SG11202108252UA - Transition metal bis(phenolate) complexes and their use as catalysts for olefin polymerization - Google Patents

Transition metal bis(phenolate) complexes and their use as catalysts for olefin polymerization

Info

Publication number
SG11202108252UA
SG11202108252UA SG11202108252UA SG11202108252UA SG11202108252UA SG 11202108252U A SG11202108252U A SG 11202108252UA SG 11202108252U A SG11202108252U A SG 11202108252UA SG 11202108252U A SG11202108252U A SG 11202108252UA SG 11202108252U A SG11202108252U A SG 11202108252UA
Authority
SG
Singapore
Prior art keywords
phenolate
complexes
catalysts
transition metal
olefin polymerization
Prior art date
Application number
SG11202108252UA
Inventor
Georgy Goryunov
Mikhail Sharikov
Vladislav Popov
Dmitry Uborsky
Alexander Voskoboynikov
John Hagadorn
Michelle Titone
Alex Carpenter
Catherine Faler
Jo Ann Canich
Original Assignee
Exxonmobil Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxonmobil Chemical Patents Inc filed Critical Exxonmobil Chemical Patents Inc
Publication of SG11202108252UA publication Critical patent/SG11202108252UA/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/14—Monomers containing five or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/02—Carriers therefor
    • C08F4/022—Magnesium halide as support anhydrous or hydrated or complexed by means of a Lewis base for Ziegler-type catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/64003—Titanium, zirconium, hafnium or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
    • C08F4/64082—Tridentate ligand
    • C08F4/6411—Monoanionic ligand
    • C08F4/64124—ONO
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Pyridine Compounds (AREA)
SG11202108252UA 2019-02-12 2020-02-11 Transition metal bis(phenolate) complexes and their use as catalysts for olefin polymerization SG11202108252UA (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201962804372P 2019-02-12 2019-02-12
EP19179811 2019-06-12
PCT/US2020/017736 WO2020167821A1 (en) 2019-02-12 2020-02-11 Transition metal bis(phenolate) complexes and their use as catalysts for olefin polymerization

Publications (1)

Publication Number Publication Date
SG11202108252UA true SG11202108252UA (en) 2021-08-30

Family

ID=72045086

Family Applications (2)

Application Number Title Priority Date Filing Date
SG11202108252UA SG11202108252UA (en) 2019-02-12 2020-02-11 Transition metal bis(phenolate) complexes and their use as catalysts for olefin polymerization
SG11202107809TA SG11202107809TA (en) 2019-02-12 2020-02-11 Bis(aryl phenolate) lewis base catalysts and methods thereof

Family Applications After (1)

Application Number Title Priority Date Filing Date
SG11202107809TA SG11202107809TA (en) 2019-02-12 2020-02-11 Bis(aryl phenolate) lewis base catalysts and methods thereof

Country Status (6)

Country Link
EP (2) EP3924394A4 (en)
JP (1) JP7242879B2 (en)
KR (1) KR20210118204A (en)
CN (2) CN113614123B (en)
SG (2) SG11202108252UA (en)
WO (3) WO2020167821A1 (en)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022072180A1 (en) 2020-09-30 2022-04-07 Exxonmobil Chemical Patents Inc. Bis(heterocyclic-olate) lewis base catalysts and methods thereof
WO2022087121A1 (en) * 2020-10-22 2022-04-28 Exxonmobil Chemical Patents Inc. Multidentate lewis base catalysts and methods for use thereof
CN112358498B (en) * 2020-10-27 2023-03-03 万华化学集团股份有限公司 Tetraaryloxy IVB group binuclear metal complex and preparation and application thereof
US20240084056A1 (en) 2020-12-29 2024-03-14 Exxonmobil Chemical Patents Inc. Polyolefin-Based Ionomers and Production Thereof
CN115838449B (en) * 2021-09-18 2024-03-29 中国科学技术大学 Metal catalyst, preparation method thereof and olefin polymerization method
WO2023114813A1 (en) 2021-12-17 2023-06-22 Exxonmobil Chemical Patents Inc. Processes for making propylene-based copolymers having broad cds and mwds
WO2023215695A1 (en) * 2022-05-04 2023-11-09 Exxonmobil Chemical Patents Inc. Substituted pyridine-2,6-bis (phenylenephenolate) complexes with enhanced solubility that are useful as catalyst components for olefin polymerization
WO2023215693A1 (en) * 2022-05-04 2023-11-09 Exxonmobil Chemical Patents Inc. Substituted pyridine-2,6-bis(phenylenephenolate) complexes with enhanced solubility that are useful as catalyst components for olefin polymerization
WO2023215694A1 (en) * 2022-05-04 2023-11-09 Exxonmobil Chemical Patents Inc. Substituted pyridine-2,6-bis(phenylenephenolate) complexes with enhanced solubility that are useful as catalyst components for olefin polymerization

