KR830002321A - 결정성 살충성 피레스로이드 대장체 쌍 및 제조방법 - Google Patents

결정성 살충성 피레스로이드 대장체 쌍 및 제조방법 Download PDF

Info

Publication number
KR830002321A
KR830002321A KR1019800002223A KR800002223A KR830002321A KR 830002321 A KR830002321 A KR 830002321A KR 1019800002223 A KR1019800002223 A KR 1019800002223A KR 800002223 A KR800002223 A KR 800002223A KR 830002321 A KR830002321 A KR 830002321A
Authority
KR
South Korea
Prior art keywords
dichloroethenyl
cis
cyano
phenoxyphenyl
methyl
Prior art date
Application number
KR1019800002223A
Other languages
English (en)
Other versions
KR840000184B1 (ko
Inventor
아더 스델츠 릴랜드
Original Assignee
찰스 씨. 휄로우
에프. 엠. 씨코포레이션
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 찰스 씨. 휄로우, 에프. 엠. 씨코포레이션 filed Critical 찰스 씨. 휄로우
Publication of KR830002321A publication Critical patent/KR830002321A/ko
Application granted granted Critical
Publication of KR840000184B1 publication Critical patent/KR840000184B1/ko

Links

Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N31/00Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
    • A01N31/08Oxygen or sulfur directly attached to an aromatic ring system
    • A01N31/14Ethers
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N53/00Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/36Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
    • A01N37/38Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system

Abstract

내용 없음

Description

결정성 살충성 피레스로이드 대장체 쌍 및 제조방법
내용없음

Claims (2)

  1. 대장체 쌍인(S)-(시아노) (3,페녹시페닐)에틸(1R, 시스)-3-(2,2-디클로로에테닐)-2,2,-디메틸사이클로프로판카복실레이트와 (R)-시아노)(3-페녹시페닐) 메틸(1S-시스)-3-(2,2-디클로로에테닐)-2,2-디메틸 사이클로프로판카복실레이트의 실제적 동몰량을 최소한 한 가지의, 배합할 수 있는 농업적으로 무독한 희석제, 담체 또는 보조제와 혼합하여 함유함을 특징으로하는 결정성 살충제 화합물의 살충유효량을 함유하는 살충성 조성물.
  2. 라세미(시아노)(3-페녹시페닐) 메틸(시스)-3-(2,2-디클로로에테닐)-2,2-디메틸사이클로프로판카복실레이트를 5내지 8개의 탄소원자를 가지는 지방족 또는 환상지방족 탄화수소 중에서 선택된 비극성용매 1 내지 10cc/g으로 처리한 뒤 결과로 얻어진 혼합물로부터 얻고자하는 결정성 화합물로 구성된 고체상을 분리함을 특징으로하여 대장체쌍(S)-(시아노)(3-페녹시페닐) 메틸(1R, 시스)-3-(2,2-디클로로에테닐)-2,2-디메틸 사이클로프로판카복실레이트)와 (R)-(시아노)(3-페녹시페닐) 메틸(1S-시스)-3-(2,2-디클로로에테닐)-2,2-디메틸사이클로프로판카복실레이트의 실질적 동몰량을 함유하는 결정성살충성 조성물을 제조하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019800002223A 1979-06-06 1980-06-05 결정성 살충 화합물의 제조방법 KR840000184B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US06/046,147 US4261921A (en) 1979-06-06 1979-06-06 Process for preparation of a crystalline insecticidal pyrethroid enantiomer pair
US46147 1979-06-06

Publications (2)

Publication Number Publication Date
KR830002321A true KR830002321A (ko) 1983-05-28
KR840000184B1 KR840000184B1 (ko) 1984-02-28

Family

ID=21941871

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019800002223A KR840000184B1 (ko) 1979-06-06 1980-06-05 결정성 살충 화합물의 제조방법

Country Status (22)

