KR830004194A - 사이클로헥산으로부터 사이클로헥산올 및 사이클로헥사논 함유 혼합물을 제조하는 방법 - Google Patents
사이클로헥산으로부터 사이클로헥산올 및 사이클로헥사논 함유 혼합물을 제조하는 방법 Download PDFInfo
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- KR830004194A KR830004194A KR1019800003900A KR800003900A KR830004194A KR 830004194 A KR830004194 A KR 830004194A KR 1019800003900 A KR1019800003900 A KR 1019800003900A KR 800003900 A KR800003900 A KR 800003900A KR 830004194 A KR830004194 A KR 830004194A
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- Prior art keywords
- cyclohexane
- benzene ring
- cyclohexanone
- ligand
- cyclohexanol
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C409/00—Peroxy compounds
- C07C409/02—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides
- C07C409/14—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides the carbon atom belonging to a ring other than a six-membered aromatic ring
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
- B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
- B01J31/1815—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
- B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
- B01J31/1825—Ligands comprising condensed ring systems, e.g. acridine, carbazole
- B01J31/183—Ligands comprising condensed ring systems, e.g. acridine, carbazole with more than one complexing nitrogen atom, e.g. phenanthroline
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
- C07C29/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C407/00—Preparation of peroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
- C07C45/53—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition of hydroperoxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
- B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
- B01J2531/0241—Rigid ligands, e.g. extended sp2-carbon frameworks or geminal di- or trisubstitution
- B01J2531/0244—Pincer-type complexes, i.e. consisting of a tridentate skeleton bound to a metal, e.g. by one to three metal-carbon sigma-bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/70—Complexes comprising metals of Group VII (VIIB) as the central metal
- B01J2531/72—Manganese
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/842—Iron
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/845—Cobalt
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/14—The ring being saturated
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
도면 1은 Co(BPI)2에 의한 CHHP 분해 반응시 발생되는 화학발광의 광강도(Ⅰ)를 시간의 함수로 도시한 것이고, 도면 3은 코발트 2-에틸헥사노에이트에 의한 CHHP 분해 반응시 발생되는 화학발광의 광강도(Ⅰ)를 시간의 함수로 도시한 것이고, 도면 5는 Co(BPI)2에 의한 CHHP분해 반응시 CHHP를 나누어 첨가하고 이때 발생되는 화학발광의 광강도(Ⅰ)를 시간의 함수로 도시한 것이고, 도면 7은 코발트 2-에틸 헥사노에이트에 의한 CHHP 분해 반응시 CHHP를 나누어 첨가하고 이때 발생되는 화학발광의 광강도(Ⅰ)를 시간의 함수로 도시한 것이고.
Claims (1)
- 사이클로헥산을 공기산화시켜 사이클로 헥실하이드로 퍼옥 사이드함유반응 혼합물을 제조하고 또 이 사이클로 헥실 하이드로퍼옥사이드를 출발물질 사이클로헥산 존재하에서 분해시켜 사이클로헥산올 및 사이클로헥사논 함유 혼합물을 제조하는 방법중,(1) 산화단계를 다음 구조식을 갖는 적어도 1개의 전이금속착화합물로 주로 구성되는 촉매물질이 촉매량만큼 존재하는 상태에서 사이클로헥산을 약 120 내지 160℃ 온도의 공기와 접촉시켜 진행하게 하고, 또/또는(2) 분해단계를 약 0.1 내지 약 10중량%의 사이클로헥실 하이드로퍼옥사이드와 사이클로헥산 함유 반응혼합물을 약 80°내지 160℃ 온도에서 촉매량 만큼의 촉매물질과 접촉시키며, 경우에 따라서는 산소분자 존재하에서 진행시키는 것을 특징으로 하는 사이클로헥산올 및 사이클로헥사논 함유 혼합물의 제조방법상기 구조식에서1차 리간드는 괄호 내 물질이고,M은 Co, Mn 또는 Fe이며,R1, R2, R3, R4, R5및 R6는 각각 수소, 저급알킬, 저급알콕시알킬, 페닐, 벤질 또는 펜에틸이거나 또는 R1내지 R6까지의 임의의 2개인접구성원은 피리딘 고리로 융해된 벤젠고리의 4개 CH구성체와 결합하고 있고, R7, R8, R9및 R10이 각각 수소, 저급알킬 또는 저급알콕시 알킬 또는 R7내지 R10까지의 임의의 2개 인접 구성원은 이소인돌린 모체의 벤젠고리로 융해된 벤젠고리의 4개 CH 구성체와 결합하고 있으며,X는 보조음이온 리간드이고,n는 1 또는 2이며,P는 0,1 또는 2이고, 또 n+P는 2 또는 3이다. 단 2개의 1차리간드가 있는 경우는 R1내지 R10의 값은 각개 리간드에 대해 다를 수 있으며, 또 2개의 보조음이온 리간드가 있는 경우는 X의 값이 다를 수 있다.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US8364479A | 1979-10-11 | 1979-10-11 | |
