KR20240029037A - 나트륨 이온 배터리에서 전이 금속 이온을 포획하기 위한 무기 첨가제 - Google Patents

나트륨 이온 배터리에서 전이 금속 이온을 포획하기 위한 무기 첨가제 Download PDF

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Publication number
KR20240029037A
KR20240029037A KR1020247002685A KR20247002685A KR20240029037A KR 20240029037 A KR20240029037 A KR 20240029037A KR 1020247002685 A KR1020247002685 A KR 1020247002685A KR 20247002685 A KR20247002685 A KR 20247002685A KR 20240029037 A KR20240029037 A KR 20240029037A
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South Korea
Prior art keywords
transition metal
metal cation
sodium ion
cathode
ion battery
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Pending
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KR1020247002685A
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English (en)
Korean (ko)
Inventor
마르끄-다비 브레다
플로랑 르끌레르끄
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스페셜티 오퍼레이션스 프랑스
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Publication of KR20240029037A publication Critical patent/KR20240029037A/ko
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/4235—Safety or regulating additives or arrangements in electrodes, separators or electrolyte
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/054—Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566—Liquid materials
    • H01M10/0567—Liquid materials characterised by the additives
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566—Liquid materials
    • H01M10/0568—Liquid materials characterised by the solutes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/24—Alkaline accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/133—Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/136—Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H01M4/587—Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/628—Inhibitors, e.g. gassing inhibitors, corrosion inhibitors
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/027—Negative electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/028—Positive electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0025—Organic electrolyte
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • General Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Cell Separators (AREA)
  • Secondary Cells (AREA)
KR1020247002685A 2021-07-07 2022-07-05 나트륨 이온 배터리에서 전이 금속 이온을 포획하기 위한 무기 첨가제 Pending KR20240029037A (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP21315123.6 2021-07-07
EP21315123 2021-07-07
PCT/EP2022/068498 WO2023280798A1 (en) 2021-07-07 2022-07-05 Inorganic additive to trap transition metal ions in sodium ion batteries

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Publication Number Publication Date
KR20240029037A true KR20240029037A (ko) 2024-03-05

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KR1020247002685A Pending KR20240029037A (ko) 2021-07-07 2022-07-05 나트륨 이온 배터리에서 전이 금속 이온을 포획하기 위한 무기 첨가제

Country Status (6)

Country Link
US (1) US20240322257A1 (enExample)
EP (1) EP4367730A1 (enExample)
JP (1) JP2024528572A (enExample)
KR (1) KR20240029037A (enExample)
CN (1) CN117981116A (enExample)
WO (1) WO2023280798A1 (enExample)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN118851144A (zh) * 2024-06-28 2024-10-29 湖南长远锂科新能源有限公司 一种碳包覆的磷酸焦磷酸铁前驱体材料及其制备方法、应用
CN119812320A (zh) * 2025-03-11 2025-04-11 江苏中兴派能电池有限公司 碳基负极材料及其制备方法、负极及钠离子电池

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CN116969432B (zh) * 2023-09-12 2024-05-17 北京化工大学 无机超离子导体材料及其制备方法和应用、无机固态电解质膜和锂电池
CN117566720B (zh) * 2023-10-30 2025-11-11 桂林理工大学 一种基于zif-8的n掺杂碳改性钠离子电池正极材料氟磷酸钒钠的制备方法与应用
CN119481293A (zh) * 2025-01-08 2025-02-18 宁波容百新能源科技股份有限公司 一种电解液及其制备方法和应用
CN119898754B (zh) * 2025-01-20 2025-09-30 哈尔滨工业大学 一种基于有机磷酸和席夫碱双交联反应制备硬碳负极材料的方法及其在钠电池中的应用

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JP2013089391A (ja) * 2011-10-14 2013-05-13 Kyushu Univ ナトリウムイオン二次電池用の電極活物質
JP2014022321A (ja) * 2012-07-23 2014-02-03 Kaneka Corp 捕捉剤を含む非水電解質二次電池
JP6741390B2 (ja) * 2014-04-25 2020-08-19 住友大阪セメント株式会社 正極材料、ペースト及びナトリウムイオン電池
FR3021045B1 (fr) 2014-05-16 2020-02-21 Solvay Sa Procede de production d'un reactif phosphocalcique, reactif obtenu et son utilisation
JP6384661B2 (ja) * 2014-08-25 2018-09-05 日本電気硝子株式会社 ナトリウムイオン二次電池用正極活物質及びその製造方法
TWI613858B (zh) * 2015-05-26 2018-02-01 Umicore 作為鈉離子電池組陰極材料之鈉錳氧化物的雙價金屬摻雜
US10243241B2 (en) * 2015-12-01 2019-03-26 GM Global Technology Operations LLC Lithium ion battery with transition metal ion traps
WO2018100815A1 (ja) * 2016-12-02 2018-06-07 旭化成株式会社 非水電解質電池用無機粒子及びこれを用いた非水電解質電池
JP6442633B2 (ja) * 2017-05-29 2018-12-19 太平洋セメント株式会社 リチウムイオン二次電池用正極活物質複合体又はナトリウムイオン二次電池用正極活物質複合体、これらを用いた二次電池、並びにこれらの製造方法
CN112512966B (zh) 2018-07-30 2024-02-20 罗地亚经营管理公司 正极组合物
JP2020047456A (ja) * 2018-09-19 2020-03-26 積水化学工業株式会社 二次電池および電解液
JP2020140921A (ja) * 2019-03-01 2020-09-03 三菱自動車工業株式会社 リチウムイオン二次電池
CN112687944A (zh) 2019-10-18 2021-04-20 宁德时代新能源科技股份有限公司 钠离子电池、钠离子电池用正极极片、正极活性材料、电池模块、电池包和装置

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN118851144A (zh) * 2024-06-28 2024-10-29 湖南长远锂科新能源有限公司 一种碳包覆的磷酸焦磷酸铁前驱体材料及其制备方法、应用
CN119812320A (zh) * 2025-03-11 2025-04-11 江苏中兴派能电池有限公司 碳基负极材料及其制备方法、负极及钠离子电池

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Publication number Publication date
US20240322257A1 (en) 2024-09-26
JP2024528572A (ja) 2024-07-30
WO2023280798A1 (en) 2023-01-12
EP4367730A1 (en) 2024-05-15
CN117981116A (zh) 2024-05-03

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