KR20210118204A - 전이 금속 비스(페놀레이트) 착물 및 올레핀 중합을 위한 촉매로서의 이의 용도 - Google Patents

전이 금속 비스(페놀레이트) 착물 및 올레핀 중합을 위한 촉매로서의 이의 용도 Download PDF

Info

Publication number
KR20210118204A
KR20210118204A KR1020217029292A KR20217029292A KR20210118204A KR 20210118204 A KR20210118204 A KR 20210118204A KR 1020217029292 A KR1020217029292 A KR 1020217029292A KR 20217029292 A KR20217029292 A KR 20217029292A KR 20210118204 A KR20210118204 A KR 20210118204A
Authority
KR
South Korea
Prior art keywords
borate
tetrakis
substituted
hydrocarbyl
group
Prior art date
Application number
KR1020217029292A
Other languages
English (en)
Korean (ko)
Inventor
게오르기 피 고류노프
미카일 아이 사리코프
블라디슬라프 에이 포포브
드미트리 브이 우보르스키
알렉산더 제트 보스코보이니코프
존 알 하가도른
미셸 이 티톤
알렉스 이 카펜터
캐서린 에이 파렐
조 안 엠 카니츠
Original Assignee
엑손모빌 케미칼 패턴츠 인코포레이티드
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 엑손모빌 케미칼 패턴츠 인코포레이티드 filed Critical 엑손모빌 케미칼 패턴츠 인코포레이티드
Publication of KR20210118204A publication Critical patent/KR20210118204A/ko

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/14—Monomers containing five or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/02—Carriers therefor
    • C08F4/022—Magnesium halide as support anhydrous or hydrated or complexed by means of a Lewis base for Ziegler-type catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/64003—Titanium, zirconium, hafnium or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
    • C08F4/64082—Tridentate ligand
    • C08F4/6411—Monoanionic ligand
    • C08F4/64124—ONO
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Pyridine Compounds (AREA)
  • Plural Heterocyclic Compounds (AREA)
KR1020217029292A 2019-02-12 2020-02-11 전이 금속 비스(페놀레이트) 착물 및 올레핀 중합을 위한 촉매로서의 이의 용도 KR20210118204A (ko)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201962804372P 2019-02-12 2019-02-12
US62/804,372 2019-02-12
EP19179811 2019-06-12
EP19179811.5 2019-06-12
PCT/US2020/017736 WO2020167821A1 (fr) 2019-02-12 2020-02-11 Complexes bis(phénolate)-métal de transition et leur utilisation en tant que catalyseurs pour la polymérisation d'oléfines

Publications (1)

Publication Number Publication Date
KR20210118204A true KR20210118204A (ko) 2021-09-29

Family

ID=72045086

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020217029292A KR20210118204A (ko) 2019-02-12 2020-02-11 전이 금속 비스(페놀레이트) 착물 및 올레핀 중합을 위한 촉매로서의 이의 용도

Country Status (6)

Country Link
EP (2) EP3924394A4 (fr)
JP (1) JP7242879B2 (fr)
KR (1) KR20210118204A (fr)
CN (2) CN113423742B (fr)
SG (2) SG11202108252UA (fr)
WO (3) WO2020167821A1 (fr)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116323694A (zh) 2020-09-30 2023-06-23 埃克森美孚化学专利公司 双(杂环-醇盐)路易斯碱催化剂及其方法
EP4232484A1 (fr) * 2020-10-22 2023-08-30 ExxonMobil Chemical Patents Inc. Catalyseurs à base de lewis multidentés et leurs procédés d'utilisation
CN112358498B (zh) * 2020-10-27 2023-03-03 万华化学集团股份有限公司 一种四芳氧基ivb族双核金属配合物及其制备和应用
CN116670188A (zh) 2020-12-29 2023-08-29 埃克森美孚化学专利公司 基于聚烯烃的离子聚合物及其制备
CN115838449B (zh) * 2021-09-18 2024-03-29 中国科学技术大学 金属催化剂及其制备方法、烯烃聚合方法
CN118414360A (zh) 2021-12-17 2024-07-30 埃克森美孚化学专利公司 具有宽的cd和mwd的基于丙烯的共聚物的制备方法
WO2023215694A1 (fr) * 2022-05-04 2023-11-09 Exxonmobil Chemical Patents Inc. Complexes de pyridine-2,6-bis(phénylène-phénolate) substitués présentant une solubilité améliorée, utiles en tant que composants de catalyseur pour la polymérisation d'oléfines
WO2023215695A1 (fr) * 2022-05-04 2023-11-09 Exxonmobil Chemical Patents Inc. Complexes de pyridine-2,6-bis (phénylènephénolate) substitués présentant une solubilité accrue et utiles comme composants de catalyseurs pour la polymérisation des oléfines
WO2023215693A1 (fr) * 2022-05-04 2023-11-09 Exxonmobil Chemical Patents Inc. Complexes de pyridine -2,6-bis (phénylènephénolate) substitués à solubilité améliorée présentant une utilité en tant que composants de catalyseur pour la polymérisation d'oléfines
WO2024167619A1 (fr) 2023-02-08 2024-08-15 ExxonMobil Technology and Engineering Company Catalyseurs pour copolymérisations