US083644 | 1979-10-11 | ||
US184635 | 1980-09-16 | ||
US06/184,635 US4326084A (en) | 1979-10-11 | 1980-09-16 | Process for producing a mixture containing cyclohexanol and cyclohexanone from cyclohexane |
Publications (2)
Publication Number | Publication Date |
---|---|
KR830004194A true KR830004194A (ko) | 1983-07-06 |
KR850000379B1 KR850000379B1 (ko) | 1985-03-23 |
Family
ID=26769541
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019800003900A KR850000379B1 (ko) | 1979-10-11 | 1980-10-11 | 사이클로헥산올 및 사이클로헥사논 함유 혼합물의 제조방법 |
Country Status (8)
Country | Link |
---|---|
US (1) | US4326084A (ko) |
EP (1) | EP0027937B1 (ko) |
JP (1) | JPS56115729A (ko) |
KR (1) | KR850000379B1 (ko) |
BR (1) | BR8006498A (ko) |
CA (1) | CA1137511A (ko) |
DE (1) | DE3062638D1 (ko) |
MX (1) | MX155320A (ko) |
Families Citing this family (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4459427A (en) * | 1981-10-31 | 1984-07-10 | The British Petroleum Company P.L.C. | Process for the conversion of an alkane to a mixture of an alcohol and a ketone |
DE3222143A1 (de) * | 1982-06-11 | 1983-12-15 | Basf Ag, 6700 Ludwigshafen | Kobalt enthaltende traegerkatalysatoren, deren herstellung und verwendung |
US4499305A (en) * | 1983-04-11 | 1985-02-12 | E. I. Du Pont De Nemours And Company | Process for preparation of cyclohexyl hydroperoxide decomposition catalysts |
US4465861A (en) * | 1983-04-11 | 1984-08-14 | E. I. Du Pont De Nemours And Company | Process for producing a mixture containing cyclohexanol and cyclohexanone |
US4482746A (en) * | 1983-04-11 | 1984-11-13 | E. I. Du Pont De Nemours & Company | Staged catalyst process for cyclohexyl hydroperoxide decomposition |
US4503257A (en) * | 1983-05-18 | 1985-03-05 | E. I. Du Pont De Nemours And Company | Cyclohexyl hydroperoxide decomposition process |
FR2558826B1 (fr) * | 1984-01-31 | 1986-11-28 | Inst Francais Du Petrole | Synthese d'alcool tertio-butylique par oxydation catalytique, en phase liquide de l'isobutane par l'oxygene |
DE3564949D1 (en) * | 1984-01-31 | 1988-10-20 | Inst Francais Du Petrole | Peroxydic metal complexes, their preparation and use in hydrocarbon oxidation reactions to alcohols and/or ketones |
EP0164463B1 (en) * | 1984-06-12 | 1988-05-11 | Sumitomo Chemical Company, Limited | Method for producing a mixture containing cycloalkanones and cycloalkanols |
US4568769A (en) * | 1984-06-20 | 1986-02-04 | Sumitomo Chemical Company | Method for producing a mixture containing cycloalkanones and cycloalkanols |
US4652647A (en) * | 1984-12-26 | 1987-03-24 | Exxon Research And Engineering Company | Aromatic-metal chelate compositions |
US4836912A (en) * | 1985-09-04 | 1989-06-06 | Exxon Research And Engineering Company | Hydroconversion process using aromatic metal chelate compositions |
FR2604998B1 (fr) * | 1986-10-10 | 1989-06-09 | Rhone Poulenc Chimie | Procede de preparation d'un melange renfermant du cyclohexanol et de la cyclohexanone a partir du cyclohexane |
FR2607805B1 (fr) * | 1986-12-05 | 1989-03-24 | Rhone Poulenc Chimie | Procede de preparation d'un melange renfermant du cyclohexanol et de la cyclohexanone a partir du cyclohexane |
NL8802592A (nl) * | 1988-10-21 | 1990-05-16 | Stamicarbon | Werkwijze voor de bereiding van een k/a-mengsel. |
FR2741340B1 (fr) * | 1995-11-16 | 1997-12-26 | Elf Aquitaine | Procede d'oxydation de substrats organiques en presence de complexes metalliques de ligands tetra-, penta- et hexacoordinants et catalyseurs d'oxydation les contenant |
DE69717295T2 (de) * | 1996-09-03 | 2003-07-24 | E.I. Du Pont De Nemours And Co., Wilmington | Verfahren zur zersetzen von hydroperoxiden |
