착계와 접촉시키는 단계로 구성되며, 상기 홈착제의 포우저사이트부는 대부분 교환가능한 양이온으로다가 양이온 교환형에 존재하며, 상기 흡착제는 탈수/탈히드록실화 상태에서 다가 이온형이 우세하도록 탈수되는 것을 특징으로 하는 질소를 함유한 기체로부터 질소를 흡착시키는 방법.
  2. 제1항에 있어서, 공기를 질소와 산소로 분리하는 방법.
  3. 제1항에 있어서, 질소를 함유한 기체의 혼합물로부터 질소를 흡착시키는 방법.
  4. 제1항에 있어서, 상기 포우지사이트의 실리콘과 알루미늄의 비는 약 1-2인 것을 특징으로 하는 방법.
  5. 제1항에 있어서, 상기 포우저사이트는 X-형 인것을 특징으로 하는 방법.
  6. 제1항에 있어서, 상기 흡착제는 적어도 75중량퍼센트의 X-형 포우저사이트를 함유하고 있으며, A-형 제올라이트, 불활성 클레이결합제, 기타 불활성 고체물질 및 이것의 혼합물로 구성되는 그룹으로부터 설택된 흡착제인 것을 특징으로 하는 방법.
  7. 제6항에 있어서, 상기 다가 양이온의 칼슘이온인 것을 특징으로 하는 방법.
  8. 제1항에 있어서, 상기 다가 양이온은 2가인 것을 특징으로 하는 방법.
  9. 제1항에 있어서, 상기 다가 양이온 마그네슘, 칼슘, 스트론륨, 바륨 또는 이것의 혼합물로부터 설택되는것을 특징으로 하는 방법.
  10. 제1항에 있어서, 상기 다가 양이온은 칼슘이온인 것을 특징으로 하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019850003603A 1984-05-24 1985-05-24 질소 흡착방법 KR890003431B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US06/614,086 US4544378A (en) 1982-11-15 1984-05-24 Nitrogen adsorption process
US614086 1996-03-12

Publications (2)

Publication Number Publication Date
KR850008100A true KR850008100A (ko) 1985-12-13
KR890003431B1 KR890003431B1 (ko) 1989-09-21

Family

ID=24459806

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019850003603A KR890003431B1 (ko) 1984-05-24 1985-05-24 질소 흡착방법

Country Status (8)

Country Link
US (1) US4544378A (ko)
EP (1) EP0164024A3 (ko)
JP (1) JPS60261524A (ko)
KR (1) KR890003431B1 (ko)
CA (1) CA1297046C (ko)
ES (1) ES8702168A1 (ko)
MX (1) MX165065B (ko)
ZA (1) ZA853887B (ko)

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Also Published As

Publication number Publication date
CA1297046C (en) 1992-03-10
ES543380A0 (es) 1986-12-16
EP0164024A3 (en) 1988-01-07
ES8702168A1 (es) 1986-12-16
JPS60261524A (ja) 1985-12-24
US4544378A (en) 1985-10-01
ZA853887B (en) 1987-01-28
EP0164024A2 (en) 1985-12-11
KR890003431B1 (ko) 1989-09-21
MX165065B (es) 1992-10-20

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