KR20250025684A - 리튬 이온 이차 전지 - Google Patents
리튬 이온 이차 전지 Download PDFInfo
- Publication number
- KR20250025684A KR20250025684A KR1020257001145A KR20257001145A KR20250025684A KR 20250025684 A KR20250025684 A KR 20250025684A KR 1020257001145 A KR1020257001145 A KR 1020257001145A KR 20257001145 A KR20257001145 A KR 20257001145A KR 20250025684 A KR20250025684 A KR 20250025684A
- Authority
- KR
- South Korea
- Prior art keywords
- secondary battery
- positive electrode
- active material
- lithium
- addition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 229910001416 lithium ion Inorganic materials 0.000 title claims abstract description 62
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 title claims abstract description 61
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 72
- 239000002245 particle Substances 0.000 claims abstract description 68
- 239000011777 magnesium Substances 0.000 claims abstract description 58
- 239000003792 electrolyte Substances 0.000 claims abstract description 53
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 52
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 50
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 48
- 239000010439 graphite Substances 0.000 claims abstract description 48
- 239000011856 silicon-based particle Substances 0.000 claims abstract description 44
- 229910000625 lithium cobalt oxide Inorganic materials 0.000 claims abstract description 42
- BFZPBUKRYWOWDV-UHFFFAOYSA-N lithium;oxido(oxo)cobalt Chemical compound [Li+].[O-][Co]=O BFZPBUKRYWOWDV-UHFFFAOYSA-N 0.000 claims abstract description 42
- 239000002344 surface layer Substances 0.000 claims abstract description 33
- 229920000642 polymer Polymers 0.000 claims abstract description 24
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims abstract description 13
- 239000013078 crystal Substances 0.000 claims description 125
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 56
- 238000004458 analytical method Methods 0.000 claims description 35
- 229910052759 nickel Inorganic materials 0.000 claims description 26
- 238000009826 distribution Methods 0.000 claims description 23
- 108010020346 Polyglutamic Acid Proteins 0.000 claims description 22
- 229920002643 polyglutamic acid Polymers 0.000 claims description 22
- 235000002639 sodium chloride Nutrition 0.000 claims description 7
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 6
- 239000011780 sodium chloride Substances 0.000 claims description 6
- IDSMHEZTLOUMLM-UHFFFAOYSA-N [Li].[O].[Co] Chemical compound [Li].[O].[Co] IDSMHEZTLOUMLM-UHFFFAOYSA-N 0.000 claims 2
- 239000007774 positive electrode material Substances 0.000 description 126
- 239000010410 layer Substances 0.000 description 61
- 238000003860 storage Methods 0.000 description 60
- 238000007600 charging Methods 0.000 description 45
- 239000000463 material Substances 0.000 description 42
- -1 lithium hexafluorophosphate Chemical compound 0.000 description 38
- 229910018871 CoO 2 Inorganic materials 0.000 description 34
- 239000011230 binding agent Substances 0.000 description 34
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 34
- 239000007773 negative electrode material Substances 0.000 description 33
- 229910052744 lithium Inorganic materials 0.000 description 30
- 229910017052 cobalt Inorganic materials 0.000 description 29
- 239000010941 cobalt Substances 0.000 description 29
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 28
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- 239000011737 fluorine Substances 0.000 description 28
- 229910052731 fluorine Inorganic materials 0.000 description 28
- 238000002149 energy-dispersive X-ray emission spectroscopy Methods 0.000 description 27
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 26
- 239000000654 additive Substances 0.000 description 26
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 26
- 230000000996 additive effect Effects 0.000 description 25
- 238000000034 method Methods 0.000 description 24
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 23
- 239000006182 cathode active material Substances 0.000 description 23
- 238000001514 detection method Methods 0.000 description 23
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- 239000000203 mixture Substances 0.000 description 18
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- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
- H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
- H01M4/587—Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M2004/021—Physical characteristics, e.g. porosity, surface area
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
- H01M2004/027—Negative electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
- H01M2004/028—Positive electrodes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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| JP2022098089 | 2022-06-17 | ||
| JPJP-P-2022-098089 | 2022-06-17 | ||
| PCT/IB2023/055752 WO2023242670A1 (ja) | 2022-06-17 | 2023-06-05 | リチウムイオン二次電池 |
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| KR (1) | KR20250025684A (https=) |
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| JP2019165005A (ja) | 2018-03-16 | 2019-09-26 | 出光興産株式会社 | 電極及び電池 |
| JP2022070247A (ja) | 2020-10-26 | 2022-05-12 | 株式会社半導体エネルギー研究所 | 二次電池および電子機器 |
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| JP2018081742A (ja) * | 2015-03-24 | 2018-05-24 | 三洋電機株式会社 | 非水電解質二次電池用負極及び非水電解質二次電池 |
| US20180145317A1 (en) * | 2016-11-18 | 2018-05-24 | Semiconductor Energy Laboratory Co., Ltd. | Positive electrode active material, method for manufacturing positive electrode active material, and secondary battery |
| JP7081908B2 (ja) * | 2017-08-07 | 2022-06-07 | 株式会社半導体エネルギー研究所 | リチウムイオン二次電池 |
| US20210005893A1 (en) * | 2018-03-02 | 2021-01-07 | Jong Eun Kim | Cellulose-templated conductive polymer containing binder for active material compositions and lithium ion batteries prepared therefrom |
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- 2023-06-05 KR KR1020257001145A patent/KR20250025684A/ko active Pending
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2019165005A (ja) | 2018-03-16 | 2019-09-26 | 出光興産株式会社 | 電極及び電池 |
| JP2022070247A (ja) | 2020-10-26 | 2022-05-12 | 株式会社半導体エネルギー研究所 | 二次電池および電子機器 |
Non-Patent Citations (1)
| Title |
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| 에다 노부오 2-4 발열의 메커니즘 데이터에서 배우는 Li 이온 전지의 충방전 기술 CQ출판사 2020년 4월 4일 발행 pp.68-72 |
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| WO2023242670A1 (ja) | 2023-12-21 |
| CN119384746A (zh) | 2025-01-28 |
| JPWO2023242670A1 (https=) | 2023-12-21 |
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