EA002422B1 (ru) | 1997-02-11 | 2002-04-25 | Е.И.Дюпон Де Немур Энд Компани | Способ разложения гидропероксида |
US6160183A (en) * | 1998-02-10 | 2000-12-12 | E. I. Du Pont De Nemours And Company | Direct oxidation of cycloalkanes |
US6693154B2 (en) | 2001-09-06 | 2004-02-17 | Equistar Chemicals, Lp | Transition metal catalysts for olefin polymerization |
WO2003042131A1 (en) * | 2001-11-15 | 2003-05-22 | Stichting Voor De Technische Wetenschappen | Hydrogenation catalyst and catalysed hydrogenation process |
TW591009B (en) * | 2003-02-19 | 2004-06-11 | China Petrochemical Dev Corp | Liquid phase oxidation of cycloalkane compound |
CN1317074C (zh) * | 2003-03-14 | 2007-05-23 | 中国科学院大连化学物理研究所 | 一种锆基复合氧化物催化剂及制备方法和应用 |
US6982040B2 (en) * | 2003-04-16 | 2006-01-03 | Zodiac Pool Care, Inc. | Method and apparatus for purifying water |
CN101462926B (zh) * | 2007-12-19 | 2011-09-07 | 中国科学院大连化学物理研究所 | 一种络合催化分解环己基过氧化氢的方法 |
FR2952055B1 (fr) | 2009-11-05 | 2011-11-11 | Rhodia Operations | Procede de preparation de composes hydroperoxyde d'alkyle |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2851496A (en) * | 1954-07-27 | 1958-09-09 | Du Pont | Preparation of oxidation products of cyclohexane |
US3530185A (en) * | 1966-08-08 | 1970-09-22 | Du Pont | Oxidation process |
FR1547427A (fr) * | 1967-05-26 | 1968-11-29 | Rhone Poulenc Sa | Perfectionnement à la préparation de mélanges cycloalcanols/cycloalcanones |
US3927105A (en) * | 1968-04-08 | 1975-12-16 | Rhone Poulenc Sa | Process for the preparation of mixtures of cycloalkanols and cycloalkanones |
FR2087365A5 (ko) * | 1970-05-15 | 1971-12-31 | Rhone Poulenc Sa | |
GB1347913A (en) * | 1970-06-09 | 1974-02-27 | Basf Ag | Production of cycloalkanols and cycloalkanones |
US3957876A (en) * | 1970-07-31 | 1976-05-18 | E. I. Du Pont De Nemours And Company | Process for the oxidation of cyclohexane |
US3816548A (en) * | 1971-04-27 | 1974-06-11 | Mobil Oil Corp | Catalytic oxidation process for isoparaffin hydrocarbons |
DE2127520A1 (de) * | 1971-06-03 | 1972-12-14 | Badische Anilin- & Soda-Fabrik Ag, 6700 Ludwigshafen | Verfahren zur Herstellung von Cycloalkanol- und Cycloalkanon-Gemischen |
US3987100A (en) * | 1974-04-11 | 1976-10-19 | E. I. Du Pont De Nemours And Company | Cyclohexane oxidation in the presence of binary catalysts |
US4034047A (en) * | 1974-11-18 | 1977-07-05 | Suntech, Inc. | Process for catalytic oxidation of olefins to form hydroperoxides |
US4243551A (en) * | 1978-12-04 | 1981-01-06 | Ashland Oil, Inc. | Catalyst for oxidizing mercaptans and mercaptide compounds and method for preparing |
-
1980
- 1980-09-16 US US06/184,635 patent/US4326084A/en not_active Expired - Lifetime
- 1980-10-09 CA CA000362017A patent/CA1137511A/en not_active Expired
- 1980-10-09 BR BR8006498A patent/BR8006498A/pt unknown
- 1980-10-09 JP JP14066580A patent/JPS56115729A/ja active Granted
- 1980-10-10 EP EP80106169A patent/EP0027937B1/en not_active Expired
- 1980-10-10 DE DE8080106169T patent/DE3062638D1/de not_active Expired
- 1980-10-10 MX MX184290A patent/MX155320A/es unknown
- 1980-10-11 KR KR1019800003900A patent/KR850000379B1/ko active
Also Published As
Publication number | Publication date |
---|---|
BR8006498A (pt) | 1981-04-14 |
JPS56115729A (en) | 1981-09-11 |
CA1137511A (en) | 1982-12-14 |
EP0027937B1 (en) | 1983-04-06 |
DE3062638D1 (en) | 1983-05-11 |
EP0027937A1 (en) | 1981-05-06 |
MX155320A (es) | 1988-02-18 |
JPS6411010B2 (ko) | 1989-02-23 |
KR850000379B1 (ko) | 1985-03-23 |
US4326084A (en) | 1982-04-20 |
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