KR20250003967A - 개선된 광학적 특성을 갖는 폴리(메트)아크릴레이트 충격 개질제 및 이의 제조 방법 - Google Patents

개선된 광학적 특성을 갖는 폴리(메트)아크릴레이트 충격 개질제 및 이의 제조 방법 Download PDF

Info

Publication number
KR20250003967A
KR20250003967A KR1020247039191A KR20247039191A KR20250003967A KR 20250003967 A KR20250003967 A KR 20250003967A KR 1020247039191 A KR1020247039191 A KR 1020247039191A KR 20247039191 A KR20247039191 A KR 20247039191A KR 20250003967 A KR20250003967 A KR 20250003967A
Authority
KR
South Korea
Prior art keywords
meth
polymer
acrylate
impact modifier
alkyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
KR1020247039191A
Other languages
English (en)
Korean (ko)
Inventor
요하네스 포르홀츠
안-카트린 다너
미하엘 슈나벨
랄프 리히터
Original Assignee
룀 게엠베하
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 룀 게엠베하 filed Critical 룀 게엠베하
Publication of KR20250003967A publication Critical patent/KR20250003967A/ko
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10—Esters
    • C08F20/12—Esters of monohydric alcohols or phenols
    • C08F20/14—Methyl esters, e.g. methyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • C08F265/06—Polymerisation of acrylate or methacrylate esters on to polymers thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/22—Emulsion polymerisation
    • C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
    • C08F2/26—Emulsion polymerisation with the aid of emulsifying agents anionic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F6/00—Post-polymerisation treatments
    • C08F6/008—Treatment of solid polymer wetted by water or organic solvents, e.g. coagulum, filter cakes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F6/00—Post-polymerisation treatments
    • C08F6/14—Treatment of polymer emulsions
    • C08F6/22—Coagulation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/08—Metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/10—Homopolymers or copolymers of methacrylic acid esters
    • C08L33/12—Homopolymers or copolymers of methyl methacrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/08—Metals
    • C08K2003/0812—Aluminium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/08—Metals
    • C08K2003/0818—Alkali metal
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/08—Metals
    • C08K2003/0818—Alkali metal
    • C08K2003/0825—Potassium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/08—Metals
    • C08K2003/0893—Zinc
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/53—Core-shell polymer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Graft Or Block Polymers (AREA)
  • Polymerisation Methods In General (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
KR1020247039191A 2022-04-28 2023-04-25 개선된 광학적 특성을 갖는 폴리(메트)아크릴레이트 충격 개질제 및 이의 제조 방법 Pending KR20250003967A (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP22170493.5 2022-04-28
EP22170493 2022-04-28
PCT/EP2023/060785 WO2023208918A1 (en) 2022-04-28 2023-04-25 Poly(meth)acrylat impact modifier with improved optical properties and method for its production

Publications (1)

Publication Number Publication Date
KR20250003967A true KR20250003967A (ko) 2025-01-07

Family

ID=81392970

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020247039191A Pending KR20250003967A (ko) 2022-04-28 2023-04-25 개선된 광학적 특성을 갖는 폴리(메트)아크릴레이트 충격 개질제 및 이의 제조 방법

Country Status (7)

Country Link
US (1) US20250277067A1 (https=)
EP (1) EP4514863A1 (https=)
JP (1) JP2025514245A (https=)
KR (1) KR20250003967A (https=)
CN (1) CN119137163A (https=)
MX (1) MX2024013111A (https=)
WO (1) WO2023208918A1 (https=)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP4196629B1 (en) * 2020-08-14 2024-07-10 Rohm and Haas Company High acid acrylic or styrene acrylic emulsion copolymer modified urea formaldehyde binders for mineral fibers
WO2022210417A1 (ja) * 2021-03-31 2022-10-06 テクノＵｍｇ株式会社 熱可塑性樹脂組成物、成形品