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9819847D0 (en) * 1998-09-12 1998-11-04 Bp Chem Int Ltd Novel compounds
US6869904B2 (en) * 2002-04-24 2005-03-22 Symyx Technologies, Inc. Bridged bi-aromatic ligands, catalysts, processes for polymerizing and polymers therefrom
US7847099B2 (en) * 2006-09-21 2010-12-07 California Institute Of Technology Non-metallocene organometallic complexes and related methods and systems
JP5595059B2 (ja) * 2010-02-10 2014-09-24 三井化学株式会社 有機金属ポリオレフィン触媒成分
CN103596686B (zh) * 2011-06-08 2015-08-12 埃克森美孚化学专利公司 包含多种非配位阴离子化活化剂的催化剂体系以及使用其的聚合方法
WO2013048848A2 (fr) * 2011-09-30 2013-04-04 Exxonmobil Chemical Patents Inc. Modulation dynamique de catalyseurs à métallocène
SG11201510689SA (en) * 2013-06-28 2016-01-28 Dow Global Technologies Llc Molecular weight control of polyolefins using halogenated bis-phenylphenoxy catalysts
WO2015088819A1 (fr) * 2013-12-13 2015-06-18 Exxonmobil Chemical Patents Inc. Catalyseurs salan substitués par cyclopentadiényle
US9315526B2 (en) * 2014-03-03 2016-04-19 Exxonmobil Chemical Patents Inc. Pyridyldiamido transition metal complexes, production and use thereof
US9394387B2 (en) * 2014-05-15 2016-07-19 Chevron Phillips Chemical Company Lp Synthesis of aryl coupled bis phenoxides and their use in olefin polymerization catalyst systems with activator-supports
JP2016050175A (ja) * 2014-08-28 2016-04-11 三井化学株式会社 遷移金属化合物、オレフィン多量化用触媒、オレフィン多量化体の製造方法および１−ブテンの製造方法
CN107428782B (zh) * 2015-03-24 2020-06-12 埃克森美孚化学专利公司 双酚盐过渡金属络合物及其制备和用途
US11041029B2 (en) * 2015-08-31 2021-06-22 Exxonmobil Chemical Patents Inc. Aluminum alkyls with pendant olefins for polyolefin reactions
WO2018022238A1 (fr) * 2016-07-28 2018-02-01 Exxonmobile Chemical Patents Inc. Compositions catalytiques et utilisation correspondante
KR102121437B1 (ko) * 2016-08-23 2020-06-10 주식회사 엘지화학 신규한 리간드 화합물 및 이를 포함하는 전이금속 화합물
WO2019027575A1 (fr) * 2017-08-02 2019-02-07 Exxonmobil Chemical Patents Inc. Complexes de métaux de transition bisphénolatés, production et utilisation associées

Also Published As

Publication number Publication date
EP3924395A4 (fr) 2022-06-22
EP3924394A1 (fr) 2021-12-22
JP2022520575A (ja) 2022-03-31
CN113614123B (zh) 2024-01-23
CN113614123A (zh) 2021-11-05
WO2020167799A1 (fr) 2020-08-20
SG11202107809TA (en) 2021-08-30
SG11202108252UA (en) 2021-08-30
CN113423742A (zh) 2021-09-21
EP3924395A1 (fr) 2021-12-22
CN113423742B (zh) 2023-05-05
EP3924394A4 (fr) 2022-06-22
WO2020167821A1 (fr) 2020-08-20
WO2020167824A1 (fr) 2020-08-20
JP7242879B2 (ja) 2023-03-20

Similar Documents

Publication Publication Date Title
US11254763B2 (en) Transition metal bis(phenolate) complexes and their use as catalysts for olefin polymerization
JP7242879B2 (ja) 遷移金属ビス（フェノレート）錯体およびオレフィン重合のための触媒としてのその使用
US11214631B2 (en) (Di)silicon bridged metallocenes that produce polyethylene with broad molecular weight distribution and high molecular weight
US20230348634A1 (en) Propylene Polymers Obtained Using Transition Metal Bis(Phenolate) Catalyst Complexes and Homogeneous Process for Production Thereof
US10807998B2 (en) Bridged bis(indenyl) transitional metal complexes, production, and use thereof
KR20220152225A (ko) 전이 금속 비스(페놀레이트) 촉매 복합체를 사용하여 얻은 폴리에틸렌 조성물 및 그의 균질한 제조 방법
WO2018182860A1 (fr) Procédé de préparation de copolymères d'éthylène en solution
KR102066335B1 (ko) 지지된 촉매 시스템 및 이의 사용 방법
WO2015095188A1 (fr) Complexes de métal de transition bis(indényle) pontés, production et utilisation de ceux-ci
US10927134B2 (en) Bridged phenolate transition metal complexes, production, and uses thereof
EP3755705B1 (fr) Catalyseurs, systèmes de catalyseurs, et procédés d'utilisation associés
US10544244B2 (en) Bridged biphenyl phenol transition metal complexes, production and use thereof
WO2019027572A1 (fr) Complexes métal de transition-biphényl phénol pontés, production et utilisation associées
US20210017303A1 (en) Silyl-Bridged Pyridylamide Catalysts and Methods Thereof
US20230348642A1 (en) Ethylene-Alpha-Olefin-Diene Monomer Copolymers Obtained Using Transition Metal Bis(Phenolate) Catalyst Complexes and Homogeneous Process for Production Thereof
JP2023538006A (ja) 遷移金属ビス（フェノラート）触媒錯体を使用して得られる環含有ポリマー組成物およびその製造方法
WO2021011638A1 (fr) Catalyseurs de pyridylamide à pont silyle et leurs procédés
EP4232484A1 (fr) Catalyseurs à base de lewis multidentés et leurs procédés d'utilisation
WO2020046785A1 (fr) Complexes de métaux de transition de phénolate pontés, production et utilisations associées
WO2018132247A2 (fr) Complexes de métal de transition bis(indényle) pontés, production et utilisation de ceux-ci
EP3568418A2 (fr) Complexes de métal de transition bis(indényle) pontés, production et utilisation de ceux-ci

Legal Events

Date Code Title Description
A201 Request for examination
E902 Notification of reason for refusal
E90F Notification of reason for final refusal