KR830004338A - 플라스티졸용 비닐수지 제조를 위한 현탁 중합공정 - Google Patents

플라스티졸용 비닐수지 제조를 위한 현탁 중합공정 Download PDF

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Publication number
KR830004338A
KR830004338A KR1019800003945A KR800003945A KR830004338A KR 830004338 A KR830004338 A KR 830004338A KR 1019800003945 A KR1019800003945 A KR 1019800003945A KR 800003945 A KR800003945 A KR 800003945A KR 830004338 A KR830004338 A KR 830004338A
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KR
South Korea
Prior art keywords
monomer
rpm
mixture
vinyl chloride
heated
Prior art date
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Pending
Application number
KR1019800003945A
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English (en)
Inventor
니얼 부쉬 찰레스
죠세프 도일리 토마스
Original Assignee
버데인 더블유·벤슨
더 비·에프·굿드리치 캄파니
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Application filed by 버데인 더블유·벤슨, 더 비·에프·굿드리치 캄파니 filed Critical 버데인 더블유·벤슨
Publication of KR830004338A publication Critical patent/KR830004338A/ko
Pending legal-status Critical Current

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Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16D—COUPLINGS FOR TRANSMITTING ROTATION; CLUTCHES; BRAKES
    • F16D13/00—Friction clutches
    • F16D13/58—Details
    • F16D13/70—Pressure members, e.g. pressure plates, for clutch-plates or lamellae; Guiding arrangements for pressure members
    • F16D13/71—Pressure members, e.g. pressure plates, for clutch-plates or lamellae; Guiding arrangements for pressure members in which the clutching pressure is produced by springs only
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/02—Monomers containing chlorine
    • C08F14/04—Monomers containing two carbon atoms
    • C08F14/06—Vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/18—Suspension polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/18—Suspension polymerisation
    • C08F2/20—Suspension polymerisation with the aid of macromolecular dispersing agents

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

내용 없음

Description

플라스티졸용 비닐수지 제조를 위한 현탁 중합공정
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (1)

  1. 예를들면, 염화비닐과 같은 중합될 단량체와 물과 같은 반응매질과, 가수분해도가 약 65 내지 약 85%인 가수분해된 폴리비닐아세테이트(단량체가 염화비닐인 경우는 72.5% 가수분해된 것)등과 같은 폴리비닐알콜 현탁제와 비이온 친수성-친유성 밸런스가 3.5이하인 C12및 C18알콜 혼합물 등과 같은 계면활성제를 포함하는 반응혼합물을 만들고, 이 반응혼합물을 교반해서 혼합물 내에서 현탁된 단량체의 방울을 만든 다음 이 혼합물을 약 30℃ 내지 약 70℃ 범위의 중합반응온도(단량체가 염화비닐인 경우 60℃)까지 가열하고, 이 온도에서 이 혼합물을 약 1분에서 약 60분까지 약 100rpm에서 약 450rpm으로 교반하고, 이 가열되고 교반된 반응혼합물에 기름에 녹는, 자유라디칼을 내는 디(2-에틸헥실) 피옥시디카보 네이트[di(2-ethyl hexyl peroxydicarbonate]와 같은 촉매를 넣고(단량체가 염화비닐인 경우는 라우로일 퍼옥사이드 -lauroyl peroxide), 같은 rpm으로 약 1/4 내지 약 2시간동안 교반하는 첫번째 단계의 반응을 행하고, (단량체가 염화비닐인 경우의 첫번째 단계는 단량체의 중합체에로의 전환율이 10% 때로 잡음), 그리고는 rpm을 두번째 단계의 교반속도인 약 50 내지 약 300rpm으로 낮추고, 이로써 약 10 내지 100미크론의 직경을 가진 치밀한 구형의 유리같은 중합체 입자를 포함하는 물의 슬러리를 만들고, 그 다음에 그슬러리로 부터 그 입자를 회수하는 것으로 이루어진, 비닐이나 비닐리덴 중합체나 이들 서로의 혹은 최소한 하나의 말단기를 가진 하나 또는 그 이상의 비닐리덴 단량체와의 공중합체를 만드는 현탁 중합공정.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019800003945A 1979-10-15 1980-10-14 플라스티졸용 비닐수지 제조를 위한 현탁 중합공정 Pending KR830004338A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US06/084,479 US4404339A (en) 1979-10-15 1979-10-15 Suspension polymerization process for making vinyl resins for use in plastisols
US084,479 1987-08-11