Country Link
US (1) US4261921A (ko)
EP (1) EP0022382B1 (ko)
JP (1) JPS55164608A (ko)
KR (1) KR840000184B1 (ko)
AR (1) AR240800A1 (ko)
AU (1) AU535625B2 (ko)
BR (2) BR8003509A (ko)
CA (1) CA1145255A (ko)
CY (1) CY1289A (ko)
DD (2) DD151254A5 (ko)
DE (1) DE3066678D1 (ko)
DK (1) DK170469B1 (ko)
EG (1) EG14484A (ko)
HK (1) HK50985A (ko)
HU (1) HU184783B (ko)
IL (1) IL60085A (ko)
IN (1) IN154326B (ko)
MX (1) MX6813E (ko)
OA (1) OA06544A (ko)
SG (1) SG15785G (ko)
SU (2) SU1431661A3 (ko)
TR (1) TR20425A (ko)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5657756A (en) * 1979-10-15 1981-05-20 Sumitomo Chem Co Ltd Preparation of more highly active carboxylic ester
CA1150301A (en) * 1979-11-27 1983-07-19 Michael J. Bull Cyclopropane carboxylic acid ester derivatives
CA1150730A (en) * 1980-04-23 1983-07-26 Michael J. Bull Process for preparing cyclopropane carboxylic acid ester derivatives
CA1162560A (en) 1980-04-23 1984-02-21 Ronald F. Mason Process for preparing cyclopropane carboxylic acid ester derivatives
CA1206483A (en) * 1982-11-11 1986-06-24 Johannes Van Berkel Process for preparing cyclopropane carboxylic acid ester derivatives
CA1275108A (en) * 1985-01-16 1990-10-09 Laszlo Pap Insecticidal composition comprising more than one active ingredients
HU198373B (en) * 1986-01-08 1989-10-30 Chinoin Gyogyszer Es Vegyeszet Artropodicide composition containing trans-cipermetrin isomeres and process for producing the active components
CA1314559C (en) * 1987-06-15 1993-03-16 John Winfrid Ager Conversion of pyrethroid isomers to more active species
JPH0554208U (ja) * 1991-12-24 1993-07-20 ストラパック株式会社 梱包機のバンドリ−ルおよびバンドリ−ルのシャフト
US5439690A (en) * 1993-05-21 1995-08-08 Ecosmart, Inc. Non-hazardous pest control
FR2713954B1 (fr) * 1993-12-22 1996-01-12 Roussel Uclaf Nouveau procédé de préparation d'émulsion ou de suspoémulsion sèche ou extrudée sous forme de granulés et granulés obtenus.
US5840958A (en) * 1996-10-17 1998-11-24 Fmc Corporation 1S to 1R Epimerizations of pyrethroid intermediates

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4024163A (en) * 1972-05-25 1977-05-17 National Research Development Corporation Insecticides
NL178590C (nl) * 1973-08-15 1986-04-16 Nat Res Dev Werkwijze voor het bereiden van een insecticide preparaat; werkwijze voor het bereiden van een synthetisch pyrethroide.
FR2348901A1 (fr) * 1976-04-23 1977-11-18 Roussel Uclaf Procede de transformation d'un ester d'acide chiral d'alcool secondaire alpha-cyane optiquement actif en ester d'acide chiral d'alcool secondaire alpha-cyane racemique
FR2375161A1 (fr) * 1976-04-23 1978-07-21 Roussel Uclaf Procede de transformation d'un ester d'acide chiral d'alcool secondaire a-cyane optiquement actif de structure (r) en ester d'acide chiral d'alcool secondaire a-cyane de structure (s)
FR2382422A2 (fr) * 1977-03-02 1978-09-29 Roussel Uclaf Procede de transformation d'un ester d'acide chiral d'alcool secondaire a-cyane optiquement actif de structure r en ester d'acide chiral d'alcool secondaire a-cyane de structure s
FR2383147A2 (fr) * 1977-03-09 1978-10-06 Roussel Uclaf Procede de transformation d'un ester d'acide chiral d'alcool secondaire a-cyane optiquement actif en ester d'acide chiral d'alcool secondaire a-cyane racemique
DE2713538A1 (de) * 1977-03-26 1978-09-28 Bayer Ag Verfahren zur trennung stereoisomerer cyclischer carbonsaeuren
GB1599876A (en) 1977-06-13 1981-10-07 Shell Int Research Conversion of a stereoisomer into its diastereoisomer
US4308279A (en) * 1979-06-06 1981-12-29 Fmc Corporation Crystalline, insecticidal pyrethroid