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9819847D0 (en) 1998-09-12 1998-11-04 Bp Chem Int Ltd Novel compounds
ATE492552T1 (en) * 2002-04-24 2011-01-15 Symyx Solutions Inc BRIDGED BI-AROMATIC LIGANDS, COMPLEXES, CATALYSTS, POLYMERIZATION PROCESSES AND RESULTING POLYMERS
US7847099B2 (en) * 2006-09-21 2010-12-07 California Institute Of Technology Non-metallocene organometallic complexes and related methods and systems
JP5595059B2 (en) 2010-02-10 2014-09-24 三井化学株式会社 Organometallic polyolefin catalyst component
WO2012170202A2 (en) * 2011-06-08 2012-12-13 Exxonmobil Chemical Patents Inc. Catalyst systems comprising multiple non-coordinating anion activators and methods for polymerization therewith
US8969482B2 (en) * 2011-09-30 2015-03-03 Exxonmobil Chemical Patents Inc. Dynamic modulation of metallocene catalysts
EP3925989A1 (en) 2013-06-28 2021-12-22 Dow Global Technologies LLC Molecular weight control of polyolefins using halogenated bis-phenylphenoxy catalysts
US9290589B2 (en) * 2013-12-13 2016-03-22 Exxonmobil Chemical Patents Inc. Cyclopentadienyl-substituted salan catalysts
US9315526B2 (en) * 2014-03-03 2016-04-19 Exxonmobil Chemical Patents Inc. Pyridyldiamido transition metal complexes, production and use thereof
US9394387B2 (en) * 2014-05-15 2016-07-19 Chevron Phillips Chemical Company Lp Synthesis of aryl coupled bis phenoxides and their use in olefin polymerization catalyst systems with activator-supports
JP2016050175A (en) 2014-08-28 2016-04-11 三井化学株式会社 Transition metal compound, catalyst for olefin polymerization, method for producing olefin polymer, and method for producing 1-butene
EP3274353B1 (en) * 2015-03-24 2021-03-31 ExxonMobil Chemical Patents Inc. Bisphenolate transition metal complexes, production and use thereof
WO2017039995A1 (en) * 2015-08-31 2017-03-09 Exxonmobil Chemical Patents Inc. Aluminum alkyls with pendant olefins for polyolefin reactions
WO2018022238A1 (en) * 2016-07-28 2018-02-01 Exxonmobile Chemical Patents Inc. Catalyst compositions and use thereof
KR102121437B1 (en) * 2016-08-23 2020-06-10 주식회사 엘지화학 Novel ligand compound and transition metal compound comprising the same
WO2019027575A1 (en) * 2017-08-02 2019-02-07 Exxonmobil Chemical Patents Inc. Bisphenolate transition metal complexes, production and use thereof

Also Published As

Publication number Publication date
EP3924394A4 (en) 2022-06-22
CN113614123A (en) 2021-11-05
SG11202107809TA (en) 2021-08-30
CN113423742A (en) 2021-09-21
WO2020167799A1 (en) 2020-08-20
EP3924394A1 (en) 2021-12-22
JP2022520575A (en) 2022-03-31
WO2020167824A1 (en) 2020-08-20
KR20210118204A (en) 2021-09-29
CN113423742B (en) 2023-05-05
JP7242879B2 (en) 2023-03-20
EP3924395A1 (en) 2021-12-22
CN113614123B (en) 2024-01-23
EP3924395A4 (en) 2022-06-22
WO2020167821A1 (en) 2020-08-20

Similar Documents

Publication Publication Date Title
SG11202108252UA (en) Transition metal bis(phenolate) complexes and their use as catalysts for olefin polymerization
SG10202101020PA (en) Silyl-bridged bis-biphenyl-phenoxy catalysts for olefin polymerization
EP3851462A4 (en) Catalyst for olefin polymerization
EP3865516A4 (en) Transition metal compound for olefin polymerization catalyst, and olefin polymerization catalyst comprising same
GB2502234A (en) Catalyst compositions containing transition metal complexes with thiolate ligands
IL283897A (en) Dimerizing agent regulated immunoreceptor complexes
SG11202112486PA (en) Activated catalyst components for olefin polymerization
IL291743A (en) Dimerizing agent regulated immunoreceptor complexes
WO2015200849A3 (en) Transition metal catalysts for olefin polymerization
IL275572B2 (en) Transition metal compound for olefin polymerization catalyst, and olefin polymerization catalyst including same
SG11201708410UA (en) Bridged bi-aromatic ligands and olefin polymerization catalysts prepared therefrom
SG11202106318PA (en) Biaryl phenoxy group iv transition metal catalysts for olefin polymerization
SG11202103779QA (en) Catalyst component and catalyst for olefin polymerization, and application thereof
SG11201808179SA (en) An olefin polymerization catalyst
PL3770144T3 (en) Continuous hydroformylation process with catalyst substitution
GB202001890D0 (en) Catalyst
EP3553093A4 (en) Transition metal compound for olefin polymerization catalyst, olefin polymerization catalyst comprising same, and polyolefin polymerized using same
ZA201807579B (en) Catalyst for the hydroformylation of olefins, and use thereof
SG11202106115WA (en) Heterocycle-heterocycle-based group iv transition metal catalysts for olefin polymerization
SG11202008654WA (en) Highly soluble bis-borate as binuclear co-catalysts for olefin polymerizations
ZA202105712B (en) Halogen-containing compound and use thereof as catalyst ligand in ethylene oligomerization
EP3708592A4 (en) Transition metal compound for olefin polymerization catalyst, olefin polymerization catalyst comprising same, and polyolefin polymerized using same
EP3553094A4 (en) Transition metal compound for olefin polymerization catalyst, olefin polymerization catalyst comprising same, and polyolefin polymerized using same
SG11202100288UA (en) Bidentate azolylamido metal-ligand complexes and olefin polymerization catalysts
MX2019001574A (en) Propyl-bridged diphosphine ligands for alkoxycarbonylation.