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4602083A (en) 1985-01-10 1986-07-22 Rohm And Haas Company Coagulation process
DE3842796A1 (de) 1988-12-20 1990-06-21 Roehm Gmbh Klare schlagzaehe acrylat-formmasse
JPH03247603A (ja) 1990-02-26 1991-11-05 Mitsubishi Rayon Co Ltd 重合体ラテックスの凝析方法および粉粒状重合体の製造方法
US5063259A (en) 1990-07-03 1991-11-05 Rohm And Haas Company Clear, impact-resistant plastics
JP2721596B2 (ja) 1990-07-18 1998-03-04 株式会社クラレ アクリル系重合体凝固組成物、その製法およびその成形物
DE4121652A1 (de) 1991-06-29 1993-01-07 Roehm Gmbh Schlagzaeh-modifizierungsmittel
DE4125857A1 (de) 1991-08-03 1993-02-04 Roehm Gmbh Mattierte polymethacrylat-folie
DE4417559A1 (de) 1994-05-19 1995-11-23 Roehm Gmbh Verfahren zum Entwässern einer wasserhaltigen Kunststoffschmelze in einem Doppelschneckenextruder
JP4080076B2 (ja) 1998-10-19 2008-04-23 株式会社クラレ アクリル系重合体凝固物およびその製造方法
DE10042120A1 (de) 2000-08-28 2002-03-14 Roehm Gmbh Verfahren zur Reduzierung des Polymergehalts bei der Entwässerung von Kunststoff/Wasser-Gemischen
DE10043868A1 (de) 2000-09-04 2002-04-04 Roehm Gmbh PMMA Formmassen mit verbesserter Schlagzähigkeit
DE10260089A1 (de) 2002-12-19 2004-07-01 Röhm GmbH & Co. KG Verfahren zur Herstellung von wässrigen Dispersionen
JP2005171141A (ja) 2003-12-12 2005-06-30 Mitsubishi Rayon Co Ltd 多層構造重合体ラテックスおよび多層構造重合体の凝固、回収方法
DE102005062687A1 (de) 2005-12-23 2007-07-05 Röhm Gmbh PMMA-Folie mit besonders hoher Witterungsbeständigkeit und hoher UV-Schutzwirkung
EP2189497B2 (en) 2008-11-21 2018-09-26 Rohm and Haas Company Polymer compositions containing phosphates
EP2657259A1 (de) 2012-04-23 2013-10-30 Bayer MaterialScience AG ABS-Zusammensetzungen mit verbesserter Oberfläche nach Wärme-Feucht-Lagerung
JP6213457B2 (ja) 2013-01-07 2017-10-18 三菱ケミカル株式会社 熱可塑性樹脂粉体およびその製造方法
DE102013214109A1 (de) 2013-07-18 2015-01-22 Bayerische Motoren Werke Aktiengesellschaft Multifunktionaler Motorradheckrahmen
SG11201602803UA (en) 2013-11-20 2016-05-30 Evonik Roehm Gmbh Continuous or semi-continuous freezing coagulation method for aqueous polymer dispersions
JP7202318B2 (ja) 2018-01-29 2023-01-11 株式会社クラレ アクリル系重合体凝固物

Also Published As

Publication number Publication date
CN119137163A (zh) 2024-12-13
WO2023208918A1 (en) 2023-11-02
MX2024013111A (es) 2024-11-08
US20250277067A1 (en) 2025-09-04
EP4514863A1 (en) 2025-03-05
JP2025514245A (ja) 2025-05-02

Similar Documents

Publication Publication Date Title
KR100815995B1 (ko) 저온 및 상온 내충격성과 착색성 및 내후성이 우수한ａｓａ 그라프트 공중합체 및 이를 포함한 열가소성 수지조성물
US5063259A (en) Clear, impact-resistant plastics
CN111303334B (zh) 接枝共聚物、橡胶质聚合物以及它们的制造方法、热塑性树脂组合物和成型品
KR101534378B1 (ko) 열 안정화제 프리 열가소성 수지 조성물 및 그 제조방법
KR20250003967A (ko) 개선된 광학적 특성을 갖는 폴리(메트)아크릴레이트 충격 개질제 및 이의 제조 방법
CN114641530B (zh) 透明热塑性树脂及其制备方法
KR102680228B1 (ko) 투명 열가소성 수지 및 이의 제조방법
CN114502646B (zh) 热塑性树脂及其制备方法
KR20220005964A (ko) 열가소성 수지 및 이의 제조방법
DE102005022632A1 (de) Agglomerisation von Kautschukdispersionen
KR100515592B1 (ko) 열가소성 수지 조성물
JP7342033B2 (ja) 多層構造重合体粒子、それを含む熱可塑性樹脂組成物、成形体及びフィルム
WO2018181897A1 (ja) 多層構造体を含有する樹脂組成物およびその製造方法
KR20180028906A (ko) 열가소성 투명 수지 및 이의 제조방법
EP4554989B1 (de) Verfahren zur herstellung von asa- oder abs-pfropfcopolymeren mit verminderter verfärbung
KR20020047539A (ko) 아크릴계 충격보강제의 제조방법
EP4514861A1 (en) Poly(meth)acrylat impact modifier with reduced metal ion content and method for its production
KR102683556B1 (ko) 투명 열가소성 수지 및 이의 제조방법
JP7455961B2 (ja) 透明熱可塑性樹脂及びその製造方法
EP1698663A1 (en) (meth)acrylic resin composition
DE4439969A1 (de) Matte thermoplastische Formmassen
JP2022528145A (ja) Ａｓａ系樹脂組成物、それを含む成形品及びその成形品の製造方法
JP3142593B2 (ja) 耐候性、耐薬品性及び耐衝撃性に優れた熱可塑性樹脂組成物
KR102869858B1 (ko) 열가소성 공중합체의 제조방법 및 이를 포함하는 열가소성 수지 조성물
JP2019001835A (ja) ビニル重合体粉体、ポリカーボネート樹脂組成物及びその成形体

Legal Events

Date Code Title Description
PA0105 International application

Patent event date: 20241125

Patent event code: PA01051R01D

Comment text: International Patent Application

PG1501 Laying open of application