Also Published As

Publication number Publication date
AR240800A1 (es) 1991-02-28
IL60085A (en) 1983-07-31
SG15785G (en) 1985-08-16
HK50985A (en) 1985-07-12
JPH0231708B2 (ko) 1990-07-16
MX6813E (es) 1986-08-04
AU535625B2 (en) 1984-03-29
EG14484A (en) 1985-03-31
IL60085A0 (en) 1980-07-31
JPS55164608A (en) 1980-12-22
OA06544A (fr) 1981-07-31
IN154326B (ko) 1984-10-20
EP0022382B1 (en) 1984-02-22
DD156364A5 (de) 1982-08-18
DK241380A (da) 1980-12-07
KR840000184B1 (ko) 1984-02-28
EP0022382A1 (en) 1981-01-14
BR8003509A (pt) 1981-01-05
SU1431661A3 (ru) 1988-10-15
HU184783B (en) 1984-10-29
SU1169529A3 (ru) 1985-07-23
AR240800A2 (es) 1991-02-28
DK170469B1 (da) 1995-09-11
TR20425A (tr) 1981-07-02
US4261921A (en) 1981-04-14
AU5907580A (en) 1980-12-11
DD151254A5 (de) 1981-10-14
CA1145255A (en) 1983-04-26
CY1289A (en) 1985-10-18
BR8003522A (pt) 1981-01-05
DE3066678D1 (en) 1984-03-29

Similar Documents

Publication Publication Date Title
KR830002321A (ko) 결정성 살충성 피레스로이드 대장체 쌍 및 제조방법
Ohno et al. 2‐Arylalkanoates, a new group of synthetic pyrethroid esters not containing cyclopropanecarboxylates
DK0577145T3 (da) Middel eller koncentrat til konservering af træ eller træmaterialer.
DE3372480D1 (en) Insecticidal product and preparation thereof
KR930021062A (ko) 피레트리노이드 함유 신규 살충제 조성물
DK57879A (da) Fremgangsmaade til fremstilling af 3-(2,2,2-trichlorethyl)-2,2-dimethylcyclopropan-1-carboxylater med hoejt indhold af den cis-isomere
ES8609197A1 (es) Procedimiento para preparar esteres de ciclopropano con ac- tividad insecticida
JO1532B1 (en) Converting isotherms of pyrethroid compounds into more effective isomers
NO931281D0 (no) Ny pyretroidblanding
JPS57150607A (en) Insecticidal composition containing 1r,cis-2,2-dimethyl-3-(2,2-dihalovinyl)cyclopropane- 1-carboxylic acid alpha-cyano-3-phenoxybenzyl and other pyrethroid compound-synergistic mixture
KR880002444A (ko) 농약조성물
JPS5324032A (en) Sublimable composition
JPS5538326A (en) Insecticidal composition
FR2442228A1 (fr) Nouveau cyclopropane-carboxylates, sa preparation et insecticides et acaricides a faible toxicite a l'egard des mammiferes et des poissons le contenant
JPS55143951A (en) Racemate of ( )alpha-cyano-3-phenoxybenzyl( )cis-2,2-dimethyl- 3-(2,2,2-trichloroethyl)cyclopropanecarboxylate, its preparation, and insecticide containing it as active component
JPS54132235A (en) Sublimable insecticide
KR830000514A (ko) 살충제 조성물
JPS5583702A (en) Sex attractant of noxious insect of lepidopteron
IL67526A (en) Fluorophenoxybenzyl-2,2-dimethyl-3-oximino-methyl cyclopropane derivatives,their preparation and pesticidal compositions containing them
DE69203526D1 (de) Insektizide bestehenden aus drei Mischungen von Methylendioxylenbenzene und Verfahren zu ihrer Aufbereitung.
JPS55145602A (en) Insecticide carrier
GB2021104A (en) Preparation of a bicyclohexene
JPS574904A (en) Novel insecticidal composition and its preparation
TH44588A (th) สารผสมควบคุมแมลงสาบ
JPS5522635A (en) Insecticide composition