Publications (1)

Publication Number Publication Date
KR830004338A true KR830004338A (ko) 1983-07-09

Family

ID=22185217

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019800003945A Pending KR830004338A (ko) 1979-10-15 1980-10-14 플라스티졸용 비닐수지 제조를 위한 현탁 중합공정

Country Status (10)

Country Link
US (1) US4404339A (ko)
EP (1) EP0037828A4 (ko)
JP (1) JPS56501322A (ko)
KR (1) KR830004338A (ko)
BR (1) BR8008873A (ko)
ES (1) ES495931A0 (ko)
GR (1) GR70347B (ko)
IT (1) IT1133831B (ko)
NO (1) NO811960L (ko)
WO (1) WO1981001005A1 (ko)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4732954A (en) * 1983-06-23 1988-03-22 Occidental Chemical Corporation Novel polyvinyl chloride suspension polymerization process and product having improved plasticizer absorption
JPH0710892B2 (ja) * 1985-03-08 1995-02-08 鐘淵化学工業株式会社 塩化ビニル系樹脂の製造法
KR100191378B1 (ko) * 1989-09-18 1999-06-15 후루타 다케시 비닐 클로라이드 수지를 제조하기위한 미세현탁중합법
DE69331310T2 (de) * 1992-11-19 2002-08-22 International Business Machines Corp., Armonk Funktionsverteilung im Paketvermittlungsnetz
US5849831A (en) * 1996-04-19 1998-12-15 Kuraray Co., Ltd. Process for producing vinyl resin
JPH10251339A (ja) * 1997-03-17 1998-09-22 Kanegafuchi Chem Ind Co Ltd ペーストブレンド用塩化ビニル系樹脂の製造方法
KR20060125801A (ko) * 2003-12-18 2006-12-06 헌츠만 페트로케미칼 코포레이션 계면활성제로 강화된 신속 방출 농약 과립
US9334344B2 (en) 2010-09-22 2016-05-10 Vinnolit Gmbh & Co. Kg Process for the production of a polyvinyl-chloride (PVC) resin

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2014016C3 (de) * 1970-03-24 1978-05-18 Hoechst Ag, 6000 Frankfurt Verfahren zur Herstellung von Vinylchlorid-Polymerisaten
US4136242A (en) * 1970-05-04 1979-01-23 Shinetsu Chemical Company Method for suspension-polymerizing vinyl chloride
GB1393678A (en) * 1971-06-25 1975-05-07 Bp Chem Int Ltd Polymerisation process
DE2629613C3 (de) * 1976-07-01 1980-12-11 Basf Ag, 6700 Ludwigshafen Verfahren zur Herstellung von Polymerisaten oder Copolymerisaten des Vinylchlorids
DD133096A1 (de) * 1977-09-13 1978-12-06 Martin Jahn Verfahren zur herstellung von homo-und/oder copolymerisaten des vinylchlorids

Also Published As

Publication number Publication date
ES8106917A1 (es) 1981-09-16
NO811960L (no) 1981-06-10
US4404339A (en) 1983-09-13
IT8025082A0 (it) 1980-10-02
EP0037828A1 (en) 1981-10-21
WO1981001005A1 (en) 1981-04-16
GR70347B (ko) 1982-09-23
IT1133831B (it) 1986-07-24
ES495931A0 (es) 1981-09-16
JPS56501322A (ko) 1981-09-17
EP0037828A4 (en) 1981-11-11
BR8008873A (pt) 1981-08-25

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PA0109 Patent application

Patent event code: PA01091R01D

Comment text: Patent Application

Patent event date: 19801014

PG1501 Laying open of application
PE0902 Notice of grounds for rejection

Comment text: Notification of reason for refusal

Patent event date: 19840316

Patent event code: PE09021S01D