KR20200127545A - Composition of natural hair-dye - Google Patents

Abstract

The present invention relates to a natural hair dye composition. The natural hair dye composition according to the present invention comprises a first agent including an oxidizing dye, an alkalizing agent, and a natural extract, and a second agent used in combination with the first agent and including an oxidizing agent. According to the configuration, the present invention can provide a natural hair dye that is less toxic to the human body, is eco-friendly, and can obtain an excellent hair dyeing effect, natural dyeing color and fastness.

Description

Natural hair dye composition {COMPOSITION OF NATURAL HAIR-DYE}

The present invention relates to a natural hair color composition, and more particularly, to a natural hair color composition that is less toxic to the human body, eco-friendly, excellent hair dyeing effect, natural dyeing color and fastness can be obtained.

In general, hair dyes can be classified into temporary hair dyes, semi-permanent hair dyes, and permanent hair dyes according to the persistence and durability of the color dyed on the hair. Among them, permanent hair dyes are divided into oxidation hair dyes, metal hair dyes, and vegetable hair dyes depending on the dyes used, and most of the hair dyes currently used are oxidation hair dyes using oxidation dyes such as oxide dye precursors and amino compounds.

However, oxidative hair dyes are chemical hair dyes containing synthetic dyes, and when frequently used together with hair damage, rash and contact skin reactions, and vision impairment, they have problems causing leukemia, bladder cancer, uterine cancer, breast cancer, etc., and can be used by pregnant women due to toxicity. There are disadvantages such as occurrence of odor during dyeing.

As a solution to this problem, the development of natural hair dyes that are harmless to the human body and eco-friendly is required. Currently, the oldest representative natural hair dye is Henna, which is harvested from plants native to tropical regions such as the Middle East, India, and has been used to dye human hair for thousands of years. In addition to henna, ink, walnut, indigo, and chamomile are used. As each color, henna is red, walnut is brown, ink is black, indigo is indigo, and chamomile is yellow. Represents a series.

In general, oxidation-type hair dyes exhibit color by mixing the first agent and the second agent to cause an oxidation polymerization reaction between the dyes contained in the first agent. In addition, the melanin pigment in the hair is decomposed by the hydrogen peroxide contained in the second agent to decolorize the hair, thereby brightening the background color of the hair, and a more vivid color can be expressed.

Oxidative dyes are small in size and can enter the cortex layer of the hair, but when a polymer is formed by an oxidation reaction, it becomes difficult to enter the hair. In this way, before the oxidizing dye penetrates into the hair, a polymerization reaction occurs, and when the size of the molecule increases, the dyeability in the hair decreases, and the color persistence after the dyeing decreases.

In order to solve the above problem, methods for improving dyeability and persistence have been proposed through methods such as controlling the reactivity of the dye and allowing it to penetrate well into the hair. Related technologies include Korean Patent Application Publication No. 2006-0033932 "A hair dye composition for oxidation and dyeing of keratin fibers containing molar acid or an ester derivative thereof" and Korean Patent Application No. 10-2007-0123256 "Oxidation containing Obaeja or Narcissus Hair dye for dyeing" and the like.

Accordingly, the inventors of the present invention have studied a method for improving the dyeing property and color persistence of a hair dye, and found that it is effective in improving the dyeing property, improving color persistence, and alleviating hair damage caused by dyeing by preparing a hair dye using natural extracts. Discovered and completed the present invention.

Domestic registered patent No. 10-1625470 (registered on May 24, 2016) Domestic registered patent No. 10-1653642 (registered on August 29, 2016) Domestic registration patent No. 10-0623992 (registered on September 07, 2006)

An object of the present invention is to provide a natural hair dye composition that is less toxic to the human body, is eco-friendly, and can obtain excellent hair dyeing effect, natural dyeing color and fastness.

Various problems to be solved by the present invention are not limited to the problems mentioned above, and other problems that are not mentioned will be clearly understood by those skilled in the art from the following description.

The natural hair dye composition according to the present invention consists of a first agent and a second agent mixed with the first agent and used.

The first agent is purified water (DI Water) 80 to 85 parts by weight, 2-amino-5-nitrophenol 1.5 to 2.5 parts by weight, Polyquaternium-10 1.5 to 2.0 parts by weight, polysorbate 80 ( Polysorbate 80) 1 to 3 parts by weight, Tetrasodium EDTA (EDTA-4Na) 0.02 to 0.04 parts by weight, p-phenylenediamine 0.8 to 1.2 parts by weight, m-aminophenol 1.5 to 2.5 parts by weight, Ethanolamine Thioglycolate 2.2 to 3.2 parts by weight, PEG-60 Castor Oil 1.2 to 1.5 parts by weight, Perfume 0.2 to 0.5 parts by weight, Dimethicone 0.005 to 0.01 parts by weight, 0.3 to 0.9 parts by weight of oleic acid, 3 to 5 parts by weight of polyoxyethylene oliyl ether, 2.5 to 4.5 parts by weight of behenyl alcohol, 0.4 to 0.8 parts by weight of sodium silicate, myristyl alcohol (Myristyl Alcohol) 1 to 3 parts by weight, monoethanolamine 1.1 to 1.3 parts by weight, Cyclodextrin 0.05 to 0.09 parts by weight, Allantoin 0.007 to 0.013 parts by weight, Aloe Extract 0.05 to 0.07 parts by weight Parts, hydroxypropyl chitosan liquid (Hydroxypropyl Chitosan) 0.005 to 0.015 parts by weight, camellia oil 0.1 to 1.3 parts by weight, Eoseongcho extract 1 to 2 parts by weight, and natural plant extract 3 to 7 parts by weight.

The second agent is purified water (DI Water) 75 to 80 parts by weight, hydrogen peroxide 10 to 20 parts by weight, sodium pyrophosphate 0.5 to 1.5 parts by weight, methyl paraben (MP) 0.8 to 1.2 parts by weight, triethanolamine ( Triethanolamine) 0.5 to 1.5 parts by weight, Etidronic Acid 1 to 2 parts by weight, Cetearyl alcohol 1 to 3 parts by weight, Glyceryl Stearate 0.1 to 0.5 parts by weight, Lanolin alcohol ( Lanolin Alcohol) 1.2 to 2.2 parts by weight, perfume (perfume) 0.3 to 0.5 parts by weight, Ceteaeth-20 (Ceteareth-20) 0.15 to 0.35 parts by weight, PEG-120 Methyl Glucose Dioleate 0.25 To 0.45 parts by weight, 0.1 to 0.3 parts by weight of Allantoin, 2 to 4 parts by weight of puer tea extract, and 1 to 2 parts by weight of onion extract.

