GB1249218A - Oxidation of secondary and tertiary alkyl aromatic hydrocarbons - Google Patents

Oxidation of secondary and tertiary alkyl aromatic hydrocarbons

Info

Publication number
GB1249218A
GB1249218A GB00837/69A GB1083769A GB1249218A GB 1249218 A GB1249218 A GB 1249218A GB 00837/69 A GB00837/69 A GB 00837/69A GB 1083769 A GB1083769 A GB 1083769A GB 1249218 A GB1249218 A GB 1249218A
Authority
GB
United Kingdom
Prior art keywords
alkyl
oxygen
oxidation
aromatic hydrocarbons
tertiary alkyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB00837/69A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sunoco Inc
Original Assignee
Sun Oil Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sun Oil Co filed Critical Sun Oil Co
Publication of GB1249218A publication Critical patent/GB1249218A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C409/00—Peroxy compounds
    • C07C409/02—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides
    • C07C409/04—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides the carbon atom being acyclic
    • C07C409/08—Compounds containing six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C407/00—Preparation of peroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C409/00—Peroxy compounds
    • C07C409/02—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides
    • C07C409/04—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides the carbon atom being acyclic
    • C07C409/08—Compounds containing six-membered aromatic rings
    • C07C409/10—Cumene hydroperoxide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C409/00—Peroxy compounds
    • C07C409/02—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides
    • C07C409/14—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides the carbon atom belonging to a ring other than a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

Abstract

1,249,218. Organic hydroperoxides. SUN OIL CO. 28 Feb., 1969 [1 March, 1968], No. 10837/69. Heading C2C. Hydrocarbons of the general formula in which R is C 1 -C 6 alkyl, R 1 is H or C 1 -C 6 alkyl or R and R 1 together with the carbon atom to which they are attached form a C 4 -C 7 cycloalkyl ring; and A is a substituted or unsubstituted aryl radical, are oxidized to the corresponding hydroperoxide compounds by treatment with oxygen or an oxygen-containing gas at elevated temperature in the presence of a catalyst comprising a cuprous halide and a heterocyclic amine of aromatic character. Suitable starting materials are, for example, p-diisopropylbenzene, see.-butylbenzene, isopropyl naphthalene, p-cymene and phenyl cyclohexane. Examples are given of the conversion of cumene to cumyl hydroperoxide.
GB00837/69A 1968-03-01 1969-02-28 Oxidation of secondary and tertiary alkyl aromatic hydrocarbons Expired GB1249218A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US70978668A 1968-03-01 1968-03-01

Publications (1)

Publication Number Publication Date
GB1249218A true GB1249218A (en) 1971-10-13

Family

ID=24851300

Family Applications (1)

Application Number Title Priority Date Filing Date
GB00837/69A Expired GB1249218A (en) 1968-03-01 1969-02-28 Oxidation of secondary and tertiary alkyl aromatic hydrocarbons

Country Status (7)

Country Link
JP (1) JPS497148B1 (en)
BE (1) BE729193A (en)
CH (1) CH508581A (en)
DE (1) DE1910258A1 (en)
FR (1) FR2003008A1 (en)
GB (1) GB1249218A (en)
NL (1) NL6903018A (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS52143825U (en) * 1976-04-27 1977-10-31
JPS5572993A (en) * 1978-11-22 1980-06-02 Nichiman Kosan Kk Panel
JPS56168698U (en) * 1981-04-06 1981-12-12

Also Published As

Publication number Publication date
CH508581A (en) 1971-06-15
NL6903018A (en) 1969-09-03
JPS497148B1 (en) 1974-02-19
FR2003008A1 (en) 1969-11-07
BE729193A (en) 1969-08-28
DE1910258A1 (en) 1969-09-25

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