Details of other embodiments are included in the detailed description.

The present invention can provide a natural hair dye that is less toxic to the human body, is eco-friendly, and can obtain excellent hair dyeing effect, natural dyeing color and fastness.

It will be fully understood that the embodiments of the technical idea of the present invention can provide various effects not specifically mentioned.

Advantages and features of the present invention, and a method of achieving them will become apparent with reference to the embodiments described below in detail. However, the present invention is not limited to the embodiments described herein and may be embodied in other forms. Rather, the embodiments introduced herein are provided so that the disclosed content may be thorough and complete, and the spirit of the present invention may be sufficiently conveyed to those skilled in the art.

The terms used in the present application are only used to describe specific embodiments, and are not intended to limit the present invention. Singular expressions include plural expressions unless the context clearly indicates otherwise.

Unless otherwise defined, all terms including technical or scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which the present invention belongs. Terms such as those defined in a commonly used dictionary should be interpreted as having a meaning consistent with the meaning of the related technology, and should not be interpreted as an ideal or excessively formal meaning unless explicitly defined in this application. Does not.

Hereinafter, a preferred embodiment will be described in detail with respect to the natural hair dye composition according to the present invention.

The natural hair dye composition according to the present invention comprises a first agent including an oxidizing dye, an alkalizing agent, and a natural extract, and a second agent used in combination with the first agent and including an oxidizing agent.

The oxidation dye performs a hair dyeing function, the alkali agent swells the hair so that the oxidation dye penetrates into the hair, and the oxidizing agent oxidizes the first agent to fix the oxidation dye on the hair. Can be done.

In the present invention, the first agent is purified water (DI Water), 2-amino-5-nitrophenol, polyquaternium 10 (Polyquaternium-10), polysorbate 80 (Polysorbate 80), Tetrasodium EDTA (Tetrasodium EDTA) (EDTA-4Na)), p-phenylenediamine, m-aminophenol, ethanolamine thioglycolate, PEG-60 castor oil, perfume, dimethicone (Dimethicone), oleic acid, polyoxyethylene oliyl ether, behenyl alcohol, sodium silicate, myristyl alcohol, monoethanolamine, cyclodextrin, allantoin, aloe extract (Aloe Extract), hydroxypropyl chitosan liquid (Hydroxypropyl Chitosan), camellia oil, Eoseongcho extract, and natural plant extracts.

In addition, in the natural hair dye composition according to the present invention, the first agent is purified water (DI Water) 80 to 85 parts by weight, 2-amino-5-nitrophenol 1.5 to 2.5 parts by weight, polyquaternium 10 (Polyquaternium-10) 1.5 To 2.0 parts by weight, 1 to 3 parts by weight of polysorbate 80, 0.02 to 0.04 parts by weight of Tetrasodium EDTA (EDTA-4Na), 0.8 to 1.2 parts by weight of p-phenylenediamine, 1.5 to 2.5 parts by weight of m-aminophenol, 2.2 to 3.2 parts by weight of ethanolamine thioglycolate, 1.2 to 1.5 parts by weight of PEG-60 Castor Oil, 0.2 to perfume (perfume) To 0.5 parts by weight, dimethicone 0.005 to 0.01 parts by weight, oleic acid 0.3 to 0.9 parts by weight, polyoxyethylene oliyl ether 3 to 5 parts by weight, behenyl alcohol 2.5 to 4.5 parts by weight, sodium Silicate 0.4 to 0.8 parts by weight, Myristyl Alcohol 1 to 3 parts by weight, Monoethanolamine 1.1 to 1.3 parts by weight, Cyclodextrin 0.05 to 0.09 parts by weight, Allantoin 0.007 to 0.013 parts by weight, Aloe Extract 0.05 to 0.07 parts by weight, Hydroxypropyl Chitosan liquid (Hydroxypropyl Chitosan) 0.005 to 0.015 parts by weight, Camellia oil 0.1 to 1.3 parts by weight, Eoseongcho extract 1 to 2 parts by weight and Natural plant extract 3 to 7 parts by weight It may be included in parts by weight.

Camellia seed oil is an oil containing a large amount of unsaturated fatty acids, and the oil rarely evaporates even if left unattended, and its specific gravity is about 0.916, which is similar to water. The main fatty acid component is oleic acid, which accounts for about 90%. It is a yellow, clear oil with a low freezing point of 25℃, and is mainly used as a substitute for hair oil, precision machine oil, and olive oil in medicine.

In the present invention, the camellia oil prepared by the following method may be used as the camellia oil.

First, after preparing high-quality camellia seeds, you can wash them thoroughly in water.

Next, the washed camellia seeds may be immersed in grape juice and rancidity inhibitors. As described above, the camellia oil produced by immersing the camellia seeds in grape juice and rancidity inhibitor can prevent discoloration or rancidity.

The washed camellia seeds can be immersed in a mixture of grape juice and rancidity inhibitor in a ratio of 1:1, and the rancidity inhibitor is mixed with vitamin C and salt solution in a weight ratio of 1:1. Can be manufactured.

The grape juice is good for preventing blood clots and preventing adult diseases such as high blood pressure, arteriosclerosis and heart disease, and can help improve memory, and the salt solution used as the rancidity inhibitor may be a salt solution having a concentration of 1 to 2% by weight, The washed camellia seeds may be immersed in a weight ratio of 100 to 120 parts by weight of a mixture of grape juice and rancidity inhibitor with respect to 100 parts by weight of the washed camellia seeds, and then maintained for 10 to 40 minutes.

Next, the camellia seeds immersed in the mixed solution of the grape juice and rancidity inhibitor may be taken out so that the grape juice and components of the rancidity inhibitor may penetrate into the camellia seeds.

In the above step, by allowing the active ingredient of grape juice and rancidity inhibitor to penetrate to the surface of the camellia seed, it is possible to prevent discoloration or rancidity of the camellia oil produced even after a long period of time. In this step, a mixture of grape juice and rancidity inhibitor The camellia seeds separated from may be stored at a temperature of 35 to 40° C. for 30 to 60 minutes.

Subsequently, the camellia seeds into which the components of the grape juice and rancidity inhibitors have penetrated can be steamed.

The steaming of the camellia seeds can be performed by steaming the camellia seeds into which the grape juice and rancidity inhibitor components are infiltrated with steam for 30 to 60 minutes.If the steaming of the camellia seeds is performed below the above lower limit, sufficient There is a problem in that steaming is not performed, and when the steaming is performed beyond the upper limit range, the difference in effect according to the increase of the steaming time may be insignificant.

Next, the steamed camellia seeds can be dried.

Drying of the steamed camellia seeds can be carried out for 10 to 20 hours at a temperature of 30 to 40°C on the steamed camellia seeds, and mechanical drying using a dryer is used to keep the drying temperature of the camellia seeds constant. Can be.

Next, the dried camellia seeds may be washed with at least one acid of acetic acid or citric acid.

The washing of the dried camellia seeds is effective in improving the flavor and color of camellia oil to be produced through a later fermentation process by washing the surface of the dried camellia seeds with one or more acids of acetic acid or citric acid.

Subsequently, the washed camellia seed may be sprayed with a fermentation broth consisting of a culture broth and lactic acid bacteria.

As the lactic acid bacteria, any one known lactic acid bacteria selected from the group consisting of lactic acid bacteria ( Lactobacillales ), Streptococcus thermophiles , and Bifidobacterium longum may be used, and the culture medium is peptone , Malt extract, sodium citrate, potassium phosphate dibasic, glucose, and distilled water, and the culture solution is 15 to 25 parts by weight of peptone, malt extract 5 to 15 It may be made by mixing in a weight ratio of 0.5 to 1.5 parts by weight of sodium citrate, 0.1 to 0.3 parts by weight of dibasic potassium phosphate, 1 to 3 parts by weight of glucose, and 100 to 200 parts by weight of distilled water.

In the culture medium, the peptone is a nitrogen source that supplies protein and supplies proteins necessary for the growth of microorganisms, and the malt extract contains various minerals, vitamin B groups, and amino acids, so that it can help the growth of microorganisms, and the sodium citrate Silver is an inorganic substance that maintains a state optimized for the growth of microorganisms by adjusting the pH of the culture medium, and can supply nutrients, and the glucose can function as an important component by which lactic acid bacteria metabolize sugar to produce organic acids.

Next, the camellia seeds sprayed with the fermentation broth may be fermented.

Fermentation of the camellia seeds may be fermented by storing the camellia seeds sprayed with the fermentation broth in a storage container maintaining a temperature of 45 to 50° C. and a humidity of 60 to 65% for 3 to 6 days.

Next, the fermented camellia seeds may be dried in cold air.

Cold air drying of the fermented camellia seeds may be performed by drying the fermented camellia seeds with cold air at a temperature of 3 to 6° C. for 5 to 10 hours and maintaining the fermented camellia seeds at a temperature of 55 to 60° C. for 1 to 3 days.

Subsequently, the cold-air dried camellia seeds are compressed at a humidity of 70 to 80%, a temperature of 120 to 150°C, and 2 to 4 kgf/cm ² , and then the oil is separated to prepare camellia oil (camellia seed oil).

The Eoseongcho extract is prepared by extracting Eoseongcho, and Eoseongcho (Houttuynia cordata thunb) is an outpost of Yakmomil, a plant of the Saururaceae, and lives in Southeast Asia and particularly Japan and Korea. Eoseongcho is also called Sip-Yak because it has ten medicinal effects, and the stem is like a sweet potato leaf, and it is also called Eoseongcho because it originates from the fact that when you touch the raw leaves, fish smells badly. Eoseongcho is also available for medicinal and edible use. It is classified as animals and plants that can only be used in a minimum amount as an auxiliary ingredient in the classification of food raw materials in the food code. Pharmacologically, it is widely known for its strong heart, diuretic, antibacterial, detoxifying, and anticancer effects. Is used as a cosmetic and health functional food that helps detoxification and beauty.

Eoseongcho extract prepared by the following manufacturing method may be used as the extract of Eoseongcho.

First, in order to prepare an extract of Eoseongcho, it may be washed after preparing Eoseongcho.

Next, the washed Eoseongcho may be pulverized into a certain particle size.

In the above step, the active ingredient of the Eoseongcho may be sufficiently extracted by pulverizing the Eoseongcho to a certain particle size, and the crushing of the Eoseongcho may be pulverized so that the particle diameter is in the range of 500 to 2500㎛. In the above step, if the particle diameter of the Eoseongcho is pulverized to less than 500㎛, it takes a long time to pulverize, and the particles are too small to cause agglomeration between particles in a later process. It may be difficult to effectively extract useful ingredients from Eoseongcho.

Thereafter, the pulverized Eoseongcho may be extracted by applying ultrasonic waves in an atmosphere of low temperature and reduced pressure to prepare a mixed solution for extracting Eoseongcho.

In the above step, after preparing a mixed solution by mixing the pulverized Eoseongcho with a solvent, it is added to an ultrasonic extractor to apply ultrasonic waves to the mixed solution to prepare a Eoseongcho extract mixture, wherein the solvent is 100 parts by weight of the pulverized Eoseongcho It is mixed at a weight ratio of 1000 to 2000 parts by weight, and any one or more solvents selected from water or an alcohol having 1 to 4 carbon atoms (C1 to C4) may be used as the solvent.

In addition, in the step, the ultrasonic wave applied to the mixed solution under a temperature of 20 to 25°C and a pressure of 0.1 to 0.5kgf/cm ² outputs 100 to 200 watts for 30 to 60 minutes at a vibration frequency of 30 to 50 KHz. It can be extracted using

Subsequently, the Eoseongcho extract can be prepared by removing solids such as pulverized Eoseongcho from the Eoseongcho extract mixture and then aging for 1 to 3 hours at a temperature of 10 to 20°C.

In the above step, the removal of solids such as crushed Eoseongcho from the Eoseongcho extract mixture may be performed by separating and removing the solids using a known sieve such as a sieve.

The natural plant extract may contain any one or more natural plant extracts selected from the group consisting of ginkgo, cypress and camellia, and the ginkgo, cypress and camellia may be used in a weight ratio of 1:1:1 have.

The ginkgo tree is denoted by the scientific name Ginkgo biloba L, and is a larch tree belonging to the ginkgo family, and has been used as a garden tree or a street tree since ancient times, and the fruit ginkgo has been used for food or medicinal purposes.

In particular, the leaves of ginkgo biloba have been widely prescribed in oriental medicine as a treatment for hypertension, Parkin's disease and diabetes, and recently, drugs using unique flavonoids extracted from ginkgo leaves are excellent for treating adult diseases such as high blood pressure, senile dementia and diabetes. It has been found to be effective, and is widely used as a raw material for cosmetics and functional foods. In addition, in recent years, research on the treatment of antibacterial materials using ginkgo tree is actively being conducted.

The cypress is an evergreen coniferous arboreous tree that grows up to 40m in height and 2m in diameter, and its branches are horizontal, the branches are drooping, the bark is reddish brown, and it is torn vertically. The leaves are ovate rhomboid, thick in quality, there is one line on the green surface, white spots on the back side, and the leaves on the side fall off only the ends.

Phytoncide produced by the cypress tree is a self-defense material of plants, and is a material exhaled or secreted by plants to resist pathogens, pests, and fungi, and itself contains sterilization and insecticidal components. The constituents of phytoncide are organic compounds consisting of phenolic compounds, alkaloids, glycosides, etc., including terpenes, and are known to have antibacterial, sedative, deodorant, and stress-relieving effects. Such phytoncide is a natural substance, not a chemical synthetic substance, is absorbed by the human body without difficulty, and selectively sterilizes bacteria harmful to humans.

The camellia (Camellia japonica Linne) is an evergreen tall tall tree belonging to the genus Tea tree family Camellia. Camellia is a tree that grows wild in the southern part of Korea and blooms in red from winter to early spring. Although it is a broad-leaved tree with broad leaves, it is said to be an evergreen broad-leaved tree because its leaves do not fall even in winter. The shape of the camellia leaf is oval, the tip is 15cm~25cm, the length is about 4~7cm, and the leaves are stiff and thick. Other names for camellias are sanda (山茶), hongdahwa (紅茶花), haehonghwa (海紅花), yeosimhwa (女心花), haemen, camellia oil tree, etc.

The flowers of the camellia tree fall whole, but you can pick up the fallen flowers and drink them with alcohol or float them on a teacup. Steamed and dried flowers are pulverized into powder, which is effective as a hemostatic agent. It is also used when spraying on trauma or bleeding nose. After bathing, I applied camellia oil to smooth my skin. In the days when there was no soap, it was said that the ash from the leaves was dissolved in water and used instead of soap. Camellia oil was used as a lubricant for machinery, lit a lamp, and applied to the wound when it burned.

In the present invention, the natural plant extract may be prepared using ginkgo, cypress, and camellia, and the natural plant extract may be a natural plant extract prepared by the following manufacturing method.

First, in order to prepare the natural plant extract, ginkgo, cypress, and camellia may be prepared, and then separated into stems and raw leaves of the ginkgo, cypress, and camellia.

Next, the stems of the ginkgo, cypress, and camellia can be manufactured using a grinder such as a ball milling device to produce ginkgo, cypress, and camellia stem powder, the ginkgo, cypress And the camellia stem powder may have a particle diameter of 1000 to 3000㎛, can be pulverized to have a specific surface area of 100 to 2500m ² /g.

When the gingko, cypress and camellia stem powder is pulverized below the above range, the pulverization time may be delayed and workability may be deteriorated due to dust or fine powder, and when it exceeds the above upper limit range, There may be a problem in that the active ingredients contained in the trunks of ginkgo, cypress and camellia are not easily extracted.

Next, the pulverized ginkgo, cypress, and camellia stem powder may be dried to remove moisture.

Drying of the pulverized ginkgo, cypress and camellia stem powder destroys the plant cells or chlorophyll of the ginkgo, cypress and camellia stem powder during sunlight drying, and the useful components of the ginkgo, cypress and camellia stem In order to prevent the reduction, it may be carried out in a dryer that maintains a constant temperature and humidity. For example, drying of the pulverized ginkgo, cypress and camellia stem powder is performed at a temperature of 18 to 22°C and a humidity of 50 to 60. It can be dried for 10 to 20 hours in a dryer maintained at %.

Subsequently, the dried ginkgo, cypress, and camellia stem powder can be steamed and steamed with steam.

Steaming of the dried ginkgo, cypress, and camellia stem powder may be performed by heating with steam at a constant temperature under a constant pressure, for example, the dried ginkgo, cypress, and camellia stem powder. It can proceed by heating with water vapor for 2 to 4 hours at a temperature of to 165° C. and a pressure of 3 to 5 kgf/cm ² .

In the present invention, when the steaming of the dried ginkgo, cypress and camellia stem powder is performed below the lower limit of the above-described process conditions, the ginkgo, cypress and camellia stem powder is not sufficiently steamed, and thus a short period of time in a later process. It may be difficult to prepare a sufficient extract within a period of time, and if it is carried out in excess of the upper limit of the above-described process conditions, the active ingredients of the ginkgo, cypress and camellia stem powders will be volatilized or the increase in the effect of further steaming will be insignificant. I can.

Subsequently, the fresh leaves of the ginkgo, cypress and camellia are prepared and washed to remove foreign substances attached to the fresh leaves of the ginkgo, cypress and camellia.

Here, the washing of the fresh leaves of ginkgo, cypress and camellia may use purified water in which sodium hydrogen carbonate is dissolved in the prepared fresh leaves of ginkgo, cypress and camellia, and 2 to 4 (w/w)% concentration and It is preferable to wash by immersing for 5 to 10 minutes in a sodium hydrogen carbonate solution at a temperature of 32 to 38°C.

Next, the washed ginkgo, cypress, and camellia leaves may be dried in a dryer.

In the present invention, in order to prevent the chlorophyll of the fresh leaves of the Ginkgo, Cypress, and Camellia from being destroyed and the useful components from volatilization, the drying of the fresh leaves of the ginkgo, cypress and camellias And the fresh camellia leaves can be dried for 3 to 7 hours in a dryer maintained at a temperature of 25 to 30 °C and a humidity of 55 to 60%.

Next, the dried ginkgo, cypress, and camellia leaves are sprayed with a Bacillus culture solution to ferment the ginkgo, cypress and camellia leaves.

The Bacillus bacillus culture medium is capable of promoting fermentation of the dried ginkgo, cypress and camellia leaves, and the weight of 50 to 100 parts by weight of the Bacillus bacillus culture solution based on 100 parts by weight of the dried ginkgo, cypress and camellia leaves After spraying at a rate and maintaining a temperature of 50 to 60° C. and a humidity of 60 to 65%, it can be fermented for 1 to 3 days.

The Bacillus Bacillus culture medium is produced by mixing Bacillus bacillus and water, and the Bacillus bacillus is grown twice a day at 25°C after mixing 10 to 12% by weight of brown sugar in godubap, placing eco-friendly rice husks on the prepared medium and covering a cloth. Bacillus bacteria are produced by incubating for 1 week while spraying water on them, and they can be re-inoculated in a medium mixed with rice bran and brown sugar at a weight ratio of 50:50 and cultured at 25° C. for 1 week to be used as the Bacillus bacteria culture solution used in the present invention. have.

In the present invention, the Bacillus subtilis is Bacillus subtilis , Bacillus subtilis , Bacillus megaterium , Bacillus licheniformis , and Bacillus licheniformis . Any one or more selected from the group consisting of ( Bacillus pumilus ) may be used.

Subsequently, the steamed ginkgo, cypress, and camellia stem powder and the fermented ginkgo, cypress, and camellia leaves are mixed and fermented to prepare a ginkgo, cypress, and camellia fermented liquid.

In the above step, after mixing in a weight ratio of 150 to 250 parts by weight of the fermented ginkgo, cypress and camellia stem powder 100 parts by weight of the steamed ginkgo, cypress and camellia stem powder, 38 to 42 ℃ Fermented ginkgo, cypress, and camellia fermented broth can be prepared by fermenting for 3 to 5 days at a temperature and a humidity of 60 to 65%.

Next, by mixing a solvent with the fermented ginkgo, cypress and camellia fermentation broth and applying ultrasonic waves, a fermented broth extracted from ginkgo, cypress and camellia may be prepared.

In order to prepare a fermented solution extracted from ginkgo, cypress and camellia, the fermented solution of ginkgo, cypress and camellia is mixed with a solvent to prepare a mixed solution, and then added to an ultrasonic extractor to apply ultrasonic waves to the mixed solution. , Cypress tree and camellia extract fermentation broth can be prepared, the solvent is included in a weight ratio of 500 to 1000 parts by weight based on 100 parts by weight of the ginkgo, cypress and camellia mixture, and water is used as the solvent. I can.

In addition, the ultrasonic wave applied to the mixture to prepare the fermentation broth extracted from the ginkgo, cypress and camellias can be extracted using an output of 150 to 250 watts for 50 to 100 minutes at a vibration frequency of 50 to 70 KHz. I can.

Next, solids such as ginkgo, cypress, and camellia stem powder, ginkgo, cypress, and fresh camellia leaves can be removed from the fermented broth extracted from the ginkgo, cypress and camellia.

In the above step, a known strainer such as a sieve may be used to separate solids such as ginkgo, cypress and camellia stem powder, ginkgo, cypress and fresh leaves of camellia.

Subsequently, the fermented broth extracted from ginkgo, cypress and camellia from which the solid content has been removed may be centrifuged.

In the above step, by centrifuging the fermentation broth extracted from ginkgo, cypress and camellias from which solids have been removed, the lower layer liquid in which the fine particles of ginkgo, cypress and camellia trunks and fresh leaves are located, and the middle layer located above the lower layer liquid It can be separated into a liquid and a supernatant.

Next, a natural plant extract containing useful components of ginkgo, cypress and camellia may be prepared by extracting the fermented broth extracted from ginkgo, cypress and camellia located in the middle and supernatant.

In the above step, the natural plant extract is first extracted for 3 to 4 hours at 85 to 90° C. with 10 to 15 L of 70% (v/v) ethanol aqueous solution in 2000 to 3000 g of ginkgo, cypress and camellia extract fermentation broth, Completing the secondary extraction for 2 to 3 hours at 85 to 90 °C with 4 to 6 ℓ of an aqueous 70% (v/v) ethanol solution, and preparing an extract until it becomes 1000 to 1500 mL in a vacuum rotary evaporator; And ethanol is added to the extract, diluted to 2 to 3 times by weight, and centrifuged at 18,000 to 20,000 rpm for 30 to 40 minutes to completely remove polymer fibers and solids that may be included in the fermentation broth extracted from ginkgo, cypress and camellia. After removal, it can be prepared by extracting the collected supernatant twice with 1.5 to 2.0 times the weight of acetic acid.

In the present invention, the second agent is purified water (DI Water), hydrogen peroxide, sodium pyrophosphate, methyl paraben (MP)), triethanolamine (Triethanolamine), etidronic acid (Etidronic Acid), cetearyl alcohol , Glyceryl Stearate, Lanolin Alcohol, Perfume, Ceteaeth-20, PEG-120 Methyl Glucose Dioleate, Behenyl Contains Behenyl Alcohol, Allantoin, Puer Tea Extract and Onion Extract.

In addition, in the present invention, the second agent is purified water (DI Water) 75 to 80 parts by weight, hydrogen peroxide 10 to 20 parts by weight, sodium pyrophosphate 0.5 to 1.5 parts by weight, methyl paraben (MP) 0.8 to 1.2 parts by weight Parts, Triethanolamine 0.5 to 1.5 parts by weight, Etidronic Acid 1 to 2 parts by weight, Cetearyl alcohol 1 to 3 parts by weight, Glyceryl Stearate 0.1 to 0.5 parts by weight Parts, Lanolin Alcohol (Lanolin Alcohol) 1.2 to 2.2 parts by weight, perfume (perfume) 0.3 to 0.5 parts by weight, Ceteaeth-20 (Ceteareth-20) 0.15 to 0.35 parts by weight, PEG-120 methylglucosediolate (PEG-120) Methyl Glucose Dioleate) 0.25 to 0.45 parts by weight, allantoin (Allantoin) 0.1 to 0.3 parts by weight, puer tea extract 2 to 4 parts by weight, and onion extract 1 to 2 parts by weight are included.

The puer tea extract is prepared using puer tea, and the puer tea is black tea that is naturally fermented in a state of high pressure or mountain tea, processed with Camellia sinensis LINNE in Yunnan, China. It is a series of post-fermentation tea.

In the Chinese literature, Bonchogangmoksiyu (本草綱目拾遺), puer tea has a unique scent, helps relieve hangovers and digestion, clears sputum, clears the stomach, relieves thirst, and removes harmful oil from the body. . In addition, since puer tea has no side effects even if taken for a long time, it is called beauty tea, diet tea, and longevity tea in Japan, France, Germany, Italy, and Macau (Son et al, Food & Nutr 18:219-224, 2005). ).

On the other hand, according to studies using puer tea, when alcohol was induced in a subacute state in ICR mice, the blood alcohol concentration of the puer tea extract intake group was not significantly different from that of the normal control group (Park et al, J East Asian Soc dietary Life, 14:634-639, 2004), puer tea and puer tea extracted from the results of examining the antioxidant effects of puer tea and puer tea proved that the total polyphenol content and electron donating ability were similar. (Son et al, Korea J Food & Nutr, 18:219-224, 2005).

In order to prepare the puer tea extract, first, the fresh puer tea leaves are prepared and washed to remove foreign substances attached to the green puer tea leaves, and then the washed green puer tea leaves may be dried.

In the present invention, in order to prevent the chlorophyll of the fresh puer tea leaves from being destroyed and the useful components volatilized during sunlight drying, the green puer tea leaves are dried for 5 to 10 hours at a temperature of 25 to 30°C. I can.

Next, the dried raw puer tea leaves may be heated to dryness.

In the step, the dried raw puer tea leaves are put into a heating container (for example, a cauldron), and then first roasted for 3 to 5 minutes at a temperature of 90 to 100°C, and the first roasted puer tea leaves are 130 It may proceed to the step of the second abrasion for 30 to 60 seconds at a temperature of to 140 ℃.

Next, a mixture of puer tea can be prepared by mixing a solvent with the roasted puer tea leaves and applying ultrasonic waves.

In the above step, after mixing the roasted puer tea leaves and a solvent, it is added to an ultrasonic extractor to apply ultrasonic waves to the mixture consisting of the roasted puer tea leaves and the solvent to prepare a puffer tea solution. It is mixed in a weight ratio of 300 to 600 parts by weight based on 100 parts by weight of fresh tea leaves, and water may be used as the solvent.

In addition, the ultrasonic wave applied to the mixture consisting of the roasted puer tea leaves and the solvent may be extracted using an output of 300 to 400 watts for 30 to 60 minutes at a vibration frequency of 60 to 80 KHz.

Subsequently, the puer tea extract may be prepared by separating and removing solids such as green puer tea leaves from the puer tea mixture and then aging them.

In the above step, a known sieve such as a sieve may be used to separate the solids such as the fresh puer tea leaves, and the aging is performed by using the puer tea extract from which the solids are removed at a temperature of 10 to 15°C. This can be done by storing for hours.

The onion extract is prepared by extracting the useful ingredients of onion, and the onion (Allium cepa) is a perennial plant belonging to the lily family, and is used as food, spices and medicinal materials to which a unique taste and aroma are applied along with a long cultivation history. have. 100g of onion contains 90g of moisture, about 72g of carbohydrates, 11g of protein, 10 to 20mg of vitamin C, calcium, phosphorus, and iron.The onion skin contains 504% sugar, 2924% fiber, 148% fat, and 499% ash. Contains.

The efficacy of onions is known for antioxidant, lowering blood lipids, antihypertension, anti-inflammatory, antibacterial, anti-tumor, and lowering blood sugar. The main physiologically active substances contained in onions include organic sulfur compounds and flavonoid compounds. In particular, onions contain very high quercetin, which exhibits antioxidant activity, compared to other vegetables and fruits. Quercetin is a plant-derived flavonoid-based phenolic compound that is not only a powerful antioxidant, but also has anti-arteriosclerosis, antibacterial activity, cholesterol lowering, anti-cancer, anti-viral and anti-allergic activities, but little toxicity. It is known. Therefore, eating foods containing a lot of quercetin is effective in improving blood circulation, lowering blood pressure and dieting such as diabetes and weight loss, strengthening immune function, inhibiting DNA damage, and inhibiting lipid peroxidation of red blood cell membranes.

In the present invention, the onion extract can be prepared by the following manufacturing method.

In order to prepare the onion extract, first, the onion is collected and 1 to 5 minutes with purified water in which sodium hydrogen carbonate (NaHCO ₃ ) having a concentration range of 1 to 3 (w/w)% and a temperature of 33 to 37°C is dissolved During washing to remove foreign substances adhering to the onion, the peel of the onion can be separated and separated into onion flesh and onion peel.

Next, the onion pulp is dried in a dryer, but drying of the onion pulp is performed in a dryer in which a constant temperature and humidity are maintained in order to prevent the chlorophyll of the onion pulp from being destroyed and the inherent flavor of the onion pulp from disappearing when drying in sunlight. For example, the onion flesh may be dried for 3 to 7 hours in a dryer maintained at a temperature of 20 to 25° C. and a humidity of 33 to 40%.

Thereafter, the dried onion pulp is mixed with purified water and heated to prepare the onion pulp extract.

The onion pulp extract may be prepared by mixing 500 to 1000 parts by weight of purified water with respect to 100 parts by weight of the dried onion pulp and heating at a temperature of 95 to 105°C for 5 to 15 hours.

Subsequently, the onion peel can be dried to remove moisture contained in the onion peel, and the onion peel can be dried for 3 to 7 hours in a dryer maintained at 30 to 35°C and 35 to 45% humidity. In the present invention, by drying the onion skin under the same conditions as described above, the moisture contained in the onion skin is gradually and evenly evaporated, so that the inherent aroma and useful ingredients of the onion skin can be more easily extracted, By destroying the cell tissue of the onion skin, it facilitates the penetration of air and promotes the fermentation, so that the useful components of the onion skin can be enriched.

Next, the dried onion peel is mixed with purified water and then heated to prepare the onion peel extract. The onion peel extract is mixed with 200 to 400 parts by weight of purified water based on 100 parts by weight of the dried onion peel. After immersing for 1 to 3 hours at a temperature of 60 to 70°C, the purified water immersed in the onion skin is added to a heater, and purified water in which the onion skin is immersed in the heater is added to a temperature of 110 to 120°C and inside a pressure vessel The onion peel extract can be prepared by heating for 3 to 5 hours at a pressure in the range of 2.5 to 3.5kgf/cm ² .

According to the present invention, the onion peel is immersed in purified water and then extracted as described above, thereby weakening the plant wall of the onion peel to increase extraction efficiency.

Next, an onion extract can be prepared by mixing the onion flesh extract and the onion peel extract, wherein the onion extract is prepared by mixing the onion flesh extract and the onion peel extract in a weight ratio of 7:3 to 6:4. I can.

Subsequently, the onion extract may be aged by storing it for 1 to 5 hours at a temperature of 3 to 7°C. By aging the onion extract under the same conditions as described above, the onion extract may be uniformly mixed and the flavor may be enhanced.

The natural hair dye according to the present invention is prepared by mixing a hair dye composition composed of the first agent and the second agent, and the first agent and the second agent may be mixed in a weight ratio of 1:1.

Hereinafter, examples for the natural hair dye according to the present invention will be described in more detail with reference to the accompanying drawings.

<Example>

A natural hair dye was prepared by mixing the first agent and the second agent in a weight ratio of 1:1.

The first agent is 83 parts by weight of purified water (DI Water), 2 parts by weight of 2-amino-5-nitrophenol, 1.8 parts by weight of polyquaternium-10, 2 parts by weight of polysorbate 80 , Tetrasodium EDTA (EDTA-4Na) 0.03 parts by weight, p-phenylenediamine 1.0 parts by weight, m-aminophenol 2 parts by weight, ethanolamine thioglycolate 2.8 parts by weight, PEG-60 Castor Oil 1.3 parts by weight, perfume 0.3 parts by weight, Dimethicone 0.008 parts by weight, oleic acid 0.6 parts by weight, polyoxyethylene oliyl ether 4 parts by weight, Behenyl Alcohol 3.5 parts by weight, sodium silicate 0.6 parts by weight, Myristyl Alcohol 2 parts by weight, Monoethanolamine 1.2 parts by weight, Cyclodextrin 0.07 parts by weight, Allantoin 0.01 parts by weight Parts, Aloe Extract 0.06 parts by weight, Hydroxypropyl Chitosan liquid (Hydroxypropyl Chitosan) 0.01 parts by weight, Camellia oil 0.7 parts by weight, Eoseongcho extract 1.5 parts by weight, and 5 parts by weight of natural plant extract were mixed in a weight ratio .

The second agent is purified water (DI Water) 78 parts by weight, hydrogen peroxide 15 parts by weight, sodium pyrophosphate 1.0 parts by weight, methyl paraben (MP) 1.0 parts by weight, triethanolamine (Triethanolamine) 1.0 parts by weight, etide Etidronic Acid 1.5 parts by weight, Cetearyl alcohol 2 parts by weight, Glyceryl Stearate 0.3 parts by weight, Lanolin Alcohol 1.8 parts by weight, Perfume 0.4 parts by weight, Cete Ares-20 (Ceteareth-20) 0.25 parts by weight, PEG-120 Methyl Glucose Dioleate 0.35 parts by weight, Allantoin 0.2 parts by weight, Puer tea extract 3 parts by weight, and onion extract 1.5 parts by weight It was prepared by mixing in parts by weight.

<Comparative Example 1>

A natural hair dye was prepared using the same composition as in Example. In Comparative Example 1, the extract of Eoseongcho and natural plant extracts were not included in the first agent, and the puer tea extract was not included in the second agent.

<Comparative Example 2>

A natural hair dye was prepared by using the same composition as in Example. In Comparative Example 2, camellia oil and natural plant extract were not included in the first agent, and onion extract was not included in the second agent.

1. Absorbance of hair

In order to check the degree of damage to the hair, a methylene blue dyeing method was used, and the methylene blue dyeing method may be described as follows.

In other words, when hair is exposed to alkaline chemicals such as dyes, the interlayer material escapes from the cortex and becomes porous depending on the degree of damage, and the adsorption rate of the material increases, and the surface of the electrically negative hair becomes more negative as it is damaged, and the cation, methylene. The blue adsorption rate is increased, and the absorbance (Optical density: OD) is measured by eluting the methylene blue adsorbed on the hair.

The degree of damage to the hair was measured using the above characteristics, and the hair sample was prepared from hair without chemical treatment (thickness: 0.07 to 0.75 mm), and cut to a weight of 5 g. After applying 10 g of the natural hair dye of Examples and Comparative Examples 1 and 2 to the hair sample and leaving it for 25 minutes, washed with lukewarm water after shampooing, rinsed thoroughly with lukewarm water, and dried naturally to prepare dyed hair for measuring absorbance.

The dyed hair is added to a 2% solution of methylene blue and immersed at 50° C. for 10 minutes so that methylene blue is adsorbed. The dyed hair to which methylene blue was adsorbed was added to 5 mL of a solution of 49% by weight of ethanol, 1% by weight of glacial acetic acid, and 50% by weight of distilled water, and methylene blue was eluted for 5 minutes to prepare a sample solution for measuring absorbance. The absorbance of the supernatant sample solution was measured with a spectrometer (Model SM1200, UMC, USA, λ=660nm) and is shown in Table 1 below.

A control group using blank hair was prepared, and the absorbance of the control group was set to 100%, and the absorbance of the sample solution was expressed as a relative value. The high absorbance indicates that the concentration of methylene blue contained in the sample solution is high, which can be determined as a high concentration of adsorbed methylene blue due to high damage to the dyed hair.

division Control Example Comparative Example 1 Comparative Example 2 Absorbance 0.034 0.131 0.215 0.219 percentage(%) 100 385 632 644

Referring to [Table 1], it can be seen that the absorbance of the dyed hair of the embodiment is low. When dyeing with the natural hair dye according to the embodiment, it can be interpreted as alleviating damage to the hair.

2. Tensile strength of hair

The elasticity change was confirmed by measuring the tensile strength of the dyed hair using the hair dye according to Examples and Comparative Examples 1 and 2.

The hair sample was used without chemical treatment (thickness: 0.07 to 0.75mm), and was prepared by cutting into 5g weight. After applying 10 g of the natural hair dye of Examples and Comparative Examples 1 and 2 to the hair sample and leaving it for 25 minutes, washed with lukewarm water after shampooing, rinsed thoroughly with lukewarm water, and dried naturally to prepare dyed hair for measuring tensile strength. .

In order to measure the tensile strength of the dyed hair, a tensile test was performed in the same direction in the hair root direction using a universal testing machine (Model No4465, Instron, USA). Seven times were measured for each dyed hair specimen, and the average value of the five measured values was calculated excluding the highest and lowest values among the measured values. Tensile strength was measured at a tensile speed of 20 mm/min and a gripping distance of 20 mm under the tensile test conditions, and are shown in Table 2 below.

division Control Example Comparative Example 1 Comparative Example 2 Tensile strength (cN) 166 160 144 146

Referring to [Table 2], the tensile strength of the hair according to the Example was measured to be 160, Comparative Example 1 was measured to be 144, Comparative Example 2 was measured to be 146, when using the natural hair dye according to the Example tensile strength It could be seen that is higher.

3. Feeling of using hair dye

In order to check the user's fatigue due to irritation of the scalp of the hair dyes according to Examples and Comparative Examples 1 and 2 and the occurrence of a pungent odor during the procedure, 30 subjects for treatment and 30 subjects for dyeing were selected and the irritating smell of the hair dye composition , The feeling of use and psychological stability during application were evaluated.

Experimental practitioners are selected as workers in the beauty industry for more than 10 years, and practitioners are women in their 30s who have not undergone chemical treatments on the hair within 1 year from the date of the test, the length of the hair is 20 to 30 cm below the ear, and the thickness of the hair is 0.07 to 0.75 mm And was selected as a person sensitive to the scent or stimulation of dyes

The hair dyes according to Examples and Comparative Examples 1 and 2 were applied to the hair of the person to be treated, left for 25 minutes, and then shampooed and dried.

The evaluation scores of the operator and the operator were averaged and shown in Table 3 below. Satisfaction for each evaluation item was divided into 5 levels and converted into 4 points (very satisfied), 3 points (satisfied), 2 points (normal), 1 point (unsatisfied), and 0 points (very dissatisfied). The higher the evaluation score, the lower the occurrence of irritating odor was evaluated. For the evaluation of psychological stability, the less fatigue caused by the irritating odor of the hair dye, the higher the evaluation score was.

division Blood surgeon Practitioner Stimulating
smell Scalp irritation Psychological
Sense of stability Stimulating
smell Scalp irritation Psychological
Sense of stability Example 3.6 3.8 3.6 3.7 3.7 3.5 Comparative Example 1 2.9 3.0 3.1 3.0 2.8 3.0 Comparative Example 2 3.1 2.9 3.0 3.1 3.0 2.9

Referring to [Table 3], it was confirmed that the hair dyeing agent according to the example had superior sensory evaluation such as irritating odor, scalp stimulation, and psychological stability compared to the hair dyeing agent according to Comparative Examples 1 and 2.

In the above, a preferred embodiment of the present invention has been described, but those of ordinary skill in the art to which the present invention pertains will understand that the present invention can be implemented in other specific forms without changing the technical spirit or essential features. I will be able to. Therefore, it should be understood that the exemplary embodiment described above is illustrative in all respects and is not limiting.

Claims (1)

It consists of a first agent and a second agent mixed with the first agent and used,
The first agent is purified water (DI Water) 80 to 85 parts by weight, 2-amino-5-nitrophenol 1.5 to 2.5 parts by weight, Polyquaternium-10 1.5 to 2.0 parts by weight, polysorbate 80 ( Polysorbate 80) 1 to 3 parts by weight, Tetrasodium EDTA (EDTA-4Na) 0.02 to 0.04 parts by weight, p-phenylenediamine 0.8 to 1.2 parts by weight, m-aminophenol 1.5 to 2.5 parts by weight, Ethanolamine Thioglycolate 2.2 to 3.2 parts by weight, PEG-60 Castor Oil 1.2 to 1.5 parts by weight, Perfume 0.2 to 0.5 parts by weight, Dimethicone 0.005 to 0.01 parts by weight, oleic acid 0.3 to 0.9 parts by weight, 3 to 5 parts by weight of polyoxyethylene oliyl ether, 2.5 to 4.5 parts by weight of behenyl alcohol, 0.4 to 0.8 parts by weight of sodium silicate, myristyl alcohol (Myristyl Alcohol) 1 to 3 parts by weight, monoethanolamine 1.1 to 1.3 parts by weight, Cyclodextrin 0.05 to 0.09 parts by weight, Allantoin 0.007 to 0.013 parts by weight, Aloe Extract 0.05 to 0.07 parts by weight Parts, hydroxypropyl chitosan liquid (Hydroxypropyl Chitosan) 0.005 to 0.015 parts by weight, camellia oil 0.1 to 1.3 parts by weight, Eoseongcho extract 1 to 2 parts by weight, and natural plant extracts 3 to 7 parts by weight,
The second agent is purified water (DI Water) 75 to 80 parts by weight, hydrogen peroxide 10 to 20 parts by weight, sodium pyrophosphate 0.5 to 1.5 parts by weight, methyl paraben (MP) 0.8 to 1.2 parts by weight, triethanolamine ( Triethanolamine) 0.5 to 1.5 parts by weight, Etidronic Acid 1 to 2 parts by weight, Cetearyl alcohol 1 to 3 parts by weight, Glyceryl Stearate 0.1 to 0.5 parts by weight, Lanolin alcohol ( Lanolin Alcohol) 1.2 to 2.2 parts by weight, perfume (perfume) 0.3 to 0.5 parts by weight, Ceteaeth-20 (Ceteareth-20) 0.15 to 0.35 parts by weight, PEG-120 Methyl Glucose Dioleate 0.25 To 0.45 parts by weight, Allantoin (Allantoin) 0.1 to 0.3 parts by weight, puer tea extract 2 to 4 parts by weight, and onion extract 1 to 2 parts by weight, characterized in that it comprises a natural hair